• Title/Summary/Keyword: 지지체

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Preparation of Oriented MFI Zeolite Membranes (배향된 MFI 제올라이트 박막의 제조)

  • Song, Kyeong-Keun;Ha, Kwang
    • Korean Chemical Engineering Research
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    • v.44 no.3
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    • pp.243-247
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    • 2006
  • MFI zeolite membranes were prepared on anodic alumina (Anodisc) as support. First, silicalite-1(${\approx}1.2{\mu}m$) seed crystals were attached to the surface of the support via chemical bonding, and the a- and b-axis oriented zeolite membranes could be synthesized on the support coated with the monolayer of the seed crystals by secondary growth hydrothermal synthesis. The zeolite membranes prepared were characterized using scanning electron microscope and analyzed by X-ray diffraction.

An Analysis of Natural Lacquer Characteristics and EM Wave Absorber's Absorption Characteristics Using Natural Lacquer as a Binder (옻의 특징과 옻을 지지재로 사용한 전자파 흡수체의 두께에 따른 전파흡순 특성 분석)

  • Kim Dong-Il;Choi Dong-Han;Kim Ki-Man
    • Journal of Navigation and Port Research
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    • v.28 no.10 s.96
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    • pp.861-867
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    • 2004
  • Generally, a silicone rubber and a chloride polyethylene(CPE) have been used as a binder for high-performance composite EM( Electromagnetic) wave absorbers. In this study, the EM wave absorption abilities for natural lacquer which is newly suggested as a binder were investigated MnZn ferrite composite EM wave absorbers mixed with the natural lacquer were prepared and their absorption ability was also investigated. The prepared MnZn ferrite composite EM wave absorbers mixed with natural lacquer showed an improved EM wave absorption characteristics compared with MnZn ferrite EM wave absorbers mixed with the conventional binders. such as a silicone rubber and a chloride polyethylene(CPE). The matching frequency and the absorption ability of EM wave absorbers varied with the thickness of them.

Property Changes of Anion Exchange Pore-filling Membranes According to Porous Substrates (지지체 종류에 따른 음이온 교환 함침막 특성 변화)

  • Jeon, Sang Hwan;Choi, Seon Hye;Lee, Byeol-Nim;Son, Tae Yang;Nam, Sang Yong;Moon, Sun Ju;Park, Sang Hyun;Kim, Ji Hoon;Lee, Young Moo;Park, Chi Hoon
    • Membrane Journal
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    • v.27 no.4
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    • pp.344-349
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    • 2017
  • Alkaline fuel cells using polymer electrolyte membranes are expected to replace proton exchange membrane fuel cells, which have similar system configurations. In particular, in alkaline fuel cells, a low-cost non-platinium catalyst can be used. In this study, to fabricate high performance and high durability anion exchange membranes for alkaline fuel cell systems, two kinds of supports, polybenzoxazole and polyethylene supports, were impregnated with Fumion FAA ionomer, by which we tried to fabricate the support-impregnated membrane which has higher mechanical strength and higher ion conductivity than the Fumion series. Finally, the Pore-filling membranes were successfully fabricated and ionic conductivity and mechanical properties were different depending on the properties of the supports. In the pore-filling membranes with Fumion ionomer on the PE support, excellent mechanical properties were obtained, but ionic conductivity decreased. On the other hand, when the PBO support was impregnated with Fumion ionomer, high ionic conductivity was shown after impregnation due to high basicity of PBO, but the mechanical strength was relatively low as compared with Fumion-PE membrane. As a result, it was concluded that it is necessary to consider the characteristics of the support according to the operating conditions of the alkaline fuel cell during the preparation of the pore-filling membranes.

Experimental Analysis of Fretting Wear Behaviors in Elastic Deformable Contacts (탄성변형 접촉에서 프레팅 마멸거동의 실험적 분석)

  • Lee, Young-Ho;Kim, Hyung-Kyu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.1
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    • pp.49-54
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    • 2010
  • Fretting wear behavior under elastic deformable contacts was experimentally examined by using a simulated dual cooled fuel rod and its supporting structure. As this fuel rod has larger outer diameter than the typical solid rod to accommodate sufficient internal flow, new supporting structure geometries should be designed and their reliabilities (i.e. vibration characteristics, fretting wear resistance, etc.) are also examined with both analytical and experimental methods. In this study, the supporting structure characteristics and fretting wear behaviors are analyzed and examined by using one of the supporting structure candidates which has an embossing shape. The supporting structure characteristics were examined by using a specially designed test rig and their results were compared with that of analytical method. Based on the test results, the relationship between the supporting structure characteristics and their fretting wear behaviors was discussed in detail.

Lateral Crush Strength of Nuclear Fuel Spacer Grid Considering Weld Properties (용접물성치를 고려한 핵연료 지지격자체 횡방향 충격강도)

  • Song, Kee Nam;Lee, Sang Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.12
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    • pp.1663-1668
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    • 2012
  • A spacer grid, which is one of the structural components in a PWR fuel, is an interconnected array of slotted grid straps that are welded at the intersections to form an egg-crate structure. The spacer grid is required to have sufficient lateral crush strength to enable nuclear reactor shut-down during abnormal operating environments. Previous studies on the lateral crush strength analysis of the spacer grid were performed using only the base material properties. In this study, to investigate the effect of the lateral crush strength of the spacer grid when using the mechanical properties in the weld zone instead of the base material properties, lateral crush strength analysis by considering the mechanical properties in the weld zone as obtained from the instrumented indentation technique was performed, and the results were compared with those of previous studies.

