• Korean Journal of Microbiology
• /
• v.50 no.2
• /
• pp.137-151
• /
• 2014

Various studies have been conducted to investigate effects of dams on river ecosystems, but less information is available regarding damming impacts on downstream denitrification. We measured denitrification enzyme activity (potential denitrification rate) and denitrifier abundances (using nirS, nirK, and nosZ as markers) in dammed headstreams of the Nakdong River in South Korea. Sediments in Phragmites-dominated riparian areas and in-stream areas across streams (dammed vs. reference) with different streambed materials (gravel and sand) were sampled occasionally. We hypothesized that (i) the higher available N and C contents in sediments downstream of dams foster larger denitrifier communities than in the reference system and (ii) differences in potential denitrification rates across the systems correspond with denitrifier abundances. Despite 30 years of different hydrological management with dams and greater inorganic N and DOC contents in sediments downstream of dams, compared to the references, abundances of denitrifier communities and potential denitrification rates within the whole sediment were not significantly different across the systems. However, nirS and nosZ denitrifier abundances and potential denitrification rates were considerably increased in specific sediments downstream of dams (gravelly riparian and sandy in-stream) with regard to flooding events and seasonal temperature variation. nirK was not amplified in all sediments. Canonical correspondence analyses (CCA) revealed that the relationship between abundances of denitrifier communities and nutrient availabilities and potential denitrification rates was a weak one.

• Economic and Environmental Geology
• /
• v.27 no.1
• /
• pp.101-113
• /
• 1994

Geochemical investigations based on measurements of water parameters and sampling of stream sediments have been carried out, in the Okdongcheon stream and its tributaries in the Sangdong area of South Korea. There are two main problems occurring in the Okdongcheon stream: an acid mine drainage in the upper reaches and toxic trace metal contamination of the stream sediments mainly in the lower reaches. Acid mine water originating from coal mining was neutralized at the confluence of the Cheonpyongcheon stream whilst suspended solids due to flocculation of iron in water caused turbidity which was undesirable. Sediments in the Okdongcheon stream have been contaminated by mining activites. Iron was heavily concentrated in sediments in the upper Okdongcheon whilst toxic trace metals including Pb, Cu, Zn, Co, Cd, As and Bi were accumulated in sediments at stations draining metallic mining areas and near the tailings dam. There is now a requrement to neutralise the acid mine drainage and to use site-specific analysis of biological communities to ensure the conservation and preservation of aquatic organisms.

• The Journal of Engineering Geology
• /
• v.14 no.3 s.40
• /
• pp.259-272
• /
• 2004

The purpose of this study is to investigate the effect of hydrochemical variation of groundwater on the gas tigtness in an unlined oil storage cavern. The groundwater chemistry is greatly influenced by the seawater mixing, the water curtain and the dissolution of grounting cements. The chemical composition of groundwater greatly varies ac-cording to both the location of monitoring wells and the sampling period. Most of groundwater shows alkaline pH and high electrical conductivity. The chemical types of groundwater show the dominant order as follows : Na-Cl type > Ca-Cl type > $Ca-HCO_3(CO_3)$ type. Thermodynamic equilibrium state between chemical composition of groundwater and major minerals indicates that carbonate minerals except clay minerals can be precipitated as a secondary mineral. It means that the secondary precipitates can not greatly exerts the clogging effect into fracture aperture in rock mass around oil storage cavern. The content of total organic carbon (TOC) shows a slightly increasing trend from initial stage to late stage. The $EpCO_2$ was computed so as to assess the gas contribution on the $CO_2$ in groundwater. The $EpCO_2$ of 0$\~$41.3 indicates that the contribution of oil gas on $CO_2$ pressure in groundwater system can be neglected.

