• Title/Summary/Keyword: 전해제염

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A Study on the Recycling of Radioactively Contaminated Metal Waste (방사성오염 금속폐기물의 재활용 연구)

  • 문제권;박상윤;정종헌;이정원;오원진
    • Resources Recycling
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    • v.6 no.3
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    • pp.22-27
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    • 1997
  • Recycling of radioactively contaminated metal wasles is very attractive to reduce thc final disposal volumc of the radioactive wastes, thereby maximizing the usage of nahrral rzsuunts and minimizmg the detrimental effects of thz rzdioaclive wastes on the environment. In the recycling process, many complicated processes arc involved. Among those processes the 'surface contamination removal techniques such as physical, chemical and electrochern~calm ethods are the most critical and Ircquently applied in accordance with the contamination characteristics and the chemical compositions of the metal wastes. In this sludy, the sulfuric acid-cerium method and electmchemical methods were applied lu removc the conatiminated suhce. The results showed the surface contaminalion could he lowered to the background levcl by lhasc mclhods.

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SC 제염용액에서 $Ce^{4+}/Ce^{3+}$이온쌍의 산화환원 특성 연구

  • 박상윤;문제권;정종헌;오원진
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05b
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    • pp.313-318
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    • 1997
  • 방사성 금속폐기물을 재활용하기 위한 제염기술로서 SC ( Sulfuric acid - Cerium) 제염의 기본특성을 파악하기 위해 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원 특성을 cyclic voltammetry 방법으로 연구하였다. 황산용액 내에서 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원 특성 조사를 위해서는 백금전극이 효과적이었다. 이중 실린더형 전해셀의 백금전극에서 Ce$^{4+}$ Ce$^{3+}$ 이온쌍의 산화환원에 대한 전달계수, 확산계수 및 비균일 속도상수 둥을 구하였으며, 각각 0,63 $\pm$ 0.05, (2.09$\pm$0.49) x $10^{-5}$ $\textrm{cm}^2$/sec 및 (2.53 $\pm$ 1.33) * $10^{-4}$ cm/sec 의 값을 나타내었다.

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Increase of Electrokinetic Soil Remediation Efficiency using Ethanoic Buffer (초산완충액에 의한 동전기적 토양복원 효과 증진 연구)

  • Kim, Gye-Nam;Oh, Won-Zin
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2007-2016
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    • 2000
  • After kaolin clay was compulsorily contaminated with $Sr^{2+}$ ion. the remediation characteristics by electrokinetic method were analyzed. In the first experiment. NaCl solution was used as an electrolyte to raise the electric field strength. After remediation for 0.8 days. the pH of the cathode side of the soil column was elevated from 4.0 to 11.7. and thereby precipitation $Sr(OH)_2$, started to be formed in the side. Therefore. efficiency of soil remediation was reduced significantly and the 32% of total $Sr^{2+}$ ion in the column was decontaminated in 6.7 days. In the second experiment. ethanoic buffer was injected in the soil column and $CH_3COOH$ was continuously inputted in cathode reservoir to restrain the pH elevation. The pH of the cathode side of the soil column was only ascended from 4.0 to 6.0 in 3.8 days and $Sr(OH)_2$ was not formed. The 21% of total $Sr^{2+}$ in the soil column was decontaminated in 0.6 days. and the 33% of total $Sr^{2+}$ in 0.9 days. and the 84% of total $Sr^{2+}$ in 1.6 days. and the 92% of total $Sr^{2+}$ in 2.5 days. and the 97% of total $Sr^{2+}$ in 3.8 days. Meanwhile. the residual concentrations in the column calculated by the developed model were similar to those by experiment.

