• Title/Summary/Keyword: 초음파합성

Search Result 216, Processing Time 0.029 seconds

Sonochemical Synthesis of UiO-66 for CO2 Adsorption and Xylene Isomer Separation (초음파 합성법을 이용한 UiO-66의 합성 및 이산화탄소 흡착/자일렌 이성체 분리 연구)

  • Kim, Hee-Young;Kim, Se-Na;Kim, Jun;Ahn, Wha-Seung
    • Korean Chemical Engineering Research
    • /
    • v.51 no.4
    • /
    • pp.470-475
    • /
    • 2013
  • Zr-benzendicarboxylate structure, UiO-66 was prepared in 1-L batch scale by using a unique sonochemical-solvothermal combined synthesis method. The produced UiO-66 showed uniform particles of ca. $0.2{\mu}m$ in size with the BET surface area of $1,375m^2/g$ in high product yield (>95%). The UiO-66 showed 198 and 84 mg/g $CO_2$ adsorption capacity at 273 K and 298 K, respectively, with excellent $CO_2$ selectivity ($CO_2:N_2=32:1$) at ambient conditions. The isosteric heat of $CO_2$ adsorption varied from 33 to 25 kJ/mol as the adsorption progressed. The UiO-66 tested for xylene isomer separation in a liquid-phase batch mode confirmed preferential adsorption of the adsorbent for o-xylene over m-, and p-xylene.

An acoustic Doppler-based silent speech interface technology using generative adversarial networks (생성적 적대 신경망을 이용한 음향 도플러 기반 무 음성 대화기술)

  • Lee, Ki-Seung
    • The Journal of the Acoustical Society of Korea
    • /
    • v.40 no.2
    • /
    • pp.161-168
    • /
    • 2021
  • In this paper, a Silent Speech Interface (SSI) technology was proposed in which Doppler frequency shifts of the reflected signal were used to synthesize the speech signals when 40kHz ultrasonic signal was incident to speaker's mouth region. In SSI, the mapping rules from the features derived from non-speech signals to those from audible speech signals was constructed, the speech signals are synthesized from non-speech signals using the constructed mapping rules. The mapping rules were built by minimizing the overall errors between the estimated and true speech parameters in the conventional SSI methods. In the present study, the mapping rules were constructed so that the distribution of the estimated parameters is similar to that of the true parameters by using Generative Adversarial Networks (GAN). The experimental result using 60 Korean words showed that, both objectively and subjectively, the performance of the proposed method was superior to that of the conventional neural networks-based methods.

The Characteristics of Vanadium based Composite Cathode for Lithium Secondary Battery (리튬이차전지용 바나듐계 복합양극의 특성)

  • Kim Jong-Jin;Son Won-Keun;Kim Jae-Yong;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.2 no.2
    • /
    • pp.61-65
    • /
    • 1999
  • A new treatment of $LiV_3O_8$ has been proposed for improving its electrochemical behavior as a cathode material for secondary lithium batteries. Lithium trivanadate, $LiV_3O_8$, can be prepared in a finely dispersed form by dehydration of aqueous lithium trivanadate gels. The ultrasonic treatment method for Liv30s has been examined in comparison with $LiV_3O_8$ prepared by solutionmethod. The ultrasonically treated products in water were characterized by XRD (X-ray diffractometry), TGA (thermogravimetric analysis) and SEM (scanning electron microscopy). These measurements showed that the ultrasonic treatment process of aqueous $LiV_3O_8$ caused a decrease in crytallinity and considerable increased in specific surface area and interlayer spacing. The product, ultrasonically treated in water for 2 h, showed a high initial discharge capacity and was charge-discharge cycled without large capacity loss. The ultrasonic treated Liv30s can improve not only the specific capacity, but also the cycling behavior

Development of Human-Head-Mimicking Phantom for Brain Treatment Using Focused Ultrasound (집속 초음파 뇌 질환 치료를 위한 두부 유사 팬텀의 개발)

  • Min, Jeonghwa;Kim, Juyoung;Noh, Sicheol;Choi, Heungho
    • Journal of the Korean Society of Radiology
    • /
    • v.7 no.6
    • /
    • pp.433-439
    • /
    • 2013
  • In this study, human head-mimicking phantom was developed for brain disease treatment study using focused ultrasound. Acoustic parameters of skin, skull and brain were investigated through literature investigation and adequate substitutes according to each tissue were suggested. In the case of skin phantom, construction ratio of glycerol-based TMM phantom was controlled to mimic real skin. The suitability of skull substitutes was evaluated through measurement of acoustic parameters. In the case of brain phantom, transparent egg white phantom was used to observe thermal properties of focused ultrasound. Combined human-head-mimicking phantom using each substitutes was fabricated for development of brain disease treatment protocol. Denaturation of brain phantom according to ultrasonic condition was observed for validation.

Joining of Polymer Materials with Ultrasonic Welding (초음파 용접을 이용한 합성수지의 결합)

  • 이철구;정규창
    • Journal of Welding and Joining
    • /
    • v.16 no.2
    • /
    • pp.48-56
    • /
    • 1998
  • This study was performed to find the best bonding conditions by comparing mechanical properties in thermoplastic resin of polyethylene (PE) and polyamide (PA) adhesion. Following results were obtained from the tests with varying welding time and welding pressure. Satisfactory adhesion was executed in ultrasonic welding for the same materials of PE and PA. The best welding conditions were found to be welding time of 1 second, welding pressure of 250kPa for PE-PE weding, 2 second and 350kPa for PA-PA welding. Welding time and welding pressure end to increase with the increase of materials strength. Dissimilar materials were adhered when adhesion and ultrasonc welding were performed simultaneously. The observation of the structure of ultrasonic welding area with microscope showed differenticated structures between well adhered region and badly adhered region.

