• Journal of Korean Society of Steel Construction
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• v.26 no.6
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• pp.523-535
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• 2014

According to the capacity design concept underlying current steel seimsic provisions, the braces in concentrically braced frames should dissipate seismic energy through cyclic tension yielding and compression buckling. On the other hand, the beams and the columns in the braced bay should remain elastic for gravity load actions and additional column axial forces resulting from the brace buckling and yielding. However, due to the difficulty in accumulating the yielding and buckling-induced column forces from different stories, empirical and often conservative approaches have been used in design practice. Recently a totally different approach was proposed by Cho, Lee, and Kim (2011) for the prediction of column axial forces in inverted V-braced frames by explicitly considering brace buckling. The idea proposed in their study is extended to X-braced seismic frames which have structural member configurations and load transfer mechanism different from those of inverted V-braced frames. Especially, a more efficient rule is proposed in combining multi-mode effects on the column axial forces by using the modal-mass based weighting factor. The four methods proposed in this study are evaluated based on extensive inelastic dynamic analysis results.

• Journal of the Korea Concrete Institute
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• v.20 no.3
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• pp.375-381
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• 2008

Various problems such as durability degradation may happen when extra water is added to concrete. Because of these reasons, the change of water content is managed by using rapid evaluation method of unit water content such as electric capacity method, heat drying method making use of micro wave, unit capacity mass method among various methods. Especially, in Japan, guidance for the change of water content ($\pm$ 10, 15, 20 kg/$m^3$ etc.) were regulated and used. However, it is the real situation that the guidance which were regulated in South Korea evaluate suitability only considering production and measurement error under the circumstances which are not considering the degree of durability degradation. Therefore, this study tries to investigate the influence of addition of extra water in the concrete on the durability degradation of concrete when it was added by artificial manipulation or by management error. From the test results, a guideline of the contents of extra water for the quality control is suggested with the consideration of the degree of durability degradation and the probable error resulted from the addition of extra water. The contents of extra water for tests are set as 0, 15, 25, 35 kg/$m^3$. To examine the durability degradation of concrete, freezing and thawing, carbonation, chloride penetration and compressive strength are tested.

• The Korean Journal of Pesticide Science
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• v.15 no.4
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• pp.389-400
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• 2011

A high-performance liquid chromatographic (HPLC) method was developed to determine residues of phenothrin and silafluofen, known as synthetic pyrethroids, in agricultural commodities. Insecticide residues were extracted with acetone from representative samples of four crops which comprised rice, apple, pepper and cabbage. The extract was purified serially by liquid-liquid partition and Florisil column chromatography. For rice and pepper samples, acetonitrile/n-hexane partition was additionally adopted to remove nonpolar interferences. Reversed phase HPLC using an octadecylsilyl column was successfully applied to separate two phenothrin isomers and silafluofen from sample co-extractives. Intact parent compounds were sensitively detected by ultraviolet absorption at 226 nm. Recovery experiment at the quantitation limit validated that the proposed method could apparently determine phenothrin and silafluofen residues at 0.02 and 0.01 mg/kg, respectively. Mean recoveries of phenothrin and silafluofen from four crop samples fortified at three levels in triplicate were in the range of 82.4~109.8% and 83.7~109.8%, respectively. Relative standard deviations of the analytical method were all less than 10%, irrespective of crop types and spiking levels. A selected-ion monitoring (SIM) LC/mass spectrometry (MS) with electrospray ionization was provided to confirm the suspected residue of phenothrin, even though no sufficient ionization of silafluofen was obtained. Both phenothrin and silafluofen could be successfully confirmed by gas chromatography/MS SIM with electron impact at 70 eV. The proposed method is sensitive, repeatable and rapid enough to apply to officially routine inspection of agricultural products.

• Journal of the Korea Institute of Military Science and Technology
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• v.20 no.6
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• pp.752-757
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• 2017

Analysis has been performed for the penetration of a long-rod into MMC/Ceramic layered armour system with several shot test and a series of simulations. Two types of MMC plate have been fabricated by a liquid pressing method; A356/45%vol.%SiCp with a uniform distribution of SiC particle and Al7075/45%vol.B4Cp with B4C particle. The mechanical properties were measured with the high-speed split Hopkins bar test, hardness test and compression test. The popular Simplified Johnson-Cook model was adopted to represent the material characteristics for FEM simulations. The performance of the MMC applied armour system has been made by comparing with the semi-infinite mild steel target using the depth of penetration(DOP). The results show that placing ceramic front layer provides a certain gain in protection, and that placing another ductile front layer provides a further gain. The application of MMC is found to be attractive.

