• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.11-11
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• 2021

2018년부터 삼척지역에는 전파강수관측소(X-band 이중편파레이더)가 설치되어 현업 운영 중에 있다. 해당 지역은 영동지역은 산지로 둘러싸여 있어 지형적인 여건으로 지상강우관측망과 기존 대형 강우레이더로도 정확한 강우관측에 한계가 있었다. 설치 이후 전파강수관측소의 품질관리와 최적 관측전략 수립, 분포형 비차등위상차 기반의 강우추정 기법의 적용으로 정량적 추정강우의 정확도가 확보되어 75m의 고해상도 격자강우 정보가 제공되고 있다. 본 연구에서는 이러한 전파강수관측소의 정량적 추정강우를 홍수예보에 활용하기 위해서 강우기반의 하천 수위 예측 기법인 하천흐름계산도표를 개발하였다. 하천흐름계산도표가 개발된 지역은 삼척 전파강수관측소의 관측 반경에 포함되는 삼척오십천 유역이며, 해당지역은 수변공원으로 조성되어 있어 시민의 접근이 용이하여 하천 수위 급상승으로 인해 피해가능성이 높은 지역이다. 2019년과 2020년 호우사례를 대상으로 개발된 하천흐름계산도표에 전파강수관측소의 정량적 추정강우를 적용하여 하천수위 상승 예측성을 평가하였다. 또한 비교대상으로 강우관측소 강우자료와 환경부 대형 강우레이더 강우자료의 적용결과를 함께 비교하였다. 비차등 위상차 기반의 강우추정 기법을 적용하여 산정된 삼척 전파강수관측소의 정량강우는 기존의 강우추정 결과(SRI, CMP_HFC)보다 강우추정 정확도가 향상된 것을 확인하였다. 특히, 10km 관측 반경을 기준으로 분석하면 정확도가 상대적으로 높았다. 삼척 전파강수관측소 추정강우를 하천흐름 계산도표에 적용한 결과, 2020년 9월 7일 호우에 의해 삼척오십천 유역에서 관심수위 초과(10:20), 주의수위 초과(11:20)가 발생하였는데, 삼척 전파강수관측소 추정강우가 관심수위 초과 1시간 50분 전에 수위상승을 예측하였고, 주의수위 초과 30분전에 수위상승을 예측하였다. 이를 통해 개발된 하천흐름계산도표와 삼척 전파강수관측소의 홍수예보 활용 가능성을 확인하였다.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.63-63
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• 2022

기상 예보자료는 발생 가능한 재난의 예방 및 대비 차원에서 매우 중요한 자료로 활용되고 있다. 우리나라 기상청에서는 동네예보를 통해 5km 공간해상도의 1시간 간격 초단기예보와, 6시간 간격 정량강우예보(Quantitative Precipitation Forecast, QPF)의 단기예보 정보를 제공하고 있다. 그러나 이와 같은 예보자료는 강우량의 시·공간변화가 큰 집중호우와 같은 기상자료를 활용한 수문학적인 해석에는 한계가 있다. 예보자료를 수문학에 활용하기 위한 시·공간적 해상도 개선뿐만 아니라 방대한 기상 및 기후 자료의 예측성능을 개선하기 위한 다양한 연구가 진행되고 있다. 본 연구에서는 기상청이 제공하는 지역 앙상블 예측 시스템(Local ENsemble prediction System, LENS)와 종관기상관측시스템(ASOS) 및 방재기상관측시스템(AWS) 관측 데이터 및 동네예보에 기계학습 방법을 적용하여 수문학적 정량적 강수량 예측(Hydrological Quantitative Precipitation Forecast, HQPF) 정보를 생산하였다. 전처리 과정을 통해 모든 데이터의 시간해상도와 공간해상도를 동일한 해상도로 변환하였으며, 예측 변수의 인자 분석을 통해 기계학습의 예측 변수를 도출하였다. 기계학습 방법으로는 처리속도와 확장성을 고려하여 XGBoost(eXtreme Gradient Boosting) 방식을 적용하였으며, 집중호우에서의 예측정확도를 높이기 위해 확률매칭(PM) 방식을 적용하였다. 생산된 HQPF의 성능을 평가하기 위해 2020년에 발생한 14건의 호우 사상을 대상으로 태풍형과 비태풍형으로 구분하여 검증을 수행하였다.

• Journal of the Korean Society of Food Science and Nutrition
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• v.46 no.3
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• pp.358-367
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• 2017

Preservatives, as food additives, are occasionally intrinsic to natural raw materials or sometimes generated during the fermentation process as reported in many research articles. Preservative compounds in raw food materials may persist in the final food product, which is not supposed to include such preservative compounds. In this study, we validated an analytical method for preservative compounds in raw materials of functional foods. Quantification of benzoic acid and sorbic acid was determined using HPLC-PDA analysis after distillation, whereas propionic acid was quantified with GC-FID. A significant set of validation data (accuracy, precision, linearity, recovery, etc) was acquired. A total of 212 samples were collected for analysis of naturally occurred preservatives, and preservatives were detected in 85 samples. Most of the detected samples showed less 10 mg/kg of preservatives. The results of this study provide fundamental data on naturally occurring preservatives in raw materials of functional foods. Moreover, building up a database of naturally occurring preservatives could solve problems in the current scientific data.

