• Title/Summary/Keyword: 주 반응영역

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Crystal growth of gypsum by neutralization reaction of waste sulphuric acid using sludge and dust in Pohang Iron & Steel plant (포항제철(주) 슬러지와 Dust를 이용한 폐황산 중화반응에서 얻어진 석고의 결정성장연구)

  • Ji whan Ahn;Ka yeon Kim;Hwan Kim;Sang bop Lee;Eu dug Hwang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.673-680
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    • 1997
  • NaOH, $Na_2CO_3, CaO, Ca(OH)_2$ and $CaCO_3$ are widely used counteractives for neoutralizing the waste sulphuric acid produced during the metal surface treatment process and/or the metal refining process. To reduce the tremendous expenses for the neutralization treatment of the waste sulphuric acid, the sludge from calcination plant and the stainless refining dust in POSCO (Pohang Iron & Steel co. Ltd.) was utilized. For the sludge, it will be effective to use calcined and then hydrated sludge in strong acid region (pH<2) and to use the sludge itself in weak acid region (pH>2), The gypsum, the by-product of this treatment, was tested to fit the industrial standard of gypsum, so it is expected that it will solve the lack of gypsum supply. For the stainless refining dust, the phase and the morphology of produced gypsum from waste suiphuric acid neutralization was compared with those from pure sulphuric acid. Because of high reactivity and reaction temperature, $CaSO_4$ non-hydrate was obtained in pure sulphuric acid. But $CaSO_4$ dihydrate was obtained in waste sulphuric acid. It is also judged to be a good material for a counteractive of the waste sulphuric acid.

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Study of the Incremental Dynamic Inversion Control to Prevent the Over-G in the Transonic Flight Region (천음속 비행영역에서 하중제한 초과 방지를 위한 증분형 동적 모델역변환 제어 연구)

  • Jin, Tae-beom;Kim, Chong-sup;Koh, Gi-Oak;Kim, Byoung-Soo
    • Journal of Aerospace System Engineering
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    • v.15 no.5
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    • pp.33-42
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    • 2021
  • Modern aircraft fighters improve the maneuverability and performance with the RSS (Relaxed Static Stability) concept and therefore these aircrafts are susceptible to abrupt pitch-up in the transonic and moderate Angle-of-Attack (AoA) flight region where the shock wave is formed and the mean aerodynamic center is moved forward during deceleration. Also, the modeling of the aircraft flying in this flight region is very difficult due to complex flow filed and unpredictable dynamic characteristics and the model-based control design technique does not fully cover this problem. In this paper, we analyzed the performance of the TPMC (Transonic Pitching Moment Compensation) control based on the model-based IDI (Incremental Dynamic Inversion) and the Hybrid IDI based on the model and sensor based IDI during the SDT (Slow Down Turn) in transonic region. As the result, the Hybrid IDI had quicker response and the same maximum g suppression performance and provided the predictable flying qualities compared to the TPMC control. The Hybrid IDI improved the performance of the Over-G protection controller in the transonic and moderate AoA region

플라스틱 미세 성형 기술과 생물학적 응용

  • Jung, Chan-Il;Jang, Jun-Geun;Han, Dong-Chul;Na, Kyung-Hwan;Park, Hoon-Jae;Choi, Tae-Hoon;Kim, Seung-Soo;Cho, Han-Sang;Jung, Seok;Kim, Joong-Kyung;Lee, Yong-Gu;Park, Jun-Ha
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.05a
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    • pp.6-6
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    • 2004
  • 마이크로 / 나노 바이오 기술은 생명공학 및 의약기술의 발전을 가능하게 하고 생체시스템 관련 연구를 위한 마이크로 및 나노 기기를 제작할 수 있게 함으로써 새로운 기술적 영역으로 부각되고 있다. 이러한 기술은 1990년대 초에 랩온어칩(Lab-on-a-chip)의 개발을 가능하게 하였다. 랩온어칩은 실험실(Lab)을 하나의 소자(Chip)에 올려놓는다(On)는 말로 쉽게 설명된다. 즉, 생물학이나 생화학 실험실에서 주로 연구되는 단백질, 세포 등 인체에 영향을 주는 다양한 물질들이 체내외에서 나타내는 반응을 쉽게 검출, 분석하는 일련의 과정들을 빠르고 정확하게 수행할 수 있도록 도와주는 도구인셈이다.(중략)

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Chemical Reactions in the Coal-Methane-Air Flame (석탄화염내 화학반응에 관한 연구)

