• 제목/요약/키워드: 점착성

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Analysis on Erosional Properties of Fine-Cohesive Sediments In Kunsan Coast (군산해역 미세-점착성 퇴적물의 침식특성 해석)

  • 이현승;조용준;황규남
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 한국해안해양공학회 2003년도 한국해안해양공학발표논문집
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    • pp.222-226
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    • 2003
  • 대부분의 경우에 하구의 미세-점착성 퇴적물은 보통 무기성 광물과 유기물 및 생화학물의 혼합체이며, 광물 입자들은 주로 점토와 실트로 구성되어 있다. 이러한 혼합체의 침식특성은 사질성 퇴적물과는 달리 입자간의 응집현상에 의한 의해 크게 영향을 받으며, 응집강도는 광물질 구성, 입경분포, 유기물 함량 등으로 묘사되는 퇴적물 자체의 물리ㆍ화학적 기본특성에 따라 크게 변화하고 (Mea, 1986), 특히 저면 퇴적물의 침식 여부는 흐름 전단응력에 의한 저면퇴적물의 저항력 즉, 저면전단강도의 상대적 크기의 차이에 좌우되므로, 그 침식 특성은 저면전단강도 흑은 저면밀도로 묘사되는 저면특성에 따라 크게 변화한다(황규남 등, 2003). 또한 각 해역마다 저면 퇴적물은 퇴적물 공급원, 수동학적 조건, 생태학적 조건 등이 모두 다른 상태에서 형성된 퇴적층이므로, 저면 퇴적물의 기본특성 및 저면특성은 "site- specific" 한 성격을 갖는다. (중략)

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An Experimental Study for Estimation of Erosion Rate of Fine Cohesive Sediments (미세-점착성 퇴적물의 침식률 산정을 위한 실험적 연구)

  • Hwang Kyu-Nam;So Sang-Don;Kim Tae-Min
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • 제17권2호
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    • pp.119-128
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    • 2005
  • An annular flume has been constructed in order to estimate the erosion rate of fine cohesive sediments. Under an uniform bed condition, some erosion tests for Kaolinite sediments have been conducted to examine the performance of the flume and to check the validity of experimental method and results. In this study, the critical shear stress for erosion and the erosion rate coefficient are estimated and compared with the existing measurements. It is concluded that the performance of the annular flume is good enough to conduct erosion tests and the experimental method and results are valid.

Effect Of Silica Concentration and Crosslinking Agent on Adhesion Properties and Thermal Stability Of UV Cured 2-EHA/AA PSAs (자외선 경화형 2-EHA/AA 점착제의 점착 물성 및 열 안정성에 미치는 실리카 함량 및 경화제 효과)

  • Kim, Ho-Gyum
    • Journal of Adhesion and Interface
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    • 제16권2호
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    • pp.55-62
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    • 2015
  • It was investigated that the effect of surface modification and concentration of fumed silica on the adhesion properties and thermal stability of 2-EHA/AA pressure sensitive adhesive (PSAs) prepared by UV irradiation. The influence of repeating units of crosslinking agent on PSAs were also studied. From SEM analysis, PSAs synthesized with surface modified silica had finer dispersion of silica particles in polymer matrix due to the interfacial interaction. Results of the study showed that increase in tack and peel strength when under 0.3 wt% of silane treated silica were added in the reaction mixture. The addition of PEGDMA for crosslinking agent offers positive effect on adhesion properties in comparison with PSAs using EGDMA for crosslinker, which may be attributed to high mobility of ethylene oxide repeating units in PEGDMA. From the thermal degradation residue of PSAs, it was revealed that thermal stability was improved with silica addition due to the strong interfacial bonding between silane modified silica and polymer matrix, which may act as a thermal barriers into 2-EHA/AA PSAs.

