• 폴리머
• /
• 제37권5호
• /
• pp.613-617
• /
• 2013

나노입자크기의 케냐프섬유를 폴리프로필렌에 첨가하였을 시, 복합소재의 물성변화를 관찰하였다. 천연크기의 케냐프섬유를 나노입자크기의 케냐프섬유로 대체하였을 시, 그 복합소재의 인장강도, 휨강도, 충격강도, 열변형온도가 증가한 반면에, 용융지수, 연신율(%), 충격강도 등이 감소하였다. 이는 나노입자크기의 케냐프섬유가 폴리프로필렌과 접촉하는 표면적의 증가와 섬유표면에 존재하는 휘발성 추출물질 등의 불순물의 감소에 따른 것으로 판단된다.

• Elastomers and Composites
• /
• 제46권2호
• /
• pp.125-131
• /
• 2011

일정한 길이로 분쇄한 케냐프섬유를 일정한 비율로 PP수지에 복합화하여 섬유의 함량에 따른 기계적특성을 조사하였다. 케냐프 섬유의 함량이 증가할수록 인장강도, 굴곡탄성률, 충격강도, 비중, 열변형온도가 증가하는 경향을 나타내었으나 신장률, 굴곡강도, 용융유동지수는 감소하는 경향을 나타내었다. 기계적물성증가의 원인은 섬유와 PP간의 계면접촉면적의 증가와 섬유간의 연결간섭으로 고찰되었다. 케냐프섬유내에 존재하는 증발성추출물질이 PP와 의 계면접착에 있어서 감소에 영향을 미치는 것으로 고려된다.

• 폴리머
• /
• 제39권1호
• /
• pp.99-106
• /
• 2015

나노케냐프 섬유가 포함된 셀룰로스 섬유를 알카리(NaOH)로 처리 후 PP 수지에 첨가하여 물성에 미치는 영향에 대하여 조사하였다. 알카리를 섬유에 처리한 효과로는 M.I., 신장율, 충격강도가 증가하는 반면 인장강도, 휨모듈러스, 열변형온도가 처리하지 않은 섬유에 비해 감소하였다. 알카리를 나노섬유에 처리하였을 때 섬유표면의 불순물과 화학물질을 제거하여 섬유표면의 특성을 변화시켜서 나노섬유와 PP 수지간의 계면간 접착력을 감소시키고 PP의 특성을 변화시키는 것으로 보인다.

• 한국의류학회지
• /
• 제27권9_10호
• /
• pp.1144-1152
• /
• 2003

Kenaf has been cultivated in Jeju Island. After being harvested at 105 DAP(day after planting) and separated from kenaf stalks , decorticated kenaf basts were treated with different concentration/temperature/time combinations in order to do chemical rotting. The following fiber properties were compared; rotting effects, colors, crystallinity, molecular structures, dyeabilities, and non-cellulose contents such as pectins, lignins, & hemicellulose. The best results of chemical rotting were obtained from the specimens treated with low concentration/ low temperature/short time. Their colors were bright yellow. The lumens of specimens diminished with the affect of NaOH. The structures of chemically rotted kenaf fibers were cellulose 1. The degree of crystallinity of chemically retted kenaf fibers were very high. Non-cellulose content, especially hemicellulose, was low in the specimens treated with the high NaOH concentration. Dyeabilities of kenaf fibers were higher among the specimens without the non-cellulose content than those with the non-cellulose content.

• 한국의류학회지
• /
• 제30권11호
• /
• pp.1581-1588
• /
• 2006

The effects of removal of lignin or hemicellulose on the cottonizing and pulping characteristics of kenaf fiber were studied by comparing the conditions of non-cellulosic material contents, fiber lengths and dyeability. And the effects of lignin or hemicellulose on dyeability of the kenaf fiber using CI Direct Green 26 and CI Direct Red 81 were investigated. The results were as follows. The lignin contents decreased and the kenaf fiber became shorter and finer as the reaction time with sodium chlorite increased. The hemicellulose could be removed by treating sodium hydroxide solution to the fiber from which the lignin partly removed. The 80% of hemicellulose could be removed by 5% of sodium hydroxide solution in 5 minutes. But if lignin were not removed at all, hemicellulose could not be removed. The fiber lengths proper for apparel were obtained after treating sodium chlorite for 10-20 minutes and those for pulping were obtained after treating sodium chlorite for 40 minutes. The kenaf fibers from which lignin and hemicellulose partly removed were dyed with CI Direct Green 26 and CI Direct Red 81. Their dyeability increased as the removal rates of lignin increased. The ${\Delta}E$ values of kenaf fiber dyed with CI Direct Green 26 were lower than CI Direct Red 81.

