• Title/Summary/Keyword: 철입자

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A Study on the Development of Model and Application Case of Water Screen Effect for Fire Behavior Simulation in Road Tunnel (도로터널 화재성상 시뮬레이션을 위한 워터스크린 효과 모델개발 및 적용사례)

  • Han, Jung-Chul;Kim, Se-Jong;Kim, Dong-Eun;Kurioka, Hitishi;Ootuki, Masato;Kwon, Young-Jin
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.83-88
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    • 2011
  • 워터스크린(이하 W/S)에 의한 화재방화시스템은 도로터널에 화재가 발생시, 공간에 수막을 사용하여 구획화하고, 열 연기의 확산을 억제하며 유해 부유입자를 세정함으로서 인간의 안전을 확보 및 구조물의 피해를 극소화 하는 시스템이다. 이 W/S에 의한 구획의 성능을 평가하기 위해, 1/2의 터널 모형에 의한 공간 내 열 성장 파악을 위한 화재 실험을 분석하였고, 그 결과, 천정 근방 온도 및 방사수열량으로서는 발열 속도의 크기, 풍속의 대소에 의하지 않고 약 80%의 저감율을 나타냈다. 또, 발생한 유해 부유입자 농도에 대해서는 약 60%, 화원 성질과 상태로서 발열 속도는 약30%의 W/S에 의한 저감 효과를 나타내었다.

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Use of Ferrous and Ferric Coagulants To Reduce Bromate and Particulate Levels (입자상 물질 및 Bromate의 저감을 위한 철염응집제의 이용)

  • Krasner Stuart-W;Yates Richard-S;Amy Gary;Garside Jason
    • 수도
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    • v.24 no.4 s.85
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    • pp.39-46
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    • 1997
  • 실험실 규모의 연구를 확대한 Pilot-Plant연구는 Bromate 감소에 대한 다양한 수질 문제에 대응할 수 있었다. 이러한 연구를 통해 산성하에서 $Fe^{2+}$을 주입시 Bromate가 감소됨을 확인하였다. 그러나 이러한 반응은 느린 반응이었으며, 온도에 의존하는 반응이었다. 단독응집제로서 $Fe^{2+}$은 탁도를 증가시켰다. 따라서 탁도를 제어하기 위해 $Fe^{2+}$를 주입하였다. $Fe^{2+}$/$Fe^{3+}$응집제의 조합으로 TOC를 제거할 수 있었다. 초기 결과를 통해 이러한 공정은 매우 면밀히 추진되어야 하며, 모든 온도에서 적용될 수 없었다. 현재까지 얻어진 결과에 의하면 오존처리함으로서 발생되는 Bromate를 최소화하는 방안은 낮은 pH조건과 $Fe^{2+}$의 주입이다. 최종 처리수에서 입자상물질과 철을 최소화하기 위해서는 pH 등과 같은 조건들을 변화시켜 여과공정 이전에 잔류 $Fe^{2+}$를 산화시킬 수 있도록 초기에 최적화가 이루어 져야 한다.

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Quantification of Particle Velocity and Intensity Estimation Error in a Discrete Domain (이산 영역에서 공간상의 입자속도, 인텐시티 예측 오차의 정량화)

  • 최영철;김양한
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.05a
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    • pp.403-407
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    • 2003
  • This paper studies the error of pressure, particle velocity, and intensity which are distributed in a space. Errors may be amplified when other sound field variables are predicted. We theoretically derive their bias error and random error. The analysis shows that many samples do not always guarantee good results. Random error of the velocity and intensity are increased when many samples are used. The characteristics of the amplification of the random error are analyzed in terms of the sample spacing. The amplification was found to be related to the spatial differential of random noise. The numerical simulations are performed to verify theoretical results.

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Interaction between Selenium and Bacterium and Mineralogical Characteristics of Biotreated Selenium (셀레늄-미생물간의 반응 및 셀레늄 광물화 특성)

  • Lee, Seung-Yeop;Oh, Jong-Min;Baik, Min-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.217-224
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    • 2011
  • Removal of dissolved selenium by D. michiganensis, a iron-reducing bacterium, and effects of dissolved metal elements such as iron, sulfate, and copper were investigated. Selenide that was reduced from selenite (2 mM) by D. michiganensis was gradually removed from the aqueous medium. As the reduced selenide was combined with aqueous iron, it was precipitated as a nanoparticulate iron-selenide. Sulfate and copper negatively affected the microbial selenite reduction, and the copper was especially toxic to the bacterium, inhibiting a microbial removal of dissolved selenite. These results show that it should be carefully biotreated for a selenium-contaminated site considering in situ sulfate or copper distribution and concentration. Consequently, the formation of iron-selenide by bacteria will be an important measure for preventing a long-distance migration of selenium in the subsurface environments.

