• Journal of Korean Society on Water Environment
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• v.33 no.1
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• pp.1-7
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• 2017

Bioretention systems, an advance low impact development and green infrastructure approach were currently utilized in different parts of the world because it promotes biodiversity thereby mimicking and preserving the pre-developed state of an area. This study investigated and compared the capability of four bioretention systems to identify factors affecting the hydraulic capabilities and pollutant removal efficiencies of each system. The two bioretention type A referred as Type A-C and Type A-FC were planted with perennials such as Chrysanthemum and Fan columbine, respectively. On the other hand, the two type B bioretention systems referred as Type B-A and Type B-JM were planted with shrub plant species such as Azalea and Japanese Meadowsweet, respectively. Based on the results, TV, infiltration mechanism, filter media depth and plant species were identified as the factors affecting the difference in flow attenuation, retained volume and pollutant removal efficiency of Type A-C, Type A-FC, Type B-A and Type B-JM bioretention systems. The design of bioretention Type B-A and Type B-JM were advantageous considering greater volume retention, groundwater recharge, longer HRT and peak flow attenuation and greater pollutant removal efficiency. On the other hand, the design of bioretention Type A-C and Type A-FC was more appropriate for design considering reduced groundwater contamination.

• Journal of Korean Society on Water Environment
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• v.33 no.6
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• pp.715-721
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• 2017

Tree box filters, an example of bioretention systems, were compacted and versatile urban stormwater low impact development technique which allowed volume and water quality treatment performance to be adjusted based on the hydrologic, runoff quality and catchment characteristics. In this study, the overall performance of a 6 year-old tree box filter receiving parking lot stormwater runoff was evaluated. Hydrologic and hydraulic factors affecting the treatment performance of the tree box filter were also identified and investigated. Based on the results, the increase in rainfall depth caused a decrease in hydrologic and hydraulic performance of the tree box filter including volume, average flow, and peak flow reduction (r = -0.53 to -0.59; p<0.01). TSS, organics, nutrients, and total and soluble heavy metals constituents were significantly reduced by the system through media filtration, adsorption, infiltration, and evapotranspiration mechanisms employed in the tree box filter (p<0.001). This significant pollutant reduction by the tree box filter was also found to have been caused by hydrologic and hydraulic factors including volume, average flow, peak flow, hydraulic retention time (HRT) and runoff duration. These findings were especially useful in applying similarly designed tree box filter by considering tree box filter surface area to catchment area of less than 1 %.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.4
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• pp.439-446
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• 2009

This study was performed to evaluate SND(simultaneous nitrification and denitrification)efficiency, nitrogen removal efficiency and filtration function of non-woven fabric by using submerging MBR packed with granular sulfur covered with non-woven fabric filter. Synthetic wastewater was used as influent wastewater. Concentration of $NH_4{^+}-N$ in influent was maintained about 40 mg/L and the experiment was performed in four phases according to the flow rate. Nitrogen loading rate divided four phases ranging from $0.04 kg\;NH_4{^+}-N/m^3-day$ to $0.16 kg\;NH_4{^+}-N/m^3-day$. As a result, the maximum $NH_4{^+}-N$ removal rate was accomplished at $0.142 kg\;NH_4{^+}-N/m^3-day$ in nitrogen loading of $0.147 kg\;NH_4{^+}-N/m^3-day$. Nitrification efficiency was higher than 95% in all phases. $NO_3{^-}-N$ loading rate was adjusted ranging from $0.22 kg\;NO_3{^-}-N/m^3-day$ to $0.89 kg\;NO_3{^-}-N/m^3-day$. The maximum $NO_3{^-}-N$ removal rate was accomplished up to $0.71 kg\;NO_3{^-}-N/m^3-day$ in $NO_3{^-}-N$ loading of $0.89 kg\;NO_3{^-}-N/m^3-day$. The maximum $NO_3{^-}-N$ removal efficiency was 95% in $NO_3{^-}-N$ loading of $0.22 kg\;NO_3{^-}-N/m^3-day$. T-N removal rate was 90% and concentration of T-N in effluent was 3.7 mg/L in T-N loading rate of $0.039 kg\;NO_3{^-}-N/m^3-day$. In this study, TMP in reactor with and without non-woven fabric filter were observed to define fouling of hollow-fiber membrane module. Reaching time to standard washing pressure(22 cm Hg) of two reactors were 29 days with non-woven fabric But the reactor without non-woven fabric reached standard washing pressure only after 4 days. Accordingly, non-woven fabric was demonstrated the superiority as a filtration ability. With high nitrogen removal rate and decreasing of fouling of membrane, MBR packed with granular sulfur covered with non-woven fabric filter submerging in activated sludge aeration tank can be used as an advanced treatment process.

