• Journal of the Korean Chemical Society
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• v.36 no.1
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• pp.3-15
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• 1992

Electronic structures and reactivities of the chromium, molybdenum, and tungsten carbene complexes, $(CO)_5Cr=CCHCH_2(XCH_3)\;,\;(CO)_5Mo=CCHCH_2(XCH_3)\;, and\;(CO)_5W=CCHCH_2(XCH_3)$, are studied by means of Extended Huckel calculations. The origin of the M=Ccarbene double bond is clarified from the diagram of the orbital correlation with the fragment orbitals. The ${\sigma}$ bond of the M=Ccarbene double bond is formed by the electron transfer interaction from the HOMO of the carbene to the LUMO of the $(CO)_5M$. The ${\pi}$ bond is formed through the back-transfer of electrons from one of the degenerated d${\pi}$ orbitals to the LUMO of the carbene. The polarization of charge of the M=Ccarbene bond is calculated to be M=Ccarbene for Mo, and W carbenes. The chemical and physical properties of these complexes are resulted from an appreciable positive charge on the carbene carbon. The electrophilic reactivity of the carbene carbon is not charge controlled, but is controlled by the frontier orbital, LUMO.

• The Journal of Engineering Geology
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• v.17 no.1 s.50
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• pp.75-87
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• 2007

The recognitions of geometrical characteristics and occurrence conditions are very important to evaluate the land-slides in natural terrains. In this paper, the geometrical characteristics of landslides are analyzed according to a geo-logical condition in three landslides areas. The three landslides areas are classified to the geological condition. The three landslides areas are Jangheung, Sangju and Pohang. The geology of Jangheung area, Sangju area and Pohang area is gneiss, granite, and the tertiary sedimentary rock, respectively. During a heavy rainfall of $150{\sim}588mm$ in these areas, 1,582 landslides have occurred in 1998. The geometrical characteristics according to the geological condition analyzed from the investigation of these landslides. The frequency of landslide is high exceedingly above 90% of a slope attitude, while the frequency is very low below 70%. The frequency of landslide is high exceedingly between $26^{\circ}$ and $30^{\circ}$ of slope angle, while the frequency is very low below $20^{\circ}$. The size of the landslides is ranged from several tens to several hundreds The length is ranged from 5 m to 300 m, and the width is ranged from 3 m to 50 m. Also, the depth is less than 1 m. Therefore, the landslides in these areas have small width, long length and shallow depth. The type of the landslides is changed from transitional slide at the scarp to debris flow at the low part of slope.

• The Journal of the Korean bone and joint tumor society
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• v.13 no.2
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• pp.195-200
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• 2007

Dedifferentiated parosteal osteosarcoma is an uncommon variant of osteosarcoma. Dedifferentiation is known to be associated with a greater metastatic potential and a more rapid lethal clinical course. Thus recognition of dedifferentiation is important to establish the treatment strategy. But there may be few significant clinical clues to distinguish between dedifferentiated parosteal osteosarcoma and conventional one. A 29-year-old woman presented with 2-year history of discomfort and swelling in her proximal thigh. Examination showed a large, hard, non-mobile mass. Radiographs revealed a large ossified mass attached to the proximal femur. Diagnosis of parosteal osteosarcoma was established by MRI and needle biopsy. But she had a history of abrupt severe thigh pain and increased swelling before surgery. Follow up MRI showed enlargement of mass with invasion to muscle around tumor. The patient underwent an en-bloc resection of tumor and reconstruction. Histological examination showed parosteal sarcoma with dedifferentiation. The patient expired due to local recurrence of tumor and distant lung metastasis 2 months after the surgery. In case with rapid growth of a lesion or unusual severe pain, one must have a high index of suspicion with regard to dedifferentiation.

