• Journal of Korean Society of Environmental Engineers
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• v.27 no.7
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• pp.697-703
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• 2005

Iron-coated sand(ICS) was prepared with variation of particle size of Joomoonjin sand, primary and secondary coating temperature, coating time, and dosage of initial Fe(III). An optimum condition of the preparation ICS was selected from the coating efficiency, stability of coated Fe(III), and removal efficiency of As(V). Coated amount of Fe(III) increased as primary coating temperature increased with smaller particle size of sand. Coating efficiency was quite similar over the investigated secondary coating temperature and time, while adsorption efficiency of As(V) onto ICS was severely reduced with ICS prepared at higher secondary coating temperature. By considering these results, an optimum secondary coating temperature and time for the preparation of ICS was selected as $150^{\circ}C$ and 1-hr, respectively. Coating efficiency increased us the dosage of initial Fe(III) up to 0.8 Fe(III) mol/kg sand and then no distinct increase was noted. Maximum As(V) adsorption was observed at 0.8 Fe(III) mol/kg sand. Secondary coating temperature and time were important parameters affecting stability of ICS, showing decreased dissolution of Fe(III) from ICS prepared at higher coating temperature and at longer coating time. From anionic type adsorption of As(V) onto ICS, it is possible to suggest the application of ICS for the removal of As(V) contaminated in acidic water system.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.833-838
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• 2007

In this study, adhesion and transport of bacteria in positively-charged media was investigated with batch and column experiments. Bacterial species used in this study was Escherichia coli ATCC 11105(length: 2.2 ${\mu}m$, diameter: 0.6 ${\mu}m$) and media used were quartz sand(particle size distribution: 0.5-2.0 mm, mean diameter: 1.0 mm) and iron-coated sand. Batch results indicate that bacterial adhesion increased as the content of iron-coated media increased. At iron-coated media 0%(quartz sand 100%), around 46% of bacteria was adhered to media while at iron-coated media 100%(quartz sand 0%) about 97% was attached. Column results also show that bacterial adhesion was enhanced with an increase of iron-coated media content. As the iron-coated media content increased from 0 to 100%, bacterial adhesion increased from 8 to 94%. The experimental results demonstrate that positively-charged media could influence transport of bacteria in porous media.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.123-123
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• 2011

알루미늄은 경량 금속으로 부식 저항력이 높아 철을 부식으로부터 보호하기 위한 표면처리 소재로 사용되고 있다. 철의 부식을 방지하기 위해서 알루미늄을 코팅하는 경우, 코팅 방법은 용융도금법이 주로 사용되고 있으며, 알루미늄을 빛의 반사막으로 활용하는 경우 진공 중에서 물리기상증착(physical vapor deposition; PVD)법을 사용하기도 한다. 알루미늄 박막을 물리기상 증착으로 코팅하면 박막성장 초기에 핵(nucleus)을 형성하고, 형성된 핵을 중심으로 주상정(column)으로 박막이 성장하는 것이 일반적이다. 알루미늄 박막의 주상정과 주상정 사이에 공극(pore)이 존재하기 때문에 알루미늄 박막을 부식방지 막으로 이용하기 위해서는 두께를 증가시켜야 한다. 본 연구에서는 스퍼터링(unbalanced magnetron sputtering)을 이용하여 치밀한 조직을 갖는 알루미늄 박막을 코팅할 수 있는 공정변수를 도출하고, 치밀한 알루미늄 조직이 철의 부식에 미치는 영향을 평가하였다. 기판은 냉연강판(cold rolled steel sheet)이 사용되었으며, 알루미늄 타겟의 크기는 직경 4 inch이었다. 알루미늄 박막의 미세조직과 밀도에 영향을 주는 공정변수를 확인하기 위해서 스퍼터링 파워, 공정 압력, 외부 자기장 세기 등의 조건을 변화시켜 코팅을 실시하였다. 알루미늄 박막의 밀도 변화에 가장 큰 영향을 준 공정변수는 외부 자기장의 세기와 방향이었다. 알루미늄 박막이 약 3 ${\mu}m$의 두께로 코팅된 냉연강판을 염수분무시험(salt spray test, 5% NaCl)으로 부식특성을 평가한 결과, 시험을 시작한 후 120시간 후에도 적청이 발생하지 않았다. 이러한 결과는 기존의 동일한 두께를 갖는 알루미늄이 코팅된 강판의 내부식 특성의 2배의 성능을 보여준다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.169.2-169.2
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• 2013

