• Title/Summary/Keyword: 질산성 질소

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Effect of SCB Liquid Manure Application in Pear Orchard Managed by Cover Crop System on Tree Growth, Potential Nutrient Recovery and Soil Physicochemical Properties (녹비작물 재배 시 SCB 액비 혼용이 배나무 생육 및 양분 환원 가능량, 토양 물리화학성에 미치는 영향)

  • Lee, Seong-Eun;Park, Jin-Myeon;Choi, Dong-Geun
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.779-786
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    • 2012
  • Many farmers have been seeking alternatives to chemical fertilizer for successful organic fruit production. This experiment was carried out to investigate the replaceability of chemical fertilizer by cover crop and slurry composting biofiltration (SCB) liquid manure (LM) application in pear orchard. Three treatments were contained in this experiment; cover crop only and cover crop + LM treatment, and control (chemical fertilizer application). Dry weight and mineral contents of gramineous cover crops were significantly increased in LM-combined treatments than that of leguminous species. Bulk density of soil was decreased in rye + LM and hairy vetch + LM treatments, compared with each cover crop treatment. Soil pH was lowest in fertilizer treatment and soil nitrate content became similar between treatments after rainy season. Available soil phosphate was lower in cover crop and cover crop + LM treatmemts than control, but exchangeable Mg was higher. The mineral content and net assimilation rate of leaves showed no difference between the treatments. As a result, it is suggested that the application of SCB liquid manure in pear orchard managed by cover crops is desirable to maintain the productivity by improving soil physical properties and potential nutrient recovery.

A Study on the Influence of Water Quality on the Phosphorus Fraction Properties from Reservoir Sediments (저수지 퇴적물로부터 인의 존재형태가 수질에 미치는 영향에 대한 연구)

  • Lee, Jin-Kyung;Ahn, Tae-Woong;Oh, Jong-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.840-850
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    • 2010
  • The present study was attempted to find the effects of structural properties of phosphorus on the water quality of Gyehwa reservoir in Saemangeum. Relationship of phosphorus fractions between water and sediment properties was closely examined, and a few types of phosphorus were found from the sample sediment as : Saloid-P, Al-P, Fe-P, Ca-P, Red-P and Occd-P. Saloid-P (1.4%), Al-P (0.5%), Fe-P (39.8%), Ca-P (56.6%), Red-P (0.4%), Occd-P (1.3%) were extracted in a mass basis from the sediment of Gyehwa reservoir. Approximately more than 97% of phosphorus were calcium related phosphorus (Ca-P, 56%) and iron bound phosphorus (Fe-P, 39.8%). The Fe-P closely relates with water quality of T-N (r=0.761, p<0.05), $NO_3$-N (r=0.754, p<0.05), $NH_4$-N (r=0.728, p<0.05), T-P (r=0.774, p<0.05) and $PO_4$-P (r=0.767, p<0.05) while the Ca-P did not show any consistent dependency on the water quality. On the other hand, the correlation of Ca-P with $P_2O_5$ was high with r=0.783 (p<0.05) in the sediment. The Fe-P was affected significantly on the Ignition Loss (r=0.569, p<0.05), T-N (r=0.715, p<0.05) and T-P (r=0.983, p<0.01). In the research of correlation between phosphorus fraction and heavy metals in the sediment, Ca-P did not show any specific relationships with heavy metals. The Fe-P showed a significant correlation with As (r=0.817, p<0.01), Cu (r=0.793, p<0.05), Cd (r=0.786, p<0.05), Zn (r=0.738, p<0.05), so that it can be stated that the presence of Fe-P may implicate the volume of various metallic elements.

Estimation of Reliability of Real-time Control Parameters for Animal Wastewater Treatment Process and Establishment of an Index for Supplemental Carbon Source Addition (가축분뇨처리공정의 자동제어 인자 신뢰성 평가 및 적정 외부탄소원 공급량 지표 확립)

