• The Journal of the Korea Contents Association
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• v.14 no.12
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• pp.999-1009
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• 2014

In this paper, $CO_2$ emission and storage amount are evaluated for real RC (Reinforced Concrete) underground structure considering $CO_2$ amount including material manufacturing, moving, and construction, repairing timing stage regarding extended service life. Four mix proportions with mineral admixtures are prepared and $CO_2$ diffusion coefficient are obtained based on a micro modeling. Referred to carbonation durability limit state, $CO_2$ emission and storage amount are evaluated, which shows higher initial $CO_2$ emission is caused due to larger unit content of cement and the storage increases with more rapid carbonation velocity. Furthermore various $CO_2$ concentration is adopted for simulation of $CO_2$ evaluation including measured $CO_2$ concentration (600ppm). With higher concentration of $CO_2$ outside, carbonation velocity increases. In order to reduce $CO_2$ emission through entire service life, reducing initial $CO_2$ emission through mineral admixture like fly ash is more effective than increasing $CO_2$ storage through OPC since $CO_2$ is significantly emitted under manufacturing OPC and $CO_2$ storage in cover concrete of RC structure is not effective considering initial concrete amount in construction.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.1
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• pp.42-48
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• 2013

The present study assessed the amount of $CO_2$ uptake owing to concrete carbonation through a case study for an apartment building with a principal wall system and an office building with Rahmen system under different exposed environments during use phase and recycling application. The $CO_2$ uptake assessment owing to concrete carbonation followed the procedure established by Yang et al. As input data necessary for the case study, actual surveys conducted in 2012 in Korea, which included data about the climate environments, $CO_2$ concentration, lifecycle inventory database, life expectancy of structures, and recycling activity scenario, were used. From the comparisons with the $CO_2$ emissions from concrete production, the $CO_2$ uptake during the lifetime of structures was estimated to be 5.5~5.7% and that during recycling activity after demolition was 10~12%; as a result, the amount of $CO_2$ uptake owing to concrete carbonation can be estimated to be 15.5~17% of the $CO_2$ emissions from concrete production, which roughly corresponds to 18-21% of the $CO_2$emissions from cement production as well.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.5
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• pp.148-160
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• 2012

This study proposed more reasonable prediction models on compressive strength and carbonation of concrete structure and developed a more effective tunnel safety diagnosis and maintenance method through field application of the proposed prediction models. For this study, the Seoul Metro's Line 1 through Line 4 were selected as target structures because they were built more than 30 years ago and have accumulated numerous diagnosis and maintenance data for about 15 years. As a result of the analysis of compressive strength and carbonation, we were able to draw prediction models with accuracy of more than 80% and confirmed the prediction model's reliability by comparing it with the existing models. We've also confirmed field suitability of the prediction models by applying field, the average error of an estimate on compressive strength and carbonation depth was about 20%, which showed an accuracy of more than 80%. We developed a more effective maintenance method using durability prediction Map before field inspection. With the durability prediction Map, diagnostic engineers and structure managers can easily detect the vulnerable points, which might have failed to reach the standard of designed strength or have a high probability of corrosion due to carbonation, therefore, it is expected to make it possible for them to diagnose and maintain tunnels more effectively and efficiently.

• Journal of the Korea Institute of Building Construction
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• v.18 no.3
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• pp.203-210
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• 2018

Corrosion of the rebar is one of the main factors affecting the durability of reinforced concrete in the world which lead to the failure of the reinforced concrete structures. In this research, a new method of fixing $CO_2$ is practiced to improve the carbonation resistance of the concrete. Brucite($Mg(OH)_2$), a kind of common $CO_2$ fixation materials, was added into ordinary Portland cement paste. Samples containing 0%, 5%, 10%, and 15% $Mg(OH)_2$ were exposed to an accelerated carbonation curing regime with 20% concentration of $CO_2$, 60% relative humidity, and a temperature of $20^{\circ}C$ until tested at 3d, 7d, 14d and 28d. After 28d of $CO_2$ accelerated curing, in the paste containing $Mg(OH)_2$, magnesian calcite was detected by SEM-EDX. Meanwhile, the paste containing $Mg(OH)_2$ exhibit the better pore distribution than ordinary Portland cement paste and the compressive strength of the cement paste containing $Mg(OH)_2$ were more than 50Mpa.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.5
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• pp.45-55
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• 2015

