• 제목/요약/키워드: 코팅부식

검색결과 317건 처리시간 0.02초

완전화 박막의 구현을 위한 기술적 과제와 도전

  • 정재인;양지훈;박혜선;정재훈;송민아
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.98-98
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    • 2013
  • 완전화 박막이란 사용자가 원하는 용도에 맞게 최적의 성능을 구현하도록 제조된 박막을 의미하며 금속이나 화합물 박막을 제조하되 각종 구조 제어 Tool이나 증착 공정을 변화시켜 나노화와 다층화 또는 치밀화를 통해 구현될 수 있다. 최근 고성능의 증착 및 제어 Tool이 개발되고 빗각증착(Oblique Angle Deposition)이나 스침각 증착(Glancing Angle Deposition) 방법 등의 기술이 개발되면서 사용자 목적에 최적인 박막 소재를 제공하여 User-friendly한 응용을 위한 연구개발이 활발히 진행되고 있다. 완전화 박막 제조에 대한 시도는 1990년대에 일본에서 시작되었다. 일본에서는 산학연이 공동으로 참여하는 NEDO 프로그램을 통해 경질코팅을 이용한 Protective Layer를 제조하여 차단 방식에 의한 내식성 구현 연구를 수행하였다. 유럽에서는 제 7차 European Framework Program (7th FT)을 통해 2007년부터 CORRAL (Corrosion Protection with Perfect Atomic Layer) 프로젝트를 만들어 완전화 박막 연구를 진행하고 있다. 상기 프로젝트는 얇은 자연 산화막이 Bulk의 부식을 방지해주는 것에 착안하여 HIPIMS나 Filtered Arc 또는 ALD 공정을 이용하여 자연 산화막과 유사한 Defect-free 산화막을 제조하여 Barrier형 내식성 박막을 구현하는 것을 목표로 하고 있다. 본 연구에서는 완전화 박막 구현을 위한 연구동향을 파악하고 완전화 박막 제조를 위한 기술적 과제와 몇 가지의 시도에 대한 기초 연구 자료를 소개한다.

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항공, 바이오, 원자력 부품의 프레팅 마모 현상 비교 연구 (Comparative study on fretting wear of aerospace, biomedical, and nuclear components)

  • 전태성;김경목
    • 항공우주시스템공학회지
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    • 제11권2호
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    • pp.16-22
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    • 2017
  • 본 논문에서는 항공, 바이오 및 원자력 부품들에서 발생하는 프레팅 마모 현상이 비교 연구되었다. 프레팅 마모 손상에 영향을 미치는 실험적 인자들을 확인하였으며 각 부품에서 관찰된 실험 인자들의 크기들을 직접 비교하였다. 초당 진동수, 상대적 변위, 그리고 수직하중의 크기는 프레팅 마모가 발생하는 부품에 따라 다양했다. 프레팅 마모 손상을 최소화시키는 최근 해결책들이 조사되었으며 저마찰 코팅 적층, 표면 처리, 기저 재료 및 접촉 형상 최적 설계 등이 해결책으로 소개되었다. 본 연구는 프레팅 마모 손상을 분석하고 마찰 부품을 설계하는데 유용한 방법과 해결책을 제공한다.

알루미늄 용사코팅의 불소실리콘 봉공재 적용에 따른 전기화학적 및 캐비테이션 특성 평가 (Electrochemical and Cavitation Characteristics of Al Thermal Spray Coating with F-Si Sealing)

  • 한민수;이승준;장석기;김성종
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.317-324
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    • 2010
  • Marine transportation by ships is characterized by remote, large-volume and lower rates than the others carry system. Ships account for over 80% of all international trading, and marine transportation is an internationally competitive, strategic, and great national important industry. The construction of larger and faster ships has brought about many problems such as cavitations and erosion corrosion. Cavitations and erosion corrosion make damages on materials and leads to break down members due to continuous physical contacts with shock waves and fluids from the generation and extinction of air bubbles in sea water vortex. The steel used for ship constructions was spray-coated with Al wire, and additionally sealed with fluorine silicone sealing material. Results of experiment, corrosion resistance of sealed thermal spray coating was improved, however in cavitation resistance, the large effect was not appeared. Accordingly, this study applied for thermal spray coating to provide better electrochemical characteristics and corrosion resistance in marine environment.

