• Title/Summary/Keyword: 제거효율평가

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A Study on Coagulation Process using Zirconium Silicate as a Coagulation-aid (지르코늄 실리케이트를 응집보조제로 이용한 응집공정에 관한 연구)

  • Cho, Jae-Seung;Yoon, Tai-Il;Jeon, Yu-Jae;Cho, Kyung-Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.3
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    • pp.203-207
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    • 2009
  • The concern of seriousness and harmful effects of environmental pollution is rising by the various water pollutions, appearances of new micro-noxious substances and increase of sustainable pollutants. The method is suggested that can effectively increase the removal of organic substances and several pollutants using a coagulation process. The experiment for characteristics of $ZrSiO_4$ (zirconium silicate) as a coagulation-aid was carried out for application to coagulation process with domestic wastewater and lake water, and the removal rate of the organic substances depending on a dosage was evaluated by PDA (Photometric Dispersion Analyzer) in this study. Zeta-potential of zirconium silicate solution was -32.22 mv at pH 7 and the lower negative(-) charge was detected in the more acidic conditions. Absorbance on $UV_{254}$ presented higher when zirconium silicate was added than in a domestic wastewater itself. Besides, the results by PDA experiment represented that injection of zirconium silicate could promote growing of floc. Tests for coagulation process were conducted by three ways which are pre-injection, co-injection and post-injection of zirconium silicate with alum. Accordingly, removal efficiency of organic substances increased over 15% in co-injection than in using of alum as a sole reagent. When a 20 mg/L of alum was used with a 10 mg/L of zirconium silicate, the removal efficiency was high up to 90%. Removal efficiency of $COD_{Cr}$ was improved more than 15% in case of dosage of coagulant either PAC (Poly aluminium chloride) or PACS (Poly aluminium chloride Silicate) together with zirconium silicate. As a result, the removal efficiency of $COD_{Cr}$ were 5~10% higher in a co-injection of zirconium silicate with a coagulant than a pre-injection and a post-injection but it of soluble substances was lower in a co-injection.

A Study on Applicability of Mercury-contaminated Tailing and Soil Remediation around abandoned Mines using Washing Process (세척공법을 이용한 광산주변 수은 함유 오염물질 처리 적용성 평가)

  • Kwon, Yo Seb;Park, So Young;Koh, Il Ha;Ji, Won Hyun;Lee, Jin Soo;Ko, Ju In
    • Economic and Environmental Geology
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    • v.53 no.4
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    • pp.337-346
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    • 2020
  • This study was carried out to evaluate the applicability of the soil washing process to remediation mercury-contaminated mine tailing or solid material (soil and sediments etc.) around abandoned mines. First, the physicochemical characteristics of mine tailing were analyzed through particle size analysis and sequential extraction. Secondly, laboratory scale washing experiments were performed using hydrochloric acid, nitric acid, potassium iodide and sodium thiosulfate. As a results of particle size analysis, mine tailing particle were concentrated below 40 mesh and the particle size below 200 mesh was the most analyzed. As a result of sequential extraction, elemental mercury fraction was analyzed as the highest with 69.12%, with strongly bound fraction 15.25% and residual and HgS fractions 11.97%, respectively. Laboratory scale washing experiments showed low applicability for nitric acid and sodium thiosulfate solutions. In case of hydrochloric acid solution, it was analyzed that mercury removal was possible at particle size of 200 mesh or more. Therefore, it is considered to be performed together with the physical sorting process. Potassium iodide solution was analyzed to have high washing efficiency at all concentrations and particle sizes. In particular, the mercury removal efficiency is high in the micro particles, and thus the applicability of the washing technology is the highest.

A Study on Organic Sludge Application and Duration Estimate for Treating Natural Purification of Acidic Mine Drainage (폐탄광폐수의 자연정화처리를 위한 유기성슬러지 적용 및 지속시간예측에 관한 연구)

  • Kim, Eun-Ho;Kim, Hyeong-Seok;Sung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.3
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    • pp.475-484
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    • 2000
  • The purpose of this study was to develop model for estimating biodegrability of organic sludge (sewage and papermill) in various environmental conditions. to assume degradable degree with operating time of SRB reactor. and evaluate duratior of organic sludge as carbon source. Average TCOD was 28.7~63.2mg/L in effluent. organic sludge did not much supply carbon source for experimental period. But in point of durability. it seemed that organic sludge was efficient because it was not consumed by degradation of much organic matter within short period. With increasing $SO_4{^{2-}}$ reduction rate. Pb and Fe was removed 77~82% and 33~59%. respectively. Because Al was precipitated as a hydroxide. its removal rate wa,. about $54{\pm}2%$ in R-l~R-3 maintaining low pH but about 78% in R-4 maintaining high pH. Because Mn was large in solubility. it showed to be much lower than other heavy metals. Considering supportable capacity or durability of orgainc matter for initial SRB mixing ratio of sewage/papermill 0.5 was regarded as appropriate substituting material and at this time. it estimated that carbon source continued about 3.08 year but safety factor must apply to be thought over. because various factors had an effect on degradation of organic sludge.