• Proceedings of the Korea Water Resources Association Conference
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• 2019.05a
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• pp.253-253
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• 2019

유사의 이동은 하천, 해안 지역과 같은 수계에서 하상의 변동, 침식과 퇴적을 일으켜 지형적인 변화를 초래한다. 유사의 이동은 유사의 특성과 유체의 유수동역학적 특성에 의해 결정되며 유체특성 간의 복잡한 상호 작용에 의해 변화한다. 유사가 가지는 점착성은 유사의 특성에 큰 영향을 끼친다. 입자의 크기가 매우 작은 점착성 유사는 그 표면이 가지는 전자기적 점착력에 의해 주위의 1차 입자나 다른 작은 알갱이들이 서로 뭉치는 응집과 충돌에 의해 크기가 작아지는 파괴의 과정을 겪는다. 이 과정을 응집현상이라고 하며 응집현상을 통해 점착성 유사의 크기와 밀도, 침강속도는 계속해서 변화한다. 따라서 점착성 유사의 응집거동 고려한 유사 이동 연구는 필수적이다. 과거 연구의 많은 사례에서 유사의 크기와 농도는 비례 관계를 가지는 것이 일반적이라 알려져 있다. 그러나 실제 현장에서 측정한 결과 유사의 크기와 농도가 반비례 관계를 가지는 특이점이 발견되었다. 실측 연구에서 발견된 응집거동에 따른 유사의 특성의 특이한 변화를 설명하기 위해 1차원 연직 수치 모형(1DV)을 이용하여 수치 실험을 수행하였다. 모의 수행 시, 흐름 조건을 크기와 방향이 일정한 순방향흐름(Current)에 특정 주기와 진폭을 가지는 진동 흐름(Oscillatory Flow)을 추가하여 진행하였다. 플럭의 성장과 그에 따른 입자의 크기는 많은 현상에 영향을 받는다. 그 중 응집현상의 응집 과정과 파괴 과정 중 어떤 현상이 더 우세한지 그 경쟁관계를 파악하여 플럭의 크기의 증감을 예측할 수 있게 농도(?)와 난류소산매개변수(?)를 이용하여 $c/G^{0.5}$로 매개화하였다. 실험 결과, 순방향 흐름을 제외하고 스토크스파 흐름 조건을 이용하여 진행된 모의에서는 플럭의 크기와 농도가 반비례하는 현상을 관찰할 수 없었으며 $c/G^{0.5}$ 의 변화 역시 흐름의 속도와 농도가 더 큰 지점에서 큰 값을 가지는 일반적인 결과를 나타내었다. 그러나 같은 조건에서 순방향흐름을 추가하여 모의한 결과에서는 플럭의 크기와 농도가 반비례하는 현상을 나타냈다. 연직 방향 $c/G^{0.5}$의 변화를 나타낸 그래프에서 응집과 파괴의 우세에 따라 $c/G^{0.5}$ 가 역전되는 현상을 확인하였다. 즉, 플럭의 크기는 난류의 구조와 그 영향에 의해 농도와 비례관계를 갖지 않을 수도 있다고 판단된다. 또한 본 연구에서 정상류 흐름 조건의 유무에 따라 플럭의 크기와 농도가 비례하거나 반비례하는 상반된 결과를 보였다. 정상류 흐름 조건이 난류의 강도에 큰 역할을 하며 이에 따라 비선형 관계에 영향을 끼친다는 것을 발견하였다. 그러나 흐름의 영향에 대한 더 자세한 분석은 본 연구에서 진행되지 않았으며 향후 연구 시에 분명히 고려되어야 할 사항이다.

• Clean Technology
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• v.27 no.3
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• pp.269-274
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• 2021

Bioenergy is generally considered to be one of the options for pursuing carbon neutrality. However, for a period of time, combustion of harvested plant biomass inevitably causes more carbon dioxide in the atmosphere than combustion of fossil fuels. This paper proposes a method that predicts and minimizes the total amount and payback period of this carbon debt. As a case study, a carbon cycle impact assessment was performed for immediate switching of the currently used fossil fuels to biomass. This work points out a fundamental vulnerability in the concept of carbon neutrality. As an action plan for the sustainability of bioenergy, formulas for afforestation proportional to the decrease in the forest area and surplus harvest proportional to the increase in the forest mass are proposed. The results of optimization indicate that the carbon debt payback period is about 70 years, and the carbon dioxide in the atmosphere increases by more than 50% at a maximum and 3% at a steady state. These are theoretically predicted best results, which are expected to be worse in reality. Therefore, biomass is not truly carbon neutral, and it is inappropriate as an energy source alternative to fossil fuels. The method proposed in this work is expected to be able to contribute to the approach to carbon neutrality by minimizing present and future carbon debt of the bioenergy that is already in use.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.5A
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• pp.849-859
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• 2006

This paper presents an extensive robust analysis of a ${\mu}$-controller in the hybrid system for various uncertainties using the benchmark cable-stayed bridge. The overall system robustness may be deteriorated by introducing active devices and the active controller may cause instability due to small margins. Therefore, a ${\mu}$-synthesis method that simultaneously guarantees the performance and stability of the closed-loop system (robust performance) with uncertainties is used for active devices to enhance the robustness in company with the inherent reliability of passive devices. The robustness of the ${\mu}$-synthesis method is investigated with respect to the additional mass on the deck, structural stiffness matrix perturbation, time delay of actuator, and combinations thereof. Numerical simulation results show that the proposed control system has the good robustness without loss of control performances with respect to various uncertainties under earthquakes considered in this study. Furthermore, the control system robustness is more affected by the perturbation of structural stiffness matrix than others considered in this study. Therefore, the hybrid system controlled by a ${\mu}$-synthesis method could be proposed as an improved control strategy for a seismically excited cable-stayed bridge containing many uncertainties.

