• Title/Summary/Keyword: 접촉 각

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이온 보조 반응법(Ion Assisted Reaction)으로 처리된 Polypropylene과 Conducting polymer의 접착력 향상

  • Lee, Chul-Soo;Cho, Jung;Choi, Sung-Chang;Joo, Jin-Su;Ko, Seok-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.201-201
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    • 1999
  • 소수성의 특성을 가지는^g , pp (polypropylene)의 표면을 이온 보조 반응법(IAR)으로 처리하여 친수성으로 개질하였다. 이온빔 보조 반응법은 고에너지 이온빔을 이용한 기존의 표면처리 방식과는 달리 1keV 영역의 에너지를 가진 이온빔을 조사하면서 시료 주위에 반응성 가스를 불어넣어 줌으로써 표면의 성질을 변화시키는 방법이다. 여기서 조사된 수소이온의 에너지는 0.6에서 1.0keV까지 변화시키고 시료의 주변에 불어주는 산소의 양은 0에서 8ml/min으로 변화시켰으며 이온 조사량은 5x1014에서 1x1017ions/$\textrm{cm}^2$까지 변화시켰다. 그 결과 처리하지 않은 시료의 접촉각은 93$^{\circ}$이었으며 이온조사량이 1x1017ions/$\textrm{cm}^2$이고 가속에너지가 1.0keV인 조건에서 수소 이온빔만으로 처리한 시편의 경우 접촉각은 60$^{\circ}$정도 였으나 수소이온보조 반응법으로 처리한 시편의 경우는 $10^{\circ}$이하까지 접촉각이 감소하였음을 알 수 있었다. 이는 표면처리에 따른 표면의 친수성 작용기의 형성을 예상할 수 있으며 그 존잴르 확인하기 위하여 대기중과 물속에서 각각 보관한 시료의 접촉각과 표면에너지를 계산하여보았다. 그 결과 대기중에서 방치한 시편의 경우40$^{\circ}$ 정도로 감소하였으나 증류수에 보관한 시료의 경우는 15$^{\circ}$정도의 변화를 보였다. 물과 Formamide의 접촉각의 측정으로 표면에너지를 계산한 결과 산소분위기에서 수소이온빔으로 처리된 시료는 23dyne/cm에서 64dyne/cm이상까지 변화함을 관찰하였다. 위의 결과들이 표면거칠기에 미치는 영향을 고찰하기 위해 처리되지 않은^g , pp 의 근(root mean square)값은 8.30nm이었고 1kevdpsj지에서 불어준 산소4ml/min이고 이온 조사량이 1x1017ions/$\textrm{cm}^2$인 경우 접촉각은 $10^{\circ}$를 나타냈으며 rms값은 20.8nm를 나타내었다. XPS (X-ray photoelectron spectroscopy) 분석을 통하여 1x1017ions/$\textrm{cm}^2$에서 산소기체를 4ml/min 불어넣어준 후 C-O, C=O, (C=O)-O등의 친수성 작용기가 형성되었음을 확인하였다.^g , pp 의 접착력을 알아보기 위해 유성 페인트를 전도성 고분자위에 후막 처리하였다. 스카치 테이프를 테스트를 통하여 이온 보조 반응법으로 처리된^g , pp 표면이 처리하지 않은 시편에 비하여 접착력 향상되었음을 확인하였다.

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Shear behavior at the interface between particle and non-crushing surface by using PFC (PFC를 이용한 입자와 비파쇄 평면과의 접촉면에서의 전단 거동)

  • Kim, Eun-Kyung;Lee, Jeong-Hark;Lee, Seok-Won
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.14 no.4
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    • pp.293-308
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    • 2012
  • The shear behavior at the particle/surface interface such as rock joint can determine the mechanical behavior of whole structure. Therefore, a fundamental understanding of the mechanisms governing its behavior and accurately estimation of the interface strength is essential. In this paper, PFC, a numerical analysis program of discrete element method was used to investigate the effects of the surface roughness on interface strength. The surface roughness was characterized by smooth, intermediate, and rough surface, respectively. In order to investigate the effects of particle shape and crushing on particle/surface interface behavior, one ball, clump, and cluster models were created and their results were compared. The shape of particle was characterized by circle, triangle, square, and rectangle, respectively. The results showed that as the surface roughness increases, interface strength and friction angle increase and the void ratio increases. The one ball model with smooth surface shows lower interface strength and friction angle than the clump model with irregular surface. In addition, a cluster model has less interface strength and friction angle than the clump model. The failure envelope of the cluster model shows non-linear characteristic. From these findings, it is verified that the surface roughness and particle shape effect on the particle/surface interface shear behavior.

