• Title/Summary/Keyword: 증류주

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Profile Position Control of Extractive Thermally Coupled Distillation System (추출 열 통합 증류계의 프로필 위치 제어)

  • Cho, Hoon;Choi, Yu-Mi;Lee, Jin-Hong;Cho, Im-Pyo;Han, Myung-Wan
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.815-824
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    • 2012
  • Extractive distillation system can be used when the components to be separated have close boiling points or form azeotropes. Extractive distillation is one of the most important and widely used separation methods in chemical process industry. The main disadvantage of the distillation is its high-energy requirements. Thermally coupled distillation system (TCDS) can provide significant savings in energy consumption and capital cost over the operation of sequences based on conventional distillation column. Despite such advantages of the thermally coupled distillation system, the process is not widely used in industry because control and operation of the column are difficult. In this study, we propose several control schemes for thermally coupled distillation system to overcome the difficulties and make the column stable when the process is confronted with feed disturbances. Profile position control scheme shows best control performance among the proposed control schemes.

Effects of Treatments on the Distribution of Volatiles in Artemisia princeps Pampan (쑥의 처리조건에 따른 휘발성 성분 변화)

  • Park, Min-Hee;Kim, Mi-Ja;Cho, Wan-Il;Chang, Pahn-Shick;Lee, Jae-Hwan
    • Korean Journal of Food Science and Technology
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    • v.41 no.5
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    • pp.587-591
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    • 2009
  • Volatiles in Artemisia princeps Pampan. cv. sajabal (sajabalssuk) and A. princeps Pampan. (ssuk) treated with different processing were analyzed using headspace-solid phase microextraction (HS-SPME)/gas chromatography- a mass selective detector (GC-MS). Sajabalssuk and ssuk were treated with steam distillation (SD) and freeze-dried/steam distillation (FD/SD) while controls were raw sajabalssuk and raw ssuk. Sajabalssuk had significantly more total volatiles than ssuk in control and FD/SD treated samples (p<0.05). Major volatiles in raw sajabalssuk were 2-hexenal, 1,8-cineol, trans-caryophyllene, and hexanal while those in raw ssuk were 1-hexanol, ${\beta}$-myrcene, limonene, and 2-hexenal, which implies that substantial lipid oxidation occurred in raw samples. Sajabalssuk with SD and FD/SD treatment had higher peak areas of 1,8-cineole, 4-terpineol, 1-octen-3-ol, and ${\alpha}$-terpineol while ssuk with SD and FD/SD treatment possessed 1,8-cineol, camphor, borneol, artemisia ketone, ${\alpha}$-thujone, and 1-octen-3-ol, which showed that steam distillation produced more volatiles from terpenoids than raw samples. Based on the results of HS-SPME/GC-MS, relative amounts of volatiles from lipid oxidation including 2-hexenal, hexanal, and 1-hexanol were reduced in sajabalssuk and ssuk with freeze-drying and/or steam distillation treatment.

Quality Characteristics of Fermented Wine Using Nuruk by Aging Container and Period of Distilled Liquor (누룩 사용 발효주로 제조한 증류주의 숙성 용기 및 기간에 따른 특성)

  • Lee, Dae-Hyoung;Park, In-Tae;Lee, Yong-Seon;Seo, Jae-Soon;Jung, Jae-Woon;Kim, Tae-Wan;Kim, Jae-Ho;Ahn, Byung-Hak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.10
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    • pp.1579-1587
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    • 2014
  • This study aimed to determine the quality characteristics of fermented wine using Nuruk according to the type of aging container (jar or stainless container) and aging time. Alcohol analysis was initiated at 40.4~39.3%, and alcohol contents in the jar and stainless container decreased as aging time increased. Volatile acid content slightly increased in the reduced pressure (RP) jar and stainless container and showed a different result in the atmospheric pressure (AP) container. Amount of acetic acid did not change either in the jar or stainless container as aging time increased. In the case of 2-thiobarbituric acid (TBA), RP was lower than AP after distillation, and TBA value did not change much either in the jar or stainless container. In the case of fusel alcohol by aging time, n-propanol content did not increase either in the jar or stainless container as aging time increased. Iso-butanol content was reduced in the jar but did not change in the stainless container. In the AP container, more aromatic components were measured on the 180th day of aging time than after distillation. High boiling point aromatic components increased in particular. In the stainless container, more aromatic components were generated on the 180th day of aging, but their amount was relatively lower than in the jar. In the jar aging sensory test, the sensory score at RP 50 cmHg was highest on the 180th day of aging. In the case of AP $80^{\circ}C$ liquor, sensory score on the 180th day was the most improved.

