• Title/Summary/Keyword: 추출농도

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토양의 특성에 따른 토양증기추출법 (Soil Vapor Extraction)의 Trichloroethylene (TCE)과 Toluene 정화 효율 실험

  • 강현민;이민희;정상용
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.191-194
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    • 2002
  • 토양증기추출(Soil Vapor Extraction)법을 이용하여 대표적 휘발성 NAPL (Non-aqueous phase liquid)인 TCE (trichloroethylene)와 toluene을 토양으로부터 제거하는 칼럼 실험을 실시하였다. 토양특성 및 증기추출 조건들이 정화효율에 미치는 영향을 규명하는데, 균질한 Ottawa sand와 실제 오염지역의 토양들을 직경 2.5cm, 길이 30cm인 유리 칼럼이 충진시켰으며, 빨갛게 염색된 TCE 또는 toluene 4 g이 주입되었다 공기 유량계를 설치하여 0.03L/min의 일정한 속도로 공기가 주입되도록 하고, 퍼지장치를 설치하여 주입 공기의 습윤도를 99% 이상으로 유지하였다. 가스크로마토그래피로 유출 가스 농도를 분석하였다. Ottawa sand로 충진된 칼럼실험에서는 매질의 입자크기, 함수율, 토양 내 오염물 체류시간 등을 변화시켜 실험을 반복하였다. TCE로 오염된 세립질 Ottawa sand 칼럼실험에서 유출 공기의 최대 농도는 조립질 Ottawa sand 칼럼의 유출 농도보다 약 20% 정도 감소하였고, 오염지역의 실제토양 칼럼실험에서는 최대유출농도가 조립질 Ottawa sand 칼럼의 농도보다 약 50% 감소하였으나, 20 liter공기 주입 후부터는 모두 비슷한 농도감소 현상을 나타내었으며, 초기 주입량의 90 % 이상이 제거되었다. 함수율증가에 따른 유출공기의 농도 감소는 거의 나타나지 않았으며, TCE 주입 후 7일 동안 방치하였다가 SVE를 실시한 칼럼 실험에서도 잔류하는 TCE의 양이 약간 증가하였지만 20 liter 공기 추출 후에는 초기 주입량의 90% 가, 40 liter공기 추출 후에는 98% 이상이 제거되었다. Toluene으로 오염된 칼럼 실험에서도 TCE와 비슷한 제거 경향을 나타냈으며 200 liter 공기 추출 후에는 오염물 초기 주입량의 98% 이상이 제거되었다. 본 실험 결과로부터 증기추출법을 이용한 TCE, toluene 정화 효율성이 규명되었으며, 휘발성 NAPL로 오염된 실제 토양을 복원하기 위한 SVE법의 적용가능성을 확인할 수 있었다.

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The Effects of Aqueous Extract and Volatile Substances of Two Angelica Plants on Seed Germination and Seedling Growth (당귀속 2종 식물의 수용추출액과 휘발성물질이 종자발아와 유묘생장에 미치는 영향)

  • Yun Kyeong-Won
    • Korean Journal of Plant Resources
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    • v.19 no.1
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    • pp.169-173
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    • 2006
  • The effects of aqueous extract and volatile substances of 2 Angelica plants on seed germination and seedling growth were investigated. The seed germination of Angelica gigas showed increase in proportion to increase in aqueous extract concentration of A. gigas, while that of Angelica acutiloba was reduced proportionally to the extract concentration. The seed germination of A. gigas and A. acutiloba treated with aqueous extract of A. acutiloba was inhibited. The seedling elongation of A. gigas and A. acutiloba was slightly increased at lower concentration of aqueous extract of A. gigas, whereas it was proportionally decreased at higher concentrations. The seedling elongation of 2 Angelica plants was decreased by the aqueous extract of A. acutiloba. The aqueous extract of A. acutiloba caused significant inhibition in seedling growth of 2 Angelica plants. The seed germination of Lactuca sativa was not affected by volatile substances emitted from 2 Angelica plants. The radicle elongation of L. sativa treated with volatile substances of 2 Angelica plants was inhibited slightly and it was not suppressed according to the concentration of volatile substances.

