• Clean Technology
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• v.19 no.4
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• pp.487-491
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• 2013

To efficiently desorb gold and copper-cyanide complexes adsorbed onto Dowex21K XLT resin, the mixed solvent with HCl and acetone which is a kind of dipolar aprotic solvent was used as a desorbing agent. The desorption efficiency for gold-cyanide complex was the highest as about 94% when the mixing ratio of HCl and acetone based on volume was the 7:3, however, the value decreased as the ratio of acetone increased. In the case of copper-cyanide complex, most of them was desorbed when the amount of HCl was relatively higher than that of acetone, however, desorption efficiency decreased as the ratio of acetone increased. The desorption efficiency for gold and copper-cyanide complexes was the 94 and 100%, respectively at the 0.6 M of HCl with the 7 (HCl) : 3 (Acetone) of mixing ratio and desorption efficiency for gold-cyanide complex not increased any more even though higher HCl concentration was used. And the desorption efficiency for gold and copper-cyanide complexes was about 100% at the S/L raio ${\leq_-}1.0$ whereas desorption efficiency for gold-cyanide complex was very low as about 20-29% at the S/L ratio > 1.0. Also, most of desorption process for gold and copper-cyanide complexes was completed within 120 min.

• Defense and Technology
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• no.1 s.155
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• pp.44-49
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• 1992

세계 여러나라의 유도무기 체계에서 사용되고 있는 착화기술에 대한 현황을 기술과 성능, 신뢰성, 안전성, 가격 측면에서 분석한 것이다. 이로써 유도무기체계 적용을 위한 각 착화기술의 상대적인 장단점을 비교할수있고, 가격대비 성능개선에 대한 예측과 무기체계 시스템에 진보된 기술들이 대체되는 경향을 평가할 수있을 것이다. 동시에 각 무기체계에 효과적인 비용과 기술로 최적의 착화시스템을 선택할수 있도록 하는 안내역으로서 보다 현실적이고 다양한 결정을 하는 기초를 제공할수 있으리라 생각된다

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.11a
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• pp.81-82
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• 2007

3가크롬 도금액은 크롬원 (황화물계 또는 염화물계), 착화제, 완충제, 전도보조제, 산화방지제, 유기첨가제등으로 구성되어 있으며, 특히 착화제와 유기첨가제가 용액의 안정성 및 균일전착성에 미치는 영향이 크다고 보고되고 있다. 본 연구에서는 카르복시기의 작용기를 갖는 유기산을 착화제로 사용하고, 다양한 유/무기 첨가제의 조합 및 첨가량을 조절하여 크롬의 전착특성을 고찰하였다.

• Proceedings of the KAIS Fall Conference
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• 2003.06a
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• pp.322-324
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• 2003

이온교환은 액체상에 존재하는 이온과 고체상에 존재하는 이온이 당량적으로 치환되는 것으로 정의하며, 치환되는 정도는 일반적으로 전하의 크기와 이온이 수화반경에 따라 달라진다. 지금까지의 이온교환 반응에 대한 모델링 연구는 실험식, 질량작용식, 열역학식, 전기이중층이론, 표면착화모델 등을 이용하여 2 성분에 대하여 다양한 시도를 하였다. 본 연구에서는 2, 3, 4성분에 대해 질량작용법칙과 전기이중층이론을 조합한 표면착화모델과 질량작용법칙을 이용한 모델을 수행하였다. 그 결과 표면착화모델이 질량작용법칙을 이용한 것보다 실험치와 일치함을 알 수 있었다.

• 방재와보험
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• s.57
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• pp.74-77
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• 1993

• Clean Technology
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• v.19 no.3
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• pp.249-256
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• 2013

The experiments have been performed to obtain zinc complex compound with smaller particle sizes, which is used as a charge control agent in manufacturing toner. Metallic salts and polyhydric alcohols have been studied to investigate their effects on the formation and the triboelectric charge of zinc complex-compound particle with different sizes. Reactants such as zinc chloride and 3,5-di-tert.-butyl salicylic acid have been used to form the complex compound. Polyethylene glycol (PEG-300), glycerin and ethylene glycol have been added into the zinc chloride solution beforehand to lower the reaction rate in the formation of zinc complex-compound. Aluminium(III) chloride has been mixed in the zinc chloride solution beforehand to restrain the particle size from growing. When PEG-300 and aluminium(III) chloride are used to lower the reaction rate and to restrain the particle size from growing, the average particle size of zinc complex compound decreases from $5.28{\mu}m$ to $2.33{\mu}m$, which was 44.1% of $5.28{\mu}m$.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.8-13
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• 2012