  • 박호영;안달홍;김종진
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.166-177
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    • 2002
  • The present study is described of the flame structure of one-dimensional, flat, premixed, laminar, coal-air flame with some addition of methane for the flame stability. A low pressure burner operating at a combustion pressure of 0.3 arm was employed in order to extend the reaction zone. Predicted results from the models considered in the present study are compared with experimental results. Comparisons are included gas temperatures, species concentrations, char analysis and measured burning velocity. Among the models, Model II $I^{*}$-d, which specified devolatilization rate constants and a char surface area factor S=4, resulted in good agreement within the present experimental ranges. The results of char analysis suggest that the extent of the reaction occurring on the panicle might be underestimated in the model so that the char surface area should be increased. A value of 4 for this factor was given by sensitivity analysis of change in char surface area. Again, model II $I^{*}$-d gave satisfactory predictions of burning velocities over most of the experimental range studied. It has been clearly shown that the particle diameter appreciably affects the rates of devolatilisation and char oxidation through the effects of thermal lag and volumetric reactive surface area, consequently laminar burning velocity.ity.

CFD Simulation of Non-reacting and Reacting Flows for a Gas Turbine Combustor Firing Biogas (바이오 가스터빈 연소기의 비반응장과 반응장의 3차원 유동해석)

  • An, Yun-Ho;Nam, Sam-Sik;Choe, Jin-Hoon;Im, Ji-Hyuk;Kim, Ho-Keun;Chun, Jae-Chul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.04a
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    • pp.439-444
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    • 2011
  • Doosan Heavy Industries & Construction Co., Ltd. has been recently developing the gas turbine engine using the biogas as fuel. This paper describes the non-reacting and reacting flow analysis of the combustor which is one of the main components in gas turbine engine. Through CFD analysis, investigation has been performed to evaluate the primary factors for aerodynamic design and to predict combustor behaviors during operation with various fuel distribution ratios. The calculation results are compared with rig test data, which reveals that CFD predictions such as pressure loss, air distribution ratio, and recirculation flow are quite reliable. The trend of NO formation was similar with the test, except the low fuel distribution ratio.

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A Case Study of Therapeutic Song Making to Enhance the Self-identity of Adolescents in Residential Treatment Facility (시설보호청소년의 자아정체감 증진을 위한 치료적 노래만들기 사례)

  • Hwang, Hyejin;Song, Inryoeng
    • Journal of Music and Human Behavior
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    • v.19 no.1
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    • pp.43-67
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    • 2022
  • This is a case study of therapeutic song making activities aimed at improving the self-identity of adolescents in residential treatment facility. The participants were three male teenagers (16 to 18 years of age). The song making intervention was conducted individually with the participants once a week over 13 weeks, and each session lasted 60 minutes. The participants took the lead in making songs by discussing on the self-image and his/her role in the relationship and using musical elements to reflect his/her perception. For analysis, an evaluation method was used to analyze the pre- and post-test results for each sub-domain of the self-identity scale, and changes in the verbal and musical responses during each session. Two of the participants demonstrated higher post-test results compared to their pre-test performance, and their highest post-test scores were for the subdomains of intimacy and initiative respectively. In terms of verbal and musical responses per session, all three participants improved their subjectivity through the self-exploration process, which contributed to the establishment of a more positive self-image. This study suggests that facility youth engaging in making creative songs can positively change their perception of their present and future selves and have a positive effect on their sense of identity.

Dose Response Relationship in Local Radiotherapy for Hepatocellular Carcinoma (원발성 간암의 국소 방사선치료 시 선량반응 관계)

  • Park Hee Chul;Seong Jinsil;Han Kwang Hyub;Chon Chae Yoon;Moon Young Myoung;Song Jae Seok;Suh Chang Ok
    • Radiation Oncology Journal
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    • v.19 no.2
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    • pp.118-126
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    • 2001
  • Purpose : In this study, it was investigated whether dose response relation existed or not in local radiotherapy for primary hepatocellular carcinoma. Materials and Methods : From January 1992 to March 2000, 158 patients were included in present study. Exclusion criteria included the presence of extrahepatic metastasis, liver cirrhosis of Child's class C, tumors occupying more than two thirds of the entire liver, and performance status on the ECOG scale of more than 3. Radiotherapy was given to the field including tumor with generous margin using 6, 10-MV X-ray. Mean tumor dose was $48.2{\pm}7.9\;Gy$ in daily 1.8 Gy fractions. Tumor response was based on diagnostic radiologic examinations such as CT scan, MR imaging, hepatic artery angiography at $4\~8$ weeks following completion of treatment. Statistical analysis was done to investigate the existence of dose response relationship of local radiotherapy when it was applied to the treatment of primary hepatocellular carcinoma. Results : An objective response was observed in 106 of 158 patients, giving a response rate of $67.1\%$. Statistical analysis revealed that total dose was the most significant factor in relation to tumor response when local radiotherapy was applied to the treatment of primary hepatocellular carcinoma. Only $29.2\%$ showed objective response in patients treated with dose less than 40 Gy, while $68.6\%\;and\;77.1\%$ showed major response in patients with $40\~50\;Gy$ and more than 50 Gy, respectively. Child-Pugh classification was significant factor in the development of ascites, overt radiation induced liver disease and gastroenteritis. Radiation dose was an important factor for development of radiation induced gastroduodenal ulcer. Conclusion : Present study showed the existence of dose response relationship in local radiotherapy for primary hepatocellular carcinoma. Only radiotherapy dose was a significant factor to predict the objective response. Further study is required to predict the maximal tolerance dose in consideration of liver function and non-irradiated liver volume.