Analysis of the transport and sedimentation processes of cohesive and non-cohesive sediments induced into a navigational river (주운하천으로 유입하는 점착성 및 비점착성 유사의 3차원 이송.퇴적 해석)

  • Ryoo, Jae-Il;Chung, Se-Woong;Chung, Jin-Woong;Kim, Hyun-Cheol
    • Proceedings of the Korea Water Resources Association Conference
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    • 한국수자원학회 2011년도 학술발표회
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    • pp.183-187
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    • 2011
  • 본 연구에서는 3차원 수리해석과 함께 유사의 이송, 침식, 퇴적 현상을 연동하여 모의할 수 있는 유한차분 수치모형인 EFDC(Environmental Fluid Dynamics Code)를 이용하여 주운하천 구간으로 유입되는 다입경 혼합유사의 입경별 시 공간적 퇴적분포 특성을 고찰하고, 하상변동 예측에 있어서 유사의 밀도와 모델의 유한차분 격자 구조에 의한 불확실성 해석을 수행하였다. 유입 유사의 입경별 공간적 퇴적특성은 하천 하류부와 단면 확대부에서 발생하는 3차원적 수리현상과 매우 밀접한 상관성을 보였으며, 굴포천과 합류하는 주운수로 유입부에서는 대부분 입경이 큰 비점착성 유사($63{\mu}m$ 이상)인 사질(sand)입자들이 주로 퇴적되는 것으로 나타났으며, 주운하천 합류부로부터 하류구간까지는 $4\sim63{\mu}m$ 입자의 실트질(silt) 유사가 대부분 이송되어 퇴적되는 것으로 분석되었다. 점착성 유사인 $4{\mu}m$ 이하의 점토(clay)는 단면이 확대되어 유속이 매우 느린 구간이나 사수역을 중심으로 퇴적되는 것으로 나타났다. 단면 횡방향 분포특성은 굴포천과 주운하천이 합류하는 합류부 구간의 주흐름 방향 남쪽에서 흐름의 정체구간이 발생되어 퇴적이 발생하고, 단면 급확대부 양안에서 사수역이 형성되므로 퇴적이 지배적으로 발생되었다. 하상변동 예측의 불확실성 해석을 위해 유사 밀도값에 대한 민감도 분석결과, 하상변동량은 유사밀도($1.3ton/m^3\sim2.65ton/m^3$)가 감소됨에 따라 약 2배까지 증가하는 것으로 분석되어 민감도가 매우 크게 나타났다. 또한 수치격자 구조의 민감도 분석결과, 수층을 3개 층으로 분석한 결과가 단일층 분석결과보다 최대 6배의 하상변동량이 많게 산정되었다. 이는 수심방향의 유속과 부유사 농도의 불균등 분포특성이 실제 자연현상에 더 가깝게 모의되기 때문으로 판단되었다.

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Manufacture and Properties of Water Soluble Acrylic Type PSA's - Effect of Functional Monomer Change and Atmospheric Plasma Treatment - (수용성 아크릴계 점착제의 제조와 물성 연구 - 기능성 단량체 변화와 대기압 플라즈마 처리영향 -)

  • Sim, Dong-Hyun;Seul, Soo-Duk
    • Polymer(Korea)
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    • 제33권1호
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    • pp.45-51
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    • 2009
  • Water soluble adhesive was polymerized from butyl acrylate (BA), methyl methacrylate (MMA) and one of various functional monomers such as acrylic acid (AA), 2-hydroxylethyl methacrylate (2-HEMA), glycidyl methacrylic acid (GMA) and acrylamide (AAm). The amount of the functional monomers was 1$\sim$5 wt%/monomer. In order to improve the adhesive power, a substrate was treated using atmospheric flat plasma method. The adhesive power was improved by the addition of the functional monomers with an order of AA> 2-HEMA> GMA> AAm. The holding power of the adhesives, which is related with the thermal properties of the adhesives, increased with the amount of the functional monomers. The effectiveness in improving the holding power has an order of AA > AAm > GMA > 2-HEMA. By treating a substrate with atmospheric flat plasma method, the adhesives containing each of AA, 2-HEMA, GMA and AAm showed the increases of the final adhesion strength by 9.1, 9.4, 9.4, and 1.8%, respectively. In conclusion, the mechanical properties such as adhesive power and holding power could be controlled by introducing.

Numerical Modeling of Cohesive Sediment Transport at Mokpo Coastal Zone (목포해역 점착성 퇴적물의 수송에 관한 수치모의)

  • Jung T.S.;Kim T.S.;Jeong D.K.
    • Journal of the Korean Society for Marine Environment & Energy
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    • 제9권1호
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    • pp.36-44
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    • 2006
  • Cohesive sediment transport in coastal region has been studied by numerical modeling. A finite element numerical model was setup to simulate hydrodynamics and sediment transport in the coastal region with complex topography. Only physical features of observed sediments has been used to determine erosion rates of bottom sediments together with the previous research results. The simulation results using the simply determined equation of erosion rates were compared with time variations of the observed SS concentration and showed good agreements. In conclusion, this method can be used to estimate transport of cohesive sediment conveniently.