• Journal of the Korean Wood Science and Technology
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• v.37 no.1
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• pp.105-113
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• 2009

The freezed Mulberry (10 kg) was extracted with 80% EtOH, concentrated, and fractionated with a series of n-hexane, ethyl acetate, and water on a separatory funnel. A portion of ethyl acetate soluble (22 g) was chromatographed on a Sephadex LH-20 column using a series of aqueous methanol as eluents. The isolated compounds were identified by cellulose TLC, $^1H-$,$^{13}C$-NMR, FAB, and EI-MS. Quercetin-3-O-${\beta}$-D-glucopyranoside (Compound I), protocatechuic acid (Compound II), p-hydroxybenzoic acid (Compound III) were isolated from the ethyl acetate soluble fraction. In antioxidative activities of the fractionated extractives using DPPH radical scavenging test, EtOAc and water soluble fractions indicated better than BHT as contro and in in vitro tests using MTT assay, there was no cytotoxicity. Also, tyrosinase inhibition and anticancer activities were not so good, but there may be a potential as a cosmetic raw material because the cell extension effect was excellent.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.135-144
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• 2007

The dried barks of Maackia amurensis were ground, extracted with 95% EtOH, concentrated, and fractionated with a series of light petroleum ether, dichloromethane, ethyl acetate and water on a separatory funnel. Each fraction was concentrated, then a portion of dichloromethane and ethyl acetate soluble was chromatographed on a Sephadex LH-20 and silica gel 60 column using a various solvent system as eluents. The isolated compounds were identified by cellulose TLC, $^1H-$, $^{13}C-NMR$, COSY, NOESY, HMQC, HMBC, FAB and EI-MS. The structures were determined as: 7-O-$\beta$-D-glucopyranosyl-4'-methoxyisoflavone, 7-O-$\beta$-glucopyranosyl(1'''->6'')-$\beta$-D-glucopyranosyl-4'-methoxyisoflavone, 7-O-$\beta$-D-glucopyranosyl(1''''->6''')-$\beta$-D-glucopyranosyl(1'''->6'')-$\beta$-D-glucopyransoyl-4'-methoxyisoflavone, 7-O-$\beta$-D-glucopyranosyl-4', 6-dimethoxyisoflavone. The Free radical scavenging activity using DPPH of the isolated compounds were similar with that of BHT but lower than of $\alpha$-tocopherol.

• Journal of Mushroom
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• v.12 no.1
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• pp.17-23
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• 2014

pH of oriental medicine sludge was 5.3, which was similar to 5.2 of the main ingredient, corncob. Its sugar content, however, was 4.8 mg/g, which was 2.5 times higher than concorb's 1.9 mg/g. According to the addition content analysis of oriental medicine sludge by using blood agar plate, the experimental group showed much more robust growth than the control group. 10% of oriental medicine sludge was added to corncob and pine tree sawdust for test-tube culture. Then they were cultivated at $25^{\circ}C$ for 6 days after inoculating Flammulina velutipes liquid spawn. The control group and experimental group showed 2.2~3.4 and 5.8~6.4 cm hypae growths respectively. At the field test for 10% herbal medicine refuse, mushroom yield dropped by 5% compared to the control group. However, it had distinctively lower number of deformity and the 2nd grade products. An economic analysis was conducted based on the cultivation facility that produces 160,000 mushrooms per day. The analysis demonstrated that the facility can save 50,000,000 won in the starting year and 130,000,000 won in the following years from the unit cost of production excluding labour and operation cost.

• Journal of the Mineralogical Society of Korea
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• v.18 no.2
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• pp.135-144
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• 2005

In the high-Ca limestone zone of the Pungchon Formation of the Lower Chosun Supergroup, cryptocrystalline alterations with reddish brown color occur as fissure-fillings or coatings, which was originated from the upper formation, i. e., the Hwajeol Formation. The precipitates result in degradation and contamination of the high-Ca limestone ore in grade and quality, showing characteristic occurrence and mineral composition typical of suggesting a supergene origin. Chalcedonic quartz, kaolinite, illite, goethite and hematite are constituting a characteristic authigenic mineral assemblage and, in places, smectite is less commonly included in the weathering product. In addition to these authigenic phases, some detrital minerals such as mica and orthoclase constituting relatively coarser grains are also rarely present in the supergene alterations. A rather complex clay facies consisting of kaolinite, illite and smectite in the alterations seems to correspond to the typical clay composition of the reported residual pedogenic soils by limestone weathering. The cryptocrystalline weathering product is partly altered to stilbite, a characteristic hydrothermal zeolite, in places, by the hydrothermal contact of late stage. The time of formation and infiltration of the supergene alterations seems to correspond to the stage just after the epithermal alteration of the Pungchon Limestone, i. e., an early Jurassic age. The supergene alteration, which may imply the stage of uplifting, weathering and erosion of the Chosun Supergroup, appears to have undergone at an oxygen-rich environment in descending water of meteoric origin by means of a chemical leaching and diffusion.