Evaluation of Interface Friction Properties between Coarse Grained Materials and Geosynthetics (조립재료와 지오신세틱스의 접촉면 마찰특성 평가)

  • Chang, Yongchai;Lee, Seungeun;Seo, Jiwoong
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.5
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    • pp.53-59
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    • 2008
  • The purpose of the study was to evaluate how much gastropod shell effected its properties better than crushed stone as coarse grained materials by comparing friction properties of a contact surface between coarse grained materials and geosynthetics with the large-scale direct shear test. To achieve the purpose, the study compared and analyzed friction coefficient and friction angle by making crushed stone or gastropod shell into model ground and by installing and shearing non-woven fabric or geostrip geosynthetics. As the results of the analysis, crushed stone had the internal friction angle of $33.8^{\circ}$ when its unit weight was $13.7kN/m^3$ and gastropod shell had the internal friction angle of $35.4^{\circ}$ when its unit weight was $5.4kN/m^3$. Also, the friction angle of a contact surface between geosynthetics and crushed stone was larger than the friction angle of a contact surface between geosynthetics and gastropod shell.

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NUMERICAL ANALYSIS OF DYNAMIC CONTACT ANGLE PROBLEMS IN ELECTROWETTING WITH LEVEL SET METHOD (레벨셋 기법을 이용한 전기습윤 현상의 동적 접촉각 문제에 대한 수치해석)

  • Park, J.K.;Kang, K.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2009.04a
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    • pp.155-158
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    • 2009
  • We developed a numerical method to analyze the contact-line problems, incorporating a dynamic contact angle model. We used level set method to capture free surface. The method is applied to the analysis of dynamic behavior of a droplet in DC electrowetting. The result is compared with an experimental data and result of perturbation method.

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A Study on Dynamic Modeling and Analysis of a Wheelset (휠셋의 동역학 모델링 및 해석에 관한 연구)

  • Kang, Ju-Seok
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.1851-1855
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    • 2011
  • The accuracy of wheel-rail contact analysis is mainly determined by the methods to find wheel-rail contact points and to calculate contact forces. The 2-dimensional approach which calculates contact points based on the profile curves of the wheel and rail has advantage of reducing calculation time but shortage of approximating the solutions when comparing with 3-dimensional analysis In this analysis, wheelset dynamic behaviors calculated by the approach based on the 2-dimensional wheel-rail curves are compared with those by the 3-dimensional wheel-rail surfaces. Yaw angle and lateral displacement of wheelset center are compared when negotiating a curve.

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Electrowetting on Hydrophobic Silica Layers (소수성 실리카 코팅층에서의 전기습윤)

  • Kim, Ji-Yeong;Kim, Sang-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.96-96
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    • 2013
  • 전기습윤이란 고체 표면에 형성된 액적에 전기장을 인가하게 되면 액적과 표면의 계면에너지 감소로 인해 접촉각이 변화되는 현상을 말한다. 이 현상은 전자종이 구현에 응용이 모색되고 있으며, 다초점 렌즈, 마이크로 프리즘, 반사형 디스플레이 등에도 응용될 수 있다. 전기습윤현상의 응용 가능성이 현실화됨에 따라 최근 여러 표면에서의 전기습윤 현상이 연구되고 있다. 예를 들면, 나노 구조로 형성된 실리콘 기판에서 molten salt (1-ethyl-3-methyl-1-H-imidazolium tetrafluoroborate)에 22 V를 인가하면 약 $180^{\circ}$에서 $110^{\circ}$로 접촉각변화를, cyclopentanol에 50 V를 인가하면 표면에 완전히 퍼지는 현상이 보고된 바 있고, 배열된 Carbon Nanotube 박막에서는 탈이온수와 0.03 M NaCl 용액에 대해서 0~50 V를 가해줌에 따라 각각 $155^{\circ}$에서 $90^{\circ}$, $130^{\circ}$에서 $50^{\circ}$로의 접촉갑 변화가 있음이 관찰되었다. 본 연구에서는 화학적으로 안정하고 그 활용도가 매우 광범위한 실리카 코팅층을 전기분무증착법(electrospray deposition)을 이용해 형성하고, 코팅층의 표면 거칠기와 구조, 전기절연층의 두께 등에 따른 전기습윤 현상 거동을 조사하였다.

