• Title/Summary/Keyword: 칼슘계

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A Study on the Chemical Resistance of Concrete Substituting Fly ash (플라이애쉬를 혼합(混合)한 콘크리트의 내약품성(耐藥品性)에 관한 연구(硏究))

  • Moon, Han Young;Seo, Joung Woo;Son, Hyung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.1
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    • pp.103-112
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    • 1988
  • The reasons why the hardened cement paste substituted the domestic fly ash are better in resisting against sulfate or calcium chloride attack the one used portland cement are as follows. First, because the fly ash could restrict the gypsum creation in resisting against sulfate attack, the $C_3A$ hydrates were not inversed to ettringite. Second, in the case of the, hardened cement paste immersed in calcium chloride solution, the fly ash was effective in resisting the deteorioration resulting from microcrack in surface and inner composition by the ionization of calcium chloride solution.

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Farm Survey on Eggshell Quality and Egg Vitamin D3 Contents in Laying Hens Fed Vitamin D3-enriched Diets (산란계 사료 내 비타민 D3 첨가에 따른 난각품질과 계란내 비타민D3 함량에 관한 농장조사)

  • Dong-Hae Joh;Byung-Yeon Kwon;Da-Hye Kim;Kyung-Woo Lee
    • Korean Journal of Poultry Science
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    • v.50 no.2
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    • pp.73-80
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    • 2023
  • Vitamin D3 is an essential nutrient which plays an important role in calcium metabolism for eggshell formation, in calcium and phosphorus metabolism for bone mineralization, and in maintaining host immunity. Although there have been a great deal of studies investigating the role of vitamin D3 in eggshell quality and vitamin D3 contents in eggs, no attempts have been made to monitor the eggshell quality and vitamin D3 contents in eggs at farm level. Thus, this survey was conducted to measure eggshell quality and vitamin D3 contents in eggs laid from laying hens fed diets containing different levels of vitamin D3. Eggs from four commercial laying hen farms were sampled before and 1, 2, 3 and 5 weeks after provision of the vitamin D3-enriched diets added with the level of 16,500 IU and 29,000 IU. Dietary vitamin D3 did not affect the eggshell color and breaking strength, but increase the eggshell thickness. In addition, vitamin D3 contents in eggs were elevated as vitamin D3 in diets was increased. It is concluded that addition of dietary vitamin D3 into the diets of laying hens at the commercial laying hen farms could improve eggshell quality and vitamin D3 contents in eggs. It is expected that the prediction equation for egg vitamin D3 contents might be produced if more data on vitamin D3 contents in diets and eggs at the farms are to be analyzed.

Evaluation of Long-term Dietary Intakes of Housewives (장기간 기록법으로 조사한 주부의 식품 및 영양소 섭취 실태)

  • 최정숙
    • The Korean Journal of Community Living Science
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    • v.15 no.1
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    • pp.91-104
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    • 2004
  • This study was designed to investigate and evaluate the dietary intake of 30 housewives, aged 35 to 59. The subjects kept daily diet records lot a period of one year. Their mean daily nutrient intakes met or exceeded the RDA (recommended dietary allowance) for all categories except energy, calcium, iron, vitamin A, and vitamin B$_2$. Mean daily calorie intakes were 81.2% of the RDA. The subjects received about 19% of their energy from fat and 15% from protein. Nutrient adequacy ratios (NAR) were 0.60 for calcium, 0.62 for iron, 0.71 for vitamin A, and 0.76 for vitamin B$_2$. The mean adequacy ratio (MAR) was 0.79. Subjects received various nutrients from rice, pork, eggs, and Kimchi. Rice was a major contribute. to many subjects' nutrient intake due to the high amount of consumption. Pork, rice, and vegetable oil greatly contributed to fat intakes while eggs, pork, and beef supplied a high level of cholesterol compared to other foods. Kimchi, anchovies, and milk were the major contributors of calcium, while rice, pork, and Kimchi were the major contributors of iron. These results indicate that the major nutritional problem of middle-aged housewives is an overall inadequate intake of energy, calcium, and iron.

