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Study on the Specular Effect in NiO spin-valve Thin Films (NiO 스핀밸브 박막의 Specular Effect에 의한 자기저항비의 향상에 대한 연구)

  • Choi, Sang-Dae;Joo, Ho-Wan;Lee, Ky-Am
    • Journal of the Korean Magnetics Society
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    • v.12 no.6
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    • pp.231-234
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    • 2002
  • Magnetic properties are investigated for top- and bottom-type spin valves of Si/SiO$_2$/NiO(60nm)/Co(2.5nm)/Cu(1.95nm)/Co(4.5nm)/NOL(t nm; Nano Oxide layer). The MR ratios of the bottom-type spin valves with NOL are larger than those of the top-type spin valves. However, the enhancement of the former is lower than the latter. Both of spin-valves also showed almost constant Ap and smaller p. Enhanced MR ratios of spin valves with NOL result mainly from small values of with constant Ap which due to specular diffusive electron scattering at NOL(NiO)/metal interfaces.

DC 반응성 스퍼터링법으로 증착한 TiN/Al, TiCN/Al 박막의 전기적.기계적 특성 및 내부식성 평가

  • Lee, Hyeon-Jun;Song, Pung-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.346-347
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    • 2012
  • 최근 화석연료 대체 에너지원으로서 자동차용으로 연구 개발 및 응용되고 있는 고분자 전해질 연료전지(PEMFC: Proton exchange membrane fuel cells)에서 분리판(Bipolar Plate)은 스택 전체 무게의 80%, 스택 가격의 60% 정도로 가장 높은 비중을 차지한다. 분리판은 연료와 산화제를 공급해주는 통로 및 전지 운전 중에 생성된 물을 제거하는 통로 역할과 anode, cathode로서 전극 역할을 통해 스택 전력을 형성하는 핵심 기능과 전지와 전지 사이의 지지대 역할을 한다. 따라서 분리판은 전기전도성, 내부식성 및 기계적 특성이 우수해야함은 물론이고, 얇고 가벼우며 가공성이 뛰어나야 한다. 현재 가장 많이 사용되고 있는 금속 분리판 소재 중 스테인리스 스틸은 전기적, 기계적 특성 및 내부식성이 우수한 반면, 가격이 비싸고, 중량이 무거운 단점이 있다. 따라서 본 연구에서는 DC 반응성 마그네트론 스퍼터링법으로 전기적, 기계적 특성 및 내부 식성이 우수한 TiN, TiCN 박막을 스테인리스에 비해 중량이 1/3, 소재 단가가 1/4인 알루미늄 기판 위에 증착하여 박막 물성을 평가하였다. DC Power는 400 W, 기판과 타겟 사이의 거리는100 mm, 공정 압력은 0.5 Pa로 고정하였고, 3 inch의 지름과 순도 99.95%를 갖는 티타늄 타겟을 사용하였다. 공정 가스는 Ar을 주입하였으며, 질소와 탄소의 공급원으로는 질소($N_2$)와 메탄($CH_4$) 가스를 사용하여 챔버 내 주입혼합가스의 전체 유량을 50 sccm으로 고정시켰다. 증착된 박막의 전기적, 기계적 특성을 측정하였고, X-ray diffraction (XRD), Scanning electron microscope (SEM)을 이용하여 박막의 미세구조 및 표면 상태를 확인하였다. 또한, 내부식 특성을 평가하기 위해 potentiostatic, potentiodynamic 법을 이용하여 박막의 부식저항을 측정하였다. 증착된 TiN 박막의 경우 질소 함량의 증가에 따라 박막 증착속도는 감소하는 경향을 보였다. 이는 타겟 부근의 질소 라디칼 비율이 증가함에 따라 질화반응이 촉진된 것으로 생각된다. 또한, 증착된 TiN과 TiCN 박막은 반응성 질소 유량과 탄소 유량에 따라 각각 다른 미세구조를 가지는 것을 확인하였다. TiN과 TiCN은 NaCl형의 면심입방격자(FCC)로 같은 구조이며, 격자상수가 비슷하여 전율고용되어 TiCN을 형성하고, 탄소와 질소의 비에 따라 전기적 기계적 특성이 달라짐을 확인하였다.

