• The Optical Journal
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• s.101
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• pp.50-52
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• 2006

광주공업고등학교 광정보기술과는 국내 실업계 고등학교에서는 유일하게 특성화학과로 개편하여 교육청 지원 하에 광기능인력을 양성하고 있는 곳이다. 이곳에서는 정밀광학·광전자·광통신 등 크게 3가지 분야에 대한 특화교육을 통해 국내에서 유일하게 광학기능사와 통신선로기능사를 배출하고 있다. 또한 학교 창업동아리 활동을 통해 광케이블 송수신장비를 연결하는 광점프코드를 창업아이템으로 삼아 조만간 사업자등록을 내고 본격 사업화에도 학교가 직접나서는‘학교기업’을 추진하는 등 활발한 활동으로 주목을 받고 있다.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.138-143
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• 2011

To investigate the electromagnetic interference shielding efficiency (EMI SE) property based on heat treatment effects of carbon fibers in various temperatures, the polyacrilonitrle-based carbon fibers were prepared by electrospinning method and treated at 1073, 1323, 1873 and 2573 K. The surface morphology of carbon fibers was investigated by using FE-SEM and the carbon crystallization was studied by Raman spectroscopy based on effects of reaction temperatures. The electrical conductivity was obtained by measuring the surface resistance with four probe method on carbon crystallization. The permittivity, permeability and EMI SE were investigated by using S-parameter in the range of 800~4500 MHz. In case of carbon fibers treated at 2573 K, the improved carbon crystallization was confirmed by Raman spectrum and the enhanced electrical conductivity showing 54.7 S/cm was also observed. The permittivity was dramatically improved by factor of 4 based on effect of high reaction temperature. Eventually, the highly improved EMI SE value was obtained showing around 41.7 dB.

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.1-8
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• 1996

The component analysis of wax for detecting temperature in automobile thermostat of the automotive engine and manufacture of it with distillation and solvent extraction were progressed. From the lift test results of prepared samples, it was found that the solvent extracted samples were in the proper range for use as an automobile thermostat of the automotive engine. And more accurate wax could be manufactured by high vacuum fractional distillation and acid treatment after solvent extraction from crude oil pitch.

• Prospectives of Industrial Chemistry
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• v.22 no.4
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• pp.13-19
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• 2019

최근 가공할만한 성능의 슈퍼컴퓨터에 머신 러닝 기법을 연동한 인공 지능형 소재 정보학이 과학 기술 및 산업계에 새로운 연구개발 패러다임으로 급속히 확산되고 있다. 본 기고문에서는 이 기법의 성공에 핵심적 요소인 정확한 데이터베이스 구축을 위해 제일원리 전산을 적용하는 것과 이를 기반으로 소재를 구성하는 원소 간 인공 신경망 포텐셜을 만드는 방법을 소개하고자 한다. 이 연구 방법론은 나노 스케일 신소재 개발에 적용할 경우, 양자역학 수준의 정밀도로 순수 제일원리 전산 대비 100배 이상의 빠른 결과를 도출할 가능성이 있음을 예시한다. 이는 향후 다양한 산업계에 막대한 파급효과를 가져올 것으로 예상된다.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.473-480
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• 1996

Synthesis of n-perfluorooctanesulfonyl fluoride(n-PFOSF), which is valuable precursor perfluoro-chemicals, was studied by electrochemical fluorination(ECF). Of prime concern was to investigate the cyclic voltamograms of Ni electrode in anhydrous hydrogen fluoride(AHF) with and without the reactants and to measure fluorine evolution potential. In a batch cell, chronoampherometric electrolysis and various chemical analysis such as GC, GC/MS and IR were used to understand the amphere change of electrode and the reaction paths. Fluorine equilibrium potential was found to be about 2.8V(vs. $Cu/CuF_2$) from the cyclic voltammograms and decay curves of anode potential in AHF. In batch processes, the ECF proceeded in two distinguished steps. The first step proceeded electrochemically and the second one chemically. Under 7V(vs. $Cu/CuF_2$), amount of crude products was proportional to the applied anode potential. Above 7V(vs. $Cu/CuF_2$), it had a hundred percentage with weight ratio of reactants and productivity of PFOSF was almost constant.

• Journal of the KSME
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• v.19 no.4
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• pp.273-278
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• 1979