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A Study on the Color and Lighting in the Assisted Living Facilities for the Elderly - Focused on the facilities in Korea and the United States - (노인주거복지시설의 색채와 조명에 관한 연구 - 한국과 미국의 사례분석을 중심으로 -)

  • Chun, Jin-Hee;Dolores A. Ginthner
    • Korean Institute of Interior Design Journal
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    • v.13 no.2
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    • pp.120-132
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    • 2004
  • 고령사회 2001의 발표에 의하면, 노년인구의 증가는 전 세계적으로 21세기까지 지속될 전망이며, 우리나라도 예외가 아니어서 이에 대한 심각한 사회문제가 예상되고, 이들을 위한 특수주거시설에 대한 환경개선이 요망된다. 본 연구는 노인주거복지시설에서 색채와 조명에 대한 개선방향을 제시하기 위한 것으로, 색채와 조명환경을 정량적, 정성적으로 비교 분석하는데 연구의 목적이 있다. 이를 위해 2003년 2월부터 8월까지 우리나라와 미국의 양로시설 20사례에 대한 현장방문조사가 수행되었고, 모든 시설이 공통적으로 가지고 있는 로비, 복도, 식당, 침실 등 4개 영역이 집중적으로 조사되었다. 1) 색상분포도 조사 결과, 한국시설은 미국 시설과 달리 주조색으로 한색을 많이 사용하고 있으며, 보조색, 강조색의 활용도가 낮은 것으로 나타났다. 2) 색상$\cdot$명도의 간격별 조화 정도에 대한 정량적 평가를 통해 한국시설은 명도대비보다는 색상대비가, 유사조화보다는 대비조화가 두드러졌는데 기능적 측면에서는 이상적이나 친근한 분위기를 만들기에는 한계가 있다. 3) 미도(Aesthetic Measure) 측정 결과, 한국과 미국 시설 모두 평균 이상을 보였는데, 특히 한국시설은 색상 대비 이외에 유사색 조화와 같은 질서요소를 강화시킬 필요가 있다. 4) 한국시설은 미국에 비해 조명 환경이 매우 열악하였는데, 자연채광의 유입은 어느정도 만족스러우나 이를 양질의 조명으로 만들기 방안이 요구된다. 5) 조명방식, 광원유형 등 인공조명에 대한 분석 결과, 한국시설은 매우 단순하며 경제적인 방법에 의존하고 있는데 광원의 선택, 배치, 설치 등 기술적인 보완이 요구된다. 6) 한국시설들의 시설별, 영역별 평균조도는 매우 낮은데, 활동시간대의 권장조도 유지는 물론, 영역 간의 조도 차이를 줄이는 방안이 요구된다.신만의 고유한 해결책으로 발전시키는지를 고찰하고자 한다. 본 논문의 목적은 서울을 사례분석 중 하나로 사용하여 인테리어 디자인 분야의 경계를 대도시로 확장하는 동시에 새로운 적용영역의 가능성을 탐구하는데 있다 하겠다.[C/N]의 값을 나타내었다.다.다.화 기술, 구동방법등에 대한 기술개요와 국내외 기술동향에 대하여 소개하고자 한다.었다.다._{2}$가 0.25[wt%] 첨가된 시편의 20[.deg.C]에서의 유전상수는 16,700으로 최대값을 유전손실을 1.28[%]로 최소값을 나타내었다. 또한 모든 시편은 온도 및 주파수에 따라 유전상수가 완만하게 변화하는 유전이완 특성을 나타내었다.다.수적인 물의 양에 따른 DIAION WA30의 라세미화 효율에 관하여 실험한 결과, 물의 양이 증가할수록 그 효율은 감소하였다. DIAION WA30을 라세미화 촉매로 사용하여 아이소옥탄 내에서 라세믹 나프록센 2,2,2-트리플로로에틸 씨오에스터의 효소적 DKR 반응을 수행해 보았다. 그 결과 DIAION WA30을 사용하지 않은 경우에 비해 반응 전환율과 생성물의 광학 순도는 급격히 향상되었다. 전통적 광학분할 반응의 최대 50%라는 전환율의 제한이 본 연구에서 찾은 DIAION WA30을 첨가함으로써 성공적으로 극복되었다. 또한 고체 염기촉매인 DIAION WA30의 사용은 라세미화 촉매의 회수 및 재사용이 가능하게 해준다.해준다.다. TN5 세포주를 0.2 L 규모 (1 L spinner flask)oJl에서 세포간의 응집현상 없이 부유배양에 적응,배양시킨 후 세포성장 시기에 따른 발현을 조사한 결과 1 MOI의 감염조건 하에서는 $0.6\times10^6$cell/mL의 early exponential시기의 세포밀도에서 72시간 배양하였을 대 최대 발현양을 나타내었다. 나타내었다.