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Kinetic study of high-temperature removal of $H_2S$ by Ca-based sorbents (황화수소 제거를 위한 칼슘계 고온탈황제의 황화반응속도에 관한 연구)

  • 김영식;전지환
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1998.04a
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    • pp.144-153
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    • 1998
  • Sorbents of calcined limestone and oyster particles having a diameter of about 0.63mm were exposed to simulate fuel gases containing 5000ppmv H2S for temperatures ranging from 600 to 800C in a TGA. The reaction between CaO and H2S proceds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. The kinetics of the sorption of H2S by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.

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Kinetic of High-Temperature Removal of $H_2S$ by Ca-based Sorbents (황화수소 제거를 위한 칼슘계 고온 탈황제의 황화반응속도)

  • 김영식;전지환;손병현;정종현;정덕영;오광중
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.125-133
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    • 1999
  • Sorbents of calcined limestone and oyster particles having a diameter of about 0.63mm were exposed to simulated fuel gases containing 5000ppm $H_2S$ for temperatures ranging from 600 to 80$0^{\circ}C$ in a TGA (Thermalgravimetric analyzer). The reaction between CaO and $H_2S$ proceeds via an unreacted shrinking core mechanism. The sulfidation rate is likely to be controlled primarily by countercurrent diffusion through the product layer of calcium sulfide(CaS) formed. The kinetics of the sorption of $H_2S$ by CaO is sensitive to the reaction temperature and particle size, and the reaction rate of oyster was faster than the calcined limestone.

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A study on the Shrinkage Properties of precast concrete using Calcium hardening accelerator (칼슘계 경화촉진제를 사용한 프리캐스트 콘크리트의 수축특성에 관한 연구)

  • Min, Tae-Beom;Jo, In-Seong;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.44-45
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    • 2014
  • On this study, initial crack index was evaluated by performing FEM analysis to crack propagation from hydration heat for development of precast concrete. On the result, as increased the usage of hardening accelerator, initial compressive strength were improved and setting time also was shortened. Additionally, central temperature of concrete was increased, the reaching time for the highest temperature could be shortened. By the result to assess crack index, there was no problem about crack despite of growth of initial high hydration heating. This result guessed because of small size element when analyzed trough FEM, realization for mass concrete's crack index should be performed.

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The Effects of Calcium and Phenothiazine Derivatives on the Thermotropic Phase Transition of Acidic Phospholipid Bilayers (산성 인지질 이중층의 열적 상전이에 미치는 칼슘과 페노치아진 유도체의 영향)

  • Kim, Nam-Hong;Roh, Sung-Bae
    • The Korean Journal of Pharmacology
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    • v.26 no.1
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    • pp.77-82
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    • 1990
  • The effects of phenothiazine derivatives and calcium on the thermotropic phase transition of bilayers in dipalmitoyl phosphatidylcholine (DPPC) and dipalmitoyl phosphatidic acid (DPPA) liposomes were investigated with differential scanning calorimeter (DSC). Bilayers underwent an abrupt organizational changes at a characteristic temperature when heated. Such temperature-dependent transition was particularly striking and sharp in the bilayers prepared from pure phospholipids. The ability of phenothiazine derivatives to modify the phase transition of phospholipids liposomes was measured by a broadening of the phase transition profile, that transition began to appear at lower temperature than which occurs in untreated liposomes. Calcium ion caused a large upward shift in the transition temperature of DPPC:DPPA (34:66mol%) liposomes. When the liposomes were first incubated with calcium ion followed by phenothiazine derivatives, disappearance of the broad curve centering at $73^{\circ}C$ indicated displacement of calcium ion by phenothiazine derivatives at the anionic site. It is supposed that calcium ion and phenothiazine derivatives might compete with each other on the head group of acidic phospholipid.