Optimization of Extraction Conditions of Polyphenolic Compounds from Amaranth Leaf using Statistically-based Optimization (통계학적 최적화를 이용한 아마란스 잎으로부터 폴리페놀 열수추출조건 최적화)

  • Jo, Jaemin;Choi, Kanghoon;Shin, Seulgi;Lee, Jihyun;Kim, JinWoo
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.315-319
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    • 2016
  • This study examined the optimization of hot-water extraction conditions for maximizing the total polyphenol compounds (TPC) extracted from amaranth leaf. The effects of three independent variables, including extraction temperature, extraction time and ethanol concentration on TPC were investigated using central composite design (CCD). The concentration of TPC increased with increased levels of extraction temperature and time. The extraction temperature and the ethanol concentration showed the significant effect on TPC production (p<0.05). The predicted values at the optimized condition were acceptable when compared to the experimental values ($R^2=0.9566$). The optimum extraction conditions were as follows: temperature of $90.1^{\circ}C$, time of 50 min and ethanol concentration of 61.6% (v/v) for the maximum TPC of 12.6 mg GAE/g DM.

Comparison of the antioxidant activities of small-black-bean-Chungkukjang-added black food and soybean Chungkukjang extracts (블랙푸드 첨가에 따른 약콩 청국장 및 대두청국장의 항산화 활성 비교)

  • Park, Hyun-Sook;Shin, Seung-Ryeul;Hong, Ju-Yeon;Yang, Kyung-Mi
    • Food Science and Preservation
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    • v.20 no.5
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    • pp.735-743
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    • 2013
  • This study was conducted to analyze the polyphenol contents and antioxidant activities of small-black-bean-Chungkukjang-added black food (SBCB) and soybean Chungkukjang (SC) extracts for the development of functional materials. The yields of the hot-water-and-ethanol SC extracts were higher than those of the hot-water-only SC extracts, which were higher than those of the ethanol-only SC extracts. The total phenol contents of the hot-water-and-ethanol SBCB extracts were higher than those of the other extracts. The EDA values of the hot-water-and-ethanol SBCB extracts were higher in the 0.625~5.0 mL/mL extract concentration than those of the other extracts, and those of the SC extracts were high in the 10 mg/mL extract concentration. The SOD-like activities of the hot-water- and ethanol-only SC extracts were higher than those of the other extracts. The nitrite scavenging ability of the ethanol-only SC extracts was higher at pH 1.2 than that of the hot-water-only SC extracts. The xanthine oxidase inhibitory activities of the hot-water- and ethanol-only SBCB extracts were higher in the 0.625 mL/mL extract concentration than those of the other extracts, and increased along with the extract concentration. The inhibitory activities of tyrosinase also increased along with the extract concentration, and the reducing power increased along with the extract concentration and was high in the hot-water-only SBCB and SC extracts.

The Cholesterol-Lowering Effects of the Extract from Pinus strobus in Chickens (닭에서 Pinus strobus 잎추출물의 혈청콜레스테롤저하 효과)

  • 이상영;이윤형;최용순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.25 no.2
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    • pp.188-192
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    • 1996
  • 닭을 실험모델로 Pinus strobus 잎의 메탄올 추출물 투여에 의한 콜레스테롤 저하효과를 검토하였다. 닭에 메탄올 추출물 100mg을 50% 에탄올용액 0.5ml에 녹여 2주간 매일 경구투여하였을 때, 유의한 추출물의 투여효과는 관찰되지 않았다. 두 번째 실험에서는 메탄올 추출물의 투여량을 하루 200, 350 또는 50mg으로 달리하여 2주간 경구투여하였다. 2주 후 하루 200mg을 투여한 군은 다른 군에 비하여 유의하게 낮은 혈청 콜레스테롤 농도를 나타내었으나, 투여량의 증가에 의한 부가적인 저하효과는 관찰되지 않았다. 메탄올 추출물은 여러 가지 추출용매로 재분획되었다. 그 중에서 에틸아세테이트 추출물(100mg/일)은 혈청 콜레스테롤 농도를 20%까지 감소시켰다. 이러한 결과로부터 Pinus strobus 잎의 메탄올 추출물의 투여는 닭에서 혈청 콜레스테롤 농도 저하의 개선효과가 있음이 시사된다.

