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A Study on High Strength Nitrogen Wastewater Treatment and Sludge Granulation Characteristics in a Pilot-scale Air-lift Sequencing Batch Reactor (파일럿 규모의 공기 유동 연속회분반응기에서 고농도 질소제거 및 슬러지 그래뉼화 특성 연구)

  • Lee, Soochul;Kim, Dong-Jin
    • Clean Technology
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    • v.18 no.4
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    • pp.398-403
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    • 2012
  • Selective nitrification and granulation have been carried out in a pilot scale air-lift sequencing batch reactor (SBR) for stable and economical nitrogen removal from wastewater. The SBR showed about 100% nitrification efficiency up to 1.0 kg ${NH_4}^+-N/m^3{\cdot}d$, about 90% efficiency at 1.0-2.0 kg ${NH_4}^+-N/m^3{\cdot}d$, and it was less than 90% when the load was higher than 2.0 kg ${NH_4}^+-N/m^3{\cdot}d$. Nitrite accumulation was induced by selective inhibition of nitrite oxidizing bacteria by free ammonia inhibition and dissolved oxygen limitation. For the purpose, high nitrite ratio (> 0.95) was obtained by keeping the pH higher than 8.0 and dissolved oxygen lower than 1.5 mg/L. In addition, sludge granulation was achieved by keeping reactor settling time to 5 minutes to wash out poor settling sludge and to promote the growth of granulation sludge. The operation accelerated sludge granulation and the sludge volume index (SVI) decreased and stably maintained to less than 75 in 60 days.

Production of Concentrated Magnesium Solution from Seawater Using Industrial By-products (산업부산물을 이용한 해수로부터 고농도 마그네슘 용액의 제조)

  • Cho, Taeyeon;Kim, Myoung-Jin
    • Resources Recycling
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    • v.25 no.3
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    • pp.63-73
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    • 2016
  • With the purpose of concentrating the magnesium from seawater, in this study, we have conducted experiments to precipitate the magnesium using three precipitants (NaOH, cement kiln dust, and paper sludge ash), and then extract it using sulfuric acid. Results show that the precipitation and extraction performance does not depend so significantly on the kind of precipitant: for all the precipitants used, the precipitation efficiency is measured almost 100% and the extraction efficiency is in the short range of 77 - 89%. The magnesium concentration in the extract is measured 4975 - 5775 mg/L, implying that the magnesium in seawater should be 3.8 - 4.4 times concentrated through the precipitation and extraction reactions. The reaction efficiency of the industrial by-product used as a precipitant in this study is almost 100% similar to those of the other existing expensive precipitants.

환경관련 특허동향 - 약품 혼합조와 침전조 일체형 초고속침전 수처리 장치 및 이를 이용한 수처리 방법(녹스 코리아(주))

  • 한국환경기술인연합회
    • Environmental engineer
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    • s.325
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    • pp.86-93
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    • 2013
  • 본 발명은 약품 혼합조와 침전조 일체형 초고속침전 수처리 장치 및 이를 이용한 수처리 방법에 관한 것으로서, 일반적인 수처리 공정에서 필요한 각각의 다수의 단위 공정들을 단일 처리조 내에서 수행하게 함으로써 약품혼합, 응집반응, 침전, 슬러지 인출 및 처리수의 배수가 시간 간격을 두어 이루어지도록 하여 전체적인 유체의 체류시간이 줄여 최대 30분 이내의 초고속 수처리가 가능하도록 하는 효과를 갖는다. 또한, 약품 혼합조, 반응조 및 침전조를 별도로 구성하지 않고 단일 처리조로 시설을 컴팩트화하여 시설비 및 소요 부지를 줄일 수 있도록 함과 아울러 처리수의 수질을 SS(Suspended Solids) 기준으로 1ppm 이하로 만족시킴으로써 후단의 여과공정이 불필요하여 시설비를 절감할 수 있는 효과를 갖는다. 또한, pH 감지부에 별도의 pH 지시계 세척부를 설치하여 안정적으로 pH 감지가 이루어지도록 하여 약품 주입을 경제적이고 효율적으로 이루어질 수 있도록 하여 수처리에 따른 유지 및 관리 비용을 절감시킬 수 있도록 하는 효과를 갖는다.

