• Title/Summary/Keyword: 중공층

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Preparation of Asymmetric Folyethersulfone Hollow Fiber Membranes for Flue Gas Separation (온실기체 분리용 폴리이서설폰 비대칭 중공사 막의 제조)

  • Kim Jeong-Hoon;Sohn Woo-Ik;Choi Seung-Hak;Lee Soo-Bok
    • Membrane Journal
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    • v.15 no.2
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    • pp.147-156
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    • 2005
  • It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

Application of Ventilated Cavity for Enhancing Insulation and Preventing Condensation of Curtain-wall System (커튼월의 단열 향상 및 결로 방지를 위한 통기구조 적용방안 연구)

  • Lee, Sunwoo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.1
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    • pp.21-28
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    • 2017
  • Curtain-wall systems have been widely applied to buildings because of their lightweight and constructability characteristics. However, as curtain-wall systems include many building materials, vapor barriers can become damaged and condensation can occur. Due to the material properties of stone curtain-walls, the external appearance and structure of a building could be damaged and the insulating performance of the curtain-wall could be worse. Natural ventilation using an air cavity in a curtain-wall is expected to be effective for the prevention of condensation in inner walls and for the reduction of building cooling energy use in the summer. The purpose of this experimental study is to analyze the influence of a ventilated cavity on the insulating performance of a curtain-wall and the ventilated cavity depth and ratio of top opening needed to prevent condensation in a curtain-wall.

Analysis for Seasonal Operation Performance of Multistory Facade (전면형 이중외피의 절기별 운용성능 분석)

  • Im, Hye-Jin;Cho, Soo;Sung, Uk-Ju;Lim, Sang-Hun;Haan, Chan-Hun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.2
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    • pp.111-120
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    • 2012
  • In this study, to present the data in the internal thermal condition of Double skin facade were measured internal temperature and inlet and outlet openings wind speed of double skin facade. Measurements were similar to temperatures in the upper double skin facade. Especially in summer, temperature stratification is through to be unfulfilled seamlessly despite inlet and outlet openings open. Double skin facade inlet and outlet openings of the air flow rate was slower outlet openings of the air flow rate than inlet openings of the air flow rate.

Preparation and Gas Permeation Characteristics of Polyetherimide Hollow Fiber Membrane for the Application of Hydrogen Separation (수소분리를 위한 Polyetherimide계 고분자 중공사막의 제조 및 기체투과 특성)

  • Kwon, Hyeon Woong;Im, Kwang Seop;Kim, Ji Hyeon;Kim, Seong Heon;Kim, Do Hyeong;Nam, Sang Yong
    • Membrane Journal
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    • v.31 no.6
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    • pp.456-470
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    • 2021
  • In this study, polyetherimide-based hollow fiber membranes were manufactured using the NIPS (nonsolvent induced phase separation) method. THF, Ethanol, and LiNO3 were used as additives to control the morphology of the PEI-hollow fiber membranes. Furthermore, for the development of a high hydrogen separation membrane, the spinning conditions were optimized through the characterization of SEM and gas permeance. As a result, as the content of THF increased, the hydrogen/carbon dioxide selectivity increased. However, the permeance decreased due to the trade-off relationship. When ethanol was added, a finger-like structure was shown, and when LiNO3 was added, a sponge structure was shown. In particular, in the case of a hollow fiber membrane with an optimized PDMS coating layer, the permeance was 40 GPU and the hydrogen/carbon dioxide selectivity was 5.6.