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A computer simulation of transport phenomena in a roller kiln (로울러 킬른 내의 이동현상에 관한 전산모사)

  • 이성철;김병수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.2
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    • pp.251-259
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    • 1999
  • A computer simulation was conducted for heat and momentum transfer in a roller kiln. Time-averaged Navier-Stokes equation conjugated with energy balance equation was numerically solved to predict the temperature distribution and fluid flow field in the roller kiln. A computer simulation was performed for a roller kiln for three cases. Firstly, when there are no ceramic materials in the roller kiln, the effect of natural convection was studied on the temperature distribution and fluid flow field. From the result, it was observed that air takes the heat of wall away from the roller kiln by natural convection and the heat was not transferred effectively. Secondly, with ceramic materials temperature difference of ceramic material from the borrom to the top of a ceramic material was about 255K in 5th zone and this is because the heat is transferred from the surface of a ceramic material to flowing air with relatively low temperature. Finally, we considered effect of radiation heat transfer. Temperature difference of ceramic material in 5th zone was about 300 K, due to radiation heat transfer on the ceramic material surfaces.

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Electrochemical Characteristics of Silicon/Carbon Composites for Anode Materials of Lithium Ion Batteries (리튬이온배터리 음극활물질 Silicon/Carbon 복합소재의 전기화학적 특성)

  • Park, Ji Yong;Jung, Min Zy;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.80-85
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    • 2015
  • Silicon/carbon composites as anode materials for lithium-ion batteries were examined to find the cycle performance and capacity. Silicon/carbon composites were prepared by a two-step method, including the magnesiothermic reduction of SBA-15 (Santa Barbara Amorphous material No. 15) and carbonization of phenol resin. The electrochemical behaviors of lithium ion batteries were characterized by charge/discharge, cycle, cyclic voltammetry and impedance tests. The improved electrochemical performance attributed to the fact that silicon/carbon composites suppress the volume expansion of the silicon particles and enhance the conductivity of silicon/carbon composites (30 ohm) compared to that of using the pure silicon (235 ohm). The anode electrode of silicon/carbon composites showed the high capacity approaching 1,348 mAh/g and the capacity retention ratio of 76% after 50 cycles.

Interpretation on GDS(Geomagnetic Depth Sounding) data in and around Korean peninsula using 3-D MT modeling (3차원 MT 모델링을 통한 한반도 및 주변의 GDS(Geomagnetic Depth Sounding) 자료 해석)

  • Yang, Jun-Mo;Kwon, Byung-Doo;Ryu, Yong-Gyu;Youn, Yong-Hoon
    • 한국지구과학회:학술대회논문집
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    • 2005.09a
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    • pp.124-131
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    • 2005
  • A GDS (Geomagnetic Depth Sounding) method, one of extremely low-frequency EM methods, has been carried out to examine deep geo-electrical structures of the Korean peninsula. In this study, five additive GDS sites acquired in south-eastern area of the Korea were integrated into twelve previous GDS results. In addition, 3-D MT modeling considering the surrounding seas of the Korean peninsula was performed to evaluate sea effect at each GDS site quantitatively. As a result, Observed real induction arrows was not explained by solely sea effect, two conductive structures that are able to explain differences between observed and calculated induction arrows, was suggested. The first conductive structure is the Imjingang Belt, which is thought as a extension of Quiling-Dabie-sulu continental collision belt. The effects of the Imjingang Belt clearly appear at YIN and ICHN sites. The second one is the HCL (Highly Conductive Layer), which is considered as a conductive anomaly by mantle upwelling generated in back-basin region. The effects of the HCL are also confirmed at KZU, KMT101, 107 sites, in the south-eastern of the Korean peninsula.

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Coastal Currents Driven by Irregular Waves (불규칙파에 의한 연안류)

  • Yoo, Dong Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.4
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    • pp.151-158
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    • 1990
  • Various factors may contribute on the mixing processes in the surf zone formed by irregular waves. The turbulence motion driven by wave breaking may be one of the major causes, the effect due to spatial variation on current velocity be a secondary one, and the additional process may result from the irregular superposition of radiation stresses or wave breaking dissipation incurred by random breaking waves in a broadened surf zone. In the present study a numerical model of spectral waves and induced currents was developed using a superposition technique with ${\kappa}-{\varepsilon}$ closure for mixing process and applied to a field situation of longshore current generated by spectral waves on a uniform beach. It was found from the application that the surf-zone mixing processes formed by irregular waves can be well described by using ${\kappa}-{\varepsilon}$ equations if the source of ${\kappa}$ is properly represented. The nonlinear energy transfer was also found to have some influence on the velocity profile of longshore current particularly in very shallow water region near coast.