• Korean Journal of Applied Biomechanics
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• v.18 no.1
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• pp.235-243
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• 2008

The purpose of this study is to find out the effect of Growth Hormone promotin and kinetic factors on Growth Hormone Activated Shoes. The results of the present study were as follows; First, there was a significient difference between a normal shoes and the Growth Hormone activated shoes in the student's GH secretion with running test, and there was a significant interaction effect between shoes and distance. therefore it can be assumed that there is a significant effect of GH secretion in student at growth period during running with Growth Hormine Activated Shoes. Second, Within 4km walking, Growth Hormone secretion was in creased averagely in student. Third, Growth Hormone Activated Shoes make a large load for light motion as walking. For heavy motion as running, it make a large impulsion but good pressure distribution and small loading rate.

• The Journal of Internal Korean Medicine
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• v.39 no.4
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• pp.463-470
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• 2018

Objectives: The aim of this study was to identify the validity of phase angle as a prognostic factor for survival in patients with metastatic cancer. Methods: Data of patients with metastatic cancer who visited the Korean medicine cancer center at Kyung Hee University Hospital in Gangdong from April 2016 to February 2018 were collected for this study. The values of phase angle (PhA) and blood hemoglobin (Hb), C-reactive protein (CRP), and serum albumin levels were also investigated by bioelectrical impedance analysis (BIA). Results: In total, 86 patients were analyzed. The cut-off value of the phase angle was determined as 5.0. Univariate and multivariate analysis revealed that phase angle (HR 3.15, 95% CI 1.79-5.54) and CRP (HR 2.15, 95% CI 1.24-3.73) predicted survival with statistical significance. The median overall survival of the low PhA group ($PhA{\leq}5.0$) was 1.8 months (95% CI 0.6-2.9 months) and 7.2 months (95% CI 5.2-9.2 months) in the high PhA group (PhA>5.0)(p<0.001). Conclusions: The phase angle could be an independent prognostic factor for patients with metastatic cancer. Further research is required to confirm these findings and their correlation with other indexes.

• Korean Journal of Applied Biomechanics
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• v.21 no.3
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• pp.361-368
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• 2011

The purpose of this study was to investigate the effect of isometric hip adduction and abduction on the muscle activities of vastus medialis oblique(VMO) and vastus lateralis(VL) during leg squat exercises. This study consisted of 21 healthy subjects who had no medical history of anterior knee pain or lower extremity disorders. The ball and belt were used to isometrically adduct and abduct the hip joint during the leg squat exercise, respectively. The surface electromyograms of VMO and VL were analyzed, and the findings were used to calculate the VMO:VL ratio during 3 different quadriceps-strengthening exercises(leg squat, LS leg squat with isometric hip adduction, LSHD leg squat with isometric hip abduction, LSHB). The muscle activities of VMO and VL and the VMO:VL ratios were compared using the paired t-test with Bonferroni adjustment. The results showed that the muscle activities of VMO and VL during LSHD were greater than those during LSHB. The VMO:VL ratio was the highest during LSHD. This finding suggests that LSHD using a ball is more effective than LS and LSHB in selectively increasing the muscle activities of VMO. Therefore, we suggest that leg squat exercise with isometric hip adduction using a ball would be useful for maintaining correct patella tracking and for selectively strengthening VMO.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.214-214
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• 2003