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Preparation and Characterization of Removal-type Acrylic Pressure-Sensitive Adhesive (4원 아크릴계 박리형 점착제의 제조와 특성에 관한 연구)

  • Seo, Young-Ok;Seul, Soo-Duk
    • Elastomers and Composites
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    • 제36권4호
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    • pp.225-236
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    • 2001
  • In order to improve the properties of the copolymer and the terpolymer that was used as removal-type pressure sensitive adhesive(PSA), we synthesized quaterpolymer with the variation of the types of monomer, initiator, and solvent, and concentration, the monomer/solvent ratio, reaction temperature and time. and determined the properties of this adhesive: the viscosity, molecular weight, conversion, solid content and structure of polymer. The prepared polymer was crosslinked by changing the type of crosslinking agent and concentration, and then we investigated the characteristics or adhesive such as peel adhesion, shear adhesion, heat resistance, weathering resistance and peel adhesion to aging. The optimum performance of RA/2- EHA/MMA/2-HEMA as a PSA were obtained when benzoyl peroxide was used as an initiator with the reactant mixture consisted of 80% BA and 2-EHA, 15%, MMA, and 5% 2-HFMA. The optimum reaction temperature and time were $80^{\circ}C$ and 8 hours, respectively. For BA/2-EHA/MMA/AA, the optimum performance was obtained when the polymerization was performed at the monomer composition of 80% BA/2-EHA, 15% MMA, and 5% AA. BPO was used as initiator and the optimum reaction temperature and time were identical to those of BA/2-EHA/MMA/ 2-HEMA. Isocyanate and melamine were used to crosslink BA/2-EHA/MMA/2-HEMA and BA/2-EHA/MMA/AA, respectively. No effect on the type of cross-linking agent on the peel adhesion was observed with aging. The quarterpolymers crosslinked with melamine left residues on the counter surface after weathering resistance test, while the polymers crosslinked with isocyanate did not.

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Pressure Sensitive Adhesion Performances of SIS/SBS based UV-curable Pressure Sensitive Adhesives using Thiol-ene Reaction (Thiol-ene 반응을 이용한 UV경화형 SIS/SBS계 점착제의 점착물성)

  • Lim, Dong-Hyuk;Do, Hyun-Sung;Kim, Hyun-Joong;Yoon, Goan-Hee;Bang, Jung-Suk
    • Journal of Adhesion and Interface
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    • 제6권3호
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    • pp.19-25
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    • 2005
  • Synthetic rubber based pressure-sensitive adhesives (PSAs) usually containing SIS or SBS block copolymer, tackifier, plasticizer, and other additives are now widely used on various applications. As these PSAs are physically crosslinked and can be applied without the use of solvent, they are thermally processable and environmentally friendly. However these PSAs cannot be used in high temperature applications and in applications where solvent and chemical resistance properties are required. We developed the PSA adding UV curable system, such as thiol-ene system, to increase adhesion properties at elevated temperature. The adhesion properties such as probe tack, peel strength, shear adhesion failure temperature (SAFT) were evaluated. The probe tack test was conducted with varying probe materials and coating thickness of PSAs. Using the contact angle, the surface property of the cured PSAs was also observed.

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Study on texture change of cooked rice within a short time after cooking (취반 후 단시간 경과에 의한 쌀밥의 조직감 변화 연구)

  • Shin, Sun-Hwa;Choi, Won-Seok
    • Korean Journal of Food Science and Technology
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    • 제52권3호
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    • pp.310-315
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    • 2020
  • The aim of this study was to investigate the texture change of cooked rice within a short time after cooking. Using four instant rice brands, the texture change within 30 min after cooking was measured by the texture profile analysis (TPA) method for hardness, adhesiveness, cohesiveness, chewiness, and springiness with different compression ratios (30, 70%) and cross-head speeds (0.5, 1.0 mm/s). In the case of cohesiveness, adhesiveness, and chewiness, there were significant differences in the rice textures at 20 to 30 min after cooking compared to that in the sample immediately after cooking. In particular, adhesiveness showed significant differences at 10 min after cooking. However, there were little significant differences within 30 min for springiness. In conclusion, when measuring cooked rice texture, it is desirable to measure it, if possible, within 10 to 20 min after cooking.