Preparation of Crack-free ZIF-7 Thin Films by Electrospray Deposition (정전분무법에 의한 결함없는 ZIF-7 박막의 제조)

  • Melgar, Victor Manuel Aceituno;Kim, Jinsoo
    • Membrane Journal
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    • v.23 no.4
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    • pp.278-282
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    • 2013
  • Zeolitic imidazolate frameworks (ZIFs) have been the focus of interest for their physical and chemical properties, especially, for their extraordinary gas separation properties. In this study, a novel and efficient method for the fabrication of continuous ZIF-7 film on ${\alpha}$-alumina substrate has been investigated. The electrospray deposition method was tried for the first time to prepare ZIF films directly without the necessity of prior substrate seeding. It has the advantage of depositing thin ZIF-7 films directly on the ${\alpha}$-alumina substrate by electrospraying the precursor solution. The ZIF-7 films have been characterized through XRD, FE-SEM, and single gas permeation tests.

An Analysis of Natural Lacquer Characteristics and EM Absorber's Absorption Characteristics Using Natural Lacquer by Binder (옻의 특징과 옻을 지지재로 사용한 전자파 흡수체의 두께에 따른 흡수 특성 분석)

  • 최동한;김동일;김기만
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.04a
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    • pp.29-34
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    • 2004
  • Generally, a silicone rubber and a chloride polyethylene(CPE) have been used for the development of high-performance composite EM(ElectroMagnetic) wave absorbers. In this study, the EM wave absorption abilities for natural lacquer which is newly suggested in this study as a binder for composite EM wave absorbers were investigated to develop an improved EM wave absorbers. In addition, MnZn ferrite composite EM wave absorbers mixed with the natural lacquer were prepared and their absorption ability was also investigated. MnZn ferrite composite EM wave absorbers which employs the natural lacquer as a binder showed an improved EM wave absorption characteristics in comparison with the conventional binder such as a silicone rubber and a chloride polyethylene(CPE). The matching frequency and the absorption ability of EM wave absorbers mixed with natural lacquer can be controled the change of the thickness of them.

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Fabrication and Evaluation Properties of Micro-Tubular Solid Oxide Fuel Cells (SOFCs) (마이크로 원통형 SOFC 제작 및 특성평가)

  • Kim, Hwan;Kim, Wan-Je;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.749-753
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    • 2012
  • In present work, anode support for micro-tubular SOFC was fabricated with outer diameter of 3 mm and characterized with microstructure, mechanical properties and gas permeability. The microstructure of surface and cross section of a porous anode support were analyzed by using SEM (Scanning Electron Microscope) image. The gas permeability and the mechanical strength of anode support was measured and analysed by using differential pressure at the flow rates of 50, 100, 150 cc/min. and using universal testing machine respectively. The unit cell composed of NiO-YSZ, YSZ, YSZ-LSM/LSM/LSCF was fabricated and operated with reaction temperature and fuel flow rate and showed maximum power density of $1095mW/cm^2$ on the condition of $800^{\circ}C$. The performance of single cell for micro-tubular SOFC increased with the increasing the reaction temperature due to the decrement of ohmic resistance of cell by the increment of the ionic conductivity of electrolyte through the evaluation of electrochemical impedance analysis for single cell with reaction temperature.

Optimal Hydrophilization and Chondrocyte Adhesion of PLLA Films and Scaffolds by Plasma Treatment and Acrylic Acid Grafting (플라스마 처리와 아크릴산 결합에 의한 PLLA 필름 및 지지체의 최적 친수화와 연골세포 점착)

  • Yang Hee-Seok;Park Kwi-Deok;Ahn Kwang-Duk;Kim Byung-Soo;Han Dong-Keun
    • Polymer(Korea)
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    • v.30 no.2
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    • pp.168-174
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    • 2006
  • To utilize as highly functional scaffolds for tissue engineering by improving hydrophobicity and cell compatibility of the exist polymer scaffolds, the biodegradable poly(L-lactic acid) (PLLA) films and scaffolds having the optimal hydrophilicity were prepared by in situ plasma treatment and grafting of a carboxyl acid-containing monomer, acrylic acid (AA) in the chamber. From the results of surface analyses, surface-modified nonporous PLLA film and dual pore scaffold surfaces showed high hydrophilicity due to the decrease in contact angle and the increase in carboxylic groups as compared with untreated PLLA control. In particular, among various surface modification methods, Ar(argon)+AA+AA sample prepared by Ar plasma and then acrylic acid treatments displayed lower contact angle and more carboxylic groups thar Ar/AA and Ar+TP(thermal polymerization) samples, indicating that Ar+AA+AA sample was optimally treated for improving its hydrophilicity. In the cases of surface modified nonporous PLLA films and dual pore scaffolds, the adhesion and proliferation of chondrocytes increased with increasing their hydrophilicity.