• 한국의류학회지
• /
• 제27권7호
• /
• pp.862-871
• /
• 2003

Kenaf has been estimated as an economic and environmentally compatible crop. This study purposed to enlarge the use of kenaf as textile materials and to develope high value-added textile fibers. Kenaf has been cultivated successfully and grown fast in Jeju. The height of kenaf stalks was about 220cm at 105 DAP and 400cm at 150 DAP, After harvesting at 105 DAP and seperating the basts from harvested kenaf stalks, decorticated kenaf basts were rotted in water at 15~$25^{\circ}C$ for biological rotting and were treated with 1%, 4% and 7% NaOH at 9$0^{\circ}C$ for chemical retting. The properties of extracted fibers were compared: such as fiber diameter. Transversal and longitudinal views, colors, crystallinities, strengths and elongations etc. The diameter of kenaf bast fibers was 15~25 ${\mu}{\textrm}{m}$. Biologically rotted kenaf bast fibers had well developed lumens which were diminished after chemical retting. The degree of crystallinities of biologically rotted kenaf bast fiber was about 92~96% showed higher than those of chemically rotting. The biologically rotted fibers were bright and had creamy color. Yelloweness increased at chemically rotted fibers. Fiber bundle strengths were from maximum 98076.9 (gf/g) to minimum 63749.5 (gf/g). Fiber bundle strengths of biologically rotted kenaf fibers appeared greater than those of chemically rotted fibers. Alkali treatments of chemical rotting could make strength lower and elongation higher. Rotting method might be one of the most importance factors affecting to final fiber properties.

• 한국의류학회지
• /
• 제28권7호
• /
• pp.873-881
• /
• 2004

This research was aimed to investigate the effect of enzyme and the addition of chelators on rotting of the Kenaf bast. Enzyme rotting was effective only when the chelators were added with the enzyme. EDTA was a more effective chelator than oxalic acid under 1% concentration. There was no difference in the rotting effect under different enzyme concentration levels, and under different treatment time and temperature. Therefore, it was found that enzyme rotting can be carried out with low enzyme concentration(0.125%) at room temperature. Retting time can be shortened when higher enzyme concentration and higher temperature are applied. Cellulose I structure of kenaf fiber did not change after enzyme rotting, and different enzyme concentration did not affect the crytallinity structure. Non-cellulosic matters such as hemicellulose, lignin, and pectin were present in the descending order in the enzyme rotted kenaf fiber, and there were no differences in their amounts due to enzyme concentration levels. There was no difference in the dyeabilities of kenaf fiber rotted with different enzyme concentration levels. Enzyme rotted kenaf fiber showed better cyeability when pectin, lignin, and hemicellulose were removed.

• 방사선산업학회지
• /
• 제8권1호
• /
• pp.53-57
• /
• 2014

The kenaf is quickly developing as a renewable resource. Kenaf can be grown under a wide range of weather conditions. Modification of kenaf fiber by graft polymerization provides a significant route to alter the chemical properties, including surface hydrophilicity or hydrophobicity. In this study, kenaf fiber surfaces were grafted with acrylic acid as a hydrophilic group using electron beam irradiation. The grafting rate increased with an increase in grafting time. The FT-IR results confirmed that acrylic acid was successfully grafted onto the kenaf fibers. The wettability of the kenaf fiber was increased, accompanied by acylic acid grafting on the fiber surface. According to the permeability test result, it was found that acrylic acid grafted kenaf fiber reinforced cement composite was more reduced than non-grafted kenaf fiber reinforced cement composite.

• 공업화학
• /
• 제33권5호
• /
• pp.471-476
• /
• 2022

폴리프로필렌(polypropylene, PP)에 고 함량의 케나프 섬유(kenaf fiber, KF)를 투입하기 위해 PP/KF 펠트가 사용되었으며, 바인더로 폴리우레탄(polyurethane, PU)이 사용되었다. PU 바인더의 조성비 선정을 위해 이소시아네이트와 polyol 비율에 따른 PP/KF/PU 펠트 복합체의 굴곡 강도를 평가하였다. 상용화제로 말레인산 무수물(maleic anhydride, MAH)이 그라프트된 PP-g-MAH가 적용되었다 PP/KF/PU 펠트 복합체의 기계적 물성 변화를 고찰하기 위해 인장, 굴곡 및 충격 특성을 평가하였고, 기계적 물성이 개선됨을 확인하였다.

• 한국염색가공학회지
• /
• 제32권4호
• /
• pp.274-280
• /
• 2020

This study compared the mechanical properties of bamboo fiber composites and kenaf fiber composites through physical treatment (ultrasonic treatment). Kenaf, a composite of PP reinforced with bamboo fiber, was made using injection molding technology. PP was used as a binder and the ultrasonic treatment time of bamboo and kenaf was increased by 30 minutes to compare and study various mechanical properties of bamboo and kenaf composites through physical treatment. Interfacial properties such as internal cracks and internal structure of the wave cross section were confirmed using a scanning electron microscope (SEM). As a result of the ultrasonic treatment, most of the characteristics were fragile as the ultrasonic treatment time was increased, and it was confirmed that the natural characteristics of the twisted fibers had a great influence on the characteristics of the composite material.