• Polymer(Korea)
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• v.38 no.3
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• pp.378-385
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• 2014

Multiwall carbon nanotubes (MWCNTs) were modified with a water soluble polymer, poly(vinyl alcohol), PVA, using a simple ultrasonic wave in water. Under the irradiation of ultrasound, PVA chains were severed as macroradicals and instantly grafted onto the surface of MWCNTs due to the radical scavenging effect of MWCNTs. To control the grafting PVA onto MWCNTs, the ultrasonication power and irradiation time were changed from 300 to 500 W and from 10 to 50 min, respectively. The grafted PVA onto MWCNTs was confirmed by FTIR, TGA, SEM, and TEM. Dispersion stability of the modified MWCNTs was monitored by Turbiscan. The amount of grafted PVA on MWCNTs increased with the increase in the sonication power and irradiation time. The grafted PVA on MWCNTs induced the improved dispersion stability of the modified MWCNTs in water. These findings exhibit that ultrasound can be readily used for the grafting polymer chains on MWCNTs.

• Transactions of the KSME C: Technology and Education
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• v.1 no.1
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• pp.115-121
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• 2013

It is greatly expected that the technologies of durability enhancement and evaluation for the core structures of plant facilities, marine plant and bridge constructures will be greatly expanded in the plant industry fields. In this study, the actively ongoing applied cases were tried to be analyzed in the present domestic industry fields through the Ultrasonic Nanocrystalline Surface Modification (UNSM) and Ultrasonic Fatigue Test (UFT) technologies using ultrasonic elastic vibrational energy, and the new application technology to improve the durability of plant industry field, especially plant facilities, marine plant and core weld components of bridge constructures will be presented.

• Journal of Ocean Engineering and Technology
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• v.22 no.2
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• pp.99-105
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• 2008

Ultrasonic nanocrystal surface modification (UNSM) is a method to induce severe plastic deformation to a material surface, so that the structure of the material surface becomes a nanocrystal structure from the surface to a certain depth. It improves the mechanical properties, namely hardness, compressive residual stress, and fatigue characteristics. Specimens of SKD61 were tested to verify the effects of the variation of UNSM static load level on fatigue characteristics. The results were as follows: the grain size of SKD61 treated with UNSM became very fine from the material surface to a $100{\mu}m$ depth. The surface hardness of SKD61 was increased up to 37% after UNSM. And fatigue strength at $10^7$ cycles was increased by 8.3, 11.2, and 17.9% respectively, when the static load levels of UNSM were 4, 6, 8 kgf.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.10a
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• pp.929-930
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• 2012

• Journal of the Korean Society for Precision Engineering
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• v.31 no.12
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• pp.1115-1119
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• 2014

In this article, a 20 kHz ultrasonic waveguide for nano-surface treatment was designed and manufactured. When designing the system, finite element analysis with ANSYS software was performed to find optimal dimensions of the waveguide, which can raise energy efficiency. Consequently an anti-resonance frequency of an Al waveguide with a piezoelectric actuator was 20 kHz, which predicted the experimentally obtained value of 18 kHz well. For the assessment of the performance, Steel Use Stainless (SUS) 304 and chromium molybdenum steel (SCM) 435 specimens were tested. Cross-sectional microscopies of SUS304 were taken and they showed that the treated thickness was $30{\mu}m$. Additionally, hardness tests of SCM435 were done and the hardness before the process was 14.0 Rockwell Hardness-C scale (HRC) and after the process was 20.5 HRC, respectively, which means 46% increase. Considering these results, the developed ultrasonic system is thought to be effective in the nano-surface treatment process.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.33 no.3
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• pp.190-195
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• 2009

All the failure in fatigue of torsion, bending and rolling contact, and in sliding wear begins mostly from surface. So much efforts have been invested to the surface technology which deal these problems during past decades, but the industrial demand keeps growing and more significant requirements are added to researchers and engineers. Nano crystal surface modification technology which makes the surface layers into nano crystalline, induces big and deep compressive residual stress, increases surface hardness, improves surface hardness, and make micro dimples structure on surface is an emerging technology which can break limits of current surface technology and relieve the burden of researchers and engineers. In this study, a nano crystal surface modification technology which is calling UNSM(Ultrasonic nano crystal surface modification) technology, is introduced and how it has been applied to industry to solve these failure problems is explained.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.36 no.4
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• pp.443-449
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• 2012

Nanoskins were fabricated on a Ti-6Al-4V material by carrying out various surface treatments, i.e., deep rolling, laser shot peening, and ultrasonic nanocrystal surface modification (UNSM). These surface treatments are newly developed techniques and are becoming more popular for industrial applications. Fatigue tests were carried out using material test system (MTS); these tests included the axial loading tension-compression fatigue test (R = -1, RT, 5 Hz, sinusoidal wave) and rotating bending fatigue test (R = -1, RT, 3200 rpm). The analysis of the crack initiation pattern in the UNSM-treated material indicated that the crack was interior originating in the axial loading tension-compression cycle, and was surface originating in the bending fatigue test. UNSM treatment significantly improved the fatigue strength for the regime of above $10^6$ cycles that S-N curve of rotating bending stress clearly show the performance of a 5 mm titanium specimen after UNSM treatment is similar to that of an untreated 6 mm titanium specimen.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2010.05a
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• pp.521-522
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• 2010

• Polymer(Korea)
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• v.34 no.6
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• pp.534-539
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• 2010

Polystyrene (PS)/multi-walled carbon nanotube (MWCNT) nanocomposites were prepared via latex technology and the effect of nanotube length on rheological properties were investigated. Monodisperse PS particle was synthesized by the emulsifier-free emulsion polymerization and two types of MWCNTs were used after surface modification to improve dispersion state and to remove impurities. Final nanocomposites were prepared by the freeze-drying process after dispersing the PS particles and the surface-modified MWCNTs in a ultrasonic bath. The effects of MWCNT content and nanotube length on rheological properties were evaluated by imposing the small-amplitude oscillatory shear flow. The PS/MWCNT nanocomposites showed that rheological properties were enhanced as the amount and length of MWCNT increased. It is speculated that the rheological characteristics of nanocomposites change from liquid-like to solid-like as the MWCNT amount increases, and the critical concentration to achieve network structure decreases as the nanotube length increases.

• Journal of Adhesion and Interface
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• v.4 no.4
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• pp.22-27
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• 2003

Chemical modification of carbon nanotube (CNT) was carried out using $HNO_3$ and $H_2SO_4$ and characterized by analyzing the CNT before and after the modification using FT-IR and titration. Aggregation behaviors were investigated using a real-time video microscope after the chemically modified CNT(mCNT) had been dispersed in organic solvents such as toluene, dimethylformamide (DMF) and N-methylpyrrolidone (NMP) by ultrasonication. The mCNT showed better dispersion in polar sovents of DMF and NMP than the rCNT. CNT/ poly(methylmethacrylate) (PMMA) films were prepared from solution DMF/PMMA solutions. The films containing mCNT also revealed the improved dispersion.