  • Pak, JaeIn;Ra, Jae In-
    • Journal of Animal Science and Technology
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    • v.50 no.4
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    • pp.561-572
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    • 2008
  • Responses of real-time control parameters, such as ORP, DO and pH, to the conditions of biological animal wastewater treatment process were examined to evaluate the stability of real-time control using each parameter. Also an optimum index for supplemental carbon source addition based on NOx-N level was determined under a consideration of denitrification rate by endogenous respiration of microorganism and residual organic matter in liquor. Experiment was performed with lab-scale sequencing batch reactor(SBR) and working volume of the process was 45L. The distinctive nitrogen break point(NBP) on ORP-and DO-time profiles, which mean the termination of nitrification, started disappearing with the maintenance of low NH4-N loading rate. Also the NBP on ORP-and DO-time profiles was no longer observed when high NOx-N was loaded into the reactor, and the sensitivity of ORP became dull with the increase of NOx-N level. However, the distinctive NBP was constantly occurred on pH(mV)-time profile, maintaining unique profile patterns. This stable occurrence of NBP on pH(mV)-time profile was lasted even at very high NOx-N:NH4-N ratio(over 80:1) in reactor, and the specific point could be easily detected by tracking moving slope change(MSC) of the curve. Revelation of NBP on pH(mV)-time profile and recognition of the realtime control point using MSC were stable at a condition of over 300mg/L NOx-N level in reactor. The occurrence of distinctive NBP was persistent on pH(mV)-time profile even at a level of 10,000mg/L STOC(soluble total organic carbon) and the recognition of NBP was feasible by tracing MSC, but that point on ORP and DO-time profiles began to disappear with the increase of STOC level in reactor. The denitrfication rate by endogenous respiration and residual organic matter was about 0.4mg/L.hr., and it was found that 0.83 would be accepted as an index for supplemental carbon source addition when 0.1 of safety factor was applied.

Characteritics of Toluene and $H_2S$ Removal in a Biotrickling filters with Plastic & Woodchip composite Media (복합플라스틱계 담체를 이용한 Biotrickling filters의 Toluene과 황화수소 제거특성)

  • Yim, Dong-Won;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.12 no.2
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    • pp.37-46
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    • 2007
  • This study developed composition-plastic media with woodchips and plastic as main materials, and examined the performance of media. Compared to the existing commercial media, the media had similar performance in removal efficiency and microbes attaching characteristic, and was evaluated that they are distinguished from economic side. Performance test of media was conducted to examine the removal capacity of toluene and hydrogen sulfide in a gas stream by using a lab-scale biotrickling filter systems packed with them. At a volumetric loading of $1.5\;m^3/hr$ with inlet concentration 260 ppm and empty bed residence time (EBRT) 42s, the toluene removal efficiency was shown over 90%, and the maximum elimination capacity of toluene in the biotrickling filter was $77g/m^3{\cdot}hr$. Effective co-treatments of $H_2S$ and Toluene were observed in the lab-scale biotrickling filters. The maximum elimination capacity of $H_2S$ was $100\;g-S/m^3{\cdot}hr$. Up to 100 ppm, the concentration of $H_2S$ did not have an effect on toluene removal efficiency, but the removal efficiency of toluene decreased with increasing inlet $H_2S$ concentration.

The Removal of NOx by Mediated Electrochemical Oxidation Using Ag(II) As a Mediator (Ag(II)를 매개체로 사용하는 전기화학적 매개산화에 의한 NOx 제거)

  • Lee, Min-Woo;Park, So-Jin;Lee, Kune-Woo;Choi, Wang-Kyu
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.3
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    • pp.121-129
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    • 2011
  • The effects of the applied current density, the $AgNO_3$ concentration, the scrubbing liquid flow rate and the NO-air mixed gas flow rate on the NO removal efficiency were investigated by using $Ag^{2+}$ mediated electrochemical oxidation (MEO). Results showed that the NO removal efficiency increased with increasing the applied current density. The effect of the $AgNO_3$ concentration on the NO removal efficiency was negligibly small in the concentration of $AgNO_3$ above 0.1 M. When the scrubbing liquid flow rate increased, the NO removal efficiency was gradually increased. On the other hands, the NO removal efficiency decreased with increasing the NO-air mixed gas flow rate. As a result of the treatment of NO-air mixed gas by using the MEO process with the optimum operating condition and the chemical absorption process using 3 M $HNO_3$ solution as a scrubbing liquid, the removal efficiency of NO and $NO_x$ was achieved as 95% and 63%, respectively.

Studies on Removal of Water Pollutants by Aquatic Plants II. Removal of Water Polluted Nutrients and Heavy Metals by Water Hyacinth (수생식물(水生植物)을 이용(利用)한 수질오염원제거(水質汚染源除去)에 관(關)한 연구(硏究) - 제2보(第2報) 부레옥잠의 영양염류(營養鹽類) 및 중금속(重金屬) 제거효과(除去效果))

  • Lee, Kyu-Seung;Kim, Moon-Kyu;Pyon, Jong-Yeong;Lee, Jong-Sik
    • Korean Journal of Weed Science
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    • v.5 no.2
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    • pp.149-154
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    • 1985
  • Removal of water pollutants by water hyacinth was examined with two nutrients, $NO_3$-N, $PO_4$-P and four heavy metals, Cu, Pb, Cd, Cr under laboratory conditions. $NO_3$-N was reduced to 0.7, 0.9 and 1.2 ppm, and 0.1, 0.2 and 0.5 ppm in $NO_4$-P from 10, 25 and 50 ppm 3 days after treatment, respectively. Among heavy metals Cu and Pb were removed faster and higher than Cd and Cr and also amount of heavy metals absorbed by water hyacinth was higher in the order of Cu > Pb > Cr > Cd. Distribution of heavy metals in this plant was higher in roots than in leaves and amount absorbed in roots was related to the treated concentrations. The harmful effect on growth of water hyacinth was observed in Cu and Cd.