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A Theoretical Relationship between Sludge Age and Sludge Recycle based on Mass Balances of Total Suspended Solids Contents in Conventional Activated Sludge Processes (활성슬러지 하수처리장의 주요 Process Control Variable인 Sludge Age와 Sludge Recycle의 상호관계 규명)

  • Ko, Kwang Baik;Choung, Youn Kyoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.1
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    • pp.69-75
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    • 1988
  • Two rational formulae depicting the relationships between sludge ages and recycle flow rates have been developed to determine sludge wasting volumes at a particular sludge age. A sensitivity analysis shows that the recycle ratio is the most important variable to be measured as accurately as possible in determining the sludge wasting volume to maintain a particular sludge age when the system is controlled by wasting recycled sludge. On the other hand, the final clarifier solids capturing capacity is the most important variable to be measured when the system is operated by wasting mixed liquor.

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Estimation on the Design Capacities of Residuals Treatment Facilities by the Quantity of Dewatered Sludge Generated from Water Treatment Plants (정수장에서 발생된 탈수슬러지의 량에 의한 배출수처리시설용량에 대한 평가)

  • Moon, Yong-Taik
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.6
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    • pp.715-723
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    • 2004
  • The quantity of residuals generated from water treatment plants depends upon the raw water quality, dosage of chemicals used, performance of the treatment process, method of sludge removal, efficiency of sedimentation, and backwashing frequency. Sludge production by the physical separation of SS occurs under quiescent conditions in the primary clarifier, where suspended solids are allowed to settle and to consolidate on the clarifier bottom. Raw primary sludge results when the settled solids are hydraulically removed from the tank. The relative solid and liquid fractions of a slurry are most commonly described by the solids concentration, expressed as mg/L or percent solids. The purpose of the present investigation is to estimate a suitability on the design capacities of residuals treatment facilities by the quantity of dewatered sludge generated from water treatment plants.

The Effect of Column Height on Sludge-Water Interface Height Change Model (슬러지계면층높이변화모델에서 컬럼높이에 대한 영향)

  • Park, Suk Gyun;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.2
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    • pp.265-272
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    • 2006
  • While sludge settles down in a column, sludge settling characteristic is influenced by effect parameters, interparticle force, wall effect etc. As the height of a column changes, the settling velocity of sludge-water interface changes, too. At lower sludge concentration, particular effect was not observed by the difference of column height, however it was observed that settleability of sludge was greatly influenced by column height when sludge settling was poor or sludge concentration was high. It is therefore required to consider the effect of column height when the power model for sludge interface settling is established. In the tests, there was hardly any $SVI_{ts}$(SVI after "t" minutes) difference in each column after 10min at $1.5kg/m^3$ of sludge concentration. When sludge concentration was at $2.5kg/m^3$, $SVI_{ts}$ tended to be constant after 20min. At $3.5kg/m^3$, $SVI_{ts}$ increased to 30minuets. The purpose of this work is to establish the correction factor that is able to compensate the errors derived from each different height of column.

