• Title/Summary/Keyword: 접촉강도

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Mechanical and Electrical Properties of Electrospun CNT/PVDF Nanofiber for Micro-Actuator (미세-작동기를 위한 전기방사 CNT/PVDF 나노섬유 기반의 탄소 복합재의 기계적 및 전기적 특성 평가)

  • Gu, Ga-Young;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.26 no.1
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    • pp.14-20
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    • 2013
  • The electrospun PVDF containing CNT was made for fabricating materials of the actuator. The electrochemical and their actuating movement were evaluated for the actuator performance in the electrochemical environment. The actuator (which was fabricated by electrospinning) had some advantages, i.e., good dispersion and flexible properties. In the electrospinning process, the final product would have different forms based on different essential factors. In this work, electrospun nanofibers were aligned by using the drum-type collector, and the morphology was identified via the field emission-scanning electron microscope (FE-SEM). The uniform dispersion of CNT in PVDF nanofiber was observed by electron probe X-ray micro-analysis (EPMA) test. The results of tensile strength and electrical resistivity provided the aligned state. The electrospun CNT/PVDF nanofiber sheet on the aligned direction showed better mechanical and electrical properties than the case of the vertically-aligned direction. The efficiency and electrical capacities of electrospun CNT/PVDF nanofiber sheets were compared with the cast PVDF sheet for actuator application. Electrospun CNT/PVDF nanofiber sheet exhibited much better the case of actuator performance than cast neat PVDF actuator, due to the excellent electrical connecting areas.

Preparation and Characterization of the Impregnation to Porous Membranes with PVA/PSSA-MA/THS-PSA for Fuel Cell Applications (연료전지 응용을 위한 다공성막에 가교된 PVA/PSSA-MA/THS-PSA의 함침을 통한 고내구성 이온교환막의 제조 및 특성 연구)

  • Kim, Il-Hyoung;Kim, Sung-Pyo;Lee, Hak-Min;Park, Chan-Jong;Rhim, Ji-Won;Cheong, Seong-Ihl
    • Membrane Journal
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    • v.21 no.3
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    • pp.299-305
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    • 2011
  • This study deals with the preparation of polymeric electrolyte membranes having high durability for the application of fuel cells. The membranes under investigation were prepared the impregnation to porous polyethylene membranes with poly(vinyl alcohol)(PVA), poly(styrene sulfonic acid-co-maleic acid), and (PSSA-MA)3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA). To characterize the resulting membranes, the water contents, the contact angles, FT-IR, the proton conductivity and the the modulus were measured. The proton conductivity of 30% content of THS-PSA at $55^{\circ}C$ gave excellent $1.27{\times}10^{-1}S/cm$ and the mechanical strength was improved 7 times higher up to the THS-PSA content 15%, as a result, the durability was elevated extensively.

Electron Beam-Induced Modification of Poly(dimethyl siloxane) (전자빔을 이용한 Poly(dimethyl siloxane)의 개질)

  • Kang, Dong-Woo;Kuk, In-Seol;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak;Nho, Young-Chang;Mun, Sung-Yong;Lee, Young-Moo
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.157-160
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    • 2011
  • In this paper, poly (dimethyl siloxane) (PDMS) was modified using electron beam irradiation and its property was investigated. PDMS sheets prepared using a conventional thermal curing method were irradiated by electron beams at absorbed doses between 20 and 200 kGy and their properties were characterized using swelling degree and contact angle measurements, universal testing machine (UTM), thermogravimetric analyzer (TGA), and X -ray photoelectron spectrometer (XPS). The results of the swelling degree measurements, UTM, and TGA revealed that the swelling degree of the irradiated PDMS sheets was reduced down to 24% in comparison to the control sheet, and their compression strength and thermal decomposition temperature increased up to maximum 2.5 MFa and $10^{\circ}C$, respectively, due to the increase in crosslinking density by irradiation. In addition, on the basis of the results of contact angle measurements and XPS, the wettability of the PDMS sheets was enhanced up to 24% owing to the generation of hydrophilic functional groups on the PDMS surface by oxidation during electron beam irradiation.