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THERMAL DESIGN OF A PROTOMODEL SPACE INFRARED CRYOGENIC SYSTEM (적외선 우주망원경 냉각시스템 시험모델 열설계)

  • Yang Hyung-Suk;Kim Dong-Lak;Lee Byoung-Seob;Kim Geon-Hee;Lee Dae-Hee;Pak Soo-Jong;Nam Uk-Won
    • Journal of Astronomy and Space Sciences
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    • v.23 no.2
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    • pp.153-160
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    • 2006
  • A Protomodel Space Infrared Cryogenic System (PSICS) cooled by a stirling cry-ocooler has been designed. The PSICS has an IR sensor inside the cold box which is cooled by a stirling cryocooler with refrigeration capacity of 500mW at 80K in a vacuum vessel. It is important to minimize the heat load so that the background thermal noise can be reduced. In order to design the cryogenic system with low heat load and to reduce the remained heat load, we have performed numerical analyses. In this paper, we present the design factors and the results obtained by the thermal analysis of the PSICS.

A Study on the Hydration and Strength of Accelerated Curing Concrete (가열양생(加熱養生) 콘크리트의 수화(水和) 및 강도(强度)에 관한 연구(研究))

  • Shin, Hyun Mook;Jeon, Chan Ki;Nam, In
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.203-212
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    • 1987
  • The hydration and strength of concrete are affected by curing conditions, especially curing temperature. In this paper, the hydration temperature of heated curing concrete specimen are measured by thermo-couples instead of conduction calorimeter, and strengths of concrete are tested. The results of this study show that the compressive strengths of concrete are especially dependent on the curing temperature. And the strength results of concrete agree approximately with the results of approach to the hydration process of cement concrete.

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Groundwater Vulnerability of Some Cemeteries in Gyeonggi Province (경기도 일부 공원묘역의 지하수 오염가능성)

  • Lee, Jae-Hwang;Lee, Jun-Soo;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.5
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    • pp.330-341
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    • 2008
  • The purpose of this study was to investigate the vulnerability for groundwater contamination at the some cemeteries in Gyeonggi Province. Twenty-eight out of 43 cemeteries in Gyeonggi province were selected for this study. The DRASTIC model was applied to those cemeteries, and the reliance of the model was assessed using the water quality data of the target areas. The DRASTIC model was used for the assessment of the potential for groundwater contamination using hydrogeological factors. Seven factors including depth of water, net recharge, aquifer media, soil media, topography, impact of the vadose zone, hydraulic conductivity of the aquifer were assessed. The DRASTIC index of the study area ranged from 82 to 126 with an average value of $113.99(\pm11.48)$. The DRASTIC index was relatively greater in the northern Gyeonggi province than that in the southern area. The DRASTIC index was similar for the areas with the similar burial rate and burial density. This study demonstrated that burial rate and burial density should be considered along with the 7 basic factors for the evaluation of groundwater vulnerability of the cemeteries.

A Study on the Evaluating Characteristics of EM Wave Absorber for Noise Suppression from PCB (PCB상의 노이즈 제거용 전파흡수체의 특성 평가에 관한 연구)

  • Kim, Dong-Il;Choi, Dong-Soo;Yoon, Sang-Gil;Yoo, Gun-Suk
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.6
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    • pp.509-515
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    • 2009
  • In this paper, we analyzed and evaluated noise suppression characteristic of EM wave absorber. We fabricated several absorber samples in different ratios of Sendust and Amorphous with CPE(Chlorinated Ploy-ethylene) as binder and calculated material constants by measured S-parameter. Then, we confirmed that the noise suppression characteristic of EM wave absorbers using microstrip line. A microstrip line with EM wave absorber placed on its top was used to evaluate the conduction noise suppression. As a result, noise suppression effect show different charateristic by changing relative permeability. Therefore, EM wave absorber using Sendust show excellent characteristic. In particular the maximum power absorption over 90 % in 1.7 GHz to over 6 GHz has obtained when composition of Sendust:CPE=80:20wt.%.