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A Study on Aggregate Waste Separation Efficiency Using Adsorption System with Rotating Separation Net (회전분리망 흡착선별기의 순환 굵은골재 이물질 제거효율에 관한 연구)

  • Cho, Sungkwang;Kim, Gyuyong;Kim, Kyungwuk;Seon, Sangwon;Park, Jinyoung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.85-91
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    • 2021
  • Aggregate waste separator with rotating separating net was designed for applying classification process of construction waste. In order to evaluate the performance of the aggregate waste separator, according to the type of waste, standardized waste samples are prepared using acrylic. The appropriate operating point was evaluated by the classification efficiency and misclassification rate of recycled aggregate according to the control frequency of the blower operating and inlet position of the separating net. The classification efficiency at the operating point of the aggregate waste separator was evaluated through flow analysis assuming recycled aggregate and waste sample as particles. As a result of the performance test, when the distance. between the conveyor belt and the inlet was 0.2m, the classification efficiency was 95%, but the misclassification rate of recycled aggregate was 2% or more, which satisfies the classification efficiency and the misclassification rate of less than 2%. The operating point was shown at a control frequency of 58Hz at a suction distance of 0.254m. As a resu lt of flow analysis, there was no misclassification of recycled aggregate. In order to redu ce constru ction waste in the existing recycled aggregate production process, adsorption system using a rotating separating net that can be operated as an installation type was built.

A Study on the Improvement of Evaluation Indicators for Adjusting Forestland Classification (산지구분 조정을 위한 산지특성평가 지표 개선에 관한 연구)

  • KWAK, Doo-Ahn;RYU, Keun-Won;KWON, Soon-Duk;KIM, Won-Kyung
    • Journal of the Korean Association of Geographic Information Studies
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    • v.19 no.1
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    • pp.12-29
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    • 2016
  • The purpose of this study was to improve forestland characteristic evaluation system's indicators for rational development and ecosystem conservation. There has been no consideration for statistical duplication between variables, and it caused inefficient data collection. Furthermore, the same evaluation criteria were applied for all forestlands without considering regionally different characteristics, and it made variation for designation cancel rates of preservation semi-preservation forestlands between cities. To solve these problems, we first removed 'DBH' variable which has a multicollinearity. Second, we applied standard normal distribution for each forest watershed type. As a result of eliminating 'DBH', the numbers of parcels for all grades except A were changed but their numbers and areas were not large enough to consider the change of total score. For the output of analyses with the existing same regional criteria, the total scores of urban type and urban-fringe type forestlands were higher than those of other types. The numbers of parcels for A and B were increased and those for C and E were decreased by applying standard normal distribution. This caused the increase of preservation-oriented parcels. Finally, we suggested a new evaluation method based on standard normal distribution to consider regional forest characteristics and to solve regional imbalance.

Fate of Nitrogen and Phosphorous in Hydroponic Waste Solution Applied to the Upland Soils (시설하우스 폐양액의 토양 처리에 따른 질소 및 인의 이동)

  • Yang, Jae-E.;Park, Chang-Jin;Yoo, Kyung-Yoal;Kim, Kyung-Hee;Ok, Yong-Sik
    • Korean Journal of Environmental Agriculture
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    • v.24 no.2
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    • pp.132-138
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    • 2005
  • Objective of this research was to evaluate the fate of nitrogen and phosphorous in hydroponic waste solution from the plastic film house cultivation applied to the upland soil by column leaching and field experiment. The pH and EC of leachate were decreased by the reaction with the upland soil in the column leaching experiment. The EC and concentrations of $H^+,\;K^+,\;and\;{NH_4}^+$ of leachate were decreased as the column length (soil depth) was increased. But these were increased as the amounts of the hydroponic waste solution were increased field experiment growing red pepper (Capsicum annum L.) to monitor the nutrients movement using ion exchange resin capsule demonstrated that the nutrient concentration of soil solution was increased in the orders of $PO_4-P. Nitrate concentration of resin capsule inserted into the soil was relatively higher than other nutrients $(NH_4-N\;and\;PO_4-P)$ at the 45 cm of soil depth. The overall results demonstrated that the hydroponic waste solution could be recycled as plant nutrients to enhance fertility of soils. But nitrate leaching was a major factor for safe use of the hydroponic waste solution in soil.

Evaluation of Swine Wastewater Pretreatment Using Anaerobic Filter (Anaerobic Filter에 의한 양돈폐수의 전처리 특성 평가)

  • Kang, Ho;Moon, Seo-yeon
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.7
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    • pp.418-425
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    • 2015
  • Anaerobic Filters (AF) packed with porous ceramic floating media were operated at different operational conditions to identify the feasibility of the renewable bioenergy, methane production from swine wastewater and to verify the suitability of effluent from anaerobic filters for the subsequent biological nitrogen and phosphorus removal. Stepwise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) with influent TCOD concentration of 14,000 mg/L were utilized at mesophilic temperature. The maximum methane productivity of 1.74 volume of $CH_4$ per volume of reactor per day (v/v-d) was achieved at an hydraulic retention time (HRT) of 0.5 day (OLR 28 g TVS/L-d). Based on the biogas production, the highest total volatile solids (TVS) removal efficiency of 63% was obtained at an HRT of 3 days (OLR 4.67 g TVS/L-d), however based on the result from the effluent total chemical oxygen demand (TCOD) analysis, the highest TCOD removal efficiency of 75% was achieved. The effluent alkalinity concentration over the range of 2,050~2,980 mg/L as $CaCO_3$ at all operational conditions, could compensate the alkalinity destruction caused by nitrification. The effluent from the anaerobic filter operated under the HRT of 2 days showed the COD/TKN ratio of 15~35 and COD/TP ratio of 38~56. Therefore effluent C/N/P ratio is able to satisfy the optimum COD/TKN ratio of greater than 8.0 and COD/TP ratio of 33 for the subsequent biological nutrient removal.

