• Title/Summary/Keyword: 질소가스

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Analysis on the Performance and the Emission of the Integrated Gasification Combined Cycle Using Heavy Oil (중잔사유 가스화 복합발전 사이클의 성능 및 환경배출 해석)

  • Lee, Chan;Yun, Yong-Seong
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.188-194
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    • 2001
  • The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.

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Evaluation Study on the Effects of $NO_x$ Reduction Techniques on the Performance and the Emission Characteristics of Medium Size Gasification Combined Cycle Plant (중급 규모 가스화 복합발전 플랜트의 $NO_x$ 저감 방식이 성능 및 환경특성에 미치는 영향에 관한 평가 연구)

  • Lee, Chan;Seo, Je-Young
    • Journal of Energy Engineering
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    • v.10 no.4
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    • pp.363-369
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    • 2001
  • Process design and performance evaluation were made for medium-size gasification combined/cogeneration plant. Based on the designed plant process configuration, the effects of $NO_x$ reduction techniques on the $NO_x$ emission, the power output, the efficiency and the stability of plant are investigated by applying various $NO_x$ reduction methods such as unsaturated/saturated nitrogen injection and fuel saturation of gas turbine combustor. The $NO_x$ reduction by nitrogen injection is more remarkable than that by fuel saturation, and its effect can be more enhanced by using saturated nitrogen. In addition, the applications of $NO_x$ reduction techniques accompany the improvement of plant power output and efficiency with the decrease of $NO_x$ emission, while it can cause unstable gas turbine operation.

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Gas Nitriding (가스 질소화)

  • 이상윤
    • Journal of the KSME
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    • v.22 no.4
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    • pp.308-315
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    • 1982
  • 가스실화업은 페라이트 화학열처리(ferritic thermochemical treatment)로서 실소운자가 500-560.deg. C의 온도범위에서 페라이트상 내에 확산삼투되므로 실온까지 냉각할 시 상변태가 일어나지 않는다. 가스실화볍은 1920년대 처음으로 이용되었으며 그 이후로 이의 적용범위가 확대되어 현재는 상당히 많은 종류의 강에 적용되고 있다.

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Change of Organic Matter Decomposition Rates and Greenhouse Gas Emission of the Soil of Gyeongan Stream under Different Environmental Conditions (환경 조건 차이에 의한 경안천 토양의 유기물 분해속도와 온실가스 발생 변화)

  • Choi, In Young;Kang, Min Kyoung;Choi, Jung Hyun
    • Korean Journal of Ecology and Environment
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    • v.46 no.1
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    • pp.75-85
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    • 2013
  • This study investigated the effects of organic matter decomposition on the emission of greenhouse gas under the influence of environmental factors such as change of climate condition ($CO_2$ concentration and temperature), vegetation, and N concentration in the soil of Gyeongan stream in the laboratory. The experimental results showed that organic matter decomposition and $CH_4$, $CO_2$ flux were influenced by changes of complex environmental conditions. Organic matter decomposition rate was affected by changes of climate condition with N concentration and climate condition with vegetation. Through the results of $CH_4$, $CO_2$ flux, $CH_4$ flux was affected by change of climate condition with N concentration and climate condition with vegetation and affected by the presence of vegetation and N concentration. $CO_2$ flux was affected by change of climate condition with vegetation and vegetation with N concentration. According to results of the study, change of (1) climate conditions, (2) vegetation, and (3) N concentration, each have an effect on organic decomposition rate, that also influences emission of greenhouse gas. It is known that climate change is related to an increase in greenhouse gasses in the atmosphere However, additional study will be needed whether vegetation could remove positive effect of nitrogen addition in soil since this study shows opposite results of organic matter decomposition in response to the nitrogen addition.

