• Title/Summary/Keyword: 지구화학모델

Search Result 88, Processing Time 0.03 seconds

Reactive transport modeling of the $CO_2-H_2O$-cement reaction in a $CO_2$ injection well for $CO_2$ geological storage ($CO_2$ 지중저장 주입정에서의 $CO_2-H_2O$-시멘트 반응 운송 모델링)

  • Jo, Min-Ki;Chae, Gi-Tak;Choi, Byoung-Young;Yu, Soon-Young;Kim, Tae-Hee;Kim, Jeong-Chan
    • The Journal of Engineering Geology
    • /
    • v.20 no.4
    • /
    • pp.359-370
    • /
    • 2010
  • $CO_2$ leakage from a geological formation utilized for $CO_2$ storage could result in failure of the facility and threaten the environment, as well as human safety and health. A reactive transport model of a $CO_2-H_2O$-cement reaction was constructed to understand chemical changes in the case of $CO_2$ leakage through a cement crack in an injection well, which is the most probable leakage pathway during geological storage. The model results showed the dissolution of portlandite and CSH (calcium silicate hydrate) within the cement paste, and the precipitation of secondary CSH and calcite as the $CO_2$ plume migrated along the crack. Calcite occupied most of the crack after 3 year of reaction, which could be maintained until 30 years after crack development. The present results could be applied in the development of technology to prevent $CO_2$ leakage and to enhance the integrity of wells constructed for $CO_2$ geological storage.

Geochemistry of Geothermal Waters in Korea: Environmental Isotope and Hydrochemical Characteristics I. Bugok Area (한반도 지열수의 지화학적 연구: 환경동위원소 및 수문화학적 특성 I. 부곡 지역)

  • Yun, Seong-Taek;Koh, Yong-Kwon;Kim, Chun-Soo;So, Chil-Sup
    • Economic and Environmental Geology
    • /
    • v.31 no.3
    • /
    • pp.185-199
    • /
    • 1998
  • Hydrogeochemical and environmental isotope studies were undertaken for various kinds of water samples collected in 1995-1996 from the Bugok geothermal area. Physicochemical data indicate the occurrence of three distinct groups of natural water: Group I ($Na-S0_4$ type water with high temperatures up to $77^{\circ}C$, occurring from the central part of the geothermal area), Group II (warm $Na-HCO_{3}-SO_{4}$ type water, occurring from peripheral sites), Group III ($Ca-HCO_3$ type water, occurring as surface waters and/or shallow cold groundwaters). The Group I waters are further divided into two SUbtypes: Subgroup Ia and Subgroup lb. The general order of increasing degrees of hydrogeochemical evolution (due to the degrees of water-rock interaction) is: Group III$\rightarrow$Group II$\rightarrow$Group I. The Group II and III waters show smaller degrees of interaction with rocks (largely calcite and Na-plagioclase), whereas the Group I waters record the stronger interaction with plagioclase, K-feldspar, mica, chlorite and pyrite. The concentration and sulfur isotope composition of dissolved sulfate appear as a key parameter to understand the origin and evolution of geothermal waters. The sulfate was derived not only from oxidation of sedimentary pyrites in surrounding rocks (especially for the Subgroup Ib waters) but also from magmatic hydrothermal pyrites occurring in restricted fracture channels which extend down to a deep geothermal reservoir (typically for the Subgroup Ia waters). It is shown that the applicability of alkaliion geothermometer calculations for these waters is hampered by several processes (especially the mixing with Mg-rich near-surface waters) that modify the chemical composition. However, the multi-component mineral/water equilibria calculation and available fluid inclusion data indicate that geothermal waters of the Bugok area reach temperatures around $125^{\circ}C$ at deep geothermal reservoir (possibly a cooling pluton). Environmental isotope data (oxygen-18, deuterium and tritium) indicate the origin of all groups of waters from diverse meteoric waters. The Subgroup Ia waters are typically lower in O-H isotope values and tritium content, indicating their derivation from distinct meteoric waters. Combined with tritium isotope data, the Subgroup Ia waters likely represent the older (at least 45 years old) meteoric waters circuated down to the deep geothermal reservoir and record the lesser degrees of mixing with near-surface waters. We propose a model for the genesis and evolution of sulfate-rich geothermal waters.

