• Title/Summary/Keyword: 충진

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Conversion of CO2 and CH4 through Hybrid Reactor Composed of Plasma and Catalyst at Atmospheric Pressure (상압 플라즈마-촉매 하이브리드 반응기를 통한 CO2와 CH4의 전환처리)

  • Kim, Tae Kyung;Nguyen, Duc Ba;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.497-502
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    • 2014
  • The conversion reaction of methane and carbon dioxide at an atmospheric pressure plasma reactor filled with Ni-$Al_2O_3$ and Ni-$MgAl_2O_4$ catalyst was performed. Effects of various process parameters such as the applied electric power, reaction gas flow rate, reactor temperature, mixing ratio of reactants and the presence of the catalyst on the reaction between methane and carbon dioxide were analyzed. From the analysis of the contribution of the catalyst in the reaction step, even if the temperature raised to $400^{\circ}C$, there was no spontaneous catalytic conversion of methane and carbon dioxide without plasma discharges. When the catalysts for the conversion of methane and carbon dioxide would be adopted to the plasma reactor, the careful selection of suitable catalysts and process parameters should be essential.

Electrical characteristics for Multi-Nanocomposites throuh Surface Control of Epoxy/Nano_Micro $SiO_2$ Particles (Epoxy/Nano_Micro $SiO_2$입자 표면제어를 통한 멀티-나노콤포지트 전기적 특성연구)

  • Park, Young-Byum;Park, Hyun-Su;O, Chung-Yon;Kim, Hak-Jae;Park, Ki-Ryung;Lee, Dae-Kyoung;Park, Jae-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.154-154
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    • 2009
  • 본 연구는 고전압 전력기기인 몰드형변압기와 계기용 변성기인 CT, PT 절연특성에 유용한 Epoxy/Nano-Micro Mixture Composites(이하,ENMMC)를 개발하기위해 무엇보다 중요한 것은 Nano입자인 $SiO_2$_10nm입자의 표면을 제어하여 즉, 표면의 소수성을 크게 하여 나노입자의 균질한 분산을 얻은것이 무엇보다 중요하다. 개발된 Epoxy/$SiO_2$_10nm Nanocomposites와 Microcomposites을 기계적 전단응력을 이용하여 균질 혼합을 실시하였다. 이런 조건을 이용한 전기적특성을 측정하기위해 구대구 전극이 완전함침된 평등전계하에서 절연파괴전압을 측정하기 시편을 제조하였다. 마이크로입자의 충진함량을 일정하게 유지하여 나노입자 충진함량비율을 4가지로 변화시켜 절연파괴특성을 연구하였다. 충진함량이 나노입자의 경우 1wt%이하의 값이 상대적으로 우수한 절연파괴특성으로 와이블 플롯을 통하여 알수있었다. 상대적으로 멀티나노콤포지트의 형상파라미터가 큰 결과값을 얻을수 있었다. 그리고 스케일파리미터는 누적확률 밀도함수로서 63.2%에서 대단히 큰 초절연성의 절연소재를 개발할수 있었다.

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Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.648-652
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    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.