본 연구에서는 gas를 이용한 PECVD 공법중 이온화 에너지가 높고 대면적 코팅이 용이한 Hybrid 코팅 장비에서 Linear Ion-Gun 이용하여 탄화수소 계열의 gas인 $C_2H_2$ 와 Si을 함유한 TMS (tetramethylsilane, $Si(CH_3)_4)$ gas를 이용하여 저마찰, 고경도 특성을 갖는 Si-DLC 코팅에 대한 연구를 수행하였다. Si-DLC 코팅에 앞서 전처리 공정으로 Linear Ion-Gun에 Ar gas를 주입하고 고전압의 DC 전원을 인가하여 제품 표면의 건식세정 및 표면 활성화를 진행 후, $C_2H_2$ 와 TMS gas를 Linear Ion-Gun에 주입하여 Si-DLC 코팅 공정을 진행하였다. Si-DLC 코팅시 $C_2H_2$ gas 주입량을 고정하고 TMS 가스 유량을 5~20sccm으로 조절하여 Si 함유량에 따른 Si-DLC 코팅막의 특성을 분석하였다. 이렇게 코팅된 Si-DLC의 박막 특성 분석으로 마찰계수 측정을 위해 ball-on-disk 타입의 tribometer를 사용하였으며, 박막 경도 측정은 Nano-indenter를 이용하여 분석을 진행하였다. 그 결과 Si을 포함하지 않는 DLC의 경우 마찰계수가 ~0.2를 가지는 반면, Si-DLC의 경우 Si 함유량이 약 1.5at%일 때, 마찰계수 ~0.04 저마찰의 우수한 특성을 지니며, 박막의 경도는 22[Gpa]로 고경도의 Si-DLC 코팅을 확인할 수 있었다.

• Polymer(Korea)
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• v.29 no.3
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• pp.266-270
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• 2005

Iron oxide nanoparticles were prepared by the thermal decomposition of iron pentacarbonyl (Fe(CO)$_5$) Poly(vinylpyrrolidone) (PVP) was used as surface-modifying agent to control the size of the iron oxide nanoparticles. The crystalline structure of PVP coated iron oxide nanoparticles was determined by XRD. The size of PVP coated iron oxide nanoparticles was determined by TEM and ELS. The particle sizes of PVP coated iron oxide nanoparticles were controlled by adjusting the molar ratio of PVP/Fe (CO)$_5$, solvent and molecular weight of PVP Particle sizes increased with increasing PVP content. Spherical $50\~100$ nm sized iron oxide nanoclusters were produced when dimethylformamide was used as a solvent. And well-defined 10 nm iron oxide nanoparticles were produced in Carbitol. The prepared PVP coated iron oxide nanoparticles exhibited a well-dispersed property in water. The results obtained in this study confirmed the feasibility of the PVP-coated iron oxide nanoparticles as a biomaterial for MRI contrast agent.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.473-482
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• 2009

In this study, iron and manganese coated sand (IMCS) was prepared by mixing Joomoonjin sand with solutions having different molar ratio of manganese ($Mn^{2+}$) and iron ($Fe^{3+}$). Mineral type of IMCS was analyzed by X-ray diffraction spectroscopy. Removal efficiency of arsenic through As(III) oxidation and As(V) adsorption by IMCS having different ratio of Mn/Fe was evaluated. The coated amount of total Mn and Fe on all IMCS samples was less than that on sand coated with iron-oxide alone (ICS) or manganese-oxide alone (MCS). The mineral type of the manganese oxide on MCS and iron oxides on ICS were identified as ${\gamma}-MnO_2$ and mixture of goethite and magnetite, respectively. The same mineral type was appeared on IMCS. Removed amount As(V) by IMCS was greatly affected by the content of Fe rather than by the content of Mn. Adsorption of As(V) by IMCS was little affected by the presence of monovalent and divalent electrolytes. However a greatly reduced As(V) adsorption as observed in the presence of trivalent electrolyte such as $PO_4\;^{3-}$. As(III) oxidation efficiency by MCS in the presence of NaCl or $NaNO_3$ was two times greater than that in the presence of $PO_4\;^{3-}$. Meanwhile a greater As(III) oxidation efficiency was observed by IMCS in the presence of $PO_4\;^{3-}$. This was explained by the competitive adsorption between phosphate and arsenate on the surface of IMCS.

