• Clean Technology
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• v.20 no.1
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• pp.28-34
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• 2014

In this study, we synthesized $TiO_2$ supports with nanosized crystalline structure by solvothermal method and prepared $TiO_2$ supported Pd-Cu catalysts. It was shown that the crystalline size of $TiO_2$ support in the catalyst influenced on the catalytic activity of nitrate reduction in water. The catalyst with the smaller crystalline size of $TiO_2$ support presented faster nitrate reduction rate, but had low nitrogen selectivity due to high pH environment of reaction medium during the reaction. Through injection of carbon dioxide as a pH buffer, the nitrogen selectivity increased by about 60%. Furthermore, we investigated that the relationships between the catalytic performance and the physicochemical properties of the prepared catalysts characterized by $N_2$ adsoprtion-desorption, X-ray diffraction (XRD), $H_2$-temperature programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS).

• The Journal of Engineering Research
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• v.6 no.2
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• pp.5-10
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• 2004

• Journal of the Microelectronics and Packaging Society
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• v.22 no.2
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• pp.21-26
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• 2015

Mesoporous ceramic materials were applied in various fields such as adsorbent and gas sensor because of low thermal conductivity and high specific surface area properties. This structure could be divided into open-pore structure and closed-pore structure. Although closed-pore structure mesoporous ceramic materials have higher mechanical property than open-pore structure, it has a restriction on the application because the increase of specific surface area is limited. So, in this work, specific surface area of closed-pore structure $TiO_2$ was increased by anneal time. As increased annealing time, crystallization and grain growth of $TiO_2$ skeleton structured material in mesoporous structure induced a collapse and agglomeration of pores. Through this pore structural change, pore connectivity and specific surface area could be enhanced. After anneal for 24 hrs, porosity was decreased from 36.3% to 34.1%, but specific surface area was increased from $48m^2/g$ to $156m^2/g$. CO gas sensitivity was also increased by about 7.4 times due to an increase of specific surface area.

• Journal of the Korean Applied Science and Technology
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• v.35 no.1
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• pp.163-172
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• 2018

In this study, selective catalytic reductions (SCR) of NO commercial catalysts were used to investigate the effect of ammonia gasification from urea solution. The effects of catalytic chemical composition on the reaction temperature and space velocity were studied. $V_2O_5/TiO_2$ catalysts, which are widely used as SCR catalysts for removal of nitrogen oxides, have better ammonia formation compare to $TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalysts. The $TiO_2$ catalyst not supporting the active metal was not affected by the space velocity as compared with the catalyst supporting $V_2O_5$ or $WO_3-V_2O_5$. The active metal supported catalysts decreased in the ammonia formation as the space velocity increased.

• Proceedings of the Membrane Society of Korea Conference
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• 1996.04a
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• pp.11-15
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• 1996

무기막은 고분자막에 비해 기계적, 열화학적 안정성이 매우 크기 때문에 다양한 분야에 응용이 가능하다. 따라서, 이러한 무기막의 장점을 이용한 분리 공정의 개발 및 분리 성능이 탁월한 새로운 형태의 무기막을 개발하려는 노력이 활발히 이루어지고 있다. 현재까지는 주로 액상분리, 농축 공정 등에 활용이 되어왔으나, 최근 들어서는 기체 분리 또는 반응 등의 분야에 이용하기 위한 다양한 형태의 막 제조와 이들을 이용한 공정개발에대한 연구가 많이 이루어지고 있다. 특히, 고분자막의 활용이 불가능한 200$\circ$C 이상의 고온조건에서 이루어지는 기체분리 또는 촉매반응 등의 분야에 무기막을 이용하려는 연구가 활발하다. 본 연구에서는 상압화학증착법을 이용하여 다공성 유리관 위에 타이타니아, 실리카, 알루미나 등의 복합박막을 제조하고, 제조변수가 분리막의 특성에 미치는 영향에 대해 살펴보았다.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.123-123
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• 2003

