• Title/Summary/Keyword: 체적팽창

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고무소재의 열응력

  • Gang, Sin-Yeong;Hong, Chang-Guk
    • Rubber Technology
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    • v.11 no.1
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    • pp.12-26
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    • 2010
  • 각종 산업제품의 주요 부품으로 사용되고 있는 고무재료는 사용 중 온도변화에 의해 체적 또는 길이 변화를 수반할 수 있어 결과적으로 고무제품의 성능이나 효율이 영향을 받게 된다. 특히 고온에서 고무제품의 치수변화를 제한하거나 일정치수를 강제할 경우 열수축이나 열팽창에 의해 응력이 발생하게 된다. 따라서 온도 변화에 따른 열응력의 측정은 고무제품의 정밀성과 성능을 평가하는 중요한 수단을 제공한다. 본 연구에서는 고무소재의 열응력 측정을 위한 새로운 측정방법을 개발하였고 이와 관련 새로운 시험장치를 설계, 제작하였다. 고무시편에 일정 변형의 인장을 준 상태에서 가열하면 열응력이 발생한다. 이 때의 열응력은 고무분자 사슬들의 운동성에 기인하며 배향된 고무분자 사슬들이 열역학적으로 랜덤 사슬형태로 돌아가려는 엔트로피적 힘이다. 따라서 온도가 높을수록 그 수축력은 증가하게 된다. 또한 고무분자 사슬의 사전 변형이 증가하면 그 열응력은 증가한다. 이때 열응력은 측정시간이 지남에 따라 최대치에 도달한 후 완화되며 그 완화속도는 설정온도에 의해 영향을 받는다. 여기서는 온도변화에 따른 고무시편의 열응력 측정결과를 소개하고, 고무분자 사슬의 엔트로피 변화와 점탄성적 흐름, 그리고 가열에 따른 고무 시편의 팽창 또는 수축이 열응력에 미치는 영향 등을 논의하였다. 특히 천연고무와 SBR 고무시편의 열응력 차이를 분자사슬의 운동과 연관하여 검토하였고, 가교밀도와 가교시스템이 각각 다른 고무시편에 대해 열응력 발생과에 따른 상관관계를 고찰하였다. 또한 시편의 형태와 두께가 열응력 발생에 미치는 영향도 검토하였다. 충전 배합고무의 경우 열응력에 영향을 미치는 인자로 고무분자 사슬의 운동성과 가교밀도 외에 고무재료와 충전제 사이의 물리 화학적 상호작용도 매우 중요한 요소가 된다. 배합고무에서 충전제의 영향을 검토하기 위해 실리카와 카본블랙을 선택하였고 배합고무의 열응력을 각각 측정하여 이들의 보강효과가 열응력에 미치는 영향에 대해 논하였다.

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Performance Test of Scroll Expander for Micro-Power Generation (소규모 발전용 스크롤 팽창기 성능시험)

  • Kim Hyun J.;Park Ik S.;Rha Phil C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.325-332
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    • 2005
  • This paper addresses the development of a scroll expander for power generation from relatively low temperature steam source. It has a double-sided orbiting scroll member so that no thrust bearing is needed to support the base plate of the orbiting scroll. Three power transmission shafts are placed at the periphery of the orbiting scroll base plate, and these shafts can also function as anti-rotation devices. Final output is obtained from the main central shaft engaged with the three power transmission shafts through gear assembly. The clearance between the fixed and orbiting scroll elements was estimated by comparing measurement of the mass flow rate with calculation results of a computer simulation. Due to large clearance, the expander total and volumetric efficiencies were measured to be $34\%\;and\;43\%$, respectively. It has been shown through the computer simulation that the total and volumetric efficiencies could be improved to $65\%\;and\;83\%$, respectively, if the current clearance is reduced by half.

The Effect of Transient Nozzle Pressure Ratio on the Characteristics of Unsteady Side Forces in an Over-Expanded Nozzle (압력비 변화과정이 과팽창 노즐에서 발생하는 비정상 횡력 특성에 미치는 영향)

  • Lee, Jong-Sung;Kim, Heuy-Dong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.678-681
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    • 2010
  • In the present work, a numerical study is conducted to investigate the effect of the transient nozzle pressure ratio (NPR) on the flow fields inside the nozzle. The unsteady, compressible, axisymmetric, Navier-Stocks equations with SST $k-{\omega}$ turbulence model are solved using a fully implicit finite volume scheme. In order to simulate the start-up and shut-down processes of the engine, NPR is varied from 2.0 to 10.0. It is observed that the interaction patterns and the hysteresis phenomenon strongly depend on the time variation of NPR, leading to significantly different characteristics in the lateral forces.