Decontamination of Mercury Contained in CCFLs (Cold Cathode Fluorescence Light) Disassembled from Waste LCDs (Liquid Crystal Display) (폐 LCD (Liquid Crystal Display) 해체 후 분리된 CCFL (Cold Cathode Fluorescence Light) 내 수은의 건식 제거 공정)

  • Park, Jae Layng;Lee, Sungkyu;Kang, Leeseung;Lee, Chan Gi;Cho, Sung-Su;Hong, Myung Hwan;Hong, Hyun Seon
    • Resources Recycling
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    • v.23 no.2
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    • pp.61-70
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    • 2014
  • LCD televisions and monitors use cold cathode fluorescence lamps (CCFLs) to illuminate the screen. Most CCFLs contain mercury and they have to be carefully handled at the end of their lives as per minimum treatment standards under the Waste Electrical and Electronic Equipment (WEEE) and Restriction of Hazardous Substances (RoHS) directives. CCFLs were carefully separated from mold frames of waste LCD units for primary decontamination of mercury/fluorescent compound mixture using CCFL decontamination system designed and fabricated in the present research. Residual mercury was further removed by employing a pyro-process, where crushed CCFL tubes transferred from primary decontamination process were subject to heat treatment at $550^{\circ}C$ in a box furnace: more than 99% of mercury was removable from waste CCFLs.

A Study of the Regeneration of Spent GAC using an Electrochemical Method (전기화학적 방법을 이용한 Spent Granular Activated Carbon (GAC)의 재생 연구)

  • Lee, Sangmin;Joo, Soobin;Jo, Youngsoo;Oh, Yeji;Kim, Hyungjun;Shim, Intae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.4
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    • pp.481-491
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    • 2022
  • This study investigates the characteristics of the GAC adsorption behavior during the operation of a multi-stage cross-flow filtration and GAC adsorption process for the purpose of devising an advanced treatment of combined sewer overflows (CSOs) and evaluates the regeneration efficiency of spent GAC that has reached the design breakpoint. During the filtration process, suspended substances are easily removed, but dissolved organic substances are not removed, necessitating a process capable of removing dissolved organic substances for the advanced treatment of CSOs. In general, GAC adsorption has been applied under low-concentration organic conditions, such as for water purification and tertiary treatments of sewage, and has rarely been applied under conditions with high organic concentrations, such as with sewage or CSOs. Accordingly, this study will provide a new and interesting experience. Also in this study, the continuous operation and breakthrough characteristics of GAC according to the strength of the inflow organic matter were investigated, electrochemical regeneration was applied to the used GAC, and the regeneration efficiency was evaluated through desorption and re-adsorption tests. The results showed that the breakthrough period was 21 days under high concentration conditions, 28 days at medium concentrations, and 32 days under low concentration conditions. The desorption of adsorbed organic matter through electrolysis occurred in the range of 188 to 609 mgCOD/L depending on the electrolysis conditions, and the effect of the electrolyte type led to the finding that NaOH was slightly higher than H2O2.

Parameter Estimation of the Aerated Wetland for the Performance of the Polluted Stream Treatment (오염하천 정화를 위한 호기성 인공습지의 운영인자 평가)

  • Kim, Dul-Sun;Lee, Dong-Keun
    • Clean Technology
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    • v.25 no.4
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    • pp.302-310
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    • 2019
  • A constructed wetland with the aerobic tank and anaerobic/anoxic tank connected in series was employed in order to treat highly polluted stream water. The aerobic tank was maintained aerobic with a continuous supply of air through the natural air draft system. Five pilot plants having different residence times were employed together to obtain parameters for the best performances of the wetland. BOD and COD removals at the aerobic tank followed the first order kinetics. COD removal rate constants were slightly lower than BOD. The temperature dependence of COD (θ = 1.0079) and BOD (θ = 1.0083) was almost the same, but the temperature dependence (θN) of T-N removal was 1.0189. The SS removal rate was as high as 98% and the removal efficiency showed a tendency to increase with increasing hydraulic loading rate (Q/A). The main mechanism of BOD and COD removal at the anaerobic/anoxic tank was entirely different from that of the aerobic tank. BOD and COD were supplied as the carbon source for biological denitrification. T-P was believed to be removed though the cation exchange between orthophosphate and gravels within the anaerobic and anoxic tanks. The wetland could successfully be operated without being blocked by the filtered solid which subsequently decomposed at an extremely fast rate.