ZrN 코팅된 치과 주조용 Co-Cr 합금의 부식거동 (Corrosion Behaviors of ZrN Coated on Dental Co-Cr Alloys)

  • 이상훈;나정숙;장재영
    • 대한치과기공학회지
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    • 제35권4호
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    • pp.343-352
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    • 2013
  • Purpose: The purpose of this study was to investigate to effect of the ZrN coated on corrosion resistance and physical property of dental Co-Cr alloys using various instruments. Methods: The specimens were used, respectively, for experiment, Arc Ion plating was carried out for dental casting alloys using ZrN coated materials with nitrogen gas. ZrN coated surface of each specimen was observed with field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), vickers hardness tester, and electrochemical tester. Results: The current density of ZrN coated specimen was smaller than that of non-coated specimen in 0.9% NaCl solution. Pit nucleated at scratch of specimen. The pitting corrosion resistant |$E_{max}-E_{rep}$| increased in order of ZrN coated (110 mV), and non-coated wire (100 mV). Conclusion: The corrosion potential of the ZrN coated specimen was comparatively high. the surface of ZrN coated specimen was more smooth than that of other kinds of non-coated specimen. ZrN coated surface showed higher hardness than that of non-coated surface.

Ti가 함유된 스테인리스강에서 Ti, Ti/Cr 코팅표면과 플라즈마질화표면의 부식특성 (Corrosion Characteristics of Ti, Ti/Cr Coated and Plasma-Nitrided Surface for Stainless Steel Containing Ti)

  • 최한철;이승훈;김관휴
    • 한국표면공학회지
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    • 제36권1호
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    • pp.89-98
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    • 2003
  • Corrosion characteristics of Ti, Ti/Cr coated and plasma-nitrided surface for stainless steel containing Ti have been studied. Stainless steels containing 0.09-0.92wt% Ti were fabricated by using vacuum furnace and solutionized for 1hr at $1050^{\circ}C$. Ti and Cr coatings were done on solutionized stainless steel surface by EB-PVD. The Ti coated specimen were coated by Cr and were nitrided by plasma at $450^{\circ}C$ for 5hr Microstructure and phase analysis were performed using SEM, OM and EDX. Corrosion behavior of the coated specimen was investigated by electrochemical test. The coated surface was of fine columnar structure. The Ti/Cr coated surface was denser than the Ti coated and the Ti coated-nitrided surfaces. The corrosion and pitting potential increased in proportion to the Ti content, coating temperature, coating thickness and formation of stable oxide film. The current density in active and passive region decreased in the case of Ti/Cr coated sample and Ti coated-nitrided samples. Especially the plasma nitrided specimen after Ti coating have a good corrosion resistance compared with the Ti coated specimen. The number and size of pits decreased as Ti content of matrix increased.

대형 고속 선박용 러더의 내침식, 부식 특성 향상을 위한 용사 코팅막 (Thermal Spray Coating Layer for Improvement of Erosion and Corrosion Resistance Applicable to Large Sized High Speed Ship's Rudder)

  • 이유송;허성현;김진홍;김여중;배일용;이명훈
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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    • pp.196-197
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    • 2011
  • Rudder, one of the most important component in the marine vessel, is now being decreased life time to serve due to cavitation erosion, vortex current, high flow speed suffer from ship speed going up dramatically. In this study, 10 kinds of thermal spray coating materials(2 of Zn alloy series, 3 of Al alloy series, 3 of Cu alloy series, 2 of STS alloy series) are chosen to apply on specimens and analyze micro structure, metallic composition, properties(porosity, oxidation) by using visual observation, XRD, EDX etc.. Additionally, to refine the characteristic of corrosion endurance for thermal spray coating layer, compared with thermal spray process and 5 kinds of heavy duty painting and AC paint (Anti-Corrosion Paint). Based on above mentioned experimental results, a priority of all coated specimens on corrosion-erosion endurances finalized and summarized there by desirable composition and process of thermal sprayed material properly.

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DC Magnetron Sputtering법으로 제작한 Ti$_{x}$N박박의 부식특성에 미치는 코팅조건과 첨가원소의 영향 (Effects of Coating and Additivw Gases on the corrosion Properties of Ti$_{x}$N Films Preapered with DC Magneton Sputtering Method)

  • 김학동;이봉상;조성석
    • 한국표면공학회지
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    • 제31권5호
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    • pp.251-260
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    • 1998
  • Stainless Steel is being used widely for various purposes due to its good corrosion resistance. There have been many researches to produce colored stainless steel by several methods such as anodizing and ion-plating. In this experiment, we $Ti_XN$(C,O) on the films SUS304, aluminium, and glass substrates with DC magentron sputterinng system made by Leybold Hereus, and strdied the structur, corrsion and pit characture of the TiXN observed by TeM image was black and whink and white columnar hed a very fine(200$\AA$) dense sturcture,and the diffraction resistance at the $3{\times}10_6A/\textrm{cm}^2$ and $10_{10}\times{cm}^2$current density were obtained in the under-stoichiometry $Ti_xN$ compound of Ar/$N_2$(Ar:$N_2$=100:6, titanium-rich compound) and the over-stoichiometry compound of Ar/$N_2$((Ar:$N_2$=60:15) respectively. When the thiness was over 1.64$\mu\textrm{m}$, good pit resistance could be obtained and its improvement was especially affected by perfect surfaceface. Typical TiN anodic polarzation curves of very unstable corrosion were observed by $Ti_xN$ film on the glass and perfect film of 3.28$\mu\textrm{m}$ thickness.