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The evaluation of water repellent effectiveness of natural oil treated wood (천연유지류 처리재의 발수성능 평가)

  • 이동흡;오형민;강창호;손동원;김종인
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.34-42
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    • 2002
  • This research was carried out to investigate water repellent effectiveness of natural oil treated wood. Linseed oil, castor oil, olive oil, bean oil, perilla oil and sunflower oil were used in this test. For evaluation of water repellent of natural oil treated wood, moisture absorption test, water-drop contact angle test and color difference test of accelerated decomposition by UV and water were used. The moisture absorption amount of natural oil treated wood was less than untreated wood until 3 hours, but it was increased with time, there was no big difference with oil treated wood and untreated wood after 48hours. Oil treated wood and untreated wood showed big difference on contact angle test. It was no big difference by kind and oil concentration. Natural oil treated wood did not showed stability on the weather aging test. Contact angle test could be used on evaluation of wood surface status treated with natural oil.

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The analysis of surface degradation on polymer material by contact angle properties (접촉각 특성을 이용한 고분자복합재료의 표면열화 해석)

  • Park, Jong-Kwan
    • Journal of the Institute of Electronics Engineers of Korea TE
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    • v.39 no.3
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    • pp.8-14
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    • 2002
  • UV, heat, and discharge treatments are arbitrary simulated for finding out the initiations and processes of surface degradation on the polymer surface. Especially, this study is focused on the inter-relation between chemical changes and electrical properties. In contact angle to measure the change of activated degree, that of polymers surface shows a slight hydrophobicity of 73$^{\circ}$~91$^{\circ}$. But, discharge treatment and UV treatment of 300 nm wavelength changed it to the hydrophilic one with the decrease of contact angle, 13.8$^{\circ}$ and 20$^{\circ}$ respectively. Thermal-treatment and UV treatment of 430~500 nm wavelength changed the surface to the hydrophobic one with the increase of contact angle, 90$^{\circ}$ and 80.1$^{\circ}$ respectively.  

Interface shear strength between Crushed Stone and Geotextile (쇄석-지오텍스타일간의 접촉면 전단강도 산정)

  • Lee, Seok-Won;Youn, Choo-Moon;An, Hyun-Ho;Seo, Byoung-Wook
    • Journal of the Korean Geosynthetics Society
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    • v.5 no.1
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    • pp.33-38
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    • 2006
  • Large-scale direct shear tests were conducted in order to evaluate both the shear strength of crushed stone itself and the interface shear strength between crushed stone and geotextile. Total three types of geotextile (i.e. one woven geotextile and two nonwoven geotextiles) were used in the experimental program, considering two different values for the unit weight of crushed stone. Total fifteen tests were conducted in this study. It has been found from the experimental results that the friction angles of crushed stone itself were $47^{\circ}$ and $57^{\circ}$ under the unit weights of crushed stone being $1.4t/m^3$ and $1.5t/m^3$, respectively. Interface friction angle between nonwoven geotextile and crushed stone showed $39^{\circ}$ for type A indicating an efficiency of 83% and $42^{\circ}$ for type B indicating an efficiency of 89%. Similarly, interface friction angle between woven geotextile and crushed stone showed $39^{\circ}$ indicating an efficiency of 83%.

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Adhesion improvement between metals and fluoropolymers by ion assisted reaction (이온보조반응에 의한 금속과 불소계 고분자의 접착력 증진)

  • Han, Sung;Cho, Jun-Sik;Choi, Sung-Chang;Yoon, Ki-Hyun;Koh, Seok-Keun
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.37-43
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    • 2001
  • Polyvinylidenefluoride and Polytetrafluoroethylene have been irradiated by 1 keV Ar+ ion beam in an $O_2$ environment. Hydrophilic functional groups (such as -(C-O)-,-(C=O)-,-(C=O)-O- and so on) were formed on fluoropolymers. Contact angles of water to PVDF were reduced from $75^{\circ}$ to $31^{\circ}$. Re-increase of contact angle was originated from carbonization phase in case of high dose irradiation above $1{\times}10^{16} Ar^+cm^2$. Contact angles to PTFE decreased at low dose irradiation and were exaggerated to about $140^{\circ}$ due to cone type surface at high dose irradiation. Hydrophilic functional groups have played an important role on adhesion between metal and fluoropolymers by acid-base interaction and chemical bond formation. Adhesion of Pt/PVDF was enhanced by acid-base interaction because Pt is inert metal. Chemical bond formation between Cu and PTFE could enlarge the adhesion strength of Cu/PTFE.

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