  • PDF

A Study on the Realization of Transmit and Receive Focusing Using Linited-Diffraction Beam in Ultrasound Imaging (초음파 영상에서 제한회절빔을 이용한 송수신 집속의 구현에 관한 연구)

  • 정목근;권성재;안영복
    • The Journal of the Acoustical Society of Korea
    • /
    • v.17 no.4
    • /
    • pp.67-71
    • /
    • 1998
  • 초음파 선형트랜스듀서에서 제한회절음장은 영상깊이에서 다른 방향으로 진행하는 평면파들의 선형적인 중첩으로부터 구한다. 제한회절음장을 구현하기 위한 송신음장은 영상 깊이를 지나가는 평면파들의 공간적인 확장으로부터 구해지는데 실제의 하드웨어로 구현하 기 어렵다. 본 논문은 진행방향이 다른 pulsed mode 평면파를 각각 송신한 후, 얻어진 데이 터로부터 합성집속 방법에 의하여 제한회절빔을 구현하였다. 제안한 방법은 모든 송신소자 에서 발사되는 음장의 크기가 동일하므로 송신전력이 증가하여 신호대잡음비와 명암비를 증 가시키며 간단한 하드웨어로 구현이 가능하다. 시뮬레이션 결과는 송신은 한점집속, 수신은 동적집속을 사용하는 기존의 방법과 비교하여 주엽(mainlobe)의 폭과 부엽(sidelobe)의 크기 관점에서 우수함을 증명하였다.

  • PDF

Diffraction-Limited Beam for One Dimensional Array in Ultrasonic Imaging (초음파 영상에서 선형어레이를 이용한 제한회절빔의 발생)

  • Jeong, Mok-Geun;Song, Tae-Gyeong;Park, Song-Bae
    • The Journal of the Acoustical Society of Korea
    • /
    • v.14 no.2E
    • /
    • pp.87-90
    • /
    • 1995
  • A new solution to the two-dimensional scalar wave equation is presented, which descries a diffraction-limited beam maintaining the lateral field response expressed by the sinc function. Physically, it is a superposition of plane waves having different wavelengths traveling in different directions. The beam can attain a line focus with one-dimensional array transducer in ultrasonic medial imaging.

  • PDF

Probing of Mortar Specimens Using Ultrasonic Method Based on the Aging of Mortar (모르타르 시편의 재령에 따른 초음파를 이용한 내부탐사)

  • Park, Young-Seo;Rhim, Hong-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2019.11a
    • /
    • pp.126-127
    • /
    • 2019
  • Ultrasonic method is useful in determining the compressive strength of concrete as a nondestructive testing technique. As the velocity of the ultrasonic wave changes depending the aging of fresh concrete, it is possible to use the ultrasonic method to measure the degree of concrete curing on site. Recently, the use of steel reinforced concrete is ever increasing. This study is to examine the effect of aging concrete on the velocity of ultrasonic wave so that the compressive strength of concrete can be predicted in the presence of steel inclusions.

  • PDF

Syntheses of Disubstituted Polysilanes (Ⅱ): Sonochemical Study (폴리실란의 합성 (Ⅱ): 초음파 화학적 연구)

  • 이규환;전태하
    • Journal of the Korean Chemical Society
    • /
    • v.43 no.1
    • /
    • pp.28-42
    • /
    • 1999
  • Polysilanes with sterically bulky substituents, -[2-( $R^1R^2$-phenyl)propyl]Si[$R^3$]-, such as poly(2-phenylpropyl)(n-hexyl)silane [$R^1=R^2$=H, $R^3$=n-hexyl] were prepared by Wurtz-type coupling reactions with Na using a sonochemical method. The high-intensity ultrasound provided the formation of high quality Na dispersion in toluene and its active surface which was important for the synthesis of polysilanes in Wurtz-type coupling reaction was freshly and continuously regenerated during the process. The polysilanes products were mixtures of high molecular weight polymers with $\={M}_W$ of ∼$10^6$ and low molecular weight polymers with $\={M}_W$ of ∼$10^3$. It was found that the formation of high molecular weight polymerr was greatly influenced by the substituents $R^3$, directly attached to Si. On the contrary, changes on substituents ($R^1, R^2$) gave no influences at all. Overall yields for polysilanes were 75-99% in general but high molecular weight polysilanes were obtained as a major product when substituent $R^3$ is n-hexyl group and low molecular weight polysilanes were obtained as a major product when substituent $R^3$ is cyclohexyl and 2-phenylethyl groups. Effects of reaction conditions to polysilane yields were investigated.

  • PDF

Preparation of Spherical $TiO_2$Powders by Spray Pyrolysis Using Ultrasonic Atomization Technique (초음파 분무 열분해법에 의한 구형 $TiO_2$ 미분말의 합성)

  • 이종흔;조형진;박순자
    • Journal of the Korean Ceramic Society
    • /
    • v.28 no.10
    • /
    • pp.831-837
    • /
    • 1991
  • Spherical TiO2 particles are prepared from TiCl4 aqueous solution by the spray pyrolysis method using ultrasonic atomization technique. The formation mechanism of TiO2 particles from atomized droplets it studied by varying the concentration of the source solution, reaction temperature, and the solvent. spherical TiO2 powders with almost the same normalized particle size distribution can be made reproducibly by changing the concentration of the source solution, and their mean sizes are in the range of 0.2~1.4${\mu}{\textrm}{m}$.

  • PDF