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The Effects of Pulsating Flow on Volumetric Efficiency in the Intake and Exhaust System in a Turbocharged Diesel Engine (흡.배기 시스템의 맥동류가 과급디젤기관의 체적효율에 미치는 영향)

  • Kim, K.H.;Kang, H.Y.;Koh, D.K.
    • Journal of Power System Engineering
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    • v.13 no.4
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    • pp.11-17
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    • 2009
  • This paper deals with the effects of pulsating flow on volumetric efficiency, which may be generated during the gas exchange procedure, due to piston motion, valve event on intake and exhaust stroke and unsteady flow of turbocharger of a three-cylinder four stroke turbo-charged diesel engine. Consequently, volumetric efficiency affects significantly the engine performance; torque characteristics, fuel economy and further to emission and noise level. As the expansion ratio became larger the engine speed varies and torque increases, the pressure pulsation in an exhaust gas pipe acts as an increasing factor of intake air charging capacity totally. The phase and amplitude of pressure pulsation in the intake system only affects volumetric efficiency favorably, if it is well matched and tuned effectively to the engine. Thus, to verify the exact phase and amplitude of the pressure variation is the ultimate solution for the air-flow ratio assessment in the intake stroke. Some experimental results of pressure diagrams in the intake pipe and gas-flow of turbine in-outlet are presented, under various kinds of operating condition.

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Extended Unmixing-Mixing Scheme for Prediction of 3D Behavior of Porous Composites (다공성 복합재료의 삼차원 거동 예측을 위한 분리-혼합 기법의 확장)

  • Choi, Hoi Kil;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.2
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    • pp.91-97
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    • 2013
  • Pyrolysis and surface recession of charring composites are progressed primarily in the thickness direction. The unmixing-mixing scheme is applied to describe the in-plane and through-thickness behaviors of porous composites. The extended unmixing-mixing equations are based on transverse isotropy of unidirectionally fiber-reinforced composites. The strain components of gas pressure in pores, thermal expansion, and chemical shrinkage are included in the constitutive model. By analyzing micromechanical representative volume elements of porous composites, the validity of the derived equations are examined.

Prediction of Thermoelastic Constants of Unidirectional Porous Composites Using an Unmixing-Mixing Scheme (분리-혼합 기법을 이용한 일방향 다공성 복합재료의 열탄성 계수 예측)

  • Shin, Eui-Sup
    • Composites Research
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    • v.25 no.2
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    • pp.34-39
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    • 2012
  • A thermo-poro-elastic constitutive model of unidirectionally fiber-reinforced composite materials is suggested by extending the unmixing-mixing scheme which is based upon composite micromechanics. The strain components of thermal expansion due to a temperature change, gas pressure in pores, and chemical shrinkage are included in the constitutive model. On purpose to verify the derived constitutive relations, the representative volume element of two-dimensional lamina subject to various loading conditions is analyzed by the finite element method. The overall stress and strain responses are obtained, and compared with the predicted values by the unmixing-mixing scheme. The numerical results show the usefulness of the proposed model to predict the thermoelastic behavior of porous composites.