  • PDF

Developmental Toxicity of Alkylphenols in Amphibians: A Review (알킬페놀류 화합물의 양서류 발생독성: 종설)

  • Park, Chan-Jin;Ahn, Hae-Sun;Ahn, Hyo-Min;Gye, Myung-Chan
    • Korean Journal of Ecology and Environment
    • /
    • v.44 no.2
    • /
    • pp.103-112
    • /
    • 2011
  • Aquatic contamination by organic pollutants has been a suspected reason for rapid decrease of amphibian populations whose embryonic and larval stages are in an aquatic environment. Amphibian embryos can be a useful model to study the ecoctoxicologial impacts of aquatic pollutants. The obtained toxicological data are useful references for the management of aquatic pollutants in public health because amphibia share many developmental events with terrestrial vertebrates including humans. Safety guidelines for the toxicological effects of aquatic contaminants of chemicals identified as hazardous should be addressed at multiple endpoints. Alkylphenols have been widely-used in agricultural, industrial, and household activities; they contaminate and can persist in aquatic environments. Exposure to alkylphenols results in endocrine disruption in aquatic animals. In this review, we summarize the developmental toxicities of alkylphenols in amphibian embryos and larva according to the exposure route, chemical concentration, duration of exposure, and affected developmental stage together with mechanisms of toxicity and typical patterns of developmental abnormality. The merits of amphibian embryos as a toxicity test model for mid- to long-term exposure to aquatic pollutants are discussed proposed.

Building of Integrated Web-GIS System for National Groundwater Data Management (지하수 정보관리체계 고찰 및 Web-GIS 기반의 국가지하수정보지도 구축 모형)

  • Kim, Gyoo-Bum;Son, Young-Chul;Kim, Jong-Wook;Kim, Dae-Ho;Lee, Chang-Won;Kim, Yang-Hee
    • Journal of the Korean Association of Geographic Information Studies
    • /
    • v.9 no.3
    • /
    • pp.107-122
    • /
    • 2006
  • The main objective of this study is to develop a web-based Geographic Information System (GIS) application, IGIS(Integrated Groundwater Information Service System), for efficient management of groundwater data. This integrated system includes various groundwater measurements, monitoring data, well data, hydrogeochemical data, hydrogeological maps and diversely analyzed results including time series analysis data for water levels and quality. It will be used efficiently for local government officers to manage groundwater within their districts and also for drillers and investigators to develop wells and assess groundwater conditions. This web-based GIS system was implemented firstly for Cheonan and Daegu city. As a result, the system makes the efficient management, distribution and utilization of groundwater data possible by web-based GIS technology.

  • PDF

Vulnerability Assessment for Fine Particulate Matter (PM2.5) in the Schools of the Seoul Metropolitan Area, Korea: Part II - Vulnerability Assessment for PM2.5 in the Schools (인공지능을 이용한 수도권 학교 미세먼지 취약성 평가: Part II - 학교 미세먼지 범주화)

  • Son, Sanghun;Kim, Jinsoo
    • Korean Journal of Remote Sensing
    • /
    • v.37 no.6_2
    • /
    • pp.1891-1900
    • /
    • 2021
  • Fine particulate matter (FPM; diameter ≤ 2.5 ㎛) is frequently found in metropolitan areas due to activities associated with rapid urbanization and population growth. Many adolescents spend a substantial amount of time at school where, for various reasons, FPM generated outdoors may flow into indoor areas. The aims of this study were to estimate FPM concentrations and categorize types of FPM in schools. Meteorological and chemical variables as well as satellite-based aerosol optical depth were analyzed as input data in a random forest model, which applied 10-fold cross validation and a grid-search method, to estimate school FPM concentrations, with four statistical indicators used to evaluate accuracy. Loose and strict standards were established to categorize types of FPM in schools. Under the former classification scheme, FPM in most schools was classified as type 2 or 3, whereas under strict standards, school FPM was mostly classified as type 3 or 4.