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Fundamental Studies on the Calcium Precipitation for the Reuse of Wastewater Containing Phosphate (칼슘 침전처리에 의한 인산폐수 재사용에 관한 연구)

  • Kim Yaung-Im;Kim Dong-Su
    • Resources Recycling
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    • v.12 no.4
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    • pp.38-43
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    • 2003
  • Phosphate is an essential material for the growth of organisms. However. since relatively small amount is required. a large amount of phosphate is abandoned in wastes and wastewater. which contaminate the ecological environment including aquatic system. Purpose of this study is to treat especially high concentrated phosphate wastewater by use of calcium precipitation method. The pH range considered was from 6 to 12 and the maximum removal of phosphate was attained at pH 12. The con-centration of phosphate was observed to decrease rapidly until a half amount of calcium ion to its equivalent for the formation of calcium phosphate precipitate was added. which resulted in the decrease of the remaining concentration of phosphate down to 0.0027 mM. The effect of fluoride ion was examined and the concentration ratio between the phosphate and fluoride ion did not have any significant influence on the removal efficiency of phosphate. The effect of pH was also investigated. With the increasing of the pH in solution, the removal rate of phosphate was increased. Also it was investigated that the effect of fluoride on the phosphate removal was not significant.

Estimation of Rheological Properties of Highly Concentrated Polymer Bonded Explosive Simulant by Microstructure Analysis (미세구조 해석을 통한 고농축 복합화약 시뮬란트의 유변물성 예측)

  • Lee, Sangmook;Hong, In-Kwon;Lee, Jae Wook;Shim, Jung Seob
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.225-231
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    • 2014
  • The rheological properties of highly concentrated polymer bonded explosive simulant were studied by using poly(ethylene-co-vinyl acetate) with 30 and 60% vinyl acetate (VA) content as a binder, respectively. Calcium carbonate and Dechlorane, whose physical properties are similar to resarch department explosive (RDX)'s, were used as fillers. The suspensions were mixed in a batch melt mixer and it was possible to fill 75 v% at maximum. From dynamic mechanical analysis, Dechlorane showed higher interaction with binder resins than that with calcium carbonate fillers. The effects of microstructural change on the rheological properties of the suspensions were investigated by a plate-plate rheometer with constant shear rate and constant shear stress modes, respectively. The theoretical maximum packing fraction of EVA31/Dechlorane suspension obtained from Krieger-Dougherty equation was 70 v% and it was thought that 2000 Pa was proper shear stress condition for this melt processing.

Evaluation of Setting Time, Solubility, and Compressive Strength of Four Calcium Silicate-Based Cements (네 가지 규산 칼슘계 시멘트의 경화시간, 용해도, 압축강도 평가)

  • Yuji Jang;Yujin Kim;Junghwan Lee;Jongsoo Kim;Joonhaeng Lee;Mi Ran Han;Jongbin Kim;Jisun Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.50 no.2
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    • pp.217-228
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    • 2023
  • This study aimed to compare the physical properties of 4 kinds of calcium silicate-based cements (CSCs): 2 kinds of powder-liquid mix type (RetroMTA® [RTMX] and Endocem® MTA Zr [EZMX]) and 2 kinds of premixed type (Well-RootTMPT [WRPR] and Endocem® MTA premixed [ECPR]) CSCs, respectively. Further, we assessed the setting times, solubility values, and compressive strengths of the cements. The shortest setting time was observed for EZMX (123.33 ± 5.77 seconds), followed by RTMX (146.67 ± 5.77 seconds), ECPR (260.00 ± 17.32 seconds), and WRPR (460.00 ± 17.32 seconds), respectively. The highest solubility was observed for WRPR (9.01 ± 0.55%), followed by RTMX (2.17 ± 0.07%), EZMX (0.55 ± 0.03%), and ECPR (0.17 ± 0.03%). Furthermore, the highest compressive strength was observed for ECPR (76.67 ± 25.67 Mpa), followed by WRPR (38.39 ± 7.25 Mpa), RTMX (35.07 ± 5.34 Mpa), and EZMX (4.07 ± 0.60 Mpa). In conclusion, the premixed type CSCs (WRPR and ECPR) exhibited longer setting times compared to the powder-liquid mix type CSCs (EZMX and RTMX). The solubility test showed that ECPR had the lowest solubility while WRPR had the highest solubility, with a statistically significant difference between them (p < 0.0083). Additionally, the compressive strength test showed that ECPR had the highest compressive strength, while EZMX had the lowest compressive strength, also with a statistically significant difference between them (p < 0.0083). ECPR is a promising material as it is premixed, eliminating the need for mixing time, and it has also demonstrated improved solubility and compressive strength, making it a potentially favorable option for clinical use.