• 한국추진공학회지
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• 제26권5호
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• pp.1-10
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• 2022

로켓엔진용으로 개발된 구리크롬 합금에 대해 저주기 피로시험을 수행하고 여러가지 피로수명 예측방법을 이용해 예측수명을 구하여 이를 시험수명과 비교하여 보았다. 피로수명 예측방법으로는 Coffin-Manson 관계식, 소성 및 전 변형률 에너지 밀도 관계식, Smith-Watson-Topper 관계식, Tomkins 관계식, Jahed-Varvani 관계식 등 총 6가지 방법을 이용하였다. 피로 예측수명을 계산한 결과 모든 방법에서 시험수명 대비 분산범위 2 이내를 만족하였다. 예측수명 편차의 정량적 확인을 통해 전 변형률 에너지 밀도 관계식이 가장 우수한 결과를 나타냈다.

• 한국응용과학기술학회지
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• 제33권3호
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• pp.441-448
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• 2016

본 연구는 구리 아연 금속합금의 산화 환원 반응과 합성 알루미늄 실리케이트의 흡착 반응을 이용한 폐수 중 중금속 처리에 관한 연구이다. 극세사 형태로 제조된 구리 아연 금속합금이 수용액 중에서 산화 환원반응에 의해 아연보다 이온화 경향이 작은 중금속은 환원 처리되고, 이온화 된 아연 및 미반응 중금속은 흡착 처리하여 제거하는 연구이다. 극세사 형태로 제조된 금속합금 물질은 표면적이 커서 1회 처리만으로도 반응 평형에 도달하게 하여 효율이 높은 것으로 나타났다. 크롬($Cr^{+3}$)은 redox 반응 1회 처리만으로도 100.0 % 제거 되었으며, 수은은 98.0 %, 주석 92.0 %, 구리는 91.4 % 정도 제거되었다. 카드뮴, 니켈, 납도 각각 40.0 %, 50.0 %, 58.0 %가 제거 되었다. 크롬($Cr^{+3}$)은 아연과 이온화 경향 차이가 거의 없지만 제거 효율이 높은 것으로 나타났는데 이는 3가 크롬은 이온 상태로 존재하면 redox 반응에서 발생한 $OH^-$ 이온과 결합하여 수산화물 침전을 형성하는 것으로 판단된다. Redox 반응 후 증가한 아연 및 미반응 중금속 농도를 알루미늄실리케이트를 1회 통과하여 거의 100.0 % 제거할 수 있었다. 이는 합성 알루미늄 실리케이트의 비표면적이 크고 금속 이온의 흡착능력이 우수한 것으로 나타났으며, 반응 후 알루미늄 이온은 증가하지 않는 것으로 보아 이온 교환이 아닌 흡착으로 아연 및 중금속 이온들을 제거할 수 있는 것으로 나타났다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.447-452
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• 2004

Vacuum interrupters in order to be used in various switch-gear components such as circuit breakers, distribution switches, contactors, etc. spread the arc uniformly over the surface of the contacts. The electrodes of vacuum interrupters are made of sinter-forged Cu-Cr materials for good electrical and mechanical characteristics. Since the closing velocity is 1-2m/s and impact deformation of the electrode depends on the strain rate at that velocity, the dynamic behavior of the sinter-forged Cu-Cr is a key to investigate the impact characteristics of the electrodes. The dynamic response of the material at intermediate strain rate is obtained from the high speed tensile test machine test and at the high strain rate is obtained from the split Hopkinson pressure bar test. Experimental results from both quasi-static and dynamic compressive tests are interpolated to construct the Johnson-Cook model as the constitutive relation that should be applied to simulation of the dynamic behavior of the electrodes. The impact characteristics of a vacuum interrupter are investigated with computer simulations by changing the amount of chromium content.