A Study on Generating a Coastal Flood Hazard Map (국내 적합한 연안침수지도제작에 관한 연구)

  • 원대희;김계현;박태옥;최현우;곽태식
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
    • /
    • 2004.03a
    • /
    • pp.435-440
    • /
    • 2004
  • 연안침수지도는 태풍이나 해일에 의한 연안침수 발생 시 방조제의 월류 및 붕괴로 인한 예상 침수구역을 강우빈도(200년)별로 나타내고, 침수면적과 깊이를 표현한 지도로서 국외 선진국에서 방재형 국토관리 정책결정과 침수피해에 대한 대민 홍보의 수단으로 활용되고 있다. 국내에서도 연안침수에 의한 피해가 나날이 커지고 국토의 개발에 따른 자연 재해가 많아짐에 따라 보다 방재형 국토개발로 국민의 안전과 복리를 증진하고, 연안침수에 의한 피해를 최소화하기 위한 노력의 일환으로 연안침수지도의 제작 필요성이 증대되고 있다. 본 연구의 시범지역인 대부도 남부지역의 GIS 데이터베이스 구축은 문헌조사 및 기구축 데이터 확보, 지역의 특성에 맞는 신규 GIS 데이터베이스 구축 방법을 제시하였다. 침수구역을 예측하기 위한 모델링을 지원하기 위한 정확도와 경제성, 객관성, 현실성이 높은 지형공간자료의 효율적인 구축이 강조되었다. 구축한 데이터베이스의 세부 유형은 침수위험구역, 침수경계구역, 침수량 화살표이며, 기존에 구축된 데이터를 활용한 레이어는 해안선, 도로, 건물, 등고선, 등심선, 연안 표고점 측량데이터이다. 연안침수지도는 효율적인 재난관리를 위하여 다양하게 활용될 수 있을 것으로 사료되며 나아가 주민의 침수에 대한 경각심 고취와 사전 교육, 지방자치단체의 침수위험 관리업무의 활용이 가능할 것으로 사료된다. 본 연구에서 제작된 연안침수지도는 지자체 주민들을 위해 보기 쉽고 다양한 정보를 얻을 수 있도록 제작되었으며, 이를 위해 사진과 삽화를 추가하여 주민들에게 침수피해에 대한 경각심과 이해를 높이는데 중점을 두었다. 유지관리 후 활용체계 정비의 중요성’을 점검하고, ‘변동자료 발생원인의 분석’, ‘명확한 변동자료 입력 근거의 확보’, ‘갱신주체별 역할의 정의 및 유지관리 기준의 설정’, ‘분야별업무 특성을 고려한 관련 기준의 마련 및 타 시스템과 연계되는 항목을 고려한 절차 정의’ 등에 대한 다양한 접근을 시도하였다. 본 연구에서 제시하는 유지관리 모델을 기반으로 각 지자체별로 적절한 컨설팅이 진행되고 이에 따라 담당자의 실천이 이루어진다면 지자체 GIS의 투자대비 효과에 대한 기대는 이상이 아닌 현실로 다가오게 될 것이다.가오게 될 것이다. 동일하게 25%의 소유권을 가지고 있다. ?스굴 시추사업은 2008년까지 수행될 계획이며, 시추작업은 2005년까지 완료될 계획이다. 연구 진행과 관련하여, 공동연구의 명분을 높이고 분석의 효율성을 높이기 위해서 시료채취 및 기초자료 획득은 4개국의 연구원이 모여 공동으로 수행한 후의 결과물을 서로 공유하고, 자세한 전문분야 연구는 각 국의 대표기관이 독립적으로 수행하는 방식을 택하였다 ?스굴에 대한 제1차 시추작업은 2004년 3월 말에 실시하였다. 시추작업 결과, 약 80m의 시추 코아가 성공적으로 회수되어 현재 러시아 이르쿠츠크 지구화학연구소에 보관중이다. 이 시추코아는 2004년 8월 중순경에 4개국 연구팀원들에 의해 공동으로 기재된 후에 분할될 계획이다. 분할된 시료는 국내로 운반되어 다양한 전문분야별 연구에 이용될 것이다. 한편, 제2차 시추작업은 2004년 12월에서 2005년 2월 사이에 실시될 계획이다. 수백만년에 이르는 장기간에 걸쳐 지구환경변화 기록이 보존되어 있는