Energy Conservation and Exergy Comparison of a Fully Thermally Coupled Distillation Column (열복합 증류탑의 에너지 절감과 엑서지 비교)

  • Kim, Byoung Chul;Kim, Young Han
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.55-60
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    • 2012
  • The energy conservation and exergy loss of a fully thermally coupled distillation commercialized as the divided wall column are compared with those of a conventional two-column system for ternary separation. The used example for the comparison is the benzene-toluene-m-xylene separation process widely used in a petrochemical plant. The design procedure of the fully thermally coupled distillation column is explained, and the energy requirement is compared using the HYSYS. When the same numbers of trays are utilized, the fully thermally coupled distillation column uses 28.2% less energy and 10.4% more exergy loss. The increase of the exergy loss is due to the additional mixing from the bidirectional inter-linking and the temperature elevation in the reboiler from the increased pressure at the bottom of the main column.

월성 발전소의 삼중수소 제거를 위한 촉매복합공정 해석

  • 배재흠;이준식;이한수;정흥석;김광락;송명재;손순환
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.121-132
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    • 1995
  • 중수로형 원자력 발전소에서는 가동년수가 증가함에 따라 중수는 삼중수소로 오염된다. 오염된 중수의 정화에 적합한 공정으로 평가되는 기액촉매교환-화학평형 -증류공정으로 이루어진 촉매복합공정의 주요 설계변수를 설정하여, 이 변수들이 촉매탑 및 증류탑의 용적과 초저온 냉동부하에 미치는 영향을 분석하였다. 촉매탑은 조작선 기울기가 약 0.634, 그리고 제 1, 제 2 증류탑의 농축율 및 삼중수소 제거율을 변화시킬 때 최적 환류비 값이 각각 약 7과 4.7일 때 최적조건임을 밝혔다. 그리고 저온증류공정해석을 위하여 Fenske, Underwood, and Gilliland Equation과 Smoker Equation을 사용하여 이 두모델식의 계산값을 비교 검토한 결과 거의 유사한 설계값을 얻을 수 있음을 확인하였다.

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Knowledge Distillation for Recommender Systems in Multi-Class Settings: Methods and Evaluation (다중 클래스 환경의 추천 시스템을 위한 지식 증류 기법들의 비교 분석)

  • Kim, Jiyeon;Bae, Hong-Kyun;Kim, Sang-Wook
    • Proceedings of the Korea Information Processing Society Conference
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    • 2022.05a
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    • pp.356-358
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    • 2022
  • 추천 시스템에서 사용되는 피드백은 단일 클래스와 다중 클래스 피드백으로 구분할 수 있다. 추천 시스템을 위한 지식 증류 기법들은 단일 클래스 환경에서 주로 연구되어 왔다. 우리는 다중 클래스 환경에서 또한 추천 시스템을 위한 최신 지식 증류 기법들이 효과적인지에 대해 알아보고자 하며, 해당 방법들 간의 추천 정확도를 비교해보고자 한다. 추천 시스템에서 보편적으로 사용되는 데이터 셋들을 기반으로 한 실험들을 통해 추천 시스템을 위한 지식 증류 기법들은 같은 조건의 기본적인 추천 시스템에 비해 정확도가 최대 193%까지 개선되는 것을 확인했다.

