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Catalytic Hydrogenation of Triglyceride in a Semi-batch Reactor (Semi-batch 반응기에서의 트리글리세라이드 접촉 수소화 반응)

  • An, Jae-Yong;Lee, Choul-Ho;Jeon, Jong-Ki
    • Clean Technology
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    • v.25 no.2
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    • pp.101-106
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    • 2019
  • The aim of this study is to investigate the feasibility of an Ni-SA catalyst, which was prepared from nickel, kieselguhr, and alumina, for the hydrogenation of triglyceride in a bench-scale reactor. Ni-SA powders were prepared by precipitating nickel precursors on a silica and alumina support. The powder was reduced in a hydrogen flow, mixed with a saturated palm oil, and then cooled to prepare an Ni-SA catalyst tablet. The sizes of NiO crystals of a commercial Pricat catalyst and the Ni-SA catalyst prepared in this study were $35{\AA}$ and $38{\AA}$, respectively. The pore volume and pore size of the Ni-SA catalyst was much larger than the pore volume and pore size of the Pricat catalyst. In addition, the average particle size of the Ni-SA catalyst was much smaller than that of the Pricat catalyst. The triglyceride hydrogenation reaction was carried out in a semi-batch reactor using catalysts impregnated with oil and molded into tablets. It was found that the Ni-SA catalyst was superior to the commercial Pricat catalyst in triglyceride hydrogenation, which could be ascribed to the raw material and the products being less influenced by the diffusion resistance in the pores of the Ni-SA catalyst. The Ni-SA catalyst prepared in this study has the potential to replace the Pricat catalyst as a catalyst for use in the commercial process for hydrogenation of triglyceride.

Preparation of Heterogeneous Bipolar Membranes Using Poly (phenylene oxide, PPO) Polyelectrolyte and Their Water Splitting Properties (Poly (phenylene oxide, PPO) 고분자 전해질을 이용한 불균질 바이폴라막 제조 및 물분해 특성)

  • Kim, In Sik;Hwang, Seong Yeon;Kang, Byung Gwan;Hwang, Taek Sung
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.65-72
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    • 2019
  • In this study, heterogeneous ion exchange membranes were prepared by casting method with various mixing ratios of PPO ion-selective solution and ion exchange resin. Then heterogeneous bipolar membranes were prepared by using this. The water content of heterogeneous cation and anion exchange membranes were 60~80% respectively, the ion exchange capacity was 2.81~3.26 meq/g, 2.31~2.74 meq/g and electrical resistances were $1.65{\sim}1.45{\Omega}{\cdot}cm^2$ and $1.55{\sim}1.05{\Omega}{\cdot}cm^2$. The tensile strength of heterogeneous bipolar membrane was lower than that of PPO resin before functionalization ($700Kg_f/cm^2$). The tensile strength of heterogeneous bipolar membrane with catalyst layer was lower than that of non-catalytic heterogeneous bipolar membrane. The water splitting voltage of the heterogeneous bipolar membrane with catalyst layer was low and stable at a minimum of 1.7~1.8 V, maximum 3.9~4.0 V, and the water splitting voltage of the non-catalytic heterogeneous bipolar membrane was constant at 3.8~4.0 V.

One-Dimensional Heat Transfer Model to Predict Temperature Distribution in Voided slabs subjected to fire (화재 시 중공슬래브의 온도분포 예측을 위한 1방향 열전달 모델)

  • Chung, Joo-Hong;Choi, Hyun-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.5
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    • pp.60-67
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    • 2019
  • In general, a reinforced concrete slabs are known to have a high fire resistance performance due to thermal properties of concrete materials. However, according to previous research, the thermal behavior of voided slabs is reported to be different from that of conventional RC solid slabs, and the differences seem to be caused by the air layer formed inside the voided slab. Therefore, it is difficult to estimate the temperature distribution of the voided slab under fire by using the existing methods that do not take into account the air layer inside the voided slab. In this study, a numerical analysis model was proposed to estimate the temperature distribution of voided slabs under fire, and evaluated. Heat transfer of slabs under fire is generally caused by conduction, convection and radiation, and time-dependent temperature changes of slab can be determined considering these phenomena. This study proposed a numerical method to estimate the temperature distribution of voided slabs under fire based on a finite difference method in which a cross-section of the slab is divided into a number of layers. This method is also developed to allow consideration of heat transfer through convection and radiation in air layer inside of slabs. In addition, the proposed model was also validated by comparison with the experimental results, and the results showed that the proposed model appropriately predicts the temperature distribution of voided slabs under fire.

