• Title/Summary/Keyword: 종이 열화

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Consolidation and Adhesion of Cellulose Nitrate of Folklore Artifacts in the 19~20th Century (19~20세기 생활민속자료에 사용된 셀룰로오스 나이트레이트의 강화와 접착 연구)

  • Oh, Joon Suk;Lee, Sae Rom;Hwang, Min Young
    • Journal of Conservation Science
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    • v.34 no.6
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    • pp.459-470
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    • 2018
  • Cellulose nitrates were used for folklore artifacts(ornamental beads and pipes in hatstrings, frames of eyeglasses, ornamental eyeglass cases, headband ornaments, and jeogori buttons) between the 19th and 20th centuries; however, they are susceptible to cracking, crazing, embrittlement, and crumbling due to deterioration. To consolidate and adhere deteriorated cellulose nitrate folklore artifacts, water-soluble acrylic emulsion adhesives were investigated. For consolidation, Plextol D 498, which has the lowest viscosity in low concentrations, was used. In adhesive films whose glass transition temperature(Tg) is lower than room temperature, the tensile stress and modulus decreased and the strain increased; therefore, the flexibility was high. The Plextol D 498 and Plextol D 498 and Dispersion K 52 films maintained their adhesiveness and flexibility after artificial-sunlight-accelerated ageing, and Plextol D 498 and Dispersion K 52 films hardly caused yellowing. Plextol D 498 was the most stable for accelerating ageing. A low concentration of Plextol D 498 emulsion resulted in the best permeability on the surface of cellulose nitrate, compared with other acrylic emulsions. To prevent ornamental hatstrings from cracking, crazing, embrittlement, and crumbling, a Plextol D 498 emulsion was used. After applying low concentrations(1%, 3%) of the emulsion to consolidate the fragments and high concentration to adhere the fragments, the ornamental hatstrings were protected from crumbling by deterioration, and their fragments were well-adhered. To preserve it from deterioration by oxygen and humidity, the treated ornament was sealed with an oxygen-barrier film using a low-humidity oxygen scavenger.

A Review of the Deterioration and Damage of the Top Flange of the Highway PSC Box Girder Bridge based on the Condition Assessment Results (상태평가 결과 기반 고속도로 PSC Box 거더교 상부플랜지 열화·손상 실태 고찰)

  • Ku, Young-Ho;Han, Sang-Mook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.6
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    • pp.23-32
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    • 2022
  • Although PSCB girder bridges account for 4% of the bridges in use on highways, they do not account for much, but 98% of PSCB girder bridges are 1st type and 2nd type of bridge. Also, the total length of the PSCB girder bridge is 16% (192km) of the total length of the highway bridge. Thus, the PSCB girder bridge can be one of the bridge types where maintenance is important. In order to analyze the damage types of PSCB girder bridges, a detailed analysis was conducted by selecting 62 places (477 spans) precision safety diagnosis reports considering ratio of the construction method and snow removal environment exposure class. Analysis of report and a field investigation was conducted, and as a result, most of the causes of deterioration damage were caused by rainwater (salt water) flowing into the bridge pavement soaking in between the top flange and the interface. After concrete slab deteriorate occurred then bridge pavement cracking and breaking increased and exfoliation of concrete occurred by corrosion and expansion of the reinforcing bars occurred. In addition, the cause of cracks in the longitudinal direction on the bottom of the top flange is considered to be cracks caused by restrained drying shrinkage. In conclusion, for reasonable maintenance considering the characteristics of PSCB girder bridges, it should be suggested in the design aspect that restrained drying shrinkage crack on top flange. Also, it is believed that differentiated maintenance method should be proposed according to snow removal environment exposure class.