한국산 장뇌산삼의 부위별 유용성분함량 및 추출용매조건의 영향

  • 김준한;문혜경;강우원;김종국
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2003.10a
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    • pp.150.2-151
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    • 2003
  • 한국산 장뇌산삼의 열매, 잎, 줄기 및 뿌리를 -7$0^{\circ}C$ 동결건조 분말화시킨 시료에 대한 추출용매와 농도에 따른 유용성분의 함량을 비교, 분석하였다. 추출액의 당도는 잎과 줄기의 80% 에탄올추출액이 각각 22.58%와 22.53%로 가장 높았고, pH는 4.43-7.41 수준이었고, 갈변도는 흡광도가 잎과 뿌리 80% 에탄올추출액이 1.803과 1.085로 가장 높았다. 색도의 경우 L값는 줄기 100% 증류수추출액이 24.56, 열매 80% 메탄올추출액이 24.35로 가장 높았고, 뿌리와 잎 80% 에탄올추출액이 각각 17.47과 19.59로 가장 낮은 값을 나타내었다. a값은 잎100% 증류수추출액이 0.41로 가장 높았고, 줄기 80%메탄올추출 액이 -0.49로 가장 낮은 값을 보였다. b값은 줄기 80% 메탄올추출액이 3.69로 가장 높았고, 열매 100% 증류수추출액 이 0.45로 가장 낮은 값이었다. 주요 유리당은 sucrose, glucose 및 fructose 이었고, 유리당 총함량은 열매와 줄기 100% 증류수추출액이 각각 6733 mg/100g과 6142 mg/100g으로 가장 많은 량을 함유하였고, sucrose는 뿌리 80% 메탄올추출액 이 3673 mg/100g으로, glucose 및 fructose는 줄기 80% 에탄올추출액과 잎 80% 메탄올추출액에 각각 4283 mg/100g과 1897 mg/100g으로 높은 함유량을 나타내었다. 또한 잎과 줄기에는 xylose가 304-524 mg/100g 수준으로 함유되어 있었고, 뿌리에는 maltose가 소량 함유하고 있었다. 주요 유기산으로는 citric acid, tartaric acid 및 malic acid가 확인되었고, citric acid는 뿌리 80% 메탄올추출액이 1849 mg/100g으로 가장 높은 함량이었고, tartaric acid는 잎 80% 메탄올추출액이 3263 mg/100g으로 가장 높은 함량이었고, malic acid는 뿌리 80% 메탄올추출액이 1856 mg/100g으로 가장 높은 함량이었으며, 뿌리 80% 메탄올추출액에는 succinic acid, malonic acid 및 oxalic acid 등이 확인되었다. 유리아미노산은 L-Arginine, ${\gamma}$-Amino-n-butyric acid, Ethanolamine, L-Proline, $\beta$-Alanine 및 L-sarcosine 등 총 35종이 확인되었고, L-Arginine은 251-7379 mg/100g 수준으로 특히, 뿌리 80% 메탄올추출액에는 1319 mg/100g으로 총함유량의 79.13%로 매우 높은 함유량을 나타내었다. P, K, Na, Ca 및 Mg 등이 주된 무기질로 확인되었고, 그 중 P는 줄기 100% 증류수추출액에 15563 mg/100g으로 가장 높았고, K은 잎 80% 메탄을 추출액에 4952 mg/100g, Ca과 Na은 잎과 열매 100% 증류수추출액에 각각 3052 mg/100g과 1798 mg/100g, Mg은 잎 100% 증류수추출액에 950 mg/100g으로 매우 높은 함유량을 보였고, 또한 미량원소로는 Zn, Cu, Cr, Mn, Co, Mo, Fe 등이 함유되어 있었다.

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A Clinical Research of Acne Skin through Natural Cosmetics with Distilled Bamboo Vinegar Contents for Skin Health Care (스킨헬스케어를 위한 증류 죽초액 함유 천연화장품의 여드름 피부 임상 적용 연구)

