• Journal of the Korean Vacuum Society
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• v.7 no.1
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• pp.17-23
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• 1998

$Pb(Fe_{0.5}Nb_{0.5}O_3(PFN)$ thin films were prepared by rf magnetron co-sputtering method on $SiO_2/Si$, ITO/glass, and $Pt/Ti/SiO_2/Si$ substrates and post-annealed at the $N_2$ atmosphere by RTA(rapid thermal annerling). The degree of crystallinity of PFN films was identified on various substrates. Electrical properties of PFN films was characterized for $Pt/PFN/Pt/Ti/SiO_2/Si$ structure. The composition of PFN films was estimated by EPMA (electron probe micro analysis). PFN films would be crystallized better to perovskite phase on ITO/glass substrate than $SiO_2/Si$ substrate. This may be induced by the deformation of Pb deficient pyrochlore phase due to Pb diffusion into $SiO_2/Si$ substrate. PFN films on $Pt/Ti/SiO_2/Si$ substrate. PFN films with 5