고체 고분자 전해질에 대한 연구는 1979년 wright와 Armand에 처음 시작된 이래로 지난 20여년간 연구가 계속적으로 지속되고 있다. 전지의 적용되기 위해 전해질이 갖추어야 할 조건중에 이온전도도가 상온에서 10-4 S/cm 이상의 전도도를 나타내야 하지만 지금까지 연구되고 있는 여러 고체 고분자 전해질은 이런 조건을 만족시키지 못하고 있는 실정이다. 본 연구에서는 이런 상온에서의 이온 전도성을 향상시키기 위해 여러 종류의 실리카와 세라믹 계열의 첨가제를 첨가하여 이온전도성의 향상을 꾀하고자 하였다. 본 연구에서는 고체 고분자 전해질의 host polymer로써 분자량 400,000 의 Polyethylene oxide를 사용하였으며 Lithuim salt로는 Lithium (bisperfluroethylsulfonyl)imide(3M)를 기본적으로 사용하였다. 여기에 가소제의 역활로써 (3-cyanopropyl)methylsiloxane cyclics를 첨가하였고 표면그룹이 CH3와 OH기로 이루어진 기능성 나노 실리카를(<11nm)이용하여 함량별 전기 화학적 특성 및 기본 물성을 측정하였다. 기본적으로 이 네 가지 물질을 유기용매 Acetonitril에 잘 용해하여 Solid Casting방법으로 80-100 마이크로의 복합고분자 전해질을 제조하였다. Homogeneous하고 uniform한 필름 제조하기 위해 9$0^{\circ}C$에서 열처리를 24h 동안 실시하였다. 제조되어진 복합고분자전해질은 XRD를 통하여 결정성을 조사하였고 DSC를 이용하여 유리 전이온도 및 결정화도를 조사하였다. 복합고체고분자의 전기화학적 성질을 평가하기 위해 blocking electrode를 제작하여 임피던스 스펙트로 스코피를 이용하여 이온전도성을 측정하였다. 또한 복합 고분자 전해질의 온도의존성에 대해서도 조사하였다. 또한 실제 전지의 작동구간에서의 전해질의 안정성을 확인하기 위해 LSV를 측정하였고. Li metal을 사용하여 non-blocking electrode를 제작하여 복합고분자 전해질과의 계면저항을 측정하였다.

• Archives of design research
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• v.15 no.4
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• pp.379-390
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• 2002

Science Revolution, which stands for new paradigm in an era as a transfer, usually is accompanied with a change in intellectual sphere. Futhermore, as there is an indissoluble connection between science and an, so the correlation of two realm lead to mutual prosperity in coexistence. Recently, concerns for the phenomena of non-linear dynamics in science and its quick adaptation in art made .it possible. What is important agenda for science and art is to suggest the process of creative evolution and its method, I believe. In order to attain these, different and contra way of thinking, spirit of research and venture for unpredictable things out of daily routine should be indispensible. In this study, I am offering and reviewing the space design based upon phenomena of nonlinear dynamics, drawn from concept of chaos in physics and mathematics. This study places a great emphasis on nonlinearity which should be understood as a whole, not partially, that enable a designer to find new cosmos and principles of creation. In addition to these, I wish that a designer would stop trying partial apply in nonlinear space. In fine, I hope this study enables a designer to adapt and generate nonlinearity as creative attribute in space by understanding of phenomena of nonlinear dynamics and its process as a whole.

• Geophysics and Geophysical Exploration
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• v.20 no.1
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• pp.18-24
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• 2017

We performed seismic imaging based on relative S-wave travel times to examine S-wave velocity of upper mantle structure beneath East Asia. We used teleseismic events recorded at 129 broadband stations of the Korea Institute of Geoscience and Mineral Resources (KIGAM), Korea Meteorological Administration (KMA), and National Research Institute for Earth Science and Disaster Prevention (NIED). Relative travel time residuals were obtained by a multi-channel cross-correlation method designed to automatically determine accurate relative phase arrival times. The resulting images show high-velocity anomalies along plate boundaries around the Japanese islands region. These anomalies may indicate subducting Pacific and Philippine Sea plates. On the other hand, a low-velocity anomaly is revealed beneath east of the Korean peninsula down to around 300 km depth, which is thought to be related to the formation of the Ulleung basin and the Ulleung island. Low-velocity anomalies revealed beneath the Jeju island may imply that the formation and volcanism of the Jeju island have been caused by magmatic sources from the deep mantle.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.8
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• pp.913-919
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• 2008

A new design and its experimental results of a microstrip-fed ultra-wideband tapered slot antenna(TSA) for millimeter-wave systems are presented. By utilizing the ultra-wideband microstrip-to-CPS transition(balun), ultra-wideband characteristics of the inherent TSA are retrieved. Also, the design procedure of the TSA is simplified by performing simple impedance matching between balun and antenna. The proposed TSA is shaped by using the Fermi-Dirac tapering function and corrugated at the outer edge. The implemented antenna demonstrates ultra-wideband performance for frequency ranges from 23 to over 58 GHz with the relatively high and flat antenna gain of 12 to 14 dBi and low sidelobe levels. In addition, a 4-element linear antenna array for phased-array systems and mm-wave sensor applications is also presented.