• Economic and Environmental Geology
• /
• v.25 no.3
• /
• pp.233-243
• /
• 1992

Ore mineralization of the Hwanghak copper deposit in the Ogsan area occurred in three stages of quartz (stage I and II) and calcite (stage III) veining along fissures in Early Cretaceous sedimentary rocks. Ore minerals are pyrite, pyrrhotite, chalcopyrite (dominant), sphalerite, hematite, galena, and Ag-, Pb-, and Bi-sulfosalts. These were deposited during the first stage at temperatures between $370^{\circ}C$ and < $200^{\circ}C$ from fluids with salinities between 0.5 and 7.6 equiv. wt. % NaCl. There is evidence of boiling and this suggests pressures of less than 180 bars during the first stage. Equilibrium thermodynamic interpretation accompanying with mineral paragenesis and fluid inclusion data indicates that copper precipitation in the hydrothermal system occurred due to cooling and changing in chemical conditions ($fs_2$, $fo_2$, pH). Gradual temperature decrease from $350^{\circ}$ to $250^{\circ}C$ of ore fluids by boiling and mixing with less-evolved meteoric waters mainly led to copper deposition through destabilization of copper chloride complexes. Sulfur isotope values of sulfide minerals decrease systematically with paragenetic time from calculated ${\delta}^{34}S_{H_2S}$ values of 8.2 to 4.7‰. These values, together with the observed change from sulfide-only to sulfide-hematite assemblages and fluid inclusion data, suggest progressively more oxidizing conditions, with a corresponding increase of the $sulfate/H_2S$ ratio of hydrothermal fluids. Measured and calculated hydrogen and oxygen isotope valutls of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values.

• Journal of the Mineralogical Society of Korea
• /
• v.20 no.2 s.52
• /
• pp.115-124
• /
• 2007

Electrum-sulfide mineralization of the Youngbogari mine area occurred in two stages of massive quartz veins that fill the fractures along the fault/shear zones in the Precambrian gneiss. Ore mineralogy is simple, consisting of arsenopyrite $(31.4{\sim}33.4atom.%As)$, pyrite, sphalerite $(4.1{\sim}17.6mole%FeS)$, galena, chalcopyrite, argentite, and electrum. Electrum $(60.3{\sim}87.6atom.%Ag)$ is associated with galena, chalcopyrite and late sphalerite infilling the fractures in quartz and sulfides. Fluid inclusion data show that ore mineralization was formed from $H_2O-CO_2-CH_4-NaCl$ fluids $(X_{CO2+CH4}=0.0\;to\;0.2)$ with low salinities (0 to 10wt.% eq. NaCl) at temperatures between $200^{\circ}\;and\;370^{\circ}C$. Gold-silver mineralization occurred later than the base-metal sulfide deposition, at temperatures near $250^{\circ}C$ and was probably a result of cooling and decreasing sulfur fugacity caused by sulfide precipitation and/or $H_2S$ loss through fluid unmixing.

• Journal of the Korean earth science society
• /
• v.27 no.3
• /
• pp.313-327
• /
• 2006

This study investigated the geochernical characteristics of Mn scale formed in groundwater wells at the Damyang area. The composition of Mn scale consists mainly of MnO and $SiO_2$. The content of Mn ranges from56.61wt.% to 68.69wt.%, and $SiO_2$ content ranges from 1.56wt.% to 10.45wt.%. The contents of Mo and Ba in Mn scale increased with increased depth; whereas, the content of Zn and Pb decreased with increased depth. Birnessite, quartz and feldspars were identified in Mn scales using x-ray powder diffraction studies. The IR absorption bands for Mn scales show major absorption band due to OH stretching, adsorbed molecular water, and birnessite stretching, respectively. In the SEM and EDS analysis, the Mn scale consists of botryoidal, spherical, spherulite, and empty straw structure. Those structure may be precipitated simply due to oversaturation with concentrated Mn content or may be formed through biogenic precipitation by Lepthothrix discophora. Under microanalysis using EDS on those structure surface of Mn scales, the Mn atomic percent range from 28 to 44, and such elements revealed the presence of Si, K, Na, Ca, Cl, Cu, Zn, and Ba.

