• Geotechnical Engineering
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• v.14 no.2
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• pp.41-54
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• 1998

Predictions of consolidation settlement and time must be always erroneous because of heterogeneity of soil media. errors associated with the measurement of soil parameters, drawback of consolidation theories and so on. When filling is done on compressible soils, the observational procedure is a useful means in practice of evaluating the final consolidation settlement and time. However, the existing observational procedures including some disadvantages such as the difficulty of ending the linearity in the settlement curves, the unavoidable personal error, and so on. A new observational procedure($\sqrt{s}$ method) is suggested here for the consolidation analysis in field. As the results of applying the $\sqrt{s}$ method with other methods to two field data. the fecal settlements predicted by the s method as well as by the Asaoka'$\sqrt{s}$ method agreed well with the measured values. However, results obtained from the hyperbolic method(Tan, 1991) were always overestimated. and there happened many cases not to be predicted by the Hoshino's method. In the settlement curve from the $\sqrt{s}$method, the linearity between 60 and 90 eye of the average degree of consolidation is shown. and then the possibility of a personal error seems to be unusual. The final consolidation times(at $U_{95}$) predicted by the $\sqrt{s}$ method agreed well with the measured ones. but the ones by Asaoka and Tan(1996) methods were very much underestimated or overestimated. where $U_{95}$, is the average degree of consolidation of 95%. The big errors of these two methods seem to result from unconsidering the effect of stage construction.

• Korean Journal of Soil Science and Fertilizer
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• v.16 no.4
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• pp.301-304
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• 1983

Effects of the clay content on soil chemical properties and rice productivity were studied to evaluate the optimum range of clay content from 42 NPK trials conducted by the provincial ORD in 1979. Nutrients content and CEC of the paddy soils were increased with the increase of clay content in paddy soils. Rice yields without NPK application showed a positive linear regression with respect to surface clay content in the paddies, while the relationship between rice yield and clay content with optimun fertilization showed a curvilinear regression, which indicated the maximum yield was observed in loam soils. However, the yield of rice was not significantly different in the range of clay content from 14 to 38%. It implies that the clay content more than 15% may be secondary constraint in determining the soil productivity.

• Analytical Science and Technology
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• v.19 no.5
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• pp.441-448
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• 2006

11-nor-9-carboxy-${\Delta}^9$-tetrahydrocannabinol (THCCOOH) is the major metabolite of tetrahydrocannabinol (THC) which is the primary psychoactive component of marijuana. It is also the target analyte for the discrimination marijuana use. A method using solid-phase extraction (SPE) and gas chromatography/mass spectrometry (GC/MS) was developed for the determination of THCCOOH in human urine. Urine samples (3 mL) were extracted by SPE column with a cation exchange cartridge after basic hydrolysis. The eluents were then evaporated, derivatized, and injected into the GC/MS. The limits of detection (LOD) and quantitation (LOQ) were 0.4 and 1.2 ng/mL, respectively. The response was linear with a correlation coefficient of 0.999 within the concentration range of 1.2 (LLE 1.3)~50.0 ng/mL. The precision and accuracy were stable within 1.20% and the recovery was 83.6~90.7%. The recovery of SPE method was lower than that of liquid-liquid extraction (LLE), but there were no apparent differences in LOD, LOQ, precision and accuracy between the two methods. While SPE method is used as a very effective and rapid procedure for sample pretreatment, and clean extracts, LLE method was not suitable for the extraction procedure of THCCOOH in urine. The applicability of the method was proven by analyzing a urine samples from a marijuana abusers.

• Analytical Science and Technology
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• v.22 no.3
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• pp.210-218
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• 2009

A gas chromatography-tandem mass spectrometry (GC-MS/MS) method was developed and validated for simultaneous determination of amphetamine derivatives and norketamine in human hair. Preparation of hair involves external decontamination, mechanical pulverization, incubation and extraction prior to instrumental analysis. The samples were derivatized using heptafluorobutyric anhydride, and analyzed by GC-MS/MS. The linear ranges were 0.05-20.0 ng/mg for the analytes except for 3,4-methylenedioxyamphetamine, with good coefficients of determination ($r^2$ >0.998). The intra-day and inter-day precisions were within 10.7% and 8.5%, respectively. The intra-day and inter-day accuracies were between -1.6 and 17.0% and -2.6 and 10.5%, respectively. The limits of detections for each analyte were lower than 0.007 ng/mg, while recoveries were 75.9-100.9%. When the method was applied to hair samples obtained from suspected drug abusers, the concentrations in hair samples were 0.97-19.30 ng/mg for methamphetamine and 0.14-2.56 ng/mg for amphetamine.

• Analytical Science and Technology
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• v.21 no.1
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• pp.41-47
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• 2008

Although liquid-liquid extraction (LLE) method has been used routinely for the analysis of amphetamine-like drugs (amphetamine; AP, methamphetamine; MA, 3,4-methylenedioxyamphetamine; MDA, 3,4-methylenedioxymethamphetamine; MDMA, 3,4-methylenedioxyethylamphetamine; MDEA), a solid-phase extraction (SPE) method, which can be automated, was applied for the simultaneous determination by GC/MS in human urine. Urine samples (3 mL) and 0.1 M phosphate buffer (1 mL, pH 7.0) were extracted by an automated SPE system. The eluent was evaporated, derivatized with trifluoroacetic anhydride (TFAA), and analyzed by GC/MS. The calibration curves was linear with correlation coefficient ($r^2$) above 0.994 in the ranges of 34.0 (AP), 28.0 (MDA)~1000.0 ng/mL for AP, MDA, and 50.0~2000.0 ng/mL for MA, MDMA, and MDEA. The limits of detection ranged from 4.0 to 10.0 ng/mL, and the limits of quantitation ranged from 12.0 to 34.0 ng/mL. The relative recoveries were 93.5~107.7 %. The precisions and accuracies were 1.9~14.8 % and -8.7~14.8 %, respectively. The present method was successfully applied to identify the MA or Ecstasy (MDMA) abusers in exact as well as rapid.