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The Formation of N-nitrosamine in Alaska Pollack during its Drying (명태의 건조중 N-nitrosamine의 생성)

  • SUNG Nak-Ju;LEE Soo-Jung;SHIN Jung-Hye;KIM Jeong-Gyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.753-758
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    • 1997
  • Dried alaska pollack is one of the representatives among dried marine fish and shellfish products in our country. This study was performed to obtain the basic data about the effect of drying method on the formation of N-nitrosamine and its precursor to ensure the safety of dried alaska pollack. The contents of nitrate and nitrite were detected 1.5 and <1.0 mg/kg in raw samples, and $3.0\~4.2,\;1.4\~2.7mg/kg$ in dried products, respectively. There was no significant change of betaine contents during drying while TMAO decreased, TMA and DMA increased in alaska pollack during d교ing. N-nitrosodimethylamine (NDMA) was only detected in alaska pollack and its dried products, and recovery from above samples spiked with $10{\mu}/kg$ for N-nitrosodipropylamine was $87.2\~107.4\%$. The levels of NDMA were found to be $2.8{\mu}/kg$ on an average in raw samples, but the levels of NDMA increased remarkably during drying of alaska pollack and its content in dried products was $8.7\~51.4{\mu}g/kg$. Regardless of drying methods, NDMA tend to increased in dried products, and its contents were 15.5 times higher in hot-air dried than raw samples, 9.0 times in sun dried and 4.4 times in freeze dried products. less NDMA was produced in the freeze dried products, so it is believed that freeze drying method is effective to decrease the NDMA levels in the dried products of alaska pollack.

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The Distributions of Nutrients, Chlorophyll-a, and Primary Productivity in the South Pacific Ocean (남태평양의 영양염, 엽록소, 일차생산성 분포)

  • Kim, Dong-Yup;Shim, Jung-Hee;Song, Hwan-Seok;Kang, Young-Chul;Kim, Dong-Seon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.1
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    • pp.40-48
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    • 2001
  • The vertical distributions of temperature, salinity, dissolved oxygen, nutrients, chlorophyll, and primary production were investigated within the top 200m water depth in the south Pacific Ocean in February,2000. The study area ($24^{\circ}-41^{\circ}S,\;81^{\circ}-168^{\circ}W$) can be hydrologically divided into two regions. Upwelling was actively occurring in the eastern region of the $110^{\circ}S$ line, meanwhile it was not active in the western region. Accordingly, chemical properties in the surface waters were different between the two regions; nitrate+nitrite and phosphate concentrations were much higher in the eastern region than in the western region due to the active upwelling, but silicate concentration was higher in the western region. Among the nutrients, the major element influencing primary production was also different between the two regions; silicon would be a major element influencing primary production in the eastern region, but nitrogen may act as a major element for primary production in the western region. Primary production showed similar values in the two regions in spite of the large differences of nutrient concentrations in the surface waters, but the total chlorophyll integrated within the 200 m water depth was almost twice as much as in the western region than that in the eastern legion.

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Catalytic Oxidation of Volatile Organic Compounds Over Spent Three-Way Catalysts (배기가스 정화용 폐 자동차 촉매를 이용한 휘발성 유기화합물의 제거)

  • Shim, Wang Geun;Kim, Sang Chai
    • Applied Chemistry for Engineering
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    • v.19 no.5
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    • pp.574-581
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    • 2008
  • The optimum regeneration conditions for the regeneration of three way spent catalysts (TWCs), which were taken from automobiles with different driving conditions, were investigated to evaluate the suitability as alternative catalysts for removing VOCs. The spent catalysts were washed with five different acids ($HNO_3$, $H_2SO_4$, $C_2H_2O_4$, $C_6H_8O_7$, and $H_3PO_4$) to remove contaminants and examine the optimum conditions for recovering the catalytic activity. The physicochemical properties of spent and its regenerated TWCs were evaluated by using nitrogen adsorption-desorption isotherms, XRD, and ICP. The relative atomic ratios of contaminants and platinum group metals (PGMs) of the spent TWCs were greatly dependent on the placed positions. The main contaminants formed were lubricant oil additives and metallic components. Also, the regeneration treatment increased the PGMs ratio, BET surface area, and average pore diameter of TWCs. The catalytic activity results indicated that the spent TWCs have the possibility for removing VOCs. Moreover, the employed acid treatments greatly enhanced the catalytic activity of the spent TWCs. Especially, nitric and oxalic acids provided the most improvement in the catalytic behavior. The catalytic activities of the regenerated TWCs were significantly influenced by the containing platinum ratios rather than the removal ratios of contaminants and the changes in the structural properties offered by the acid treatments.

