• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.296-296
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• 2008

국내 절토비탈면은 이상 기후 및 건설공사의 증대로 인해 증가하고 있는 추세이며 장마철 및 태풍으로 인해 비탈면의 붕괴로 많은 인명 및 재산피해가 발생되고 있는 실정이다. 국내에서 사용되고 있는 기존의 비탈면의 설계기준은 암반의 불연속면에 대한 조사를 실시하고는 있지만 주로 암반의 굴착난이도를 토층, 리핑암, 발파암으로 구분하여 각각의 비탈면 절취경사를 결정하여 사용하는 방법을 사용하였으며 이러한 기준은 단순히 암석의 강도를 기준으로 설정되어 있으므로 암석의 공학적 특성 즉, 암반내 불연속면 방향성, 연속성, 충진물질, 마찰각, 풍화속도 등의 영향으로 공용후 비탈면 구배의 재조정 및 보강이 빈번하다. 국내외 절토비탈면의 설계기준은 각 기관별로 산재되어 있었으며 비탈면에 대한 설계 및 시공 등에 관한 기준은 도로와 철도 설계기준에 일부 반영되어 있을 뿐 항만, 댐, 택지조성 등 기타 시설 설계기준에는 비탈면에 대한 기준이 마련되어 있지 않아 표준적인 비탈면 설계기준 및 유지관리지침이 등이 필요하였다. 이러한 문제점을 보완하기 위해 2004년부터 2006까지 한국시설안전공단, 한국도로공사, 대한주택공사가 협동으로 연구한 건설공사 비탈면 설계 시공 및 유지관리에 관한 연구의 결과로 2006년도에 "건설공사 비탈면 설계기준"이 수립되었다. 이 설계기준은 건설공사에서의 기존 상이한 기준들을 정리하고 동일화하는 작업을 수행하였으며 지반의 조사에서부터 대책공까지를 막나하여 정리하였다. 그러나 최근에 급격한 기후변화로 인한 비탈면붕괴 빈번함에 따라 과거 적용되어 왔던 이들 기준을 적용하는 경우, 특히 상부 토층 및 풍화암 구간에서 많은 설계안전율을 만족하지 못해 많은 보강을 수반해야 하는 문제가 발생되고 있어 그 원인에 대한 분석을 수행하고자 하였다. 2006년도 정리된 기준은 과거에 적용하여 온 유기시의 안전율 조건을 Fs > 1.1~1.2을 적용하였던 것을 Fs > 1.2로 통일하였으며 지하수위 조건은 지표면에 위치하도록 하였다. 지하수위 조건은 풍화암 및 토층의 경우, 과거 지표면에 -3m를 적용한 시기가 있었으나 지표면에 지하수위를 적용하는 것이 일반적인 해석방법이다. 이러한 결과의 원인을 검토해 보면 다음과 같다. 첫째, 풍화암 및 토층에 적용되어 온 지반강도 정수가 과거 적용한 값보다 최근에는 작아지는 경향을 보이고 있다. 둘째, 지하수위 적용문제로 현재 지표면에 지하수위를 두어 안전율을 감소시키는 문제로 이는 최근 들어 많은 연구기관에서 강우시 간극수압의 증가에 대한 연구가 활발하게 진행되고 있다. 그러나 침투수 해석은 현행 기준에도 강우의 침투를 고려한 해석을 실시하는 경우 FS > 1.3 적용하는 것으로 되어 있으나 대부분의 해석에서는 적용이 되지 못하고 있는 실정이다. 셋째, 안전율이 과거에 주로 적용된 Fs > 1.1에서 Fs > 1.2로 상향 조정되어 우기시의 설계안전율 만족시키지 못하는 문제이다. 그러므로 이러한 문제점을 개선하기 위한 검토가 필요하며 장기적으로 이에 대한 합리적인 기준을 개정하는 작업이 추후에 수행되어야 할 것으로 판단된다.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.310-316
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• 2012

The chromaticity of polyethylene glycol (PEG) generated from the recyling of a silicone slurry waste was improved by using activated carbon powder and a carbon filter. The color change of the PEG waste was investigated by changing the amount of adsorbent, adsorption time and temperature. The surface area of activated carbon did not have a significant impact on improving the color of the PEG waste. According to the results for the APHA color variation of the PEG waste changing the amount of the carbon adsorbent, the optimal usage to achieve the low APHA value was 100~150 mg-C/g-PEG. From the investigatnion on the effect of the adsorption temperature range from $25^{\circ}C$ to $100^{\circ}C$, it was found that the optimal temperatures were $40{\sim}50^{\circ}C$ in terms of achieving the lowest APHA value. The variation of the APHA color was investigated by changing the operation condition of the activated carbon filters. The use of ACF was a good way to enhance the chromaticity of the PEG waste. As a result, the APHA value of the PEG waste (APHA=53 at the initial waste) was reduced to be 10 through the ACF purification. It was also confirmed that the performance of the used carbon adsorbent can be recovered by the washing with purified water.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.357-363
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• 2015