• Clean Technology
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• v.17 no.2
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• pp.124-133
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• 2011

In addition to six substances regulated in EU RoHS including lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE), priority substances are identified in new RoHS II as hexabromocyclododecane (HBCDD), dibutyl phthalate (DBP), butyl benzyl phthalate (BBP) and diethylhexyl phthalate (DEHP). In this study, 20 plastic samples were collected from 12 domestic electrotechnical companies and levels of four restricted substances were determined by gas chromatography-mass spectrometry, Among 20 parts that compose washer, refrigerator or microwave oven, HBCDD was detected in three samples of NBR material with the amount of 42~381 mg/kg while DBP and BBP was not detected in any samples collected respectively, implying that these substance may not be used widely in plastic materials for EEE. However, DEHP was detected in all samples of NBR, PP, PBT, EPDM and PVC materials with the amount of 42 up to 59,400 mg/kg that exceeds the limit value of 0.1 wt% (1,000 mg/kg). Presence of a restricted substance in polymer material makes a great negative influence on a number of final product. To cope with coming RoHS II as well as REACH, action not to use DEHP in plastic material or the relevant notification in case of REACH seems to be needed. Screening test of Arsenic compounds such as diarsenic pentaoxide, diarsenic trioxide, lead hydrogen arsenate, triethyl arsenate that are included in REACH SVHC was done by ICP measurement Arsenium was detected in four samples made of NBR and PBT materials in the level of 15~700 mg/kg. By considering the screening method used in this study, the amount of arsenium compounds in the thermistor made of PBT material has a high chance of exceeding the regulated limit value.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.1
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• pp.109-116
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• 2017

This paper describes the investigation into the durability alkali-activated materials(AAM) mortar and paste samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS) exposed to a sulfate environment with different GGBFS replace ratios(30, 50 and 100%), sodium silicate modules($Ms[SiO_2/Na_2O]$ 1.0, 1.5 and 2.0). The tests involved immersions into 10% sodium sulfate solution($Na_2SO_4$), 10% magnesium sulfate solution($MgSO_4$), 10% magnesium nitrate solution($Mg(NO_3)_2$) and 5% magnesium nitrate($Mg(NO_3)_2$+5% sodium sulfate solution+$Na_2SO_4$). The evolution of compressive strength, weight, length expansion and microstructural observation such as x-ray diffraction were studied. As a results, in case of immersed in $Na_2SO_4$, $Mg(NO_3)_2$ and $Mg(NO_3)_2+Na_2SO_4$ shows increase in long-term strength. However, for samples immersed in $MgSO_4$, the general observation was that the compressive strength decreased after immersion. The most drastic reduction of compressive strength and expansion of weight and length occurred when GGBFS or Ms ratios were higher. Also, the XRD analysis of samples immersed in magnesium sulfate indicated that expansion of AAM caused by gypsum($CaSO_4{\cdot}2H_2O$) and brucite(MgOH). The results showed that, an additional condition $Mg^{2+}$ in which ${SO_4}^{2-}$ is the presence of a certain concentration, sulfate erosion has to be accelerated.

• Clean Technology
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• v.25 no.2
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• pp.107-113
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• 2019

Numerical model that considered the shrinking core model and elutriation and degradation of particles was developed to predict selective chlorination of ilmenite and carbo-chlorination of $TiO_2$ in a two stage fluidized bed chlorination furnace. It is possible to analyze the fluidized bed chlorination reaction to be able to reflect particle distribution for mass balances and the chlorination reaction. The numerical model showed an accuracy with error less than 6% compared with fluidized bed experiments. The chlorination degree with particle size change was greater with a smaller particle size, and there was a 100 min difference to obtain a chlorination degree of 1 between $75{\mu}m$ and $275{\mu}m$. This was not shown to such a great extent with variation of temperature ($800{\sim}1000^{\circ}C$), and there was only a 10 min difference to obtain a chlorination degree of 0.9. In the first selective chlorination process, the mass reduction rate approached to the theoretical value of 0.4735 after 180 min, and chlorination changed the Fe component into $FeCl_2$ or $FeCl_3$ and showed nearly 1. In the second carbo-chlorination process, the chlorination degree of $TiO_2$ approached 0.98 and the mass fraction reached 0.02 with conversion into $TiCl_4$. In the first selective chlorination process, 98% of $TiO_2$ was produced at 180 min, and this was changed into 99% of $TiCl_4$ after an additional 90 min. Also the mass reduction rate of $TiO_2$ was reduced to 99% in the second continuous carbo-chlorination process.