• Analytical Science and Technology
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• v.14 no.3
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• pp.274-285
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• 2001

In this study, the thermal desorption-cryofocusing-gas chromatographic(TD-C-GC) method was developed for determination of volatile organic compounds(VOCs) in ambient air and was applied at the municipal solid waste landfill sites. On-column cryofocusing was possible only with a 100 ml dewars bottle in TD-C-GC method with a stainless steel column. However, high operating pressure was needed for purging VOCs from the absorbent trap, which was able to solve by pressure programming with a electric pressure controller. By using both pressure and temperature programming brought increasing of resolution power in on-column cryofocusing method, but the high pressure caused a leakage of sample tube with repeated use. A loop cryofocusing devise was also developed and compared with the direct on-column method. In loop cryofocusing method, VOCs were concentrated on a 0.8mm i.d. loop which is located between the injector and separation column by using liquid nitrogen. In order to purge VOCs from the absorbent trap, only 0.4 psi of pressure was need in the loop cryofocusing method. Dual detection system was applied for the analysis of VOCs; a FID was used for hydrocarbons and a FPD was used for sulfur-containing compounds. Qualitative analysis was done by on-column cryofocusing GC-MS system. Among the large number of VOCs, toluene was the most abundant. Hydrogen sulfide, dimethyl sulfide, carbon disulfide, dimethyl disulfide and methyl propyl disulfide were detected at landfill site by FPD.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.6 no.4
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• pp.297-306
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• 2008

This study was carried out to identify the characteristics of hydrochemistry controlling groundwater chemical condition in a repository site of Gyeongju. For this study, 12 bore holes of all monitoring bore holes in the study area were selected and total 46 groundwater samples were collected with depth. In addition, 3 surfacewater samples and 1 seawater sample were collected. For water samples, cations and anions were analyzed. The environmental isotopes(${\delta}^{18}O-{\delta}D$, Tritium, ${\delta}^{13}C,\;{\cdot}{\delta}^{34}S$) were also analyzed to trace the origin of water and solutes. The result of ${\delta}^{18}O\;and\;{\delta}D$ analysis showed that surface water and groundwater were originated from precipitation. Tritium concentrations of groundwater decreased with depth but high concentrations of tritium indicated that groundwater was recharged recently. The results of ion and correlation analysis showed that groundwater types of the study area were represented by Ca-Na-$HCO_3$ and Na-Cl-$SO_4$, which was caused by sea spray and water-rock interaction. Especially, high ratio of Na content in groundwater resulted from ion exchange. For redox condition of groundwater, the values of DO and Eh decreased with depth, which indicated that reducing condition was formed in deeper groundwater. In addtion, high concentration of Fe and Mn showed that redox condition of groundwater was controlled by the reduction of Fe and Mn oxides.

• Economic and Environmental Geology
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• v.22 no.3
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• pp.253-266
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• 1989

The Cu-Pb-Zn-Ag hydrothermal vein type deposits which comprise the Dongil and Dong-cheogogsan mines occur within the Cretaceous sedimentary rocks in the Euiseong Basin of the southern Korean peninsula. The ore mineralization is contained within three stage(I,II and III) quartz and calcite veins. Ore minerals occur as dominant chalcopyrite, galena, sphalerite, tetrahedrite and Pb, Ag, Sb and Bi-bearing sulfosalts. Stage I ore minerals were deposited between $400^{\circ}C$ and $200^{\circ}C$ from the fluid with moderate salinities(7.0 to 4.5 eq. wt. % NaCl). Evidence of boiling suggests pressure of less than 150 bars during stage I mineralization. This pressure corresponds to maximum depths of 650 m and 1700 m, respectively, assuming lithostatic and hydrostatic loads. The data on mineralogy, temperature and salinity, together with information on the solubility of Cu complex, suggest that Cu deposition is a result of boiling coupled with declining temperature from $350^{\circ}$ to $250^{\circ}C$ or declining log $a_{o_2}$(from -29.8 to -35.9 atm.)and increasing in pH. Pb, Ag, Sb and Bi-bearing sulfosalts were deposited by cooling and dilution at temperature of less than $250^{\circ}C$ from the ore fluid with less than -35.9 atm. of log $a_{o_2}$.