  • PDF

Development of the Elementary Science Curriculum to Enhance Creative Problem-Solving Abilities: Theme Based Construction of Contents (창의적 문제해결력 신장을 위한 과학교육과정 개발 연구-주제 중심의 초등과학교육과정 내용구성-)

  • Cho, Youn-Soon;Choi, Kyung-Hee;Suh, Ye-Won
    • Journal of The Korean Association For Science Education
    • /
    • v.18 no.4
    • /
    • pp.527-537
    • /
    • 1998
  • This article is a part of a research on the elementary science curriculum development to enhance creative problem-solving abilities. The components of the curriculum have been identified as 'scientific knowledge', 'process skills' & 'divergent/critical thinking'. Among these components, construction of the scientific knowledge that enables creative problem-solving abilities has been selected as an intensive research topic for the purpose of the present research. To avoid or to prevent the knowledge learned from separate facts and concepts, five themes have been selected so as to incorporate with all three areas of the elementary science curriculum, i.e., physical science, earth science and life science. The five themes are, 'structure', 'change', 'interaction', 'energy' and 'stability'. The contents of elementary science, which have been selected from the 3rd, 6th and 7th National Elementary Science curriculum, were reconstructed based on the five themes given above. The results of reconstruction are presented in the form of matrix, such that the vertical axis represents how the concepts are related within each domain of science, while the horizontal axis shows how the concepts are interconnected between domains of science. Therefore, based upon the five themes, individual or separate knowledge can be put into more unified knowledge so that contribution of knowledge transfer to new ones can be expected for leaners who will be creative in problem-solving. The process and products of the curriculum development as well as the background of the present research are described and discussed in detail.

  • PDF

Pore Water Chemistry of Intertidal Mudflat Sediments: 1. Seasonal Variability of Nutrient Profiles (S, N, P) (조간대 퇴적물의 공극수 지구화학 : 1. 용존 영양염 (S, N, P)의 계절변화)

  • Lee, Chang-Bok;Kim, Dong-Seon
    • 한국해양학회지
    • /
    • v.25 no.1
    • /
    • pp.8-20
    • /
    • 1990
  • A series of pore water data were obtained during the different time over one year period between October 1987 and October 1988, from a site on a muddy intertidal flat, located in the Kyeong-gi Bay, west coast of Korea, The results have revealed that the tidal flat is an environment of active nutrient the subface supplied by the overlying seawater is almost completely removed from the pore water at depth of about 10 cm below the sediment surface. The nutrients such as ammonium and phosphate are produced through this process and subsequently accumulated in the pore water forming steep gradients near the sediment surface. Below the main sulfate redirection zone, a secondary peak of dissolved sulfate was often observed. Greal seasonal variation of the pore water nutrient profiles was observed, which was particularly clear in their maximum concentration as well as in their concentration gradient. The rate constants of sulfate reduction and nutrient regeneration, estimated by using a diagenetic model (Berner, 1980), differ by an order of magnitude between the summer and winter seasons. The difference in sediment temperature may account for most of the calculated variation. The C:N:P ratio, calculated from the pore water nutrient gradients also exhibits a slight seasonal difference. The organic matter being decomposed by sulfate reduction appears to be depleted in depleted in nitrogen, compared to the average marine organic matter.