Consolidation Behaviour of Dredged Clay Ground Improved by Horizontal Drain Method (수평배수공법에 의해 개량된 준설점토지반의 압밀거동에 관한 연구)

  • 김형주;원명수
    • Geotechnical Engineering
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    • v.13 no.1
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    • pp.137-146
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    • 1997
  • In this study, a large consolidation test was carried out to estimate the consolidation behaviour of dredged clay ground improved by horizontal drain using plastic board drain with a vacuum pressure. The test results were analyzed by a numerical simulation using potential consolidation theory applied to a hollow cylinder. The rapid decreases in pore pressure and the drain speed in the plastic board indicate that the consolidation occurred quickly after the vacuum state was applied to the test soil. According to the numerical analysis obtained by applying the linear potential consolidation theory to a clay hollow cylinder with external radial drainage, the pore pressure is affected by the strain and the permeability of the soil rather than by the diffusion types. Therefore, measured surface settlement agreed with the numerical solution at the point where consolidation pressure increasing rate u: -0.5. Also the behaviour of the clay layer settlement in the place where the drain was installed was similar to that shown in Barron's consolidation theory. Finally, the design and construction procedure including the selection of the appropriate arrangement of horizontal drains were discussed based on the results of the laboratory tutsts. It is also shown that the potential consolidation theory make it possible to predict consolidation behaviour in the field using horizontal drains exactly.

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A Study on Analysis Method for Performance Evaluation of Double-leaf facade of Office Building (업무용 건물의 이중외피 성능평가를 위한 해석기법의 고찰 - 이중외피 설계안의 에너지 저감 성능 및 환기성능을 중심으로 -)

  • Chung, Hwan-Kyo;Chung, Kwang-Seop;Lee, Yong-Jun;Shin, Seung-Chul;Kim, Young-Il
    • Journal of Energy Engineering
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    • v.21 no.2
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    • pp.168-178
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    • 2012
  • The objective of this study is applied to office buildings to evaluate quantitative evaluation method about performance of double-skin at design stage to establish the basis for the purpose of evaluation performance. Select the evaluation building about design plan for applying the double-skin using the dynamic heat load analysis program the annual heating and cooling load of before and after the double-skin. Using CFD to analyze wind factor and applied ventilation for realistic results. Effects of double-skin to apply, and control techniques that can be done more realistically proposed through to set and control for shade control mode of ventilator and inside cavity wall of double-skin. Apply for the building the double-skin due to interpretation of the annual heating and cooling loads applied to interpret the quantitative effect confirmed the possibility. According to the form of a double skin was confirmed cavity environmental changes.

An Experimental Study on Fire Spreading External Wall of Buildings Using Dry Construction Method (건식공법을 이용한 건축물의 외벽 화재 확산의 실험적 연구)

  • Park, Jung-Woo;Cho, Nam-Wook
    • Fire Science and Engineering
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    • v.32 no.4
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    • pp.75-85
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    • 2018
  • The Grenpell tower fire in England in June of 2016 is a representative example of damage caused by a vertical fire spreading through external insulation. Organic insulation materials, which are widely used in external insulation, have the disadvantage that they have good insulation performance but are vulnerable to fire. Aluminum composite panels are used as exterior wall finishing materials, and plastics used in aluminum are regarded as the cause of vertical fire spread. Due to the steel frame used to secure the aluminum composite panel to the outer wall, a cavity is formed between the outer wall and outer wall finish. When a fire occurs on the outer wall, the flammable outer wall as well as the flame generated from the heat-insulating material spreads vertically through the cavity, resulting in damage to people and property. In Korea, material unit performance tests are carried out by the Ministry of Land, Infrastructure and Transport notice 2015 - 744. However, in the UK, the BS 8414 test is used to measure the vertical fire spreading time on the outer wall in real scale fire tests. In this study, the risk of external wall fire was evaluated in an actual fire by conducting a real scale wall fire test (BS 8414), which was carried out in Europe, using aluminum composite panels of semi-noncombustible materials suitable for current domestic standards. The purpose of this study was to confirm the limitations of material unit evaluation of finishing materials and to confirm the necessity of introducing a system to prevent the spread of outer wall fire through an actual scale fire test.