The Problems and its Improvement of Sea Area Utilization Consultation and Impact Assessment for Projects Related to Marine Environment Restoration (해양환경복원관련 사업에 따른 해역이용협의·영향평가의 문제점 및 개선방안)

  • Yi, Yong Min;Jun, Eun Ju;Lee, Dae In;Kim, Gui Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.1
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    • pp.34-44
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    • 2019
  • Marine activities are becoming more diverse and extensive due to recent social developments, exceeding the environmental capacity of the marine ecosystem. The resilience, resistance, and constancy of marine ecosystems are being damaged or degraded. This prevents the ecosystem from functioning properly, leading to a decline in ecosystem services and value. As a means of returning the damaged ecosystem to health, more and more people are interested in restoration. At a time when restoration projects are gradually expanding, various problems that may arise when implementing the Sea Area Utilization Consultation and Impact Assessment for restoration projects need to be checked, in addition to confirming the direction to be pursued. Therefore, in this study terms related to restoration from research papers and reports were summarized, and the status of the Sea Area Utilization Consultation related to restoration projects and the status of the restoration project were reviewed. In addition, problems with Sea Area Utilization Consultations were considered through a case study to ensure the successful execution of restoration projects. Based on this, we intend to present improvement measures for Sea Area Utilization Consultations and Impact Assessments for restoration projects. This will provide effective information for future policies and plans.

Superhongmi bran extract improves lipid profile and menopause symptoms: a randomized, placebo-controlled clinical trial (슈퍼홍미 미강 추출물의 폐경 후 여성의 혈중 지질 농도 및 대사성 질환 개선 효과)

  • Chung, Soo Im;Nam, Su Jin;Liang, Jie;Ma, Jing Wen;Kang, Mi Young
    • Korean Journal of Food Science and Technology
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    • v.51 no.2
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    • pp.182-187
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    • 2019
  • Women who undergo natural menopause transition have increased numbers of risk factors relating to metabolic syndrome due to estrogen deficiency. This study was conducted to investigate the effect of Superhongmi bran extract on metabolic syndrome improvement in menopausal women. Thirty women, who participated in a randomized, double-blind, placebo-controlled trial, were assigned to placebo-control (n=15) or Superhongmi bran extract (n=15) groups and were asked to consume two tablets (350 mg per extract per tablet) per day. After 12 weeks, weight, body mass index (BMI), plasma triglyceride (TG) levels, and total cholesterol (TC) levels were significantly decreased, whereas HDL-cholesterol (HDL-C), apolipoprotein A1 (ApoA1), adiponectin, superoxide dismutase 1 (SOD1), and GSH (glutathione) concentrations were significantly increased in the Superhongmi bran extract group. Moreover, $17{\beta}-estradiol$, and progesterone levels in the Superhongmi group were significantly higher than those in the placebo-control group. These results suggest that Superhongmi bran extract alleviates metabolic symptom in menopausal women.

Effect of the Density of Heterodera glycines on Soybean Yield (콩씨스트선충(Heterodera glycines)의 밀도가 콩 수량에 미치는 영향)

  • Kang, Heonil;Park, Byeongyong;Park, Sekeun;Kim, Eunwha;Park, Eunhyeong;Ko, Hyoung-Rai
    • Korean Journal of Plant Resources
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    • v.34 no.4
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    • pp.257-262
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    • 2021
  • This study was conducted to investigate the yield loss of soybean by initial density of Heterodera glycines in soil. A soybean cultivar named 'Cheongja5ho' was cultivated as test material in Dangjin city, Chungcheongnam-do, Korea. Each seed was planted with distance of 25 cm in 35 plots by initial density of egg of the cyst nematode on June 21st, and allowed to harvest on November 12st in 2019. As a results, the yield of soybean decreased sharply when as the initial density of eggs of cyst nematode increased. The initial density of eggs in soil affected largely on the decreased yields of the soybean by more than 20% in above 2,000 eggs, and 30% in above 6,000 eggs of the cyst. Beyond the 6,000 eggs, the yield loss was more slowly decreased compared with the above cases. Eggs of H. glycines are widely distributed in Korea, resulting in the serious soybean yield loss by H. glycines.

Current Perspectives on the Effects of Plant Growth-promoting Rhizobacteria (식물생장촉진 근권미생물의 영향에 대한 연구 현황 및 전망)

  • Le, Thien Tu Huynh;Jun, Sang Eun;Kim, Gyung-Tae
    • Journal of Life Science
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    • v.29 no.11
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    • pp.1281-1293
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    • 2019
  • The rhizosphere is the active zone where plant roots communicate with the soil microbiome, each responding to the other's signals. The soil microbiome within the rhizosphere that is beneficial to plant growth and productivity is known as plant growth-promoting rhizobacteria (PGPR). PGPR take part in many pivotal plant processes, including plant growth, development, immunity, and productivity, by influencing acquisition and utilization of nutrient molecules, regulation of phytohormone biosynthesis, signaling, and response, and resistance to biotic- and abiotic-stresses. PGPR also produce secondary compounds and volatile organic compounds (VOCs) that elicit plant growth. Moreover, plant roots exude attractants that cause PGPR to aggregate in the rhizosphere zone for colonization, improving soil properties and protecting plants against pathogenic factors. The interactions between PGPR and plant roots in rhizosphere are essential and interdependent. Many studies have reported that PGPR function in multiple ways under the same or diverse conditions, directly and indirectly. This review focuses on the roles and strategies of PGPR in enhancing nutrient acquisition by nutrient fixation/solubilization/mineralization, inducing plant growth regulators/phytohormones, and promoting growth and development of root and shoot by affecting cell division, elongation, and differentiation. We also summarize the current knowledge of the effects of PGPR and the soil microbiota on plants.