나노튜브는 반도체 재료로서 뿐만 아니라 다른 분야로까지 다양한 응용범위를 가진 물질로서 기존에는 주의 탄소를 사용하여 제작, 사용되어지고 있으나 게이트옥사이드(Gate Oxide) 물질인 지르코니아(ZrO$_2$), 타이타니아(TiO2$_2$) 등을 이용한 나노튜브는 많이 제작되어지고 있지 못하다. 따라서 보다 나은 성질을 갖는 물질로서 나노튜브를 제작할 시 반도체 재료에서의 고집적화를 통해 좋은 성질을 갖게 할 수 있으며 여러 분야로까지 확대가 가능한 재료를 사용하여 광학 및 환경분야 등 응용범위를 넓힐 수 있다. 본 실험은 나노튜브 제작에 있어서 템플레이트의 구멍 내부를 ALD 기술을 이용하여 균일한 두께를 갖는 금속 산화물층을 성장시킨 후 템플레이트 재료의 식각을 통해 금속산화물 나노튜브가 남아있게 하여 제작하는 방법이다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.553-554
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• 2007

By sol-gel method, we have fabricated silica-titania hybrid film using silane treated colloidal $TiO_2$ and characterized the film through FT-IR, TGA, UV-VIS and AFM. The silica-titania hybrid film showed Ti-O-Si chemical bond at FT-IR peak of $910{\sim}940cm^{-1}$. The fabricated hybrid film showed thermal stability of around $350^{\circ}C$(5wt% loss temperature) and transparency more than 90%. In addition, the good surface smoothness was confirmed by AFM. Therefore, the silica-titania hybrid film with outstanding properties can be potential for application in electronics and displays.

• Journal of Korean Society for Atmospheric Environment
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• v.15 no.6
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• pp.791-797
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• 1999

The activity of domestic pigment titania$(TiO_2)$ impregnated with vanadia$(V_2O_5)$ was investigated in the laboratory microreactor. The meta-titanic acid$(TiO(OH)_2)$ which was produced at Hankook Titanium was selected as the precursor for support. The domestic pigment $TiO_2$ showed higher activity in the reduction of NO with $NH_3$ than the foreign commercial $TiO_2$. $WO_3$ were added to domestic $V_2O_5/TiO_2$ catalytic system to improve the catalytic activity at higher reaction temperature between 400~50$0^{\circ}C$ Also, the deactivation of domestic $V_2O_5/TiO_2$ and $WO_3-V_2O_5/TiO_2$ catalyst by $SO_2$ and $H_2O$ was investigated.

• Journal of the Korean Ceramic Society
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• v.33 no.2
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• pp.192-202
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• 1996

In Li0.4Ca0.05AlP0.5Si0.75O4.5 composition glass, glass-ceramic having a near 100% crystallinity after nucleation heat treatment of 74$0^{\circ}C$/2 h and crystallization heat treatment of 90$0^{\circ}C$/2 h and in-situ TiO2 whisker reinforced glass-ceramic after heat treatment of 105$0^{\circ}C$ for 20 h were fabricated with the addition of 4% TiO2 as a nucleating agent. With these materials a ball-on-disc type wear test was conducted in order to examine the effect of TiO2 whisker prepcipitation on ambient and high temperature wear properties of the glass-ceramic. Wear test results indicated that all specimens exhibited micro-fracture wear mechanism in ambient temperature. As temperature increased the wear rates of the materials were increased. However the in-situ TiO2 whisker reinforced glass-ceramic exhibited the lowest wear rate over the test temperature range. This resulted from the improvement of harness and fracture toughness of the material as the glass converted into the glass-ceramic followed by precipitation of TiO2 whiskers throughout the glass-ceramic matrix.

• Journal of Industrial Technology
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• v.43 no.1
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• pp.1-6
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• 2023

TiO₂ is a versatile metal oxide material that is frequently used as a photo-catalyst for organic pollutant oxidation and a functional material for ultraviolet-ray protection. To improve its chemical/physical properties and widen the range of industrial application, it is demanded to control the crystalline feature and morphology precisely by applying advanced nano-synthesis methods. In this study, we prepared TiO₂ nanoparticles using the water-in-oil (W/O) microemulsion method and compared them with the particles synthesized by the conventional precipitation method. Also, we tried to find the optimum conditions for obtaining nano-sized, anatase-rich TiO₂ particles by the W/O microemulsion method. We analyzed the crystalline feature and particle size of the prepared samples using X-ray diffraction (XRD) and Transmission electron microscopy (TEM). In summary, we found the W/O microemulsion is more effective than precipitation in obtaining nano-sized TiO₂. The best result was derived when the microemulsion was formed using AOT surfactant, hydrolysis was performed under basic condition and the sample was calcined at 200℃.