• Proceedings of the KAIS Fall Conference
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• 2008.11a
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• pp.93-96
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• 2008

500나노 입자 및 기본 물성이 우수한 이중층상구조금속수화물(LDH)를 합성하고 PVC 수지에 적용하여 고온, 저온열안정성 및 가공특성으로 인장강도, 신율, 체적저항 등이 우수한 시제품을 합성한 후 개발한 이중층상구조금속수화물(LDH) 시제품을 사용하여 무독성안정제(금속석검계), 내외부활제류, 가공조제, 산화방지제 등 기타 첨가제 등을 사용하여 PVC수지에 적용하여 수지배합에 따른 시험편을 제작하여 배합비별로 고온, 및 저온열안정성, 체적고유저항, 가공성(인장강도, 신율 등), 내후성, 초기 착색성 등 물성, 기계적 가공특성 및 성능이 우수한 할로겐수지용 무독성배합을 개발한다. 최종적으로 개발한 이중층상구조금속수화물(LDH)을 사용하여 제조하여 PVC 수지의 열안정성 및 기계적 가공특성이 우수한 중금속계대체용 무독성복합열안정제를 개발하였다.

• The Journal of the Acoustical Society of Korea
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• v.17 no.4
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• pp.30-37
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• 1998

본 논문은 중공형 층상 복합체 멘드릴(mandrel)을 이용하여 기본 공진주파수가 15kHz이상이고, 우수한 감도 특성을 지닌 광섬유 하이드로폰의 최적 구조를 설계하는 것에 관한 것이다. 유한요소법을 이용하여 Al/foraming 및 Nylon/foaming층상 복합체의 공지주 파수를 분석하여 설계 변수의 범위를 결정하였고, 멘드릴 형상에 따른 광음향 감도 특성을 분석하여 최적구조를 결정하였다. 그 결과로 멘드릴의 외경이 감소할수록, 길이가 증가할수 록 감도가 향상되었다. AL 멘드릴의 경우, 내경/외경 비가 낮을수록, Nylon멘드릴의 경우 내경/외경 비가 높을수록 감도 증가를 위하여 효율적이다. 그리고 결정된 최적구조의 Al/foaming 및 Nylon/foaming멘드릴을 사용한 광섬유 하이드로폰의 감도는 각각 1rad./Pa 대비 약 82dB 및 85.7dB 정도 이었고, Al층상 복합체 보다는 Nylon층상 복합체를 이용하는 것이 고 감도의 광섬유 하이드로폰을 제조하는데 유리함을 알 수 있었다.

• Composites Research
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• v.13 no.6
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• pp.23-29
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• 2000

The internal residual stresses within the multilayered structure with sharp interface induced by the difference in thermal expansion coefficient between the materials of adjacent layers often provide the source of failure such as delamination of interfaces etc. Recent development of the multilayered structure with functionally graded interface would be the solution to prevent this kind of failure. However a systematic thermo-mechanical analysis is needed for the customized structural design of multilayered structure. In this study, theoretical model for the thermo-mechanical analysis is developed for multilayered structures of the $Al-SiC_p$ functionally graded composite for electronic packaging. The evolution of curvature and internal stresses in response to temperature variations is presented for the different combinations of geometry. The resultant analytical solutions are used for the optimal design of the multilayered structures with functionally graded interface as well as with sharp interface.

• Polymer(Korea)
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• v.30 no.1
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• pp.56-63
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• 2006

We have synthesized two types of diamine monomers containing various chain length to prepare polyimides with layered structure. By using these diamines, homo-polyimides and co-polyimides having hydrophobic and hydrophilic segment of flexible side chain were synthesized. The segregated layered structures were formed by repulsive force with main chain as the side chains reach a critical length because the rigid main chains are packed into layered structure with the flexible side chains occupying the space between layers. As a result, the gallery space of each homo-polyimide was increased at spacing of $32.7\~48{\AA}\;or\;7\~10.5{\AA}$ as the increased hydrophobic or hydrophilic side chain length through X-ray diffraction. The gallery space of co-polyimides was also showed similar phenomenon by repulsive force of side chains with different properties. We have also confirmed that gallery space and molar volume were significantly depended on length of flexible side chain via molecular modeling.

• Economic and Environmental Geology
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• v.50 no.5
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• pp.375-387
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• 2017

Amphibolite-hosted Fe-Ti mineralization at the Soyeonpyeong Island, located in central western part of the Korean Peninsula is a typical orthomagmatic Fe-Ti oxide deposit in South Korea. The amphibolite intruded into NW-SE trending Precambrian metasedimentary rocks. Lower amphibolite is characterized by igneous layering, consisting of feldspar-dominant and amphibole-Fe-Ti oxide-dominant layers. The igneous layering shows complicated and/or sharp contact. In contrast, upper amphibolite has a more complicated lithofacies (garnet-bearing, coarser, and schistose), and massive Fe-Ti oxide ore alternates with schistose amphibolite. NS- and EW-trending fault systems lead to redistribute upper amphibolite-hosted Fe-Ti orebody and igneous layering of lower amphibolite, respectively. The whole-rock compositions of amphibolite and Fe-Ti oxide ore reflect their constituent minerals. Amphibolite shows significantly positive Eu anomalies whereas Fe-Ti oxide ore has weak negative Eu anomalies. Plagioclase (Andesine to oligoclase) and Fe-Ti oxide minerals have constant composition regardless of their distribution. Amphibole has a compositionally variable but it doesn't reflect the chemical evolution. Mineral compositions within individual layers and successive layers are relatively constant not showing any stratigraphic evolution. This suggests that there are no successive injections of Fe-rich magma or assimilation with Fe-rich country rocks. Contrasting Eu anomalies between amphibolite and Fe-Ti oxide ore also suggest that extensive plagioclase fractionation during early crystallization stage cause increase in $Fe_2O_3/FeO$ ratio and overall Fe contents in the residual magma. Thus, Fe-rich residual liquids may migrate at the upper amphibolite by filter pressing mechanism and then produce sheeted massive Fe-Ti mineralization during late fractional crystallization.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.3
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• pp.431-434
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• 1998

Layered basic copper acetate, $Cu(OH)(CH_3COO){cdot}H_2O$ was synthesized. Intercalation compounds of alkyl sulfonates into layered basic copper acetate have been synthesized via anionic exchange. From the X-ray diffraction data and the alkyl sulfonate size, the orientation of the intercalated alkyl sulfonate into layered basic copper acetate was determined.

• Ceramist
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• v.20 no.2
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• pp.25-33
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• 2017

• Electrical & Electronic Materials
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• v.16 no.3
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• pp.12-21
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• 2003

• Electrical & Electronic Materials
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• v.20 no.3
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• pp.9-21
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• 2007

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.1283_1284
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• 2009

본 연구는 에폭시-층상실리케이트 나노콤포지트 분산을 위해 여러 분산기법을 적용한 경우이다. 층상실리케이트는 층상과 층상사이로 고분자체인의 삽입으로 층과 층사이가 팽창되어 지는 특성을 갖고 있다. 층상실리케이트 나노콤포지트가 완전한 박리가 일어나게 되면 전반적인 물성의 향상이 동반 상승되는 특성을 갖고 있다. 이런 이유로 homogenizer를 이용한 분산특성실험에서는 삽입되는 정도만을 확인할수있었고, 최적 시간/속도특성을 구할수 있었다. 또한 초음파 분산법으로 나노콤포지트가 박리가 일어나는 경우 존재하였고, 그 조건에 대한 최적특성을 구할 수 있었다.