Corrosion Characteristics of Ti, Ti/Cr Coated and Plasma-Nitrided Surface for Stainless Steel Containing Ti

Ti가 함유된 스테인리스강에서 Ti, Ti/Cr 코팅표면과 플라즈마질화표면의 부식특성

  • Published : 2003.02.01

Abstract

Corrosion characteristics of Ti, Ti/Cr coated and plasma-nitrided surface for stainless steel containing Ti have been studied. Stainless steels containing 0.09-0.92wt% Ti were fabricated by using vacuum furnace and solutionized for 1hr at $1050^{\circ}C$. Ti and Cr coatings were done on solutionized stainless steel surface by EB-PVD. The Ti coated specimen were coated by Cr and were nitrided by plasma at $450^{\circ}C$ for 5hr Microstructure and phase analysis were performed using SEM, OM and EDX. Corrosion behavior of the coated specimen was investigated by electrochemical test. The coated surface was of fine columnar structure. The Ti/Cr coated surface was denser than the Ti coated and the Ti coated-nitrided surfaces. The corrosion and pitting potential increased in proportion to the Ti content, coating temperature, coating thickness and formation of stable oxide film. The current density in active and passive region decreased in the case of Ti/Cr coated sample and Ti coated-nitrided samples. Especially the plasma nitrided specimen after Ti coating have a good corrosion resistance compared with the Ti coated specimen. The number and size of pits decreased as Ti content of matrix increased.

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References

  1. E. C. barn, R. H. Abron, j. j. B. Rutherfold, Trans. Amer. Soc. SteelTreat, 21 (1933) 481
  2. 차승옥, 최한철, 김관휴, 대한금속학회지, 36 (1998) 138
  3. S. O. Cha, H. C. Choe, K. H. Kim, J. of the Korean Inst. of Met & Mater, 37 (1999) 137
  4. H. Uno, A. Kimmura, T. Misawa, Corrosion, 48 (1992) 467 https://doi.org/10.5006/1.3315962
  5. E. Harju, A. S. Korhonen, Laizhu Jiang, E. Ristolaien, Surface and Coating Technology, 856 (1996) 189
  6. J. A. Thomton, Ann. Rev. ScL, 7 (1977) 239 https://doi.org/10.1146/annurev.ms.07.080177.001323
  7. A. Mochvan, A. V. Demchishin, Fiz. Met. Metalloved.,28 (1969) 635
  8. 최한철, 김관휴, 대한금속학회지, 37 (1995) 475
  9. M. Poubaix, Atlas of Electrochemical Equilibria in Aqueous Solutions, NACE, Houston, (1974) 213