The experiments have been performed to obtain zinc complex compound with smaller particle size, which is used as a charge control agent in manufacturing toner. Metallic salts and polyhydric alcohols have been studied to investigate their effects on the formation of different sizes of zinc complex-compound particle. Reactants such as zinc chloride and 3,5-di-tert-butyl salicylic acid have been used to form the complex compound. Polyethylene glycol (PEG-300), glycerin and ethylene glycol have been added into the zinc chloride solution beforehand to lower the reaction rate in the formation of zinc complex-compound. Zirconium (IV) oxychloride octahydrate has been mixed in the zinc chloride solution beforehand to restrain crystals from growing. When PEG-300 and zirconium (IV) oxychloride octahydrate are used to lower the reaction rate and to restrain the particle size from growing, the average particle size of zinc complex compound decreases from 5.28 to 1.84 ${\mu}m$, which is 34.9% of 5.28 ${\mu}m$.

• Journal of the Korean Chemical Society
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• v.51 no.6
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• pp.526-535
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• 2007

Ru(II)-terpyridine complexes (8, 9, 11) linked with adamantyl or β-cyclodextrin moieties were synthesized and characterized based on their 1H and 13C NMR spectra as well as MS spectra. Ru(II)-terpyridine complexes (8, 11) linked with adamantyl moiety were readily dissolved in aqueous solution via encapsulation by β-cyclodextrin when they were mixed with an equimolar amount of β-cyclodextrin. In the similar way, the adamantane guest of the Ru(II)-terpyridine complexes (8, 11) were encapsulated by β-cyclodextrin moiety of the ruthenium complex 9 to afford supramolecular assemblies in aqueous environment. Formation of assemblies was corroborated by 1H NMR spectroscopy.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.359-365
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• 2021

We investigated experimentally the ignition characteristic of dust and the hazard evaluating for electrostatic discharge. The ignition energy experiments were performed on sample dusts such as PE(HD), PE(LD), PMMA using the MIKE-3 apparatus. The formation of flame during the ignition of PE(HD) dust clouds occurred after the delay time of about 8 ms, and the flame kernels were not observed in center of ignition occurrence area. The voltage increased with increasing the number of dust dispersions and the increase rate of measured voltage with dust concentration was the highest in the order of PMMA, PE(LD) and PE(HD). For the effect of dispersion condition on the voltage in PE(HD) dust, the results were obtained that the voltage increased as the number of dispersions increased and as the concentration increased under the same dispersion number. The safety voltages to prevent fire and explosions by electrostatic ignition were estimated that PE(HD), PE(LD)-1, PE(LD)-2, and PMMA were 2.58, 44.72, 25.82, and 8.16 kV, respectively. We proposed the method for estimating the minimum ignition energy by using the measured voltage data for efficient investigation of electrostatic ignition hazard.

• Journal of the korean Society of Automotive Engineers
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• v.2 no.1
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• pp.9-20
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• 1980

디이젤기관의 냉시동성이 가솔린기관에 비하여 떨어지는 것은 이미 우리가 알고 있는 사실이다. 근년에는 소형트럭, 승용차, 소형건설기계 등의 분야에 있어서도 고속디이젤기관을 널리 사용하게 되었고 앞으로 디이젤연료의 중질화 및 세탄가 저하의 영향 등을 고려할 경우 시동성의 확보는 더욱 중요한 문제로 된다. 시동성에 영향을 미치는 인자 혹은 시동성개선의 방책으로서는 분 무의 착화에 직접 관련되는 것 외에 축전지의 저온특성 혹은 기관의 마찰토오크 등 여러가지에 걸쳐 있으나 이들 중에서 특히 분무의 착화에 직접 관련되는 방책에 관해서는 그것이 시동성에 미치는 영향에만 그치는 것이 아니고 시동개시직후에 있어서 배출가스, 혹은 출력성능 등에 미 치는 영향에 대해서도 함께 고려를 하여야 할 경우가 있다. 본고에 있어서는 냉시동시의 분무의 착화에 대하여 직접 관련하거나 그것을 촉진시킨다고 생각되는 몇개의 인자와 구체적인 방책을 취급하므로써 그것들이 시동성 및 시동직후의 청백연 혹은 출력성능 등에 대하여 미치는 영향에 대해서 기술하며 아래에서 취급되는 시동시의 착화를 촉진하기 위한 실제적인 인자 및 방책은 어느 것이나 기본적으로는 하나의 개념에 집약된다. 즉 그것은 연표와 효소로부터 이루어지는 연소계에 있어서 착화조건을 갖추어야함을 말할 것도 없다.