Design and Implementation of Gas Leakage Alarm IoT System for Safety Helmet (안전모 장착용 가스 누출 경보 IoT 시스템 설계 및 구현)

  • Ju, Yong-Min;Lee, Hyo-Seung;Oh, Jae-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.6
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    • pp.1411-1416
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    • 2018
  • Currently, most of the industrial areas like chemistry, manufacturing, shipbuilding, and steel, perform the work related to gas, and the staffs who are in charge of this work have a risk of suffocation without cognizing incidents like gas leak. For example, when the nitrogen gas leaked in 2015 at Paju, two people were killed and four people were injured. In 2018 at Pohang, four workers were suffocated to death from nitrogen gas. In order to solve this problem, this study realized the system in which workers could immediately cognize the gas leak and also deliver the situation to the staff in charge of safety at the same time, by installing the IoT device composed of gas sensor and communication module on the safety helmet that should be worn by field workers. This study is expected to be able to reduce the casualties caused by gas leak in industrial sites.

NO Gas Sensor with Enhanced Sensitivity Using Activated Carbon Prepared from Pyrolysis Fuel Oil and Polyethylene Terephthalate (열분해 연료유 및 PET 기반 활성탄을 이용한 NO 가스 센서의 감도 향상 연구)

  • Kwak, Cheol Hwan;Seo, Sang Wan;Kim, Min Il;Im, Ji Sun;Kang, Seok Chang
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.42-48
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    • 2021
  • In this study, a sensor for detection of nitric oxide (NO) gas was developed using petroleum pitch-based activated carbon which was synthesized from pyrolysis fuel oil (PFO). Polyethylene terephthalate (PET) was added to increase molecular weight by stimulating a polymerization of components in PFO during the pitch synthesis process. The increase in the molecular weight of pitch contributed to the improvement of textural properties of activated carbon, such as the specific surface area and micropore volume. It also enhanced the sensitivity of NO gas sensor based on the activated carbon. In addition, the effect of PET addition during the pitch synthesis on the surface oxygen content and conductivity of activated carbon was investigated. Finally, the correlation of the sensitivity with physical properties of activated carbon was analyzed.

Investigation of Effects of Shield Gas on Counterflow Flame Structure (차폐가스가 대향류 화염구조에 미치는 영향의 조사)

  • Park, Woe-Chul
    • Journal of the Korean Society of Safety
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    • v.17 no.2
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    • pp.112-117
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    • 2002
  • The effects of shield gas on the structure of methane-air nonpremixed counterflow flames were numerically investigated. The near extinction flame of a low global strain rate 20 $s^{-1}$ of 19% methane diluted by 81% nitrogen by volume and undiluted air was computed. The flame shape, centerline temperature and axial velocity profiles were compared for different velocity of the shield gas and with and without the shield gas. The effects of the velocity of the shield gas were negligible for $V_{S}/V_{F}{\leq}2$ in normal gravity. Under normal gravity conditions, the flame shape and its position with the shield gas were different from those of the flame without the shield gas, whereas no discernible effects of the shield gas along the centerline were observed in zero gravity.

인도네시아의 질소비료 현황

  • 한국비료공업협회
    • 비료회보
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    • s.573
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    • pp.10-21
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    • 2005
  • 데이비드 헤이스는 지역의 천연가스 수요의 계속적인 증가 및 국가보조금의 삭감으로 인한 여분 천연가스 원료물질의 부족이 증가하고 있는 추세에 대해 인도네시아 요소 산업이 어떻게 대처하고 있는지에 대하여 보고한다.

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Background Reduction for the ${\gamma}$-Ray Spectrometry of Environmental Radioactivity (환경방사능의 감마선 분광분석을 위한 백그라운드 소멸)

  • Seo, Bum Kyoung;Lee, Kil Yong;Yoon, Yoon Yeol;Lee, Dae Won
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.212-220
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    • 2001
  • This study was performed to establish the analytical method of radium and radon in various environmental samples with the ${\gamma}$-ray spectrometry. The major problem in the measurements of low level ${\gamma}$-ray, such as environmental radioactivity, is the fluctuation of ${\gamma}$-ray background spectrum. To overcome this problem, a nitrogen gas was filled up in the detector chamber to reduce the background counts due to airborne radioactivities, i.e., $^{214}Pb$ and $^{214}Bi$, the daughters of $^{222}Rn$ in air. When nitrogen gas flowed around the detector, peak counts of ${\gamma}$-rays from the daughters of $^{222}Rn$ decreased about 80% below 1 MeV and about 20~50% above 1 MeV. The use of nitrogen purging results in approximately tenfold increment of sensitivity.

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