  • PDF

A Preliminary Study on Stratigraphy and Petrochemistry of the Okcheon Group, Southwestern Okcheon Metamorphic Belt (서남 옥천변성대 옥천층군의 층서 및 암석화학에 대한 예비연구)

  • 유인창;김성원;오창환;이덕수
    • Economic and Environmental Geology
    • /
    • v.36 no.6
    • /
    • pp.511-525
    • /
    • 2003
  • The Okcheon Group in the southwestern part of the Okcheon Metamorphic Belt is subdivided into two distinct tectonostratigraphic units: the Boeun unit in the south and the Pibanryeong unit in the north. The Boeun unit consists of petites, psammites, carbonaceous petites, limestones and pebble-bearing quartzites. The Pibanryeong unit is composed of petites, well-sorted fine-grained psammites, carbonaceous psammites and quartzites. In order to outlining stratigraphy and depositional environments of the Okcheon Group, detailed stratigraphic sections were measured in three locations; one section(Gosan section) of the Boeun unit and two sections(Sorungjae and Hwangryeongzae sections) of the Pibanryeong unit. The Gosan section of the Boeun unit is interpreted to be deposited in the shallow marine environments, whereas the Sorungjae and Hwangryeonaiae sections of the Pibanryeong unit appear to be deposited in slope and deep basin environments. This result indicates rapid subsidence between deposition of the Boeun and Pibanryeong units in sedimentary environment. The trace of sedimentological environments in the Hwasan area was investigated by geochemical analysis of 109 metapelitic and psammitic rock samples. Distinct chemical variations of politic and psammitic rocks from the Boeun and Pibanryeong units in the study area are evident from plots of major elements and $A1_2O_3$/$SiO_2$ versus Basicity Index($Fe_2O_3{+}MgO$)/($SiO_2{+}K_2O{+}Na_2O$). The rocks show a progressive chemical trend from the Boeun unit to the Pibanryeong unit on these diagrams. They in the southern sector of the Boeun unit display lower values and a comparatively wide range of $A1_2O_3$/$SiO_2$ and Basicity Index, as compared with those from the northern sector of the Boeun and Pibanryeong units. The southern sector of the Pibanryeong unit including narrow staurolite-bearing zone is characterized by values that are transitional between the Boeun and Pibanryeong units. These data, combined with depositional environment progressively deepened towards the northwest, support a half-graben model for the Okcheon basin, as proposed by Cluzel et al.(1990)

Characteristics and Relationships of Teachers' PCK Components in charge of Science Gifted Middle School Students (중학교 과학영재 담당교사의 PCK 요소의 특징과 관련성)

  • Kim, Sun-Kyoung;Min, Hee-Jung;Bang, Eun-Jung;Paik, Seoung-Hey
    • Journal of Gifted/Talented Education
    • /
    • v.21 no.4
    • /
    • pp.801-828
    • /
    • 2011
  • In this study, we analyzed the characteristics of Pedagogical Content knowledge(PCK)'s components through actual course of teachers of science gifted students in the middle school. For this study, four middle school science teachers of gifted students belonging to the gifted education professional organizations in a metropolis were selected, each of them was physics, chemistry, biology, and earth science teacher. Two of them were full-time teachers to teach only gifted students and two were part-time teachers who had taught general students in ordinary time and specially had taught the gifted students once a week. Qualitative data were collected through classroom observations, interviews, and documents. As a result, some unique characteristics of PCK's components were identified. The teachers' orientations to teaching science were closely correlated with PCK's components. The teachers' knowledges of science curriculum were different individually. But the decisions about type of teaching(acceleration or enrichment) were connected with the objectives of gifted education and lesson objectives. Also, the teachers' knowledges of science curriculum were influenced by the knowledge of students' understanding. Teachers used different instructional strategies according to the knowledge of science curriculum and the knowledge of students' understanding. We found that PCK's components were so closely connected and could show the direction of relationships among those PCK's components. We suggested teachers' PCK model which was named "Tetrahedron Model of PCK", to explain the characteristics and relationships of PCK's components.