• Title/Summary/Keyword: 질량 측정방식

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Analysis of EDCs by Mass Spectrometry and their Removal by Membrane Filtrations (질량분석법에 의한 내분비계 장애물질의 분석과 막 여과에 의한 제거)

  • Kim Tae-Uk;Yeon Kyeong-Ho;Cho Jaeweon;Moon Seung-Hyeon
    • Membrane Journal
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    • v.15 no.4
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    • pp.297-309
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    • 2005
  • As a number of potential endocrine disrupting compounds (EDCs) are released into the environment, recently growing attention has been drawn to them. Therefore sensitive and reliable analytical methods are essential to monitor those compounds. In this study, complementary CC-MS and LC-MS were employed to analyze the endocrine disrupters, and the results of two methods were compared for di(2-ethylhexyl)phthalate (DEHP), benzylbutylphthalate (BBP), pentachlorophenol (PCP), and 4,4'-Isopropylidenediphenol (Bisphenol-A, or BPA). The results indicate that it was possible to lower the detection limits of EDCs by LC-MS. Also, LC-MS enabled to identify the EDCs as almost intact molecules. Furthermore, this study presented a nanofiltration membrane (MWCO 250) and a ultrafiltration membrane (MWCO 1,000) filtration system as methods far removing EDCs from drinking water containing $\gamma$-BHC, p,p'-DDE, BBP, p,p'-DDT, DEHP, PCP, and BPA. Cross-flow type nanofiltrations showed $100\%$ removal of EDCs, and the result implies that MWCO 250 nanofilter was sufficient for treatment of EDCs. The ratio of permeate flux to mass transfer coefficient of nanofiltration, high flux ultrafiltration, and low flux ultrafiltration with ultrapure water were 0.67, 3.4, and 0.44, respectively. It was found that nanofiltration and low flux ultrafiltration were operated at a diffusion dominant condition, and the high flux ultrafiltration was operated at a convection dominant condition. Furthermore, a diffusion dominant process attained reasonable rejection of EDCs. The removal in the ultrafiltration was depending on the molecular weight of an EDC, and the filtration was governed by diffusion-dominant hydrodynamic conditions.

Experimental Study on the Spray Characteristics of a Fuel Injector for a Non-Road Small Engine (노외용 소형엔진 인젝터의 분무특성에 대한 실험적 연구)

  • Yeom, Kyoung-Min;Park, Sung-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.5
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    • pp.2005-2010
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    • 2011
  • Since recently exhaust gas regulation for a non-road small engine as well as commercial vehicle engine has been enforced, a carburettor of a small engine should be replaced by an electronic fuel injection system. In this study, the spray characteristics of the 400cc gasoline small engine injector has been experimentally analyzed. Based on the experimental results, suitable injector for the small engine has been selected. Through the test rig measuring spray mass distribution, fuel distribution characteristics of 3 hole- and 6 hole-injector has been analyzed. Through the visualization equipment, injector spray angle, penetration length and spray width have been measured and analyzed. Considering spray characteristics and stability, 6 hole-injector is selected for the 400cc gasoline small engine.

Numerical Simulation of Inkjet Drop Formation in Piezo Inkjet Head (피에조 잉크젯 헤드의 액적 토출 형상 전산해석)

  • Joo, Youngcheol;Park, Sangkug;Kwon, Key-Si
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.7
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    • pp.641-647
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    • 2016
  • A drop-on-demand inkjet is used widely for various applications. Therefore, it is important to understand the jetting behavior of the drop from the piezo inkjet. In this study, to predict the jetting behavior, VOF (Volume-of-Fluid) simulation techniques were used and compared with the experimental results. The experimentally measured meniscus movement was used as the input data for the simulation. To verify the simulation, the measured jetting behavior of the mixture fluids of ethylene glycol and IPA (isopropyl alcohol), which has a mixing ratio of 50:50, was used. The numerical simulation of the drop formation using various mixture ratios and its comparison with the measured drop formation confirmed that the proposed method can predict the actual jetting. On the other hand, the satellite drop behavior showed slight differences because the small sized droplet is subject to a more aerodynamic effect during flight because the kinetic energy of the satellite droplet is far smaller than that of the main droplet.

Measurement of Physical Properties of Pepper for Particle Behavior analysis of sorting system for Pepper Harvester (고추수확기용 선별장치의 입자 거동 해석을 위한 고추 물성측정)