  • Park, Ga-Hui;Park, Jeong-Yeon
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.7
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    • pp.589-597
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    • 2020
  • The purpose of this study was to verify the acne care improvement effects of natural cosmetics with distilled bamboo vinegar contents and develop the materials for acne cosmetics. For the research subjects, 20 teenage boys and girls were selected and based on random number table, 10 subjects were assigned in the control group that used natural cosmetics (foam cleanser, toner, facial pack) and 10 subjects were assigned in the experimental group that used natural cosmetics with distilled bamboo vinegar contents (foam cleanser, toner, facial pack). The natural cosmetics was used for 12 weeks, and Mark-·Vu facial analysis system was used to measure the sebum, pore size, and redness before using the natural cosmetics, 6 weeks after using the natural cosmetics, and 12 weeks after using the natural cosmetics. For the collected data, SPSS v. 21.0 statistics package program was used for the analysis, and the results are as follows. First, it is a safe natural cosmetics based on the results of the patch test to confirm the skin safety of the natural cosmetics. Second, homogeneity was secured based on the results of the test of homogeneity for the sebum, pore size, and redness of the control group and experimental group. Third, in the verification of acne skin improvement effects of natural cosmetics with distilled bamboo vinegar content, the experimental group had higher reduction rate of changes in the sebum, pore size, and redness on the forehead and right cheek compared to the control group. Therefore, it was identified that the natural cosmetics with distilled bamboo liquid content is safe for the skin and effective for reducing the sebum, pore size, and redness for acne skin. For this reason, it is anticipated for distilled bamboo vinegar to be used in the cosmetics industry.

Cytotoxic Effect of the Distilled Pine-Needle Extracts on Several Cancer Cell Lines in vitro (솔잎 수액 증류액의 암세포주에 대한 in vitro 세포독성)

  • Chung, Young-Jin;Bae, Myung-Won;Chung, Myoung-Il;Lee, Ji-Seon;Chung, Kyeong-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.4
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    • pp.691-695
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    • 2002
  • This study was performed to examine the cytotoxic effects of the distilled pine-needle extracts against several cancer cell lines. First, cell lines including mice leukemic cancer cell line (L1210), sarcoma 180 and human monocyte-like cancer cells (U937) were tested using XTT methods in uitro. Pine-needle extracts were prepared by pressing the pine needles and distilling it at below 98$^{\circ}C$ and then added to the growth medium in a final dilution of 10, 20, and 40 times. Growth of three kinds of cancer cells was significantly inhibited by more than 50% with the addition of the extracts. Fifty six to seventy six % of inhibition was shown with the 40 times dilution of the extracts. Greater inhibition was achieved with the 20 times dilution (81~90%) and the 10 times dilution (77~89%) of the extracts. Next, other human cancer cell lines including 3 kinds of breast cancer cell lines (T47D, MDA-MB-231 and MW7A) and one hepatoma cell line (SNU-354) were tested with the 20 times dilution of the extract. T47D and MDA-MB-231 cell lines showed lower inhibition (12%) with the addition of the extract. However, MH7A and SNU-354 cell lines showed 64% and 72% inhibition with the extract, respectively. These results suggest that the distilled pine-needle extracts have strong cytotoxic effect on certain cancer cell lines and the intensity of the effect may vary depending on the process of the pine needle.

Physicochemical properties of rice-distilled spirit matured in oak and stainless steel containers (숙성용기를 달리한 전통 쌀 증류식 소주의 숙성 중 이화학 특성 및 향기성분의 변화)

  • Kang, Sun-Hee;Kim, Jae-Ho;Lee, Ae-Ran;Kim, A-Ra;Kim, Tae-Wan
    • Korean Journal of Food Science and Technology
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    • v.49 no.4
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    • pp.369-376
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    • 2017
  • Maturation of distilled spirit can generate diverse flavors and tastes. Rice Soju was matured in oak casks (MSO) and stainless steel containers (MSS) for one year at ambient temperature. Ipguk (Aspergillus luchuensis) and Saccharomyces cerevisiae Y88-4 were used, and reduced pressure ($110{\pm}20Torr$) distillation was applied to brew Soju. Acidity and conductivity were increased in both MSO and MSS. MSO reduced alcohol content (from 43 to 40%) and volume (from 18,000 to 12,730 mL), and significantly altered yellowness (from 0.2 to 30.2). Furthermore, MSO increased the isoamyl alcohol (from 276.7 to $339.2{\mu}g/mL$) and isobutyl alcohol (from 122.3 to $144.2{\mu}g/mL$) content. Gas chromatography-mass spectrometry was used to detect volatile compounds in Soju, which included 20 esters, 7 alcohols, 2 acids, and 5 miscellaneous compounds. Oak lactone was detected only in MSO and was considered as a specific flavor component associated with oak maturation. Thus, maturation materials contribute to the physicochemical property of distilled spirits.