The development of the environment-friendly tire that meets the standard requirements according to tire labeling system can be improved through using highly homogeneous silica immobilized zinc oxide nanoparticles. In this study, a considerable amount of nanoporous silica was essentially added into nano zinc oxide to improve the physiochemical properties of the formed composite. The introduction of nanoporous silica materials in the composite facilitates the improvement of the wear-resistance and increases the elasticity of the tread. Therefore, the introduction of nanoporous silica can replace carbon black as filler in the formation of composites with desirable properties for conventional green tire. Herein, mesoporous silica immobilized zinc oxide nanoparticle with desirable properties for rubber compounds was investigated. Composites with homogeneous dispersion were obtained in the absence of dispersants. The dispersion stability was controlled through varying the molar ratio, ageing time and mixing order of the reactants. A superior dispersion was achieved in the sample obtained using 0.03 mol of zinc precursor as it had the smallest grain size (50.5 nm) and then immobilized in silica aged for 10 days. Moreover, the specific surface area of this sample was the highest ($649m^2/g$).

• Clean Technology
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• v.24 no.1
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• pp.50-54
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• 2018

In this work, N-methyl-2-pyrrolidone (NMP) was added into diethylenetriamine (DETA) aqueous solution for high $CO_2$ loading via phase splitting of absorbents during $CO_2$ absorption. Immiscible two phases were formed in the range of more than 30 wt% of NMP in 2 M DETA + NMP + water absorbents because of low solubility of DETA-carbamate in NMP solution. As the composition of NMP in the absorbents increased, the difference of $CO_2$ loading between each phase increased and the volume of bottom phase decreased. In $CO_2$ absorption in packed column by 2 M DETA + NMP + water absorbents, the absorption rate decreased in the range of more than 40 wt% of NMP. It is due to the increasing of mass transfer resistance in liquid film of absorbents at the high concentration of NMP. DETA + NMP + water absorbent is expected as the promising one for reducing the regeneration energy of absorbents according to volume reduction of $CO_2-rich$ phase.

• The Korean Journal of Mycology
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• v.44 no.3
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• pp.150-154
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• 2016

To determine a favorable substrate formulation for Grifola frondosa, physicochemical conditions, culture properties, and yields according to various substrate formulations were investigated. Based on these analyses, T4 (80:5:15 ratio of oak sawdust to dried bean-curd refuse to corn husk) resulted in a shorter cultivation period and higher yields (weight of fresh mushrooms harvested at maturity) than those of other treatments. The physicochemical properties of T4 were pH 5.4, 2.4% crude fat contents, 54 C/N ratio, 74.3% porosity, and 0.26 g/cm3 bulk density. These results emphasize the importance of optimal substrate development on the production efficiency of G. frondosa mushrooms and have implications for commercial applications.

• Journal of Navigation and Port Research
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• v.39 no.4
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• pp.345-351
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• 2015

This study investigated the optimum depth for the application of bioremediation in contaminated coastal sediment using a lab scale column experiment. The biostimulants were placed in the top surface of the sediment facing seawater, 3cm, 6cm and 10cm of the depth from the surface, respectibely. During the experiment, the changes of organic pollutants and heavy metal fractions in the sediment were monitored in 1 month and 3month time intervals. The organic pollutants found during various analysis such as chemical oxygen demand, total solids and volatile solids, significantly reduced when the depth of the biostimulant was 3cm or less. In contrast, at a depth of over 6cm, the reduction of organic pollutants decreased, and the results were similar to the control. Heavy metals fractions in the sediment also changed with the depth of the biostimulants. The exchangeable fraction of the metals was quite reduced at the sediment surface in the column, but the organic bound and residual fractions considerably increased at a depth of 3cm. Based on this study, the optimum biostimulants depth for in-situ bioremediation of contaminant coastal sediment is 3cm from the sediment surface.