Currently, extreme weather events such as super typhoon, extreme snowfall, and heat wave are frequently occurring all over the world by natural and human caused factors. After industrial growth in the 1970s, earth's temperature has risen sharply. due to greenhouse effect. Global warming can be attributed to gases emitted from using fossil fuel such as average carbon dioxide, perfluorocarbons, nitrous oxide, and methane. Especially, carbon dioxide has the highest composition of about 90%. in the fossile fuel usage emitted gas. Concrete has excellent durability as a building material climate change. However, due to various of physical and chemical environmental effect such as conditions during its curing process, the performance degradation may occur. Carbon dioxide in the atmosphere causes steel corrosion and durability decreases by lowering the alkalinity of concrete. Therefore, in this study, concrete durability performance with respect to carbonation from curing conditions change due to wind speed and sunshine exposure time. Concrete carbonation experiment are performed. using wind speed (0, 2, 4, 6) m/s and sunlight exposure time (2, 4, 6, 8) hrs. Also, performance based evaluation through the satisfaction curve based on the carbonation depth and carbonation rate test results are performed.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.5
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• pp.342-351
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• 2014

The present paper investigates the performance of direct wet mineral carbonation technology to fix carbon dioxide ($CO_2$) from relatively high $CO_2$ concentration feeding gas using wollastonite ($CaSiO_3$)-water (and 0.46 M acetic acid) suspension solution. To minimize the energy consumed on the process, the carbonation in this work is carried out at atmospheric pressure and slightly higher room temperature. As a result, carbon fixation is confirmed on the surface of $CaSiO_3$ after carbonation with wollastonite-water suspension solution and its amount is increased according to the $CO_2$ composition in the feeding gas. The leaching and carbonation ratio of wollastonite-water suspension system obtained from the carbonation with 50% of $CO_2$ composition feeding gas is 13.2% and 10.4%, respectively. On the other hand, the performance of wollastonite-acetic acid in the same condition is 63% for leaching and 1.39% for carbonation.

• Journal of the Korea Concrete Institute
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• v.19 no.3
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• pp.367-375
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• 2007

Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

• Resources Recycling
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• v.16 no.2 s.76
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• pp.23-31
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• 2007

In this study, the crystallization of neodymium carbonate from neodymium chloride solution by addition of ammonium bicarbonate was investigated. The concentration of reactants such as neodymium chloride and ammonium bicarbonate, and reaction temperature play an important part in order to obtain the crystal of neodymium carbonate. It seemed that amorphous neodymium carbonate was prepared by aggregation of primary particles formed through nucleation. If reaction rate was increased by increasing the concentration of reactants and reaction temperature, then neodymium carbonate crystal could be obtained. Lanthanite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}8H_2O$] and tengerite-type neodymium carbonate[$Nd_2(CO_3)_3{\cdot}2.5H_2O$] could be obtained with reaction renditions. Lanthanite-type neodymium carbonate was sensitive to temperature. The thermal decomposition of neodymium carbonate contained the processes or dehydration, decarbonation and crystalization of $Nd_2O_3$. The shape of lanthanite-type neodymium carbonate was irregular lump type, and tengerite-type neodymium carbonate had the shape of needle type. The shape of $Nd_2O_3$ was affected by the shape of neodymium carbonate.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.245-246
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• 2009

This paper presents the development of lightweight aggregate self-consolidating concrete using lightweight aggregates. Lightweight concrete is known for its advantage of reducing the self-weight of the structures, reducing the areas of sectional members as well as making the construction convenient. Thus the construction cost can be saved when applied to structures such as long-span bridge and high rise building. Therefore experimental tests were performed as such mechanical properties and carbonation of self-consolidating concrete using lightweight aggregates.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.192-193
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• 2022

In this study, concrete durability was reviewed before CGS, a by-product generated from IGCC, was used as a fine aggregate for concrete. The characteristics of concrete and effect on carbonization according to the type of pre-mixed cement and the CGS substitution rate were analyzed. As a result of the analysis, the depth of carbonation according to the pre-mixed cement types increased by up to 52%, and the carbonation resistance tended to be similar overall when CGS was used as a fine aggregate.