• Journal of Food Hygiene and Safety
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• v.33 no.4
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• pp.296-305
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• 2018

Spiroxamine, one of fungicides, is used to control powdery mildew in various crops and black yellow sigatoka in bananas. The major strength of spiroxamine is to control powdery mildew in various crops and bananas yellow sigatoka in bananas. The compound has shown a high level of activity, good persistence and crop tolerance. Besides powdery mildew, good control of rust, net blotch and Rhynchosporium diseases been indicated in cereals, together with a complementary activity against Septoria diseases. In 2017, the maximum residue limit (MRL) of spiroxamine established in Korea. According to Ministry of ood and rug afety) regulations, spiroxamine residues defined only parent compound. Thus, a analytical method is needed to estimate the residue level of the parent compound. The objective of this study was to develop and validate analytical method for spiroxamine in representative agricultural commodities. Samples were extracted with acetonitrile and partitioned with dichloromethane to remove the interfering substances. The analyte were quantified and confirmed liquid chromatograph-tandem mass spectrometer (LC-MS/MS) in positive-ion mode using multiple reaction monitoring (MRM). Matrix matched calibration curves were linear over the calibration ranges ($0.0005{\sim}0.1{\mu}g/mL$) for the analyte in blank extract with coefficient of determination ($r^2$) > 0.99. For validation purposes, recovery studies will be carried out at three different concentration levels (LOQ, 10LOQ, and 50LOQ) performing five replicates at each level. The recoveries 70.6~104.6% with relative standard deviations (RSDs) less than 10%. All values were consistent with the criteria ranges in the Codex guidelines (CAC/GL40, 2003) and MFDS guidelines. proposed analytical method be used as an official analytical method in the Republic of Korea.

• Journal of Food Hygiene and Safety
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• v.33 no.4
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• pp.266-271
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• 2018

The Ministry of Food and Drug Safety (MFDS) is amending its test methods for health-functional foods (dietary food supplements) to establish regulatory standards and specifications in Korea. In this regard, we continue our research on developing analytical methods for the items. Octacosanol is the major component of polycosanol and is a high-molecular-mass primary fatty alcohol, obtained from sugar cane wax. Previous researchers have shown that octacosanol can lower cholesterol and has antiaggregatory properties, cytoprotective uses, and ergogenic properties for human health. Recently, octacosanol products have been actively introduced into the domestic market because of their functional biological activity. We have developed a sensitive and selective test method for octacosanol that the TMS derivatives by means of gas-chromatographic-tandem mass spectrometry (GC-MS). The trimethylsilyl ether derivative of the target analyte showed excellent chromatographic properties. The procedure was validated in the range of $12.5{\sim}200{\mu}g/L$. Standard calibration curves presented linearity with the correlation coefficient ($r^2$) > 0.999, and the limits of detection (LOD) and limits of quantitation (LOQ) were $4.5{\mu}g/L$ and $13.8{\mu}g/L$, respectively. The high recoveries (92.5 to 108.8%) and precision (1.8 to 2.4%) obtained are in accordance with the established validation criteria. Our research can provide scientific evidence to amend the octacosanol test method for the Health-Functional Food Code.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.269-277
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• 2014

The multiclass pesticide multiresidue method for the simultaneous determination of diflubenzuron in agricultural products was conducted by using HPLC-UVD. The method was validated through the guidelines of linearity, specificity, limit of detection (LOD), limit of quantification (LOQ), accuracy and precision with pesticide-free spinach, Korean cabbage, eggplant, squash, sweet pepper, cucumber, Korean melon. The calibration curve of diflubenzuron was linear over the concentration range of 0.05-5 mg/kg with correlation coefficient of above 0.99999. The limit of detection and quantification was 0.008 and 0.02 mg/kg. Mean recoveries of diflubenzuron for each sample were 77.5-105.6%. Relative standard deviation (RSD) in recoveries were all less than 20%. The intra-day and inter-day precision (RSD) were 0.4-1.9% and 0.7-1.9%, respectively. The result of validation indicated that this method was accurate and rapid assay.

• The Korean Journal of Pesticide Science
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• v.20 no.2
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• pp.93-103
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• 2016

A simultaneous analytical method was developed for the determination of isoxaflutole and metabolite (diketonitrile) in agricultural commodities. Samples were extracted with 0.1% acetic acid in water/acetonitrile (2/8, v/v) and partitioned with dichloromethane to remove the interference obtained from sample extracts, adjusting pH to 2 by 1 N hydrochloric acid. The analytes were quantified and confirmed via liquid chromatograph-tandem mass spectrometer (LC-MS/MS) in positive-ion mode using multiple reaction monitoring (MRM). Matrix matched calibration curves were linear over the calibration ranges ($0.02-2.0{\mu}g/mL$) for all the analytes into blank extract with $r^2$ > 0.997. For validation purposes, recovery studies were carried out at three different concentration levels (LOQ, 10LOQ, and 50LOQ) performing five replicates at each level. The recoveries were ranged between 72.9 to 107.3%, with relative standard deviations (RSDs) less than 10% for all analytes. All values were consistent with the criteria ranges requested in the Codex guideline (CAC/GL40, 2003). Furthermore, inter-laboratory study was conducted to validate the method. The proposed analytical method was accurate, effective, and sensitive for isoxaflutole and diketonitrile determination in agricultural commodities.