Effect of the Powder Characteristics of Iron Oxides on the Magnetic Properties of Sr-ferrite (산화철의 분체특성이 Sr-ferrite의 자기특성에 미치는 영향)

  • 조태식;김효준;최승덕;남효덕;염충진
    • Resources Recycling
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    • v.7 no.4
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    • pp.43-49
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    • 1998
  • We investigated the effects of the powder characteristics of various domestic iron oxides (${\alpha}Fe_2O_3$) on the magnetic properties of Sr-ferrites The particle size and the distribution of iron oxides were classified hy three different rerinning methods, and greatly a affected on the magn$\xi$tic prope$\pi$ies and the mmphology of Sr-ferntes. The agglomeration of Ruthner iron oxides and the large particles of Chemirite (CY) above $0.80{\mu}\textrm{m}$ were degraded the prope며es of Sr-fcrrites. The optimal magnetic prope$\pi$ies of Srt territes, showing 68.2 emu/g of saturation magnetization and 4300 Oe of intrinsic coerClvity, were achieved at the following c conditions; Chemirite (P2EP) iron oxides of $0.14{\mu}\textrm{m}$ molar ratio of 5.8. and calcination of $1150^{\circ}C$/1 hr.

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A Research on Superparamagnetic Iron Oxide Nanoparticles' Toxicity to U373MG Cell and its Effect on the Radiation Survival Curve (산화철 나노입자의 U373MG 세포 독성평가 및 방사선 세포생존 곡선에 미치는 영향에 대한 연구)

  • Kang, Seonghee;Kim, Jeonghwan;Kim, Dokyung;Kang, Bosun
    • Journal of the Korean Society of Radiology
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    • v.6 no.6
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    • pp.507-513
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    • 2012
  • This research was performed to evaluate the superparamagnetic iron oxide nanoparticles'(SPIONs) cell toxicity and to measure the radiation cell survival curve changes of SPIONs-uptake glioblastoma multiforme cells. The results could be practically used as the fundamental data to ameliorate proton beam cancer therapy, for example, providing necessary GBM treatment dose in the proton beam therapy when the therapy takes advantage of SPIONs. The assessment of the toxicological evaluation of synthesized SPIONs was accomplished by MTT assay as an in vitro experiment. The results showed no meaningful differences in the cell survival rate at the $1-100{\mu}g/ml$ SPIONs concentrations, but the cell toxicity was shown as the cell survival rate decreased up to 74.2% at the $200{\mu}g/ml$ SPIONs concentration. Then, we measured each radiation cell survival curve for U373MG cells and SPIONs-uptake U373MG cells with 0~5 Gy of proton beam irradiations. It is learned from the analysis of the experimental results that the SPION-uptake cells' radiation survival rate was more rapidly decreased as the irradiation dose increased. In conclusion we confirmed that SPIONs-uptake in U373MG cells induces cell death at the much less dose than the lethal dose of SPION-non-uptake cell. This research shows that the therapeutic efficacy of glioblastoma multiforme treatment in proton beam therapy can be improved by SPIONs targeting to the GBM cells.

A Study on the Removal of Cu and Fe Impurities on Si Substrate (Si 기판에서 구리와 철 금속불순물의 제거에 대한 연구)

  • Choi, Baik-Il;Jeon, Hyeong-Tag
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.837-842
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    • 1998
  • As the size of the integrated circuit is scaled down the importance of Si cleaning has been emphasized. One of the major concerns is abut the removal of metallic impurities such as Cu and Fe on Si surface. In this study, we intentionally contaminated Cu and Fe on the Si wafers and cleaned the wafer by cleaning splits of the chemical mixture of $\textrm{H}_2\textrm{O}_2$ and HF and the combination of HF treatment with UV/$\textrm{O}_3$ treatment. The contamination level was monitored by TXRF. Surface microroughness of the Si wafers was measured by AFM. The Si wafer surface was examined by SEM. AES analysis was carried out to analyze the chemical composition of Cu impurities. The amount of Cu impurities after intentional contamination was abut the level of $\textrm{10}^{14}$ atoms/$\textrm{cm}^2$. The amount of Cu was decreased down to the level of $\textrm{10}^{10}$ atoms/$\textrm{cm}^2$ by cleaning splits. The repeated treatment exhibited better Cu removal efficiency. The surface roughness caused by contamination and removal of Cu was improved by repeated treatment of the cleaning splits. Cu were adsorbed on Si surface not in a thin film type but in a particle type and its diameter was abut 100-400${\AA}$ and its height was 30-100${\AA}$. Cu was contaminated on Si surface by chemical adsorption. In the case of Fe the contamination level was $\textrm{10}^{13}$ atoms/$\textrm{cm}^2$ and showed similar results of above Cu cleaning. Fe was contaminated on Si surface by physical adsorption and as a particle type.