다양한 동결처리에 따른 과채류의 내부압력 변화 비교

  • 정진웅;정승원;박기재
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.179.2-180
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    • 2003
  • 본 연구에서는 과채류의 냉동냉장시 내부압력에 따른 조직파괴를 방지하기 위한 기초연구로 동결방법에 따른 내부압력 변화에 대하여 조사하였다. 과채류의 동결에 의한 중량감소율은 침지식 동결방식에서 0.44∼l.38% 수준으로 가장 적게 나타났으며, 동결방식에 따른 중량감소율 차이는 수박에서 가장 심하여 수분함량에 클수록 동결속도에 따른 효과가 비교적 크다는 것을 알 수 있었다. 동결속도에 따른 내부압력은 배, 사과 및 메론에 있어 침지식 방법에 의한 동결시 체적팽창 및 수축에 따른 내부압력 차가 가장 적게 나타났으며, 송풍식 동결에서 가장 크게 나타나 동결속도가 빠를수록 내압의 크기는 적다는 것을 알 수 있었으나 딸기 및 수박의 경우는 오히려 침지식에서 내압이 가장 크게 나타났다. 균온 처리하지 않은 동결에 있어 과일의 내부압력 변화는 약 2 psig수준인 반면에 균온 처리한 수박의 내부압력 변화는 균온 처리하지 않은 수박의 내부압력 변화 경향과 유사하지만 일정한 수준의 내압을 발생시킴으로써 내부압력의 크기도 약 1.3 psig수준으로 상당히 적게 나타났다. 또한, 해동시에 있어서도 균온처리한 시료의 내부압력 크기가 균온처리하지 않은 내부압력 크기보다 상대적으로 적게 나타났다. 균온처리 동결시, 다단계 처리보다는 3∼4회 수준의 일정한 균온 처리가 내부압력의 증감 폭을 줄일 수 있었다.

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The Stress-Strain Behavior of a Pure Silt Compared with Sand and Clay (사질토 및 점성토와 비교한 순수 실트의 응력 -변형률 거동)

  • 정상섬
    • Geotechnical Engineering
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    • v.9 no.4
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    • pp.27-36
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    • 1993
  • The drained and undrained behavior of pure silt was investigated experimentally. Special attention was given to the stress-strain behavior of silt prior to failure and behavior at failure under monotonic and cyclic loading. A pure silica flour was chosen to form samples with two different densities of D,=80%, eo=0.68 and D,=35%, eo=0.9. The isotropically consolidated samples were tested in the triaxial testing device under monotonic undrained, drained compression and extension conditions. Also samples were tested under cyclic undrained condition. Based on the experimental results. it was qualitively identified that the overall behavior of silt is similar to that of sand. When compared with clay, silt shows a significantly different behavior due to its dilatant nature under both the monotonic and cyclic shear loadings.

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Preparation and Electrochemical Characterization of Si/C/CNF Anode Material for Lithium ion Battery Using Rotary Kiln Reactor (회전킬른반응기를 이용한 리튬이온전지용 Si/C/CNF 음극활물질의 제조 및 전기화학적 특성 조사)

  • Jeon, Do-Man;Na, Byung-Ki;Rhee, Young-Woo
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.901-908
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    • 2018
  • Graphite is used as a sample anode active material. However, since the maximum theoretical capacity is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of a high capacity lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is higher than that of graphite. However, it is not suitable for direct application to the anode active material because it has a volume expansion of 400%. In order to minimize the decrease of the discharge capacity due to the volume expansion, the Si was pulverized by the dry method to reduce the mechanical stress and the volume change of the reaction phase, and the change of the volume was suppressed by coating the carbon layers to the particle size controlled Si particles. And carbon fiber is grown like a thread on the particle surface to control secondary volume expansion and improve electrical conductivity. The physical and chemical properties of the materials were measured by XRD, SEM and TEM, and their electrochemical properties were evaluated. In this study, we have investigated the synthesis method that can be used as anode active material by improving cycle characteristics of Si.

Earth Pressure Analysis of Tunnel Ceiling according to Tunnel Plastic Zone (터널 소성영역에 따른 터널 천단토압 해석)

  • Park, Shin-Young;Han, Heui-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.753-764
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    • 2020
  • In this study, the plastic zone and internal earth pressure of the tunnel were calculated using the following three methods: metal plasticity to analyze the deformation of metal during plastic processing, Terzaghi's earth pressure theory from the geotechnical perspective and modified Terzaghi's earth pressure theory, and slip line theory using Mohr-Coulomb yield conditions. All three methods are two-dimensional mathematical analysis models for analyzing the plane strain conditions of isotropic materials. Using the theory of metallurgical plastics, the plastic zone and the internal earth pressure of the ground were obtained by assuming that the internal pressure acts on the tunnel, so different results were derived that did not match the actual tunnel site, where only gravity was applied. An analysis of the plasticity zone and earth pressure via the slip-line method showed that a failure line is formed in a log-spiral, which was found to be similar to the real failure line by comparing the results of previous studies. The earth pressure was calculated using a theoretical method. Terzaghi's earth pressure was calculated to be larger than the earth pressure considering the dilatancy effect.