  • Byun, Jun Hee;Kim, Su Bin;Kim, Myoung Ho;Kim, Dae Cheol
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.9-9
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    • 2017
  • 입자거동해석소프트웨어(EDEM)은 DEM(Discrete Element Method)기법을 이용한 입자 거동 전용 해석툴로 입자 유입량, 위치 등을 조절하여 입자거동과 관련된 제품 개발, 프로세스 최적화를 위한 비용 및 시간 절감에 활용도가 뛰어난 소프트웨어이다. EDEM을 활용하기 위해선 적용대상에 대한 물성치를 적용하여야 한다. 따라서 본 연구에서는 EDEM를 이용하여 현재 연구개발 중인 카드클리너 방식의 고추 선별기의 성능을 분석을 수행하기 위해 고추 물성측정 실험을 수행 하였다. EDEM을 이용한 입자거동해석에 필요한 개인 물성치에는 포아송비, 전단탄성계수, 밀도가 있다. 또한 입자-입자, 입자-Geometry 간의 상호관계를 위한 물성치인 반발계수, 정지마찰계수, 구름마찰계수가 필요하다. 공시 시료인 고추는 광주광역시 남구 승촌동 소재의 개인농가 Plastic 온실로 재배된 '천상'품종을 사용하였다. 푸아송 비와, 전단 탄성계수를 측정하기 위한 인장시험기기로는 만능인장시험기(TA-XT2, Stable Micro, 영국)를 이용하였으며, 인장에 의한 고추의 변형량 축정은 초고속카메라(NX4-SI, IDT, 미국)을 이용하였다. 밀도는 비중병법에 기초하여 질량과 부피를 측정하여 밀도를 계산하였다. 반발계수는 고추의 충돌 실험을 통해 변화한 높이를 이용하여 계산하였고, 충동 실험을 통해 변화한 높이는 초고속카메라를 이용하여 측정하였다. 정지마찰계수와 구름마찰계수는 고추의 미끄러짐이 시작하는 각도와 등속도 운동으로 구르는 각도를 초고속카메라를 이용하여 측정 후 계산하였다. 모든 실험은 3번 반복을 통해 평균값을 시험 결과 값으로 이용하였다. 고추의 대한 물성치 실험결과 고추의 푸아송 비는 0.294(std : 0.2), 전단탄성계수 4.624E+06 Pa, 밀도 $600kg/m^3$로 나타났다. 또한 입자-입자 간의 물성치인 반발계수는 0.383, 정지마찰계수는 0.455, 구름마찰 계수는 0.043로 나타났다. 추후 본 연구에서 측정한 고추의 물성치를 적용한 EDEM 입자거동해석 시뮬레이션을 통해 카드클리너 방식의 고추 선별기의 성능에 대한 분석을 하고자 한다.

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Mechanical Properties on Resin of New Austrian Tunneling Coatings on Stainless Steel 316L (스테인레스강 316L 상의 New Austrian Tunneling Method Coatings의 수지에 관한 기계적 특성)

  • Lee, Jooyoub;Sung, Wanmo;Kim, Joohan;Seong, Minjeong;Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.4
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    • pp.1034-1040
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    • 2020
  • The mechanical properties of NATM resin of synthetic polyurethane-epoxy resin for stainless steel were measured by SEM, FT-IR, tensile properties, and specific mass loss by EIS analysis, etc. As interest in eco-friendly medium coatings increased, the Heavy duty coatings were synthesized for various metals such as stainless steel composed of Polyol, MDI, water bored Epoxy resin, filling agent, silicon surfactant, catalyst etc. The coatings of synthetic NATM resin were increased tensile strength due to various temperature change, and the low-Specific Mass Loss was measured in a highly electrolytic solution. In conclusion, the NATM coatings composed of polyurethane and waterbored Epoxy, polyurea resin were synthetic microstructure with cross linkage can be good material for coating of anticorrosion of metal substrates such as stainless steel.

Thermal conductivity of acrylic composite films containing graphite and carbon nanotube (흑연과 탄소나노튜브를 함유한 아크릴 복합체 박막의 열전도도)

  • Kim, Jun-Yeong;Gang, Chan-Hyeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.185-185
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    • 2016
  • 아크릴계 수지(resin)에 인조 흑연과 탄소나노튜브(carbon nanotube)를 1:1 비율로 혼합한 충전제(filler)와 용제(solvent) 및 기타 첨가제(additives)를 혼합하여 방열도료를 제조하여 수직방향 열전도도를 상온에서 평가하였다. 충전제의 함량을 1, 2, 5 중량 %로 변화시키며 원료들을 준비하여 교반기로 혼합한 뒤 3단 롤 밀(three roll mill)로 분산공정을 진행하여 3 종류의 도료를 제조하였다. 제조한 도료를 가로 11 mm, 세로 11 mm, 두께 0.4 mm의 Al 5052 알루미늄 기판에 스프레이 코팅 방식으로 도포한 후 $150^{\circ}C$에서 30분 동안 열경화 건조 과정을 거쳐 샘플을 제작하였다. 측정 시료의 형상은 대략적으로 Fig. 1과 같다. 열전도도는 식 $k={\alpha}{\cdot}C_p{\cdot}{\rho}$를 사용해서 계산된다. 여기서 k는 열전도도($W/m{\cdot}K$), ${\alpha}$는 열확산계수($mm^2/s$), $C_p$는 비열($J/kg{\cdot}K$), ${\rho}$는 밀도($g/cm^3$)를 나타낸다. 열확산계수는 독일 NETZSCH 사의 Laser Flash Analysis 장비(모델명 LFA 457)를 사용하여 측정하였는데, 기판 뒤쪽에서 레이저를 조사하고 도료층 전면에서 적외선 온도센서를 통해 시간에 따른 온도 상승곡선을 구한 후, 두 물체의 계면에서의 접촉 열저항(contact thermal resistance)을 감안하여 장비에 내장되어 있는 소프트웨어로 열확산계수가 계산된다. 비열은 같은 회사의 DSC(Differential Scanning Calorimetry) 200 F3 장비를 사용해 측정했으며, 밀도는 부피와 질량을 측정한 값을 이용하여 계산하였다. 도료를 도포하지 않은 bare Al plate에 대해서는 쉽게 열확산계수, 비열, 밀도를 측정하여 열전도도를 구할 수 있다. 도료가 코팅된 샘플에 대해서는 도료층을 일부 떼어내 비열을 측정하고, 밀도를 구한 후, 도료층의 열전도도가 2-layer 법으로 장비 내장 소프트웨어로 계산된다, 이때 Al 기판의 열확산계수, 비열, 밀도는 미리 측정한 bare Al plate의 값을 적용하였다. 실험 결과를 Table 1에 정리하였다. 흑연과 탄소나노튜브를 혼합한 충전제를 함유한 아크릴 복합체 박막에서 측정된 열전도도는 보통 고분자 재료의 열전도도 값의 상한 영역에 육박하는 값이며, 충전제 함량이 증가할수록 열전도도가 증가하는 경향을 보이고 있다.