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Autotrophic Perchlorate-Removal Using Zero-Valent Iron and Activated Sludge: Batch Test (영가철과 활성슬러지를 이용한 독립영양방식의 퍼클로레이트 제거: 회분배양연구)

  • Ahn, Yeong-Hee;Ha, Myoung-Gyu
    • Journal of Life Science
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    • v.21 no.3
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    • pp.444-450
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    • 2011
  • Perchlorate ($ClO_4^-$) is a contaminant found in surface water and soil/ground water. Autotrophic perchlorate-reducing bacteria (PRB) use hydrogen gas ($H_2$) as an electron donor to remove perchlorate. Since iron corrosion can produce $H_2$, feasibility of autotrophic perchlorate-removal using zero-valent iron (ZVI) was examined in this study using activated sludge that is easily available from a wastewater treatment plant. Batch test showed that activated sludge microorganisms could successfully degrade perchlorate in the presence of ZVI. The perchlorate biodegradation was confirmed by molar yield of $Cl^-$ as perchlorate was degraded. Scanning electron microscope revealed that rod-shaped microorganisms on the surface of iron particles used for the autotrophic perchlorate-removal, suggesting that iron particles could serve as supporting media for the formation of biofilm as well. DGGE analyses revealed that microbial profile of the inoculum (activated sludge) was different from that of biofilm sample obtained from the ZVI-added enrichment culture used for $ClO_4^-$-degradation. A major band of the biofilm sample was most closely related to the class Clostridia.

Preparation of the Dexamethasone-incorporated Lipid Nanosphere: Characteristics of Lipid Nanosphere by Varying Species and Ratio of Lipid (덱사메타손이 봉입된 지질나노입자의 제조: 지질의 종류와 함량 변화에 따른 지질나노입자의 특성)

  • Jeong, Seok-Hyeon;Lee, Jeong-Eun;Seong, Ha-Su;Sin, Byeong-Cheol
    • Journal of the Korean Chemical Society
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    • v.50 no.6
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    • pp.464-470
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    • 2006
  • the coricosteroid drug dexamethasone is an efficacious antiinflammatory drug, it is difficult to formulate in an injectable formulation due to its poor aqueous solubility. A lipid-based nanosphere formulation containing dexamethasone was designed for solubilization of the drug in aqueous solution and sustained release of the drug from the nanosphere. The lipid nanospheres, composed of phospholipid, cholesterol and cationic lipid, were prepared by self emulsification-solvent diffusion method followed by diafiltration. Physicochemical characteristics such as mean particle diameter, zeta potential and drug loading efficiency of the lipid nanospheres were investigated according to the variation of either the kind of lipid or the lipid composition. The lipid nanospheres had a mean diameter 80-120 nm and dexamethasone loading efficiency of greater than 80%. The drug loading efficiency increased with the increase of the length of aliphatic chain attached to the phospholipid. However, the drug loading efficiency was inversely proportional to the increase of cholesterol content in the lipid composition. The lipid nanosphere could not be prepared without the use of cationic lipid and the drug loading efficiency was proportional to the increase of cationic lipid content. The lipid nanospheres containing dexamethasone are a promising novel drug carrier for an injectable formulation of the poorly water-soluble drugs.

Bioassessment of Nanoparticle Toxicity based on Seed Germination and Germination Index of Various Seeds (다양한 씨앗의 발아 및 발아지수에 근거한 나노입자 생물학적 독성평가)

  • Gu, Bon Woo;Lee, Min Kyeung;Shi, Yu Tao;Kong, In Chul
    • Clean Technology
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    • v.21 no.1
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    • pp.39-44
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    • 2015
  • This study investigated the effects of six metal oxide nanoparticles (NPs: CuO, NiO, TiO2, Fe2O3, Co3O4, ZnO) on seed germination and germination index (G.I) for five types of seeds: Brassica napus L., Malva verticillata L., Brassica olercea L., Brassica campestris L., Daucus carota L. NPs of CuO, ZnO, NiO show significant toxicity impacts on seed activities [CuO (6-27 mg/L), ZnO (16-86 mg/L), NiO (48-112 mg/L)], while no significant effects were observed at > 1000 mg/L of TiO2, Fe2O3, Co3O4. Tested five types of seed showed different sensitivities on seed germination and root activity, especially on NPs of CuO, ZnO, NiO. Malva verticillata L. seed was highly sensitive to toxic metal oxide NPs and showed following EC50s : CuO 5.5 mg/L, ZnO 16.4 mg/L, NiO 53.4 mg/L. Mostly following order of toxicity was observed, CuO > ZnO > NiO > Fe2O3 ≈ Co3O4 ≈ TiO2, where slightly different toxicity order was observed for carrot, showing CuO > NiO ≈ ZnO > Fe2O3 ≈ Co3O4 ≈ TiO2.