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Effect of a Soy-Sprout Beverage Prepared with High-Concentrated Oxygen Water on Alcohol Metabolism in Rats (고농도 산소수로 재배한 콩나물 추출 음료의 알코올 분해 효능)

  • Sung, Hea Mi;Jung, Hyun Jung;Yun, Su Kyoung;Kim, Tae Yong;Kim, Ki Myong;Wee, Ji-Hyang
    • Korean Journal of Food Science and Technology
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    • v.46 no.5
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    • pp.616-621
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    • 2014
  • This study was conducted to investigate the detoxification effect of extract from soy-sprout grown using high concentrated oxygen water extract (SE) against alcohol-induced hangover in male Sprague-Dawley (SD) rats. The rats were orally administered with different concentrations of SE beverage [26, 260 and 2,000 mg/kg body weight (b.w.)] and, after 30 min, with alcohol at a dose of 3 g/kg b.w. After 1 and 3 h of alcohol administration, blood was collected from the retro-orbital plexus, while after 5 h, blood was collected from the heart. In the 2,000 mg/kg b.w. SE group, the concentration of blood alcohol was significantly reduced after 1-5 h of alcohol loading as compared with that in the other groups. In addition, the blood acetaldehyde concentration was reduced by SE (2,000 mg/kg b.w.). These results suggest that SE beverage can alleviate alcohol hangover symptoms by stimulating the activities related to hepatic alcohol-metabolizing enzymes.

Biological Activities of Dried Garlic, Red Ginseng and Their Mixture (건조 마늘, 홍삼 및 이들 혼합물의 생리활성)

  • Shin, Jung-Hye;Jung, Kang-Min;Lee, Soo-Jung;Yang, Seung-Mi;Rue, Gi-Hyun;Sung, Nak-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.12
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    • pp.1633-1639
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    • 2009
  • Water extracts were extracted on water bath for 3 hrs at 90${^{\circ}C}$ after 5 times water was added to hot-air dried garlic (DG) and red ginseng (RG), respectively. Its extracts were dried on rotary evaporator, and then the mixture samples were prepared from RG extracts added to DG extracts at 5, 10, and 15%. To test biological activities such as DPPH, nitrite scavenging, tyrosinase, $\alpha$-glucosidase, human gastric (AGS), and human colon cancer cell (HT-29) growth, dryness of DG, RG, and mixture samples were diluted 500-10,000 $\mu$g/mL adding deionized water, respectively. DPPH scavenging activities of mixture sample were slightly higher than DG and RG sample alone. Nitrite scavenging activity was the highest in DG, and the other samples were below 45%. Inhibition activity of tyrosinase was below 35.0% in tested all samples. Inhibition activity of $\alpha$-glucosidase was lower in DG or RG alone, while its activity of mixture sample was increased in proportion to concentration of RG extracts. Inhibition of AGS cell growth was more effective in mixture samples than DG and RG alone, while inhibition of HT-29 cell growth was more effective in DG or RG alone than mixture samples.

Antioxidant and Anticancer Activities of Poria cocos and Machilus thunbergii Fermented with Mycelial Mushrooms (버섯균사체로 발효시킨 복령과 후박의 항산화 및 항암효과)

