• Title/Summary/Keyword: 지오폴리머 콘크리트

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Strength Development and Durability of Geopolymer Mortar Using the Combined Fly ash and Blast-Furnace Slag (플라이애시와 고로슬래그 미분말을 혼합 사용한 지오폴리머 모르타르의 강도발현 및 내구성)

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.35-41
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    • 2013
  • In this study, we investigated the strength development and durability of geopolymer mortar using blast furnace slag only, and admixed with blast-furnace slag and fly ash as cementious materials in oder to develop cementless geopolymer concrete. In order to compare with the geopolymer mortar, the normal mortar using ordinary portland cement was also test. In view of the results, we found out that strength development, the resistance to freezing-thawing of the geopolymer mortar have better than the mortar using ordinary portland cement. Especially, using the combined with blast furnace slag and fly ash develop high strength of above 60 MPa, and improve the resistance of freezing-thawing of approximately 20%, but promote the velocity of carbonation of 2.2~3.5 times.

Anti-Corrosion Property of Geopolymer Evaluated by an Impressed Current Cathodic Protection Method, Exposed to Marine Environment (염해환경에서 외부전원법에 의한 지오폴리머 시험체 보강철근의 방식특성 평가)

  • Lee, Hae-Seung;Cho, Ggu-Hwan;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.397-405
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    • 2014
  • There are many literatures reporting that the service life of re-bars in concrete structures is reduced in the oceanic environment due to chloride attack. To solve this problem, this study used geo-polymer as a mix material for concrete to increase its resistance to salt damage, and the external voltage method, one of the electric methods, is was applied to evaluate the likelihood of re-bars in the oceanic structure being exposed to the extreme salt environment. The items evaluated include the natural potential of re-bars and the corrosion rate. The results of the tests showed that in all of the salt environmental conditions (submerged zone, tidal zone, and crack), the tested materials were remarkably effective compared with ordinary concrete. The corrosion protective property was found not only in the evaluation of the natural potential but also in the evaluation of the corrosion rate, suggesting that the external voltage method can be used stably for geo-polymer RC structures in an extreme salt environment.

Synchrotron X-ray diffraction study on alkali-activated slag cement and fly ash-based geopolymers (플라이 애시 지오폴리머와 활성 슬래그 시멘트 생성물의 방사광 X선 회절 실험 연구)

  • Oh, Jae-Eun;Jun, Ssang-Sun;Choi, Se-Jin;Paulo, J.M-Monteiro
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.319-320
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    • 2009
  • The alkali activation products of slag, fly ash C and fly ash F were investigated using compressive strength test and synchrotron x-ray diffraction. We propose that the predominantly amorphous geopolymer formed under ambient conditions is a disordered form of one of the ABC-6 group of zeolites, which includes poly-types such as hydroxycancrinite, hydroxysodalite, chabazite, levyne or fransinite.

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Development of Geopolymer Mortar Based on Fly Ash (플라이애시 기반 지오폴리머 모르타르 개발)

  • Koh, Kyung-Taek;Ryu, Gum-Sung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.119-126
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    • 2012
  • Portland cement production-1.5billion tonnes yearly worldwide-contributes substantially to global atmospheric pollution(7% of total of $CO_2$ emissions). Attempts to increase the utilization of fly ash, by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the sources of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in oder to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

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Study on Characteristics of Fine Bottom Ash Based Geopolymer Mortar (미분쇄 바텀애시 기반 지오폴리머 모르타르 특성에 관한 연구)

  • Lim, Gwi-Hwan;Lee, Jeong-Bae;Jeong, Hyun-Kyu;Kim, Seong-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.418-424
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    • 2016
  • This study is an experimental study on the recycling of bottom ash in coal ash discharged from a thermal power plant. Bottom ash has limited research on recycling because it has more porous and higher water absorption ratio than fly ash. In this paper, the bottom ash was pulverized to a specific surface area of $4,000cm^2/g$ in order to use as a binder, and the flow, compressive strength test and microstructure analysis of the bottom ash based geopolymer mortar were performed. The flow measurement results of the geopolymer mortar showed that the flow rate was improved by increasing mixing water as the molar concentration of activator was increased. Compressive strength increased with increasing curing temperature and molar concentration. Through the microstructure analysis, we could confirm the geopolymer gel produced by the reaction of the condensation polymerization. It is considered that it is possible to make the bottom ash based geopolymer concrete through proper molar concentration of activator and high temperature curing.

Influence of Na/Al Ratio and Curing Temperature of Geopolymers on Efflorescence Reduction (Na/Al 비와 양생온도가 지오폴리머의 백화억제에 미치는 영향)

  • Kim, Byoungkwan;Heo, Ye-Eun;Chon, Chul-Min;Lee, Sujeong
    • Resources Recycling
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    • v.27 no.6
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    • pp.59-67
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    • 2018
  • Efflorescence is a white deposit of powders in the surface of cement concrete which can also occur in geopolymers. Efflorescence occurs when sodium ions in alkali activator react with atmospheric carbon dioxide to form sodium carbonate components. In this study, we investigated whether the secondary efflorescence can be reduced by controlling the Na/Al mole ratio or by changing the curing temperature and heat curing time in fly ash-based geopolymers. The 28 days compressive strength in geopolymers having Na/Al ratio of 1.0 was higher than geopolymers having Na/Al ratio of 0.8. The strength increased with the increasing curing temperature and longer heat curing time. On the other hand, efflorescence was lower when the curing temperature was high and the heat curing time was longer in the geopolymers having Na/Al ratio of 1.0. The geopolymers having Na/Al ratio of 0.8 showed accelerated efflorescence occurrence than the geopolymers having Na/Al ratio of 1.0. In order to reduce the occurrence of the secondary efflorescence of fly ash-based geopolymers, it will be advantageous to maintain the Na/Al ratio at 1.0, increase the curing temperature, and lengthen the heating curing time.