화학적 가공이란 화학적 절식이라고 말할 수 있는 방법으로서 주조 또는 공작기계에 의한 절삭 가공대신에 약품에 의한 용해작용을 이용해서 성형품을 만드는 방법이라 할 수 있다. 이 방법은 금속자의 눈금의 조각이나 프라스틱 제품에 눈금을 넣는 금형등에 이용되고 있다. 이는 원래 항공기공업방면에서 중용되어 개발된 기계가공에 대응하는 방법이다. 크기나 정밀도에 있어서 주조(die casting)가 부적당한 경우 혹은 모양이나 능률에 있어서 기계절삭에 의하는 것이 부적 당한 경우에는 이 방법이 이용된다. 최근에 와서는 항공기기계제작 분야에 있어서의 알루미늄의 표면가공뿐만 아니라, 자동차, 건축부분의 구조부품의 성형분야에도 진출하는 경향이 있으며 가 공대상금속도 실용금속일반에 걸쳐 확대되어 감으로써 가장 용도가 넓은 철강류에 확대되어 감 으로써 가장 용도가 넓은 철강류에 까지도 응용되어 가는 실정이다. 이와 같이 종래의 기계적인 수단이 유일한 방법이라고 생각되었던 금속가공분야에 있어서 이러한 화학적 가공법이 도입되 었다는 것은 십분주목할만 한 가치가 있다. 이 화학적 가공법의 특징을 종래의 기계가공법과 비교하면 다음과 같다. (1) 피가공판의 크기는 이를 수용하는 가공조의 용량에 따라 제한될뿐이며 어떠한 대형 물이라도 가공 가능하다. (2) 가공모양은 자유롭게 설계할 수 있고 더욱이 1매 금속 판에서 1공정으로서 복잡한 모양으로 성형할 수 있다. (3) 따라서 이작업에서는 리벳팅, 용접등의 부대작업을 필요로 하지 않는다. (4) 그 가공면은 일반으로 평활하고 마루리 연마공정을 생략할 수 있다. (5) 가공조작이 간편하여 특별한 숙련을 요하지 않고 설비도 가공조의에는 별로 고가의 기기류가 필요치 않다. (6) 이상과 같은 이유에서 본법의 가공비는 기계가공에 비해서 일반적으로 저렴하다. Symposium보고및 전문서가 많이 있으나 여기에는 중요한 몇가지만 소개한다.

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.21-25
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• 2011

In this study, anatase/brookite hybrid $TiO_2$ was prepared using different acid catalysts and microwave to improve photodegradation of organic pollutants. The methylene blue photodegradation properties of the prepared photocatalysts with different particle/crystal size and brookite fractions were investigated. Surface characteristics and particle sizes of anatase/brookite hybrid $TiO_2$ were evaluated using scanning electron microscopy (SEM) and laser diffraction particle size analyzer, respectively and crystal structures were investigated with X-ray diffraction (XRD). Methylene blue photodegradation properties were evaluated with UV-vis spectrophotometer. Anatase and anatase/brookite hybrid $TiO_2$ had less than 500 nm size of clusters and the average particle size of $6.66{\sim}6.85{\mu}m$, suggesting that types of acid catalysts did not affect the size. XRD of the prepared $TiO_2$ showed that the photocatalysts had anatase/brookite hybrid crystal structure and applying microwave did not change their crystal structure. Photodegradation of methylene blue with the prepared photocatalyst did not increased proportionally to the fraction of brookite and the crystal size and decreased when brookite fraction and the crystal size increased further. Anatase/brookite hybrid $TiO_2$ with brookite fraction of 9.4% and crystal size of 4.53 nm shows the best photodegradation activity of methylene blue.

• Applied Chemistry for Engineering
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• v.30 no.4
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• pp.509-511
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• 2019

Hydrazine derivatives used in fine chemicals, pharmaceuticals and cosmetics can be synthesized by reduction reaction from diazonium derivatives. The reduction method using $SnCl_2$ facilitates the reaction conversion, but the use of $SnCl_2$ is limited when residual heavy metals are issued in the final product. For the conversion of protected (2-hydroxyphenyl)diazonium derivatives into its hydrazine derivatives in Ramalin preparation process, the reduction method was developed by using $NaHSO_3$. In this study, the effect of steric hindrance according to the protected 2-hydroxygroupinphenyldiazonium derivatives was found, and linear C1~C5 alkyl groups for the hydroxy protection were preferable during the diazonium reduction reaction. Considering the economical efficiency and industrial production for the preparation of Ramalin, a variety of protecting groups were investigated. As a result, 2-(allyloxyphenyl)hydrazine was obtained with 85% yield and 99.7% purity when the hydroxy protecting group was used as an allyl group that could be easily deprotected.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.258-266
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• 2020

The chemical fixation of CO₂ into cyclic carbonates is considered to be one of the most promising way to alleviate global warming and produce fine chemicals. In this work, the catalytic applicability of metal-organic frameworks (MOFs) as porous crystalline materials for the synthesis of five-membered cyclic carbonate from CO₂ and epoxides was reviewed. In addition, we have briefly classified the materials based on their different structural features and compositions. The studies revealed that MOFs exhibited good catalytic performance towards cyclic carbonate synthesis because of the synergistic effect between the acid sites of MOFs and nucleophile. Moreover, the effect of structure of designed MOFs and mechanism for the cycloaddition of CO₂ were suggested.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.467-472
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• 2011

This study investigated illite/polypropylene (PP) composite filament formation via melt-spinning and evaluated their physical properties to prepare functional fibers using natural materials. When composite filaments were formed, the composite filaments exhibited smaller fiber diameters compared to that of neat PP filament because of the lubricant effect of illite induced by its layered structure. Moreover, fluorination effect increased interfacial affinity and dispersion in the polymer, resulting in smaller diameter of fluorinated illite/PP composite filament, which was 2/3 of the neat PP filament diameter. Addition of raw and fluorinated illite improved thermal stability of illite/PP composite filament. Raw illite/PP composite filament cannot be used for a practical application, because it broke during drawing process, whereas the fluorinated illite/PP composite filament can be used for a practical application, because it exhibited similar tensile strength of the neat PP filament and 50% increased modulus. Even with improved illite/PP interfacial affinity and illite dispersion in the polymer, illite/PP composite filament formed microcomposite, because non-expandable illite had strongly bound layers, resulting in only a little illite exfoliation and PP intercalation into illite.