  • Shon, Mi-Yae
    • Food Industry And Nutrition
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    • v.12 no.2
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    • pp.51-57
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    • 2007
  • 한국산 복령과 후박의 이용성 확대를 위하여 각각 추출물의 ABTS와 DPPH라디칼의 소거능, 환원력의 항산화능 효과 및 인체암 세포주의 항암활성에 대하여 조사하였다. 복령과 후박을 버섯균사체로 발효시킨 한약 추출액의 항산화활성(ABTS와 DPPH 라디칼소거, 환원력)은 시료 추출물의 농도가 증가할수록 비례적으로 증가하였으며, DPPH 라디칼 소거활성은 ABTS보다 비교적 높게 나타났고, 원료후박 추출물($21.16{\sim}24.68%$)은 원료복령 추출물($45.46{\sim}49.63%$)에 비하여 약 2배 이상 높았다. 복령 시료 추출물의 농도별에 따른 환원력은 원료 복령($0.55{\sim}0.63$)에 비하여 동충하초, 팽이버섯 및 큰 느타리 균사체로 발효시킨 시료($0.50{\sim}0.62$)의 흡광도로 서로 비슷한 증가를 나타내었고, 후박 시료 추출물의 농도별에 따른 환원력은 원료 후박 추출물($0.98{\sim}1.06$)이 3가지의 버섯 균사체 발효후박 추출물($0.76{\sim}1.01$)에 비하여 약간 높았다. 자궁경부암세포(HeLa)와 대장암세포(HT-29)는 원료복령과 후박의 추출물이 각각의 발효한약에 비하여 저해활성이 높았다. 간암세포(HepG2)는 $200{\mu}g/assay$ 농도에서 팽이버섯 균사체 발효복령의 추출물이 가장 높았는데, 원료복령과 동충하초 및 큰 느타리에 비하여 각각 1.79, 1.35, 1.03배 높은 저해활성을 나타내었다. 그리고 팽이버섯과 동충하초 균사체를 배양한 발효후박에서 각각 $11.39{\sim}53.92%$, $10.71{\sim}50.21%$ 범위였으며, 원료후박에 비하여 $200{\mu}g/assay$ 농도에서 각각 2.21배, 2.05배 높은 저해활성을 나타내었다. 유방암세포(MCF-7)는 발효복령 추출물의 저해활성이 팽이버섯 균사체($58.35{\sim}72.87%$)에서 가장 높았으며, 큰 느타리버섯($61.04{\sim}67.66%$)과 동충하초($39.74{\sim}66.40%$) 및 원료복령($50.32{\sim}69.24%$)은 서로 비슷하였다.

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Separation of Platinum(IV) and Rhodium(III) from Acidic Chloride Solution by Solvent Extraction with Tri 2-Ethylhexyl Amine(TEHA) (염산용액(鹽酸溶液)에서 Tri 2-Ethylhexyl Amine(TEHA)에 의한 백금과 로듐의 분리(分離))

  • Sun, Pan-Pan;Lee, Man-Seung
    • Resources Recycling
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    • v.22 no.5
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    • pp.29-34
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    • 2013
  • Solvent extraction experiments were performed to separate platinum and rhodium from mixed chloride solution by using tri 2-ethylhexyl amine (TEHA) and its mixture with TBP and LIX 63. Effects of extraction conditions on the separation of the two metals were investigated as a function of extractant concentration in the HCl concentration range from 1 to 9 M. The concentration of Pt (IV) and Rh(III) was controlled to $1{\times}10^{-3}M$ and $2{\times}10^{-4}M$, respectively. In the extraction with TEHA and its mixture, Pt was quantitatively extracted irrespective of HCl concentration, while the extraction percentage of Rh depended on the extraction condition. When the concentration of HCl in the mixed solution was low, the extraction of Rh was nil and separation of Pt and Rh was possible. Adding TBP to TEHA had little effect on the extraction of both metals, while adding LIX63 to TEHA favored the extraction of Rh.

Solvent Extraction of Preservative Components from CCA Treated Wood (CCA 처리재로부터 방부제 유효성분의 용제추출)

  • Kim, Gyu-Hyeok;Kong, Il-Gon;Ra, Jong-Bum;Cho, Jae-Sung;Kim, Jae-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.4
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    • pp.50-56
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    • 2003
  • This research was performed to select an appropriate agent to extract preservative components from CCA-treated wood, and then to evaluate the effect of reagent concentration, extracting temperature, and extracting time on the removal of chrome, copper, and arsenic from treated wood. Hydrogen peroxide was selected as the best extracting agent when considered extraction yield as well as use and environmental safety. Its extraction yield was dependent on extracting variables (temperature, concentration, and time), and a highly significant interaction existed among variables. It should be possible to optimize extraction by manipulating these extracting variables. The results may suggest that the required temperature conditions for the reasonable removal of CCA components are at least above 40℃ because extracting time is too long at low temperature (20℃). Reagent concentrations for extracting at above 40℃ should be decided by considering the extracting time.