• Title/Summary/Keyword: 총탄화수소

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Effect of Environmental Parameters on the Degradation of Petroleum Hydrocarbons in Soil (환경인자가 토양내 석유계탄화수소의 분해에 미치는 영향)

  • 황의영;남궁완;박준석
    • Journal of Korea Soil Environment Society
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    • v.5 no.1
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    • pp.85-96
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    • 2000
  • The purpose of this study was to Investigate the effect of environmental conditions on the degradation of total petroleum hydrocarbons(TPH) in soil. The soil used for this study was sandy loam. Target contaminant, diesel oil, was spiked at 10.000mgTPH/kg dry soil. Moisture content was controlled to 50%, 70%, and 90% of field capacity of the soil. Temperature was controlled to $5^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$, and $30^{\circ}C$. The active degradation of TPH was observed at the moisture contents of 50% and 70% of field capacity, and temperature of $10^{\circ}C$ to $30^{\circ}C$. Degradation rate of n-alkanes was about two times greater than that of TPH. Volatilization loss of TPH was about 2% of initial concentration. Biocide control and no aeration experiments indicated that removal of TPH was primarily occurred by biodegradation under aerobic condition.

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Comparison of Extraction Methods for the Analysis of Total Petroleum Hydrocarbons in Contaminated Soil (오염토양내 석유계 총탄화수소 분석을 위한 추출방법의 비교)

  • Eui-Young Hwang;Wan Namkoong;Jung-Young Choi
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.45-53
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    • 2000
  • Two extraction methods for total petroleum hydrocarbon (TPH) from contaminated soil were evaluated. The soil used for this study was sandy loam. Diesel oil was selected as representative petroleum hydrocarbons and was spiked at 100, 10,000, 50,000mg TPH/kg dry soil. Percentage recovery of TPH by shaking method was higher compared to Soxhlet extraction. At extraction time of 2 hours and sample to solvent ratio of 1 : 5, the highest percentage recovery was obtained. In this condition, percentage recovery of TPH in soil contaminated with 100mg/kg and 50,000mg/kg as TPH was 95.9% and 95.5%, respectively The volume of solvent lost by volatilization in shaking method was relatively small compared to Soxhlet extraction.

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A Study on the Remediation using Microbial Activator from Oil-Contaminated Soil (미생물활성화제를 이용한 유류오염토양 복원에 관한 연구)

  • Lee, Chae-Young;Chung, Chan-Kyo;Kim, Jong-Moon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.41-48
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    • 2011
  • In this study, the soil remediation by landfarming was carried out using microbial activators. Feasibility studies and reduction capacity of TPH(Total Petroleum Hydrocarbons) were investigated in order to find out how fast and eco-friendly the contaminated soil can be recovered. The lab-test confirmed not only the performance and degradation efficiency of microbial activators but also the effect of TPH reduction in the contaminated soil. The optimum growth conditions for indigenous microorganisms were identified using microbial activators. Based on the results of TPH removal, although there had been a little of difference in between natural decomposition and microbial activators until 20 days, the sample groups of microbial activators were higher than the control ones after 20 days. Microbial activators were applied to the field experiments on landfarming. Based on the results of removal rate in each floor of soil, it was found that the removal rates were 85.8 % in the upper, 84.4 % in the middle, and 66.10 % in the bottom. Considering that the reduction rate of TPH for the control group averaged 71.1%, the microbial activators might not be fully transferred into the bottom, which resulted from the piles of soil. As the piles have already reached 1 m in the field experiments, the low piles of soil under 0.6 m may enhance the treatment efficiency of TPH.

A Proposal of Standard Method for the Analysis of Total Petroleum Hydrocarbons (TPHs) in Marine Sediments and Biota (해양환경시료(해저퇴적물과 해양생물)에 축적된 석유계총탄화수소(TPHs) 분석에 대한 공정시험기준 제안)

  • Kim, Chang-Joon;Hong, Gi-Hoon;Jeon, Ji-Yeun;Kim, Suk-Hyun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.4
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    • pp.249-262
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    • 2010
  • Regulatory test method for Total Petroleum Hydrocarbons (TPHs) in the marine sediment and biota has not still been established even though TPHs are one of the major pollutants in marine environment. Based on the Korean Soil Standard Method (SSM) for TPHs, we considered a new treatment method for determining TPHs in marine environmental samples by using a Gas chromatography coupled with Mass spectrometric detector. We suggested an improved recovery test for quality control procedures and introduced analytical procedures of removing sulfur, polar organic materials, water and saponification for removing neutral lipids in marine bottom sediments and biota.

Comparison of Diurnal BTEX Characteristics between Seoul and Naju Forested Areas (서울과 나주 산림지역간 BTEX의 일변화 분포특성 비교)

  • 김조천;이강웅;전의찬;김기준;기준학
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.52-54
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    • 1999
  • 최근에 자동차의 급증과 각종 유기용매 사용의 증가로 휘발성유기화합물(VOC)이 대기질에 커다란 영향을 주는 것으로 알려지고 있다. 최근의 국제적인 연구 추세로서 총탄화수소와 같은 일체적인 개념보다는 개별 VOC에 대한 관리와 연구가 선호되고 있는 실정인 바, 우리나라는 VOC에 대한 측정사례가 외국에 비해 많지 않고 그 종류와 농도에 대한 연구도 아직은 미비한 실정이다.(중략)

