• Title/Summary/Keyword: 질소산화물 저감

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A Study on the Regeneration of SCR Catalyst Deactivated by Unburned Carbon Deposition (탄소침적으로 피독된 탈질 촉매의 재생에 관한 연구)

  • Moon, Seung-Hyun;Lee, Seung-Jae;Ryu, In-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.928-935
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    • 2010
  • A bag filter system was partially burnt down during a trial run of waste wood incineration boiler. This brought about unburned hydrocarbon which caused a rapid deactivation of low temperature SCR catalyst set up in two stage after the bag filter. The deactivated catalyst was investigated in order to trace the origin by several characterization methods such as XRD, EDX, BET, TGA, SEM. The deactivated catalyst was regenerated by different methods such as acid washing, water washing in ultrasonication, and calcination treatment under air condition. It is found the calcination treatment under air condition at $450^{\circ}C$ for 2 hours to be the best regeneration method. The catalytic activity was measured in the form of 2 cm ${\times}$ 2 cm ${\times}$ 10 cm (catalyst weight 10 g) honeycomb type. A deNOx efficiency of the regenerated catalyst showed 100% at $180^{\circ}C$ which is the same level of fresh one.

A Study of Improving Fuel Droplet Movement with Sonic Wave Radiation (음파를 이용한 연료 입자 운동성 향상에 관한 연구)

  • Min, Sunki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.608-613
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    • 2019
  • NOx (Nitrogen oxide) in the exhaust gas from vehicle engines is considered one of the most harmful substances in air pollution problems. NOx is made when combustion occurs under high temperature conditions and EGR (exhaust gas recirculation) is normally used to lower the combustion temperature. As the EGR ratio increases, the NOx level becomes low, but a high EGR ratio makes the combustion unstable and causes further air pollution problems, such as CO and unburned hydrocarbon level increase. This study showed that fuel droplets could move more freely by the radiation of sonic wave for the stable combustion. In addition, the engine performance improved with increasing EGR ratio. As a basic study, the effect of sonic wave radiation on the velocity of fuel droplets was studied using CFD software. The results showed that the velocity of small droplets increased more under high frequency sonic wave conditions and the velocity of the large droplets increased at low frequency sonic wave conditions. In addition, an engine analysis model was used to study the effects of the increased combustion stability. These results showed that a 15% increase in EGR ratio in combustion resulted in a 45% decrease in NOx and a 10% increase in thermal efficiency.

Pyrolysis Effect of Nitrous Oxide Depending on Reaction Temperature and Residence Time (반응온도 및 체류시간에 따른 아산화질소 열분해 효과)

  • Park, Juwon;Lee, Taehwa;Park, Dae Geun;Kim, Seung Gon;Yoon, Sung Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.7
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    • pp.1074-1081
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    • 2021
  • Nitrous oxide (N2O) is one of the six major greenhouse gases and is known to produce a greenhouse ef ect by absorbing infrared radiation in the atmosphere. In particular, its global warming potential (GWP) is 310 times higher than that of CO2, making N2O a global concern. Accordingly, strong environmental regulations are being proposed. N2O reduction technology can be classified into concentration recovery, catalytic decomposition, and pyrolysis according to physical methods. This study intends to provide information on temperature conditions and reaction time required to reduce nitrogen oxides with cost. The high-temperature ranges selected for pyrolysis conditions were calculated at intervals of 100 K from 1073 K to 1373 K. Under temperatures of 1073 K and 1173 K, the N2O reduction rate and nitrogen monoxide concentration were observed to be proportional to the residence time, and for 1273 K, the N2O reduction rate decreased due to generation of the reverse reaction as the residence time increased. Particularly for 1373 K, the positive and reverse reactions for all residence times reached chemical equilibrium, resulting in a rather reduced reaction progression to N2O reduction.

A Study on the Installation of SCR System for Generator Diesel Engine of Existing Ship (기존 선박의 디젤발전기용 SCR 시스템 설치에 관한 연구)

  • Ryu, Younghyun;Kim, Hongryeol;Cho, Gyubaek;Kim, Hongsuk;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.412-417
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    • 2015
  • The IMO MEPC has been increasingly strengthening the emission standard for marine environment protection. In particular, nitrogen oxide (NOx) emissions of all ocean-going ships built from 2016 will be required to comply with the Tier-III regulation. In this study, a vanadia based SCR (Selective Catalytic Reduction) system developed for ship application was installed on a diesel engine for power generation of the training ship T/S SAENURI in Mokpo National Maritime University. For the present study, the exhaust pipeline of the generator diesel engine was modified to fit the urea SCR system. This study investigated the NOx reduction performance according to the two kind of injection method of urea solution (40%): Auto mode through the PLC (Programable Logic Control) and Manual mode. We were able to find the ammonia slip conditions when in manual mode method. So, the optimal urea injection quantity can be controlled at each engine load (25, 35, 50%) condition. It was achieved 80% reduction on nitrogen oxide. Furthermore, we found that the NOx reduction performance was better with the load up-down (while down to 25% from 50%) than the load down-up (while up to 50% from 25%) test.