• Journal of Navigation and Port Research
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• v.34 no.5
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• pp.367-373
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• 2010

When the numerical analysis is carried out, it is necessary to set proper elements as a feature of analysis domains for more accurate simulations. In this study, Distinct Element Method(DEM) is applied, only considering repulsive force and tensile force except for frictional force and resisting force of particle. When the filled particles with initial Quad-tree type is relocated by DEM, a blank space existing among the particles can be minimized because the shape of particle is circular. Finally, it is the effective feature that the centroidal disposion of the particles is similar to an equilateral triangle. Triangular mesh are formed by using the Delaunay triangular technique on these relocated particles, the quality of triangular mesh is more improved by carrying out Laplace interpolations. The compared result of Aspect Ratio before and after the Laplace interpolation is shown that although the quality of triangular mesh made by DEM is good, the later triangular mesh are higher quality than the formers. In this study, although the developed technique takes a longer calculational time than the previous technique to generate triangular mesh, it is considered that the applicable possibility is very high in the generation of finite element mesh about wave analysis and various numerical simulation to need a complex or reappearance of exact topography.

• KSBB Journal
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• v.10 no.3
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• pp.283-291
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• 1995

The characteristics of aminopeptidase M(ApM) immobilized covalently on Cellufine Formyl and the continuous production of authentic human growth hormone(hGH) from methionyl human growth hormono(met-hGH) using the column reactor packed with immobilized ApM were investigated. Immobilized ApM with the proportion of 2.3mg ApM per 1g Cellufine Formyl gel had the highest met-hGH conversion activity. The optimum pH(7.0) and temperature($55^{\circ}C$) showed no appreciable difference between free and immobilized enzymes and the optimum temperature in continuous operation of the column reactor was also found to be $55^{\circ}C$. Under the conditions at which met-hGH was converted completely to hGH, the yield and productivity were about 77% and 0.8mg hGH/ml$.$h, respectively. In two column reactors of different sizes, met-hGH was converted to hGH with the same conversion rates and hGH yields at the same space velocities. The half-life of the reactor systems at $45^{\circ}C$ and $55^{\circ}C$ were projected from the continuous operations for 90 days to be 225 days and 81 days, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.169-178
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• 2000

Perovskite oxide catalysts doped on porous alumina beads are prepared in a citric acid solution. To investigate the applicability of the catalysts to the hot gas cleanup, a series of experiments on the reduction characteristics of $NO_x$ by CO as a reducing agent are carried out in a packed bed reactor containing the catalysts. Parameters tested are the operating temperature and $CO/NO_x$ molar ratio. It is found that mixed complex oxides of $La_{0.5}Sr_{0.5}CoO_3$, $SrAl_{12}O_{19}$ and $LaAl_{11}O_{18}$ are uniformly distributed on the alumina beads. The conversion efficiency of $NO_x$ by CO sharply increases with the operating temperature up to $700^{\circ}C$ and then approaches 100% when $CO/NO_x$ molar ratio is greater than 1.0. The conversion efficiency of $NO_x$ is maintained by over 98% during a continuous operation for 23 hours at $800^{\circ}C$ and space velocity of $10700hr^{-1}$.

• Economic and Environmental Geology
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• v.42 no.1
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• pp.1-8
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• 2009

The Haman mineralized area is located within the Cretaceous Gyeongsang Basin along the southeastern part of the Korean peninsula. Almost all occurrences in the Haman area are representative of copper-bearing polymetallic hydrothermal vein-type mineralization. Within the area are a number of fissure-filling hydrothermal veins which contain tourmaline, quartz and carbonates with Fe-oxide, base-metal sulfide and sulfosalt minerals. The Gunbuk, Jeilgunbuk and Haman mines are each located on such veins. The ore and gangue mineral paragenesis can be divided into three distinct stages: Stage I, tourmaline + quartz + Fe-Cu ore mineralization; Stage II, quartz + sulfides + sulfosalts + carbonates; Stage III, barren calcite. Equilibrium thermodynamic data combined with mineral paragenesis indicate that copper minerals precipitated mainly within a temperature range of $350^{\circ}C$ to $250^{\circ}C$. During early mineralization at $350^{\circ}C$, significant amounts of copper ($10^3$ to $10^2\;ppm$) could be dissolved in weakly acid NaCl solutions. For late mineralization at $250^{\circ}C$, about $10^0$ to $10^{-1}\;ppm$ copper could be dissolved. Equilibrium thermodynamic interpretation indicates that the copper in the Haman-Gunbuk systems could have been transported as a chloride complex and the copper precipitation occurred as a result of cooling accompanied by changes in the geochemical environments ($fs_2$, $fo_2$, pH, etc.) resulting in decrease of solubility of copper chloride complexes.