Study on the Physical Properties and Characteristics of Adhesives for Woodcraft (목공예용 천연 및 합성 접착제의 특성 연구)

  • Kim, Seong Eun;Lee, Jin Kyung;Lee, Chae Hoon;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.681-688
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    • 2019
  • In this study, the characteristics of natural and synthetic adhesives used in woodcraft were evaluated. The pattern of deterioration of wood and adhesives according to changes in temperature and humidity were compared. For materials, one type of anlmal glue, three kinds of polyvinyl acetate adhesives, one type of epoxy adhesive and one type of zelkova wood were selected. Characteristics of physical and chemical characteristics, weather resistance and drying speed assessment were carried out. The adhesion characteristic evaluation showed that the adhesion strength of anlmal glue and one type of polyvinyl acetate adhesive were 6.54 N/㎟ and 7.01 N/㎟, pH meter of anlmal glue and polyvinyl acetate adhesives was pH 7.03 and pH 3.32-3.59 which were range of available as an adhesive. According to the test results of weather resistance, epoxy adhesives had the highest decreasing value in adhesion strength after deterioration. In the reversible test of the adhesive, it was found to be highly reversible in NaOH, a soluble solvent excluding epoxy, but attention is required when using the wood since it may show discoloration during processing.

Preservation Values and Effects on Cleaning and Adhesive Agents for Plastic Artifacts (플라스틱 작품의 보존 가치 및 세척제와 접착제의 효능 평가)

  • Chung, Yong Jae;Yu, Ji A;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.127-138
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    • 2013
  • Plastic, widely used as a material for contemporary art, get damaged as directly exposed to temperature, humidity, ultra violet, etc. And it is very quickly damaged in early time, once damaged, it can't recover into original state. But like this characteristics, there is a few advanced research in Korea. So this study deal with a rising value of plastic artifacts in other country, United Kingdom and France, current conservation state, identification and cleaning method. Also 5 types of cleaners(distilled water, ethanol, acetone, eraser) and adhesives(cyanoacrylate, epoxy, acrylic, chloroprene rubber) were evaluated by produced plastics(PVC, PE, PP, PS, PU). As a result of experiment, ethanol and acetone that were previous evaluated in other research performed in other country are the best cleaner. Result of degradation after adhesive, cyanoacrylate and epoxy resin showed better performance and stability. As a basic research, this study is expected that can be used in future researches.

Study on Accelerated Aging Characteristics of Paper-Records by Air Pollutants (종이 기록물의 대기 중 유해물질에 의한 가속 열화 특성 연구)

  • Park, Mi-Seon;Jeong, So-Yoon;Hwang, Ji-Hyun;Kim, Hyoung-Jin;Kim, Shin-Do
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.4
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    • pp.76-84
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    • 2014
  • Preventive conservation is one of most important issues in the field of conservation for paper-records. Many researchers have been studied environmental factors such as effects of humidity, temperature, biological attack and air pollutants. Air pollutants strongly associated with oxidative and hydrolytic degradation of cellulose. It is important to control air pollutants in storage environment to improve stabilities of conservation environment. Four paper samples have been analyzed for their accelerated aging characteristics by air pollutants, sulfur dioxide, nitrogen dioxide, ozone, carbon monoxide. Physical and optical properties and weight molar masses(Mw) showed that interactions between air pollutants and paper sample. Nitrogen dioxide, ozone caused severe damage to cellulose in paper by hydrolytic and oxidative decompositions during aging.

Effects of Optical Brightening Agent on the Chemical Degradation Characteristics of Paper Cellulose (형광증백제가 종이 셀룰로오스의 화학적 열화특성에 미치는 영향)

  • Lee, Jae-Hun;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.66-72
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    • 2015
  • This study was conducted to investigate the effects of optical brightening agents (OBA) on the chemical degradation characteristics of paper cellulose during humid heating aging. Three different types of OBAs were applied to a filter paper by dipping it in OBA solutions whose concentrations were controlled to 1% and 2%. The filter papers with an OBA were artificially aged at $80^{\circ}C$ and 65% RH, and the changes in pH of paper and viscosity of cellulose were evaluated. Their functional groups were also analyzed by ATR-FTIR (at-tenuated total reflectance fourier transform infrared spectroscopy). It was found that OBAs influenced the chemical degradation of paper cellulose during humid heating aging. Higher concentration of OBA solutions accelerated the degradation of paper cellulose. Especially, after aging for 12 days, the paper cellulose treated with the tetra-type OBA were the most significantly aged among the three types of OBAs. It was assumed that pH of OBA solutions affected the aging characteristics.