Ceramic Membrane Application for the Bayer Process of Aluminium hydroxide Production (수산화알루미늄 제조 Bayer 공정에서 Ceramic membrane 여과 실용화 공정 개발)

  • 김정학;이성오;구자경;남승하;이시철
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.11a
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    • pp.146-148
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    • 2003
  • Bayer 공정은 가성소다를 이용하여 보오크사이트로부터 수산화알루미늄을 추출하는 공정이다. 그러나 보오크사이트 추출 후 1차 침전공정에서 반응한 보오크사이트 잔사는 침전시킴으로써 깨끗한 공정액을 분리하는 데 이때 침전되지 못한 다량의 분산성 고형물이 공정액 중에 존재하게 되는데 이를 분산성 보오크사이트(레드머드) 미립자라하며 보통 80-100mg/$\ell$의 농도를 나타낸다. 그러므로 이를 제거하기 위해 다음 공정인 입상여과필터 공정을 사용하는데 이때 필터링 효율증대를 위해 보조제로써 다량의 소석회(Ca(OH)$_2$)를 투여하여 공정액 중의 고형물을 농도를 8-100mg/$\ell$에서 5mg/$\ell$로 낮추는 공정을 사용하고 있다. 특히 국내 수산화알루미능 제조회사일 KC(주)의 경우 소석회 사용량이 일 10톤, 년간 약 3,600톤을 사용함으로써 소석회의 사용량에 따라 같은 량의 슬러지가 발생되게 된다. 따라서 여과후 발생되는 슬러지의 처리비용 문제(연간 9천만원)와 소석회의 미립자에 의한 공정액의 2차 오염과 제품 품질 저하(quality claim) 및 소석회 사용량에 따른 연간 원료비(연간 3억원) 등의 상당한 문제점을 나타내고 있는 실정이다. 아울러 최근 고품위 수산화알루미늄의 공급 요구에 따라 여과시 정제기준이 점차 낮아져 이제는 1mg/$\ell$ 이하를 유지하여야 하는 근본적인 문제에 봉착해있는 실정이다. 그러므로 본 연구에서는 소석회를 사용하는 입상여과법을 대체하기 위한 신공정개발을 추진하였으며, 그동안 카트리지여과법 등의 다양한 실험 결과로부터 최근 필터 보조제를 첨가하지 않는 물리적 여과방법인 세라믹 막 여과법의 적용 가능성을 확인하고 친환경공정인 세라믹 막 여과 실용화 공정 기술을 개발하였다. 세라믹 막 여과 법은 여과 보조제를 사용하지 않으므로 2차적인 슬러지 발생등의 환경문제를 발생하지 않으며, 공정액에 첨가제를 투입하지 않으므로 순환형 친환경공정으로 각광받을 수 있다. 본 연구에서는 고온, 고농도의 NaOH 수용액의 처리에 적합한 막소재와 발생될 수 있는 제반 문제점 등을 파악하였고, 장기간의 실험을 거쳐 최적 투과 압력(Trans membrane pressue), 세정 조건 및 주기, 막재질에 있어서 보강하여야 할 Point, 최적 운전 조건들을 토출해 내었고, 향후 실제 Plant에 적용할 계획이다.

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Recovery of Presource from Sewage Sludge by a Struvite-forming Method (Struvite 결정화를 이용한 하수슬러지내의 인 자원 회수에 관한 연구)

  • Choi, Won-Joon;Park, Kyu-Man;Yoon, Bae-Geun;Kim, Min-Chul;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.557-564
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    • 2009
  • The objective of this study is to efficiently recover phosphorus contained in sewage sludge by a struvite-forming method. The performances were evaluated under various operating conditions(elution with the kind of acid, Mg-compound and temperature) in order to reach the optimum conditions of struvite-forming. As a result, as an elution solution, the elution efficiency of $H_2SO_4$ was 2.65 times higher than that of HCl. Also, the precipitation efficiency of struvite was the highest (97.4%) in case of using $MgCl_2{\cdot}6H_2O$ as Mg-compounds at $25^{\circ}C$. However, the side reaction by Fe, Al and Zn appeared in process of phosphorus recovery. To solve some problems caused by side reacton, large quantities of co-precipitation materials produced by side reaction were removed by precipitating phosphorus compounds in pH 7. Consequently, the recovery efficiency of phosphorus by a struviteforming method was 82.99%, and purity of the recovered struvite product was high.