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Modeling of Sound-structure Interactions for Designing a Piezoelectric Micro-Cantilever Acoustic Vector Sensor (압전 미세 외팔보 형 수중 음향 벡터센서의 작동 원리와 설계 기법)

  • Yang, Seongkwan;Kim, Junsoo;Moon, Wonkyu
    • The Journal of the Acoustical Society of Korea
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    • v.34 no.2
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    • pp.108-116
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    • 2015
  • An acoustic vector sensor is a device that is capable of measuring the direction of wave propagation and the acoustic pressure. In this paper, the modeling of micro-cantilever sensor for the vector sensor are proposed by consideration of acoustic phenomenon in water. Two models based on unimorph structure are proposed in this paper and corresponding transfer function which describes the relation between input pressure wave and output voltage depending on incidence angle and frequency of pressure wave is derived based on lumped model. It has been shown that very thin and flexible micro-cantilever can be used to measure directly the particle velocity component in water.

Applications of Isotope Ratio Infrared Spectroscopy (IRIS) to Analysis of Stable Isotopic Compositions of Liquid Water (동위원소비 적외선 분광법(IRIS)을 이용한 물 안정동위원소 분석)

  • Jung, Youn-Young;Koh, Dong-Chan;Lee, Jeonghoon;Ko, Kyung-Seok
    • Economic and Environmental Geology
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    • v.46 no.6
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    • pp.495-508
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    • 2013
  • Recently, stable isotopes (${\delta}^{18}O$ and ${\delta}D$) of water are increasingly analyzed using laser-based technologies. These methods have advantages over Isotope Ratio Mass Spectrometry (IRMS) in that they can be used for in-situ measurements and require much less maintenance and preparation work. Two types of laser-based methods are currently available, which have different analytical principles; OA-ICOS (off-axis integrated cavity output spectroscopy) and WS-CRDS (wavelength-scanned cavity ring-down spectroscopy). In the WS-CRDS instrument, water is vaporized at controlled environment and transferred to an optical cavity by nitrogen carrier gas, and stable isotopic compositions of water vapor are measured using the degree of absorbance of specific wavelengths and the ratios of attenuation time of the laser intensity with the sensitivity of ppb to tens of ppt level. In this study, we introduce the principle of the WS-CRDS technology and the performance results including stability and comparisons with Isotope Ratio Mass Spectrometry (IRMS) and suggest possible applications of various topics in isotope hydrology.

A Study on Properties of Polyurethane-Epoxy Hybrid Coatings on Stainless Steel 316L at Various Temperatures (스테인레스강 316L의 다양한 온도에서 폴리우레탄-에폭시 복합코팅 특성에 관한 연구)

  • Sung, Wanmo;Kim, Kijun;Kim, Joohan;Seong, Minjeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1358-1364
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    • 2019
  • The mechanical properties of Heavy duty resin of synthetic polyurethane-epoxy resin for stainless steel were measured by SEM, FT-IR, tensile properties, and specific mass loss by EIS analysis, etc. As interest in eco-friendly medium coatings increased, the Heavy duty coatings were synthesized for various metals such as stainless steel composed of Polyol, MDI, water bored Epoxy resin, filling agent, silicon surfactant, catalyst etc. The coatings of synthetic Heavy duty resin were increased tensile strength due to various temperature change, and the low-Specific Mass Loss was measured in a highly electrolytic solution. In conclusion, the Heavy Duty coatings composed of polyurethane and waterbored Epoxy resin were synthetic microstructure with cross linkage can be good material for coating of anticorrosion of metal substrates such as stainless steel.

Measurements and Calculation of Injection Mass Rate of LFG for Intake Injection in Spark Ignition Engines (불꽃점화 엔진의 흡기관 분사를 위한 매립지가스 분사량의 측정 및 계산)

  • Kim, Kyoungsu;Choi, Kyungho;Jeon, Wonil;Kim, Bada;Lee, Daeyup
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.