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A Study for Remediation of Railroad Ballast Gravel Using Dry Washing Method (건식세척기술을 이용한 철도 도상자갈 정화 연구)

  • Bae, Jiyong;Jeong, Taeyang;Kim, Jae Hun;Lee, Sang Tak;Joo, Hyung Soo;Oh, Seung-Taek;Cho, Youngmin;Park, Duckshin
    • Journal of the Korean Society for Railway
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    • v.20 no.3
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    • pp.365-373
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    • 2017
  • This study proposes a newly developed dry washing method for removing pollutants such as total petroleum hydrocarbon (TPH) and oxidized iron from the surface of ballast gravel. A batch-type dry washing method showed a good performance in a previous study. In this study, a continuous-type dry washing system, instead of a batch-type system, was prepared to improve the efficiency of the system. A drier and a separator were also applied to this system as pre-treatment process, and the performance of this system was evaluated. In this experiment, blasting media was blasted on the polluted gravels through 12 nozzles by a pressure of $5-6kg/cm^2$ for 20-30 mins to remove TPH and oxidized iron. It was found to be possible to remove 80-90% of TPH and oxidized iron by using this system. Several ways to improve the performance were suggested in this study.

Long-term Trends of Visibility and Air Quality in Seoul, Ganghwa, Seosan, Gwangju, Jeju (서울, 강화, 서산, 광주, 제주 지역에서의 장기간 대기오염과 시정 변화경향에 대한 연구)

  • 문광주;한진석;홍유덕;장건우;이석조;전영신
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.111-112
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    • 2003
  • 시정장애현상의 직접적인 원인은 주로 0.1~2.0$\mu\textrm{m}$ 크기의 미세입자들에 의한 빛의 산란 및 흡수현상으로(Feidlander, 1977), 이러한 미세입자들은 각종 오염원에서 직접 배출되기도 하지만, 대부분 대기 중에서 1차 오염물질들이 서로 반응, 응축, 응집하여 생성, 성장한 2차 에어로솔이다(국립환경연구원, 1994). 2차 에어로솔의 생성 및 성장, 성분 및 농도는 기체상의 SO$_2$, NOx CO, CO$_3$, 총탄화수소 등과, 입자상인 부유분진의 농도와 같은 1차 오염물질들 뿐만 아니라, 온도, 습도, 풍향, 풍속, 일사량, 혼합고 등의 여러 기상조건 및 지형조건의 영향을 받는다. (중략)

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The Analytical Bias of Total Hydrocarbon (THC) Measurements in Relation to the Selection of Standard Gas Compound (총탄화수소의 계측에서 표준시료성분의 선택에 따른 오차 발생 연구)

  • Kim, Ki-Hyun
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.4
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    • pp.449-452
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    • 2010
  • In this article, the performance of the THC analyzer was inspected using two different span gases of methane ($CH_4$) and propane ($C_3H_8$). To explore the effect of standard gas selection, MicroFID system was tested by the following procedures. Initially, the system is spanned by propane gas of 60 ppm (or 180 ppmC). The system is then run against methane standards prepared at 5 different concentrations of 200, 250, 300, 400, and 500 ppm. According to the suggestion of the KMOE's test procedure to use multiplying a factor of 3 (for propane), the resulting THC values derived by methane standards were systematically biased with ~500% error relative to true value. This paper discusses the interpretation procedures to obtain the least biased THC values for a given span set-up.

Study of the Performance of a Dry Cleaning Method for Polluted Ballast Gravel of Railroad Fields (철도부지 오염도상자갈의 건식 정화 기술 성능 연구)

  • Cho, Youngmin;Park, Duckshin;Kwon, Tae-Soon;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.552-557
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    • 2015
  • Ballast gravel in a railroad field is often polluted by grease and heavy metals. In this paper, the performances of a dry cleaning method for polluted ballast gravel in which pollutants on the gravel surface can be physically removed was extensively studied. A polluted ballast cleaning device able to shoot emery blasting media onto the surface using compressed air was prepared. Polluted ballast gravel was put into this device for cleaning, with the treatment time varied from 1 to 10 min. The cleaning efficiency of the total petroleum hydrocarbons and heavy metals were studied. The total petroleum hydrocarbon removal efficiency was 70-80% for gravels sampled from a locomotive waiting line, while it was 40-60% for gravels sampled from a turnout area. The heavy metal removal efficiency exceeded 90% for copper and lead, while it was 65-80% for nickel and zinc. This system was found to be effective for the remediation of polluted ballast gravels.

Performance of Soil Flushing for Contaminated Soil Using Surfactant (계면활성제를 이용한 오염 토양 세정 성능 평가)

  • Lee, Chaeyoung;Jang, Yeongsu
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.6
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    • pp.17-23
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    • 2011
  • In this study, a series of experiments were carried out to remove total petroleum hydrocarbon(TPH) and toluene by soil flushing. In batch experiments, Triton X-100 and SWA 1503 showed TPH removal efficiency of 79.0% and 69.0%, respectively. Although the TPH removal efficiency increased as the surfactant was increased in the concentration range 1-11mmol/L, the optimum concentration was 1mmol/L, considering the ratio of the removal efficiency to the amount of surfactant injected. In column experiment, the optimal velocity was 0.3mL/min. The physical aquifer model(PAM) result revealed that the soil flushing removed as much as 5.5% of the toluene under 3 pore volume(PV) conditions. To improve the soil flushing efficiency, it is necessary to find optimal condition through recirculation or reuse of surfactant.