Physiology and Nutrition of Pasture Plants (목초의 생리 및 영양)

  • 이주삼
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.12 no.3
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    • pp.64-129
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    • 1992
  • 최근 초지중심 사양형태의 증가와 초지면적의 확대에 따라 단순한 사료로서가 아니라 영양가치가 높고 기호성이 높은 목초생산이 요구되고 있다. 그러나, 고위생산을 위해 다량으로 사용된 질소질비료에 의하여 질산태 중독 등의 문제가 야기되고 있어 목초의 생리 및 영양에 관한 연구가 필요하게 되었다. 사료성분 혹은 영양가치에 대한 연구는 이미 일찍부터 다루어져 왔으나, 주로 야초류, 청예작물 및 농가부산물 등의 일반성분 특히, 조단백질과 조섬유함량의 연구가 주가 되었고 다년생 목초류에 대한 연구는 1975년경부터 본격화 되기 시작하였다. 그동안 한국초지학회지와 축산학회지($1972\sim1991$)에 게재된 총 151편의 생리 및 영양에 관한 연구 중에서 다년생 목초류를 취급한 것은 불과 63편에 머물고 있다. 이 분야의 연구는 각종 목초 사료작물에 대한 재배조건과 생육단계에 따른 생리생태학적 연구와 사료성분, 소화율 및 가소화양분 함량의 일반적인 변화, 경향을 검토하여 사료 가치 평가를 위한 기준으로 삼았다. 그러나 다년생 목초류는 물론 사료 작물에 있어서 육종 생리분야의 연구는 매우 미흡한 상태로써 단지 발아, 생육, 저장탄수화물 및 유독성분 등 단편적인 연구만이 행해지고 있을 뿐이다. 또한 사료 성분이 가축의 기호성에 미치는 영향을 구명하기 위한 연구는 거의 이루어지고 있지 않으므로 금후 탄수화물과 미량 요소에 대한 자세한 연구 검토가 필요하다고 생각된다. 특히 목초와 사료작물의 화학적인 조성과 가축의 생리에 관련한 여러가지 문제들도 앞으로 보다 깊이 연구되어야 할 과제라고 생각된다.권을 잡기 위해 10년지기였던 IBM과 MS사는 각각 OS/2와 윈도즈를 내세우고 양보할 수 없는 힘겨루기에 들어갔다. 또 이들 양사는 펜컴퓨터,멀티미디어등 차세대제품의 운영체제 시장을 둘러싸고 일찍부터 격전에 들어갔으며 IBM과 MS사의 혼전을 틈타 썬마이크로시스템을 필두로한 워크스테이션 업체 및 유닉스진영까지 고성능 PC시장을 겨냥한 OS를 속속 개발, 90년대의 OS 전쟁은 한치 앞을 내다볼 수 없는 안개국면으로 접어들고 있다. DOS에서 32비트시대,펜컴퓨터, 멀티미디어에 이르는 차세대제품을 둘러싼 업계의 OS 쟁탈전을 통해 OS의 발전동향과 미래를 전망해 본다. results in the large change of the objective function, the sum of squares of deviations of the observed and computed groundwater levels. 본 논문에서는 가파른 산사면에서 산사태의 발생을 예측하기 위한 수문학적 인 지하수 흐름 모델을 개발하였다. 이 모델은 물리적인 개념에 기본하였으며, Lumped-parameter를 이용하였다. 개발된 지하수 흐름 모델은 두 모델을 조합하여 구성되어 있으며, 비포화대 흐름을 위해서는 수정된 abcd 모델을, 포화대 흐름에 대해서는 시간 지체 효과를 고려할 수 있는 선형 저수지 모델을 이용하였다. 지하수 흐름 모델은 토층의 두께, 산사면의 경사각, 포화투수계수, 잠재 증발산 량과 같은 불확실한 상수들과 a, b, c, 그리고 K와 같은 자유모델변수들을 가진다. 자유모델변수들은 유입-유출 자료들로부터 평가할 수

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