Multi-fidelity Data-fusion for Improving Strain accuracy using Optical Fiber Sensors (이종 광섬유 센서 데이터 융합을 통한 변형률 정확도 향상 기법)

  • Park, Young-Soo;Jin, Seung-Seop;Yoo, Chul-Hwan;Kim, Sungtae;Park, Young-Hwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.40 no.6
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    • pp.547-553
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    • 2020
  • As aging infrastructures increase along with time, the efficient maintenance becomes more significant and accurate responses from the sensors are pre-requisite. Among various responses, strain is commonly used to detect damage such as crack and fatigue. Optical fiber sensor is one of the promising sensing techniques to measure strains with high-durability, immunity for electrical noise, long transmission distance. Fiber Bragg Grating (FBG) is a point sensor to measure the strain based on reflected signals from the grating, while Brillouin Optic Correlation Domain Analysis (BOCDA) is a distributed sensor to measure the strain along with the optical fiber based on scattering signals. Although the FBG provides the signal with high accuracy and reproducibility, the number of sensing points is limited. On the other hand, the BOCDA can measure a quasi-continuous strain along with the optical fiber. However, the measured signals from BOCDA have low accuracy and reproducibility. This paper proposed a multi-fidelity data-fusion method based on Gaussian Process Regression to improve the fidelity of the strain distribution by fusing the advantages of both systems. The proposed method was evaluated by laboratory test. The result shows that the proposed method is promising to improve the fidelity of the strain.

Molecular detection of blaVIM, blaBIC, blaKPC, and blaSIM genes from isolated bacteria in retail meats (육류용 고기로부터 분자진단을 이용한 항생제내성 유전자 양상)

  • Hwang, You Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.6
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    • pp.413-419
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    • 2021
  • The purpose of this study was to investigate the ability to treat and prevent infection by multiple Gram-negative bacterial pathogens as a last choice option in the treatment of serious infections in clinical settings. The global spread of extended-spectrum 𝛽-lactamases (ESBLs) and/or carbapenemases in microorganisms are of enormous concern to health services because they are often associated with multi-drug resistance which significantly restricts the antibiotic treatment options. In this study, the antimicrobial resistance profiles of bacteria isolated from South Korean market-derived meat samples were determined by the disc diffusion method. PCR was used to detect the presence of antibiotic resistance genes and ESBL producing genes. In total, we tested 181 isolated colonies from 36 market-derived meat samples. Single PCR and DNA sequencing results revealed that genes blaVIM, blaBIC, blaKPC, and blaSIM were present in the bacteria isolated from retail meat. The bacteria in the meat were separately sequenced and based on alignment, four different bacteria were identified. These findings suggest that bacteria found in retail meats are a reservoir for the spreading of ESBL blaVIM, blaBIC, blaKPC, and blaSIM resistance genes and bacteria strains.

Evaluation of Field Applicability of Slope of Improved Soil for Ground Stabilizer (지반안정재 개량토의 토사 비탈면 현장 적용성 평가)

  • Lee, Kang-Il;Park, Seong-Bak;Choi, Min-Ju
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.1
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    • pp.35-44
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    • 2021
  • This research studies the stabilization method for improved soil sloped through the on-site application of Paper Flyash ground stabilizers. The target strength required for improved soil is 500 kPa, and the compressive strength for the slope surface needs to be less than 1,000 kPa after the improvement in order to plant vegetation. To meet this condition, we mixed soil from the site and the ground stabilization material, which is the main material for surface improvement material, performed mixing design and conducted various tests including strength test, permeability test and plantation test. After analyzing the results of the compression test on improved soil slope, we proposed soil constants for the improved soil. In order to evaluate the applicability of the improved soil on the slope, the site construction was carried out on the collapsed slope and the reinforcement evaluation of the surface of the improvement soil was conducted. The stability was not secured before the reinforcement, but the test shows after the reinforcement with improved soil, the safety rate is secured up to 48 hours during the raining period. In addition, the compressive strength of the improved soil at the site was secured at more than 200 kPa adhesion as planned, and the soil hardness test result was also found to be within the specified value of 18-23 mm, which increased the resistance to rainfall and ability to grow plant on the surface for improved soil.