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Al-Zn-Zr 용사코팅층의 고체입자 충돌 침식특성에 미치는 봉공처리의 영향 (Effect of Sealing Treatment on Solid Particle Impingement Erosion of Al-Zn-Zr Thermal Spray Coating Layer)

  • 허호성;김성종
    • Corrosion Science and Technology
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    • 제21권1호
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    • pp.68-76
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    • 2022
  • Several technologies are employed to protect substrates from corrosion and erosion damage. In particular, arc thermal spray coating technology is widely used as anti-corrosive technology for steel and concrete structures and is applied to offshore plants and petrochemical and drilling facilities. In this investigation, solid particle impingement erosion experiments were performed on an arc thermal spraying-coated specimen using 85% Al-14% Zn-1% Zr wire rod in KR-RA steel. This study investigated the effect of fluorosilicone sealing on the erosion resistance characteristics of the thermal spray coating layer. The erosion rates of the thermal spray-coated and sealed specimens were 4.1×10-4 and 8.5×10-4, respectively. At the beginning of the experiment, the fluorosilicone sealant was almost destroyed by the impact of the solid particles. The destruction time for the coating layer was 10 minutes for the thermal spray-coated specimen and 13 minutes for the sealed specimens, indicating that the sealed specimens had better erosion resistance characteristics to solid particle impingement.

MMO(Ti/Ru) 코팅된 타이타늄의 고분자 전해질 연료전지 양극환경에서의 전기화학적 거동 (Electrochemical Characteristics of MMO(Ti/Ru)-Coated Titanium in a Cathode Environment of Polymer Electrolyte Membrane Fuel Cell)

  • 허호성;김성종
    • Corrosion Science and Technology
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    • 제21권5호
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    • pp.340-347
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    • 2022
  • In this research, mixed metal oxide (TiO2, RuO2) coating was applied to grade 1 titanium as a bipolar plate for polymer electrolyte membrane fuel cell (PEMFC). Electrochemical experiments were carried out in an aqueous solution of pH 3 (H2SO4 + 0.1 ppm HF, 80 ℃) determined by DoE. The air was bubbled to simulate a cathode environment. Potentiodynamic polarization test revealed that corrosion current densities of the titanium substrate and MMO-coated specimen were 0.180 µA/cm2 and 4.381 µA/cm2, respectively. There was no active peak. After potentiostatic experiment, current densities of the titanium substrate and the MMO-coated specimen were 0.19 µA/cm2 and 1.05 µA/cm2, respectively. As a result of observing the surface before and after the potentiostatic experiment, cracked dried clay structures were observed without corrosion damage. Both the titanium substrate and the MMO-coated specimen could not satisfy the interfacial contact resistance suggested by the DoE. Thus, further research is needed before they could be applied as bipolar plates.

수소연료전지 자동차의 수소밸브용 알루미늄 합금의 수소취화에 의한 기계적 특성에 미치는 CrN과 TiN 코팅의 영향 (Effects of CrN and TiN Coating by Hydrogen Embrittlement of Aluminum Alloys for Hydrogen Valves of Hydrogen Fuel Cell Vehicles on Mechanical Properties)

  • 허호성;신동호;김성종
    • Corrosion Science and Technology
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    • 제22권4호
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    • pp.232-241
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    • 2023
  • The mechanical properties of the hydrogen valve responsible for supplying and blocking hydrogen gas in a hydrogen fuel cell electric vehicle (FCEV) were researched. Mechanical properties by hydrogen embrittlement were investigated by coating chromium nitride (CrN) and titanium nitride (TiN) on aluminum alloy by arc ion plating method. The coating layer was deposited to a thickness of about 2 ㎛, and a slow strain rate test (SSRT) was conducted after hydrogen embrittlement to determine the hydrogen embrittlement resistance of the CrN and TiN coating layers. The CrN-coated specimen presented little decrease in mechanical properties until 12 hours of hydrogen charging due to its excellent resistance to hydrogen permeation. However, both the CrN and TiN-coated specimens exhibited deterioration in mechanical properties due to the peeling of the coating layer after 24 hours of hydrogen charging. The specimens coated at 350 ℃ presented a significant decrease in ultimate tensile strength due to abnormal grain growth.