• Journal of the Korean earth science society
• /
• v.35 no.4
• /
• pp.225-236
• /
• 2014

Multivariate statistical analyses have been extensively applied to hydrochemical measurements to analyze and interpret the data. This study examines anthropogenic factors obtained from applications of correspondence analysis (CA) and principal component analysis (PCA) to a hydrogeochemical data set. The goal was to synthesize the hydrogeochemical information using these multivariate statistical techniques by incorporating hydrogeochemical speciation results calculated by the program, commonly used, WATEQ4F included in the NETPATH. The selected case study was LPG underground storage caverns, which is located in the southeastern Korea. The highly alkaline groundwaters at this study area are an analogue for the repository system. High pH, speciation of Al and possible precipitation of calcite characterize these groundwaters. Available groundwater quality monitoring data were used to confirm these statistical models. The present study focused on understanding the hydrogeochemical attributes and establishing the changes of phase when two anthropogenic effects (i.e., disinfection activity and cement pore water) in the study area have been introduced. Comparisons made between two statistical results presented and the findings of previous investigations highlight the descriptive capabilities of PCA using calculated saturation index and CA as exploratory tools in hydrogeochemical research.

• Economic and Environmental Geology
• /
• v.35 no.6
• /
• pp.533-544
• /
• 2002

In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).

• Journal of Korea Water Resources Association
• /
• v.35 no.4 s.129
• /
• pp.425-442
• /
• 2002

The land reclamation area of Saemangeum(Kunsan) is located between $126^{\circ}10'\;E{\sim}126^{\circ}50'\;E\;and\;35^{\circ}35'\;N{\sim}36^{\circ}05'\;N$ at the western coast of the Korean peninsula. The reclamation area of Saemangeum has a range of 5.6m spring tide and the maximum tidal current speed is about $1.41m\;s^{-1}$. In ordinary spring tide. Most of the sediments deposited on the tidal flats are transported from the Geum river, the Mankyung river and the Dongjin river. The soil in this area consists of silty sand with the depth of 10m to 30m. The wind in winter is strong from the direction of northwest. Saemangeum coastal area is being constructed 33km the sea dike and 40,100ha reclamation area. The purpose of this study Is to find the residual circulations in four seasons before and after the dike construction by a robust diagnostic and prognostic numerical model.

• Economic and Environmental Geology
• /
• v.34 no.2
• /
• pp.227-241
• /
• 2001

Several $Co_2$-rich springs in the Chungcheong area, Le., the Angsung spring, the Chojung spring, the Myungam spring, the Bukang spring and the Daepyung spring have been long known for their particular water chemistry. The occurrences of these springs are closely related to the geologic structure of Mesozoic granite such as dyke swarms, fault zones and the geologic boundary between granite and its adjacent gneiss. The $Co_2$-rich water samples show a high $Co_2$ concentration ($P_{CO2}$ 0.25 atm to 0.99 atm), weak acidic pHs and the electrical conductivity ranging from 101 to 2,950 ${\mu}$S/cm. The $Co_2$-rich water samples are classified into the Ca-$HC0_3$ type and the Ca(Na)-$HCO_3$) type in chemical composition. Environmental isotopic data $^{2}H/^{1}H, ^{18}O/^{16}O$) indicated that $Co_2$-rich water was meteoric origin. The ${\delta}^{13}C$ values of $Co_2$-rich water range from -3.1$\textperthousand$ to -6.8$\textperthousand$ PDB. The values indicate that $H_2CO_3^0$ and $HC0_3^-$ of the water samples are mainly originated from a deep-seated source and partly contributed from carbonatc minerals. The major minerals determining the chemistry of $Co_2$-rich watcr arc probably the carbonate minerals which are present as veins and secondary minerals, and the plagiocalse in granite and gneiss.