• 대한기계학회논문집A
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• 제30권6호
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• pp.670-677
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• 2006

Vacuum interrupters are used in various switch-gear components such as circuit breakers, distribution switches, contactors. The electrodes of a vacuum interrupter are manufactured of sinter-forged Cu-Cr material for good electrical and mechanical characteristics. Since the closing velocity is 1-2m/s and impact deformation of the electrode depends on the strain-rate at the given velocity, the dynamic material property of the sinter-forged Cu-Cr alloy is important to design the vacuum interrupter reliably and to identify the impact characteristics of a vacuum interrupter accurately. This paper is concerned with the dynamic material properties of sinter-forged Cu-Cr alloy for various strain rates. The amount of chrome is varied from 10 wt% to 30 wt% in order to investigate the influence of the chrome content on the dynamic material property. The high speed tensile test machine is utilized in order to identify the dynamic property of the Cu-Cr alloy at the intermediate strain-rate and the split Hopkinson pressure bar is used at the high strain-rate. Experimental results from both the quasi-static and the high strain-rate up to the 5000/sec are interpolated with respect to the amount of chrome in order to construct the Johnson-Cook and the modified Johnson-Cook model as the constitutive relation that should be applied to numerical simulation of the impact behavior of electrodes.

• 한국추진공학회지
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• 제18권6호
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• pp.88-95
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• 2014

액체로켓 엔진 재생냉각챔버의 무게 감량을 위하여 내피에 스피닝 공정을 적용하였다. 스피닝 도중 실린더부와 노즐목부의 블랭크에 파손이 발생하였다. 이 문제를 극복하기 위해 맨드럴 및 블랭크 형상을 수정하였으며 이러한 수정을 통해 스피닝을 사용하여 내피를 제작할 수 있었다. 제작된 노즐목부 스피닝 시제품은 균열이나 네킹없이 성공적으로 벌징이 되어 연소기 제작에 적용할 수 있는 충분한 성형성을 확보한 것을 확인하였다.

• 한국재료학회지
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• 제28권6호
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• pp.317-323
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• 2018

Crystal structure of the $L1_2$ type $(Al,X)_3Ti$ alloy (X = Cr,Cu) is analyzed by X-ray diffractometry and the nonuniform strain behavior at high temperature is investigated. The lattice constants for the $L1_2$ type $(Al,X)_3Ti$ alloys decrease in the order of the atomic number of the substituted atom X, and the hardness tends to increase. In a compressive test at around 473K for $Al_{67.5}Ti_{25}Cr_{7.5}$, $Al_{65}Ti_{25}Cr_{10}$ and $Al_{62.5}Ti_{25}Cu_{12.5}$ alloys, it is found that the stress-strain curves showed serration, and deformation rate dependence appeared. It is assumed that the generation of serration is due to dynamic strain aging caused by the diffusion of solute atoms. As a result, activation energy of 60-95 kJ/mol is obtained. This process does not require direct involvement. In order to investigate the generation of serrations in detail, compression tests are carried out under various conditions. As a result, in the strain rate range of this experiment, serration is found to occur after 470K at a certain critical strain. The critical strain increases as the strain rate increases at constant temperature, and the critical strain tends to decrease as temperature rises under constant strain rate. This tendency is common to all alloys produced. In the case of this alloy system, the serration at around 473K corresponds to the case in which the dislocation velocity is faster than the diffusion rate of interstitial solute atoms at low temperature.

• 대한치과보철학회지
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• 제30권2호
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• pp.155-166
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• 1992

In dentistry, precious metal alloys are, mainly due to economic factors, increasingly displaced by alternatives containing Ni-Cr-Co. There are some reports where hypersensitive reactions to Ni-Cr-Co alloys are presented and discussed. The reactions reported vary from mucosa contact stomatitis to generalized dermatitis without any oral mucosal reaction. The purpose of this study was to investigate the incidence of nickel, chrome, cobalt and copper, and to know whether subjects with positive skin reaction to nickel would also demonstrate adverse intraoral reaction to a non-precious metal nickel. The patch tests were performed in 81 subjects(male 39, female 42) and nickel sulfate 5% aq., potassium bichromate 0.5% at., cobalt chloride 2% aq., & copper sulfate 1% aq., were used for test allergens. And then the intraoral tests were performed in 16 subjects, 8 subjects with positive allergic skin reaction to nickel and 8 subjects with negative allergic skin reaction. A pure metallic nickel plate was attached to the buccal side of the upper second premolar. The results are as follows : 1. The frequency of nickel sensitivity was 9.9% (2 men, 6 women), cobalt was 4.9% (1 man, 3 women), and chrome was 2.5% (2 men) respectively and there was no positive reaction to copper 2. The positive reactions were 8 of 23 (34.8%) with a history of jewelry allergic reactions and 3 of 58 (5.1%) without a history of jewelry allergic reactions. 3. Three of 8 subjects with positive skin reaction. gave reactions to the metal plates.