Genomic epidemiology for microbial evolutionary studies and the use of Oxford Nanopore sequencing technology (미생물 진화 연구를 위한 유전체 역학과 옥스포드 나노포어 염기서열분석 기술의 활용)

  • Choi, Sang Chul
    • Korean Journal of Microbiology
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    • v.54 no.3
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    • pp.188-199
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    • 2018
  • Genomic epidemiology exploits various basic microbial research areas. High-throughput sequencing technologies dramatically have been expanding the number of microbial genome sequences available. Abundant genomic data provide an opportunity to perform strain typing more effectively, helping identify microbial species and strains at a higher resolution than ever before. Genomic epidemiology needs to find antimicrobial resistance genes in addition to standard genome annotations. Strain typing and antimicrobial resistance gene finding are static aspects of genomic epidemiology. Finding which hosts infected which other hosts requires the inference of transient transmission routes among infected hosts. The strain typing, antimicrobial resistance gene finding, and transmission tree inference would allow for better surveillance of microbial infectious diseases, which is one of the ultimate goals of genomic epidemiology. Among several high-throughput sequencing technologies, genomic epidemiology will benefit from the more portability and shorter sequencing time of the Oxford Nanopore Technologies's MinION, the third-generation sequencing technology. Here, this study reviewed computational methods for quantifying antimicrobial resistance genes and inferring disease transmission trees. In addition, the MinION's applications to genomic epidemiology were discussed.

Effect of Properties of Fiber and Mineral Filler on Aging of Archival Documents (재료적 특성(섬유 및 금속)이 종이 기록물의 열화도에 미치는 영향)

  • Shin, Joung-Soon
    • Journal of the Korean Graphic Arts Communication Society
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    • v.30 no.3
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    • pp.13-21
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    • 2012
  • This study was carried out to evaluate the stability of archival documents produced using papers. The properties of archival documents depend on the type of fillers of papers that are used such as fiber, non cellulose fiber, and mineral. The physio-chemical characteristics of archival documents were analyzed by employing acid hydrolysis against cellulose fiber substances. Fibers of Korean hand-made (Hanji), flex, and cotten papers showed higher pH and the degree of polymerization (DP) than wood fiber and mechanical fiber. Mechanical pulp containing 12.8% of lignin showed the greatest decrease of DP due to acid hydrolysis, and this resulted in increase of degree of aging. The filler found to clay and talc did not contain metal such as $Fe^{+2}$, $Fe^{+3}$, and $Cu^{+2}$. The alkaline metals such as Mg, Ca, and Ti showed greater resistance to acid hydrolysis.

Manufacturing of Korean Traditional Handmade Paper with Reduced Fiber Damage(III) (섬유의 손상이 적은 한지 제조(제 3보)-K2CO3 증자하여 제조한 한지의 열 열화특성-)

  • 이명기;문성필
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.90-95
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    • 1999
  • The durability of handmade paper prepared by potassium carbonate cooking of paper multiberry (Broussonetia Kazinoki Sieb).was investigated. The potassium carbonate paper before and after heat aging had better strength properties, breaking length and folding endurance than those of the soda paper, except of lower brightness .After 30 days of heat aging , these strength properties were still maintained . however, there was almost no difference in the infrared spectra and the crystallinities calculated by X-ray diffraction curves between the potassium carbonate paper and the soda a paper. The durability of the potassium carbonate paper was though to be due to decrease in the pulp damage caused by weak alkaline cooking condition. The results indicated that the paper prepared by the potassium carbonate cooling method could have better permanence than that prepared by the conventional soda cooking method.

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Studies on the Densification of Recycled Sheet Structure with Thermal Image Analysis and CLSM (열화상분석 및 CLSM을 이용한 재생지의 고밀화 현상 연구)

  • 이학래;김철환;윤혜정;정태민
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.8-15
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    • 1999
  • The effects of Condebelt press drying on the densification of recycled sheets made from KOCC , AOCC UKP and BKP were examined using CLSM (Confocal Laser Scanning Microscope) and thermal image analysis techniques. It was shown that significant improvement in sheet density, compression strength, tensile strength, surface smoothness was obtained by Condebelt drying. Densification effect by press drying was most prominent for recycled KOCC sheets. And this beneficial effect of Condebelt drying of increasing sheet density and strength was shown to provide opportunities of reducing the utilization ratio of AOCC for cost saving.

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