Gene cloning of β-mannanase C from Cellulosimicrobium sp. YB-43 and characterization of the enzyme (Cellulosimicrobium sp. YB-43으로부터 mannanase C 유전자의 클로닝과 효소 특성)

  • Yoon, Ki-Hong
    • Korean Journal of Microbiology
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    • v.54 no.2
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    • pp.126-135
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    • 2018
  • The characteristics of enzyme and gene for mannanase B had been reported from Cellulosimicrobium sp. YB-43 producing some kind of mannanase. A gene coding for the enzyme, named mannanase C (ManC), was expected to be located downstream of the manB gene. The manC gene was cloned by polymerase chain reaction and sequenced completely. From this nucleotide sequence, ManC was identified to consist of 448 amino residues and contain a carbohydrate binding domain CBM2 besides a catalytic domain, which was homologous to mannanase belonging to the glycosyl hydrolase family 5. The catalytic domain of ManC showed the highest amino acid sequence similarity of 55% with the mannanases from Streptomyces sp. SirexAA-E (55.8%; 4FK9_A) and S. thermoluteus (57.6%; BAM62868). The His-tagged ManC (HtManC) lacking N-terminal signal peptide with hexahistidine at C-terminus was produced and purified from cell extract of recombinant Escherichia coli. The purified HtManC showed maximal activity at $65^{\circ}C$ and pH 7.5, with no significant change in its activity at pH range from 7.5 to 10. HtManC showed more active on konjac and locust bean gum (LBG) than guar gum and ivory nut mannan (ivory nut). Vmax and Km values of the HtManC for LBG were 68 U/mg and 0.45 mg/ml on the optimal condition, respectively. Mannobiose and mannotriose were observed on TLC as major products resulting from the HtManC hydrolysis of mannooligosacharides. In addition, mannobiose and mannose were commonly detected as the hydrolyzed products of LBG, konjac and ivory nut.

Exchange Reaction Mechanism of $Pb(II)-N_2O_m$ Macrocyclic Complexes by $^{207}Pb-NMR$ Spectroscopy ($^{207}Pb-NMR$ 분광법에 의한 $Pb(II)-N_2O_m$계 거대고리 리간드 착물형성 반응의 교환 메카니즘)

  • Kim, Jeong;Yun, Chang Ju;Yu, Han Jun;Kim, Geon;Kim, Si Jung
    • Journal of the Korean Chemical Society
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    • v.38 no.1
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    • pp.41-49
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    • 1994
  • Exchange reaction mechanisms of the Pb(II) ion for the complexes between Pb(II) ion and nitrogen oxygen donor macrocyclic ligands, such as 1,13-diaza-3,4 : $1011-dibenzo-59-dioxacyclohexa-decane(NtnOtnH_4)$, 1,15-diaza-3,4 : $1213-dibenzo-5811-trioxacycloheptadecane(NenOdienH_4)$, and 1,15-diaza-3,4 : $1213-dibenzo-5811-trioxacyclooctadecane(NtnOdienH_4)$, were studied by $^{207}Pb-NMR$ spectroscopy in N,N'-dimethylformamide(DMF) solutions. The associative-dissociative mechanism dominated in $NtnOtnH_4-Pb(II)$ and $NtnOdienH_4-Pb(II)$ system. For $NenOdienH_4-Pb(II)$ system, the bimolecular exchange mechanism prevailed below $-5^{\circ}C$, and both bimolecular exchange and associative-dissociative mechanism dominated above $+5^{\circ}C.$ The order of activation energies for dissociation was $NtnOdienH_4\;<\;NtnOtnH_4\;<\;NenOdienH_4$ which was reverse to the order of stabilities.

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