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Electrosorption Behavior of $TiO_2$/Activated Carbon Composite for Capacitive Deionization (축전식 이온제거에 대한 $TiO_2$/Activated Carbon 화합물의 전기흡착 거동)

  • Lee, Jeong-Won;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.265-271
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    • 2010
  • Desalination effects of capacitive deionization (CDI) process was studied using $TiO_2$/activated carbon electrode. In order to enhance the wettability of electrode and decrease a electrode resistance, $TiO_2$ was coated on activated carbon. By means of $TiO_2$ coating on activated carbon, electric double layer to adsorption content in CDI process was increased. It was identified from TEM, XRD, and XPS that the activated carbon based on $TiO_2$ composite was fabricated successfully by means of sol-gel method. As a results of cyclic voltammetry and impedance, it was identified that $TiO_2$/activated carbon electrode has more electric double later capacitance and less diffusion resistance than activated carbon. Also charge-discharge and ion conductivity profiles showed that the ion removal ratios of $TiO_2$/activated carbon electrode in NaCl electrolyte of $1000\;{\mu}S/cm$ more increased about 39% than that of activated carbon. In conclusion it was possible to identify that the carbon electrode coated $TiO_2$ as electrode material was more effective than raw carbon electrode.

Removal of Cesium and Cobalt within Soil around TRIGA Reactor by Electrokinetic method (동전기적방법을 이용한 TRIGA 연구로 주변 토양내의 세습과 코발트 제거)

  • 김계남;원희준;정종헌;오원진
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.13-23
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    • 2004
  • The characteristics of cesium and cobalt removal from soil around the TRIGA reactor using the electrokinetic method were analyzed and a device to restrain the pH increase in the soil column was suggested. When a NaCl solution was used as the electrolyte to raise the electric field strength, a precipitate was formed in the cathode in the soil column, resulting in a low removal efficiency. Thus, an acetate buffer solution (compound solution of $CH_3COONa$ and $CH_3COOH$) was injected into the soil column and acetic acid was periodically infected into the cathode reservoir to restrain any pH increase. Many $Cs^{2+}$ and $Co^{2+}$ ions were transferred by electromigration rather than electroosmosis during the initial remediation period, and no precipitate was formed in the soil column. 96% of the total amount of cesium in the soil column was removed after 5.9 days, while 94% of the total amount of cobalt was removed. Furthermore, the residual concentrations predicted by the developed model were similar to those obtained by experiment.

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The Economic-Geographical Consideration of Fisheries of the West Coast Area, Chungnam in the 1910s in "Hangooksusanji" ("한국수산지" 를 통해 본 1910년경 충남 서해안 지역 수산업에 관한 경제지리학적 고찰)

  • Jo Chang-Yon;Kim Hag-Tai
    • Journal of the Economic Geographical Society of Korea
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    • v.8 no.1
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    • pp.153-169
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    • 2005
  • In this study, we analysed the state of the fisheries in Chungnam around 1910 from Hangook Susanji. As a result, there were about 30 ports in the west coast area in Chungnam, and we can classify their locations into 5 types Type I is located in small and mid sized rivers. Type II is located in a costal port. Type III is ports facing the open sea, and type IV is ports in a bay. Type V is ports on islands of coast. Species of fish are porges, mackerels, sting rays, croakers, hairtails, shrimps, etc. The base of fishing porge was Jukdo and Yeondo. The fishing banks of croakers are formed from Chilsantan, Jeonlado to the area of seashore, Chungnam. Hairtails were caught near all the areas of seashore. Salt manufacturing is done near all coasts of Chungnam, Seocheon-bay, Ungcheon-bay, Ocheon-bay, Anmyeon island, Taean, Dangjin area, etc represent this work. Especially, the salt which was produced in Taeangun was so famous that it was called ' Taeansalt'. In the Kum-river area there were 32 fishing villages. Freshwater fish were caught in the upper stream area and the mouth of Geumgang, down stream, was the center for producing Baengeo. There were 23 fishing villages, and the species consisted of croaker, hairtail, Forge, gray mullet, sting ray, sharks, anchovy, shrimps, etc in Biin-bay. The coast of Boryeong had about 33 fishing villages, but their fishing industry was not developed more than their good salt manufacturing. Though there are records that Chunsu-bay had 28 fishing villages, Taean peninsula and Garolim-bay had about 70 fishing villages, and Asan-bay area had about 55 fishing villages, they were developed a little, but not more than Weir fisheries or salt manufacture on the base of salt area and the tideland because these areas were just for farming. South of Anmyeon island of West coast island areas is the biggest area of Stow nets on stakes fishing and the island areas down mouth of Kum river were centers for producing porge.

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