Evaluation of EGR applicability for NOx reduction in lean-burn LPG direct injection engine (초희박 LPG 직접분사식 엔진에서 질소산화물 저감을 위한 배기재순환 적용성 평가)

  • Park, Cheolwoong;Cho, Seehyeon;Kim, Taeyoung;Cho, Gyubaek;Lee, Janghee
    • Journal of the Korean Institute of Gas
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    • v.19 no.4
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    • pp.22-28
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    • 2015
  • In order to keep the competitiveness of LPG fuel for transportation fuel, the difference in fuel consumption with gasoline and cost for an aftertreatment system should be reduced with continuous development of technology for LPG engine. In the present study, spray-guided type direct injection combustion system, whose configuration is composed of direct injector in the vicinity of spark plug, was employed to realize stable lean combustion. A certain level of nitrogen oxides($NO_x$) emits due to a locally rich mixture regions in the stratified mixture. With the application of EGR system for the reduction of $NO_x$, 15% of $NO_x$ reduction was achieved whereas fuel consumption and hydrocarbon emission increased. By the application of EGR, the combustion speed reduced especially appeared at initial flame development period and peak heat release rates and increasing rates for heat release rate decreased as EGR rate increased due to the dilution effect of intake air.

The Fuel Effect for VOCs exhausted from vehicle (자동차배출 VOCs의 연료영향에 관한 연구)

  • 류정호;엄명도;임철수;유영숙;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.05b
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    • pp.333-334
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    • 2003
  • 자동차로 인한 대기오염은 규제물질 뿐만 아니라 많은 미량유해물질들에 크게 기여하고 있다. 이러한 자동차 배출가스들은 1차 대기오염물질로 배출되기도 하지만 그중 탄화수소나 질소산화물 등은 대기중 광산화반응을 거쳐 2차 오염물질 생성에 관여하여 더 심화된 대기질 저하에 기인하고 있다. 이처럼 자동차에서 배출되는 탄화수소류에 포함되어 있는 VOCs는 이러한 2차 오염물질로 생성되는 성분중 오존에 긴밀히 관여하여 인체 등에 미치는 영향이 크기 때문에 VOCs 저감을 위한 여러 가지 방안들이 고려되고 있다. (중략)

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An Experimental Study on NOx Reduction in Exhaust Gas from Agricultural Diesel Engine with Plasma and Catalyst (플라즈마와 촉매를 이용한 농용 디젤기관 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 이승규;조기현;황의현
    • Journal of Biosystems Engineering
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    • v.24 no.6
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    • pp.465-472
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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The need to develop Nitrogen Oxides(NOx) Reduction Equipment and Regulation in Marine (선박용 질소산화물(NOx) 저감장치 개발의 필요성 및 규제현황)

  • Kim, Sungyun;Kim, Min
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.69-74
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    • 2012
  • Looming global environmental pollution problems around the world movement to minimize the environmental pollution is actively taking place. International Maritime Organization (IMO) a significant portion of the marine pollution by exhaust gases emitted from vessel considered, and accordingly developed around the ship and ship-related environmental regulations, emission standards are going to strengthen gradually, the development of environmentally friendly vessels and equipment is proceeding actively.

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Low NOx Burner for Bio-fuel (바이오연료용 저 NOx 버너)

  • Baik, Doo-Sung;Lee, Jong-Sun
    • Proceedings of the KAIS Fall Conference
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    • 2008.11a
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    • pp.436-438
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    • 2008
  • 에너지와 환경에 대해 사회적인 이슈가 되어 왔으며, 이중 바이오 연료는 친환경적인 연료로 이미 연구를 해오고 있다. 그러나 바이오연료 특성상 질소산화물이 경유에 비해서 20~30%가 더 많이 배출되므로 적용에 따른 환경문제가 대두되었다. 따라서 본 연구는 폐식용유를 이용한 바이오연료를 버너에 적용하여 발생되는 배기가스를 저감할 수 있는 기술을 개발하고자 했다.

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An Experimental Stduy on NOx Reduction in Exhaust Gas from Diesel Engine with Plasma (플라즈마를 이용한 디젤엔진 배기가스 중의 NOx 저감에 관한 실험적 연구)

  • 조기현;황의현
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.8
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    • pp.83-90
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

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