Finite Element Analysis of Reinforced Concrete Masonry Infilled Frames with Different Masonry Wall Thickness Subjected to In-plane Loading (채움벽 두께에 따른 철근콘크리트 조적채움벽 골조의 면내하중에 대한 유한요소해석)

  • Kim, Chungman;Yu, Eunjong;Kim, Minjae
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.29 no.1
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    • pp.85-93
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    • 2016
  • In this study, finite element analyses of masonry infilled frames using a general purpose FE program, ABAQUS, were conducted. Analysis models consisted of the bare frame, infilled frames with masonry wall thickness of 0.5B and 1.0B, respectively. The masonry walls were constructed using the concrete bricks which were generally used in Korea as infilled wall. The material properties of frames and masonry for the analysis were obtained from material tests. However, four times increased the tensile strength was used for 1.0B wall, which is seemingly due to the differences in locating the bricks. The force-displacement relation and development of crack from the FE analysis were very similar to those from the experiments. From the FEA results, contact force between the frame and masonry, distribution of shear force and bending moments in frame members were analyzed. Obtained contact stress shows a trianglur distribution, and the contact length for 0.5B speciment and 1.0B specimen were close to the value estimated using ASCE 41-06 equation and ASCE 41-13 equation, respectively. Obtained shear force and bending moment distribution seems to replicate actual behavior which originates from the contact stress and gap between the frame and masonry.

Evaluation of Fiber Arrangement Condition of CF/PP Composites Using Electrical Resistance Measurement and Wettability (전기저항 평가법 및 접촉각을 이용한 CF/PP 복합재료 사출성형품 섬유 배열성 평가)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.17 no.1
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    • pp.15-20
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    • 2016
  • Fiber arrangement was important for fiber reinforced thermoplastic composites using injection fabrication. In this work, fiber arrangement in CF/PP was investigated to use electrical resistance (ER) method during injection times. There were 3 types of injection products of CF/PP with different ER change ratio by fiber arrangement. High ER change ratio case of injection CF/PP products had better increased tensile strength. This reason was due to the fiber arrangement of CF/PP by injection. Fractured surface and contact angle of CF/PP products were used to evaluate for injection product quality. Uniform fiber arrangement of CF/PP by injection type exhibited the uniform heat condition of melted CF/PP. Steady thermal transfer effect occurred from melted CF/PP to steel injection mold. Steady thermal transfer effect of CF/PP was transmitted to high ER change ratio of mold. Ultimately, good condition CF/PP product by injection molding method could be predicted by using ER method.

Nonlinear Lateral Behavior and Cross-Sectional Stress Distribution of Concrete Rocking Columns (콘크리트 회전형 기둥의 비선형 횡방향 거동 및 단면응력 분포 분석)

  • Roh, Hwa-Sung;Hwang, Woong-Ik;Lee, Hu-Seok;Lee, Jong-Seh
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.285-292
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    • 2012
  • Fixed connection is generally used for beam and column connections of concrete structures, but significant damages at the connection due to severe earthquakes have been reported. In order to reduce damages of the connection and improve seismic performance of the connection, several innovative connections have been suggested. One newly proposed connection type allows a rotation of the connection for applications in rotating or rocking beams, columns, and shear walls. Such structural elements would provide a nonlinear lateral force-displacement response since their contact depth developed during rotation is gradually reduced and the stress across the sections of the elements is non-linearly distributed around a contact area, which is called an elastic hinge region in the present study. The purpose of the present study is to define the elastic hinge region or length for the rocking columns, through investigating the cross-sectional stress distribution during their lateral behavior. Performing a finite element analysis (FEA), several parameters are considered including axial load levels (5% and 10% of nominal strength), different boundary conditions (confined-ends and cantilever types), and slenderness ratios (length/depth = 5, 7, 10). The FEA results showed that the elastic hinge length does not directly depend on the parameters considered, but it is governed by a contact depth only. The elastic hinge length started to develop after an opening state and increased non-linearly until a rocking point(pre-rocking). However, the length did not increase any more after the rocking point (post-rocking) and remained as a constant value. Half space model predicting the elastic hinge length is adapted and the results are compared with the numerical results.

Evaluation of Deformation Characteristics and Vulnerable Parts according to Loading on Compound Behavior Connector (복합거동연결체의 하중재하에 따른 변형 특성 및 취약부위 산정)

  • Kim, Ki-Sung;Kim, Dong-wook;Ahn, Jun-hyuk
    • Journal of the Society of Disaster Information
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    • v.15 no.4
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    • pp.524-530
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    • 2019
  • Purpose: In this paper, we construct a detailed three-dimensional interface element using a three-dimensional analysis program, and evaluate the composite behavior stability of the connector by applying physical properties such as the characteristics of general members and those of reinforced members Method: The analytical model uses solid elements, including non-linear material behavior, to complete the modeling of beam structures, circular flanges, bolting systems, etc. to the same dimensions as the design drawing, with each member assembled into one composite behavior linkage. In order to more effectively control the uniformity and mesh generation of other element type contact surfaces, the partitioning was performed. Modeled with 50 carbon steel materials. Results: It shows the displacement, deformation, and stress state of each load stage by the contact adjoining part, load loading part, fixed end part, and vulnerable anticipated part by member, and after displacement, deformation, The effect of the stress distribution was verified and the validity of the design was verified. Conclusion: Therefore, if the design support of the micro pile is determined based on this result, it is possible to identify the Vulnerable Parts of the composite behavior connector and the degree of reinforcement.