Effect of Addition of Cosolvent γ-Butyrolactone on Morphology of Polysulfone Hollow Fiber Membranes (폴리설폰 중공사막 구조에 대한 조용매 γ-Butyrolactone 첨가 영향)

  • Yun, Sukbok;Lee, Yongtaek
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.274-280
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    • 2014
  • Polysulfone (PSf) hollow fiber membranes were prepared via the nonsolvent induced phase separation technique. The cosolvent of ${\gamma}$-butyrolactone (GBL) was added to the polymer solution containing a mixture of PSf and N,N-dimethylacetamide (DMAc). Water was utilized as a precipitation nonsolvent. The morphology of prepared membranes was investigated using a field emission scanning electron microscopy. The fabricated membrane showed a typical asymmetric structure such as the dense layer on the porous support layer by the addition of GBL to the polymer solution. As the concentration of GBL increased, the asymmetric porous structure was shown to be more intensified. It was thought that the added GBL played a role of enhancing the liquid-liquid phase separation of the polymer solution, since the cosolvent of GBL might change the thermodynamic solubility parameter of the doping solution. Permeation properties through the prepared hollow fiber membranes were characterized by measuring the pure water flux and the solute rejection using $0.05{\mu}m$ polystyrene latex (PSL) beads. Experimental results revealed that the use of PEG as the internal coagulant enhanced the pure water flux up to 130 times compared to the use of EG while the rejection of the PSL beads decreased only 5%.

Hydrophilic Coating and Characterization of PVDF Membrane with Flower Type Cross-section made from Thermally Induced Phase Separation (열유도 상분리로 제조한 플라워 형태 단면을 갖는 PVDF 분리막의 친수성 코팅 및 특성평가)

  • Im, Kwang Seop;Lee, Jeong Woo;Jang, Jae Young;Nam, Sang Yong
    • Membrane Journal
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    • v.29 no.6
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    • pp.362-376
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    • 2019
  • In this study, hydrophilic coating characteristics of PVDF [poly(vinylidene fluoride)] hollow fiber membranes with flower type cross-section prepared by thermally induced phase separation were studied. The hollow fiber used in this study was provided from PureEnvitech Co. Ltd., and the hydrophilic coating experiment was performed with different concentration and number of coating of PEBAX 1657, 2533 and 3533 block copolymer solution using a dip coating method. The hydrophilic coated hollow fiber membrane was characterized to scanning microscope and contact angle measurements to determine the degree of hydrophilization. As a result of SEM characterization, it was confirmed that the thickness of the coating layer increased as the coating concentration increased and the number of coatings increased. Contact angle of surface of hollow fibers decreased as the concentration of the coating solution increased and the number of coatings increased. Gas permeance of oxygen gas was measured for the application of the hydrophilized hollow fiber to Membrane Areated Biofilm Reactor. As a result of gas permeation test, it was confirmed that gas permeance decreased with increasing coating concentration and number of coatings, and the more hydrophilized hollow fiber coated with PEBAX 1657 showed lower gas permeance than those coated with PEBAX 2533 and 3533.

한외여과 관형막에서 대류촉진체의 영향

  • 민병렬;최안섭;진양기
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.46-47
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    • 1996
  • 막분리 공정의 공업적인 이용을 위해서는 막을 특정 용기에 적재한 모듈의 형태가 요구되는데 모듈의 형태에 따라 평판형(plate and frame), 나권형(spiral wound), 관형(tubular), 중공사형(hollow fiber)모듈 등이 있다. 이 중에서 관형 시스템은 내경이 12.5~25 mm, 길이 0.6~6.4 m에 이르는 비교적 큰 open channel로 되어 있으며 공급액 유로가 일반적으로 커서 전처리를 행하지 않고도 fouling이 적으며, 또한 막 표면의 세정이 약품에 의한 것 이외에 스폰지 볼 등에 의한 물리적 세정도 가능하므로 응용 범위가 넓다는 것이 특징이다. 한외여과 공정의 가장 큰 문제점은 농도분극 및 fouling 현상에 의한 플럭스 감소이다. 농도분극 현상은 경계층에서 용질의 대류,확산적인 전달에 기인하여 막 표면으로 갈수록 진해지는 용액층의 형성을 의미한다. 이 현상은 가역적인 과정으로서 감압함으로 원상태로 회복이 가능하며 조작 압력에서 정상상태가 되면 막투과 플럭스는 일정한 값을 유지한다.

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