• Proceedings of the KSMRM Conference
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• 2003.10a
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• pp.35-35
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• 2003

목적： 나노 산화철 입자 및 생고분자인 PCL(Polycarprolacton)로 표면 코팅한 T2 MR 조영제를 합성하고 동물 종양 모델을 이용하여 In vivo 특성을 조사하고자 하였다. 대상 및 방법： $FeC1_2$.$4H_2$O와 $FeC1_3$.$6H_2$O을 무게비를 1：2로 정량하여 첨가하고 NaOH 혹은 TMAOH로 pH를 조절한후 PCL를 첨가하여 magnetite가 생성되는 동시에 고분자로서 코팅을 한후 증류수로 여러번 씻어준다. TEM, SEM, DLS 및 IR spectroscopy와 SQUID등을 측정하여 최종 반응물의 입자크기, 자성, 코팅 상태등을 평가하였다. 최소의 입자크기를 형성하는데 필요한 실험 조건을 찾기 위해 반응온도, 코팅할 고분자의 함량, 교반속도별로 실험하여서 최적의 조건을 찾으려 하였다. 토끼의 간에 VX2 암종을 이식한 동물 모델을 이용하여 PCL로 표면 코팅된 나노자성체의 in vivo 영상 특성을 알아보았다.

• Journal of Food Hygiene and Safety
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• v.36 no.1
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• pp.51-59
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• 2021

In this study we analyzed the elution rates of 11 metals from 82 metallic kitchen utensils purchased in the market. The elution frequency of the 11 types of metals was iron > aluminum > chromium, nickel > zinc > copper > lead > arsenic > antimony > stannum > cadmium. For metallic kitchen utensils, the elution rate of heavy metals was 7.3-93.9%, and the average elution concentration was 0.001-13.473 mg/L. The average elution concentration of heavy metals was ranged between none-detected (N. D.) to 30.473 mg/L for non-coated kitchen utensils and 0.000-10.005 mg/L for coated kitchen utensils. The average elution concentration of metals from domestic kitchen utensils ranged from 0.001-25.145 mg/L, and from 0.000-33.518 mg/L for imported kitchen utensils. In particular, aluminum was found to be high in domestic kitchen utensils while iron was high in imported kitchen utensils. The average elution concentration of heavy metals was N.D.-2.670 mg/L for stainless steel, N.D.- 31.575 mg/L for aluminum, and N.D.-307.737 mg/L for iron. The amount of transition to food after cooking was investigated.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.151-154
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• 2019

We report the effective fabrication processes for more practical monolith catalysts consisting of washcoated alumina on a cordierite honeycomb monolith (CHM) and iron oxides nanoparticles in the alumina prepared by a simple dry coating method. It is confirmed that iron oxide nanoparticles were well deposited into the mesopore of washcoated alumina which is formed on the corner wall of honeycomb channel, and the effect of annealing temperature was evaluated for carbon monoxide oxidation catalysts. $Fe_2O_3/{\gamma}-Al_2O_3/CHM$ catalysts annealed at $350^{\circ}C$ exhibited the most enhanced catalytic activity, 100% conversion efficiency at more than $200^{\circ}C$ operating temperature.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2004.05a
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• pp.324-328
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• 2004

본 연구에서는 활성탄을 염화철로 표면 처리한 염화철처리 활성탄을 사용하여 지하수중의 ${NO_3}^{-}$－/-N 제거 가능성과 그 제거에 미치는 영향을 검토하고자 한 것으로 다음과 같은 결론을 얻었다. 1) 조제된 염화철 코팅 활성탄의 표면을 SEM으로 분석한 결과를 보면 활성탄의 표면에 염화철이 코팅되어 있는 것을 확인할 수 있었다. 2) 통수유속이 0.5~4 BV $hr^{-1}$/로 낮을 경우는 질산성 질소 파과시점이 비슷하였으며, 통수유속이 커질수록 활성탄의 비표면적에 접하는 시간이 짧아져서 파과시점이 짧아진 것으로 사료된다. 3) 연속컬럼 실험(3.1 L)에서 통수량 약 82 L까지는 ${NO_3}^{-}$/-N의 파과시점이 나타나지 않았으며 재생액의 농도가 0.5 M-KCl에서는 약 9 L, 1 M-KCl에서는 약 7 L의 재생액이 사용되었고, 재생 후 각각의 파과시점은 약 53 L, 59 L로 유지되었다. 1 M-KCl의 재생액을 사용하여 재생하였을 경우 두번째 재사용과 재생부터 총 질산성 질소 제거량은 약 1,531~l,357 mg/kg, 탈착량은 약 1,526~1,306 mg/kg으로 일정하였다.