Improvement of Interfacial Adhesion of Plasma Treated Single Carbon Fiber Reinforced CNT-Phenolic Nanocomposites by Electrical Resistance Measurement and Wettability (젖음성 및 전기저항 측정을 이용한 플라즈마 처리된 단일 탄소섬유 강화 탄소나노튜브-페놀수지 나노복합재료의 계면접착력 향상)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Gu, Ga-Young;Park, Jong-Kyoo;Lee, Woo-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.12 no.3
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    • pp.88-93
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    • 2011
  • Optimal dispersion and fabrication conditions of carbon nanotube (CNT) embedded in phenolic resin were determined by electrical resistance measurement; and interfacial property was investigated between plasma treated carbon fiber and CNT-phenolic composites by electro-micromechanical techniques. Wettability of carbon fiber was improved significantly after plasma treatment. Surface energies of carbon fiber and CNT-phenolic nanocomposites were measured using Wilhelmy plate technique. Since surface activation of carbon fiber, the advancing contact angle decreased from $65^{\circ}$ to $28^{\circ}$ after plasma treatment. It was consistent with static contact angle results of carbon fiber. Work of adhesion between plasma treated carbon fiber and CNT-phenolic nanocomposites was higher than that without modification. The interfacial shear strength (IFSS) and apparent modulus also increased with plasma treatment of carbon fiber.

Preparation and Characterization of Silicone Hydrogel Lens Containing Poly(ethylene glycol) (PEG를 포함한 실리콘 수화젤 렌즈의 제조 및 특성)

  • Jang, Ha-Na;Chung, Youn-Bok;Kim, Sung-Soo
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.169-174
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    • 2009
  • Silicone hydrogels incorporated with poly(ethylene glycol)(PEG) were prepared and characterized to evaluate the effects of PEG on contact lenses. The silicone hydrogels were copolymerized with methacryloxypropyl tris(trimethylsiloxy) silane (TRIS), methyl methacrylate (MMA), N,N-dimethyl acrylamide (DMA) and PEG-containing monomers such as poly(ethylene glycol) methyl ether methacrylate (PEG- MEM). The silicone hydrogels were characterized using Fourier transform infrared spectroscopy (FT-IR), electron spectroscopy of chemical analysis (ESCA), and scanning electron microscopy (SEM). Water absorbance, water contact angle and light transmittance of the silicone hydrogels were evaluated. The experiments of protein adsorption were also carried out to evaluate the protein adsorption in tears. The peak intensity of C-O bond was increased by the incorporation of PEG-containing monomers and thus PEG incorporation into silicone hydrogels could be confirmed. Phase separation was not shown by the SEM observation of the cross-section of silicone hydrogels. Water absorbancy was increased, while water contact angle and light transmittance were decreased with increasing incorporation of the PEG-containing monomers. The absorption of proteins in tears, albumin, lysozyme and $\gamma$-globulin, on the surface of silicone hydrogels was decreased with increasing incorporation of the PEG-containing monomers.

Development of High-Durability Ceramic Hollow Fiber and Performance Evaluation of Contact Membrane Process according to Pressure Conditions (고내구성 세라믹 중공사 개발과 압력 조건에 따른 접촉막 공정의 특성 평가)

  • Lee, Seung Hwan;Jeong, Byeong Jun;Shin, Min Chang;Zhuang, Xuelong;Jung, Jiwon;Lee, Yeon Jun;Won, Dongyeon;Park, Jung Hoon
    • Membrane Journal
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    • v.30 no.6
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    • pp.443-449
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    • 2020
  • In this study, CO2 separation experiment was performed on a CH4/CO2 mixed gas using a ceramic hollow fiber membrane contactor module (HFMC). In order to fabricate high-durability HFMC, a high-durability hollow fiber membrane was prepared and evaluated. HFMC was fabricated using the prepared hollow fiber membrane, and the experiment used a mixture of CH4/CO2 (30% CO2, CH4 balance) and monoethanolamine (MEA). During HFMC operation, the effect of gas and absorbent pressure on the CO2 removal efficiency was evaluated. The CO2 removal efficiency increased as the gas pressure increased, and the CO2 absorption flux also showed a tendency to increase with the liquid flow rate. In addition, when the CO2 absorption rate was less than 40%, LTS-1, a counter-current form where the absorbent enters from the bottom, has higher CO2 removal performance than LTS-2, a countercurrent form in which the absorbent enters from the top. and when the absorption rate was 40% or higher, LTS-2 had higher performance than LTS-1.