• The Korean Journal of Food And Nutrition
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• v.29 no.4
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• pp.474-479
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• 2016

This study aimed to investigate the concentration of vitamin C in Momordica charantia (MC) by cultivar, harvest time, and maturity. The methods for determining vitamin C levels were validated by measuring their linearity, specificity, limit of detection (LOD), limit of quantification (LOQ), precision, and accuracy using HPLC. Results showed high linearity in the calibration curve, with a coefficient of correlation ($R^2$) of 0.9994. The LOD and LOQ values for vitamin C were 0.05 and $0.16{\mu}g/mL$, respectively. The relative standard deviations (RSDs) for intra- and inter-day precision of vitamin C measurements were 2.34 and 1.34%, respectively. Depending on cultivar, the concentration of vitamin C in MC varied from 20.75~107.31 mg/100 g, fresh weight, with an average level $68.85{\pm}25.57mg/100g$, FW. When MC was analyzed by harvest time, the 20150612 MC showed the highest amount of vitamin C ($113.20{\pm}1.89mg/100g$, FW). On the other hand, the highest vitamin C content by maturity was $48.59{\pm}0.87mg/100g$, FW (15 day old MC). This information on the comparative vitamin C levels of MC might be useful to food scientists and should be explored for functional food development.

• Journal of the Korean Society of Food Science and Nutrition
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• v.43 no.6
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• pp.955-961
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• 2014

This study was carried out to investigate the amounts of vitamin C in 22 sweet potato cultivars cultivated in Korea as well as evaluate the effects of cooking methods on vitamin C contents. Methods for determining vitamin C was validated by determining linearity, specificity, limit of detection (LOD), limit of quantification (LOQ), precision, and accuracy using HPLC. Results showed high linearity in the calibration curve with a coefficient of correlation ($R^2$) of 0.9999. The LOD and LOQ values for ascorbic acid (AA) were 0.03 and $0.10{\mu}g/mL$, respectively. The relative standard deviations (RSDs) for intra- and inter-day precision of AA were less than 5%. The recovery rates of AA and dehydroascorbic acid (DHA) were in the range from 98.21~98.64 and 98.28~100.68%, respectively. Depending on cultivar, contents of AA, DHA, and total ascorbic acid (TA) in sweet potatoes varied in the range from 37.76 (Sinyulmi)~89.25 (Juhwangmin), 23.37 (Sinjami)~63.94 (Sinyulmi), and 68.52 (Sinjami)~115.95 (Juhwangmin) mg/100 g, respectively, and their average levels were $56.98{\pm}12.53$, $36.46{\pm}9.03$, and $93.44{\pm}12.00mg/100g$, respectively. The average TA levels were also dependent on flesh color, whish was significantly higher in general sweet potato and orange sweet potato than in purple sweet potato. Steaming, baking, and frying processes significantly reduced AA (10.61~58.41%), DHA (2.57~52.81%), and TA (14.54~49.92%) contents in sweet potatoes. The highest reduction of AA, DHA, and TA contents was observed after baking, followed by steaming and frying. We expect that the basic information provided by this study will be useful to plant breeders and food scientists.

• Korean Journal of Food Science and Technology
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• v.45 no.3
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• pp.376-381
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• 2013

In this study, we monitored total mercury and methylmercury concentrations in tuna, billfish, and deep-sea fish distributed in Seoul city. With the acquired data, we carried out statistical analysis and an exposure assessment for intake. The mean concentrations (mg/kg) of total mercury and methylmercury were $0.32{\pm}0.31/0.20{\pm}0.20$ for tuna, $0.43{\pm}0.48/0.20{\pm}0.17$ for patagonian toothfish, $0.99{\pm}0.72/0.51{\pm}0.40$ for billfish and $1.20{\pm}0.70/0.95{\pm}0.51$ for sharks, respectively. We found that sharks, billfish, patagonian toothfish, and tuna were more contaminated with total mercury and methylmercury, in sequence, and that 66% of the total mercury concentration consisted of methylmercury, on average. Although the estimated weekly intakes of methylmercury from commercial deep-sea fish were lower than the weekly intakes recommended by the Joint FAO/WHO Expert Committee on Food Additives (JECFA), we identified that the total mercury and methylmercury concentrations in tuna, billfish, and deep-sea fish continued to increase with the passage of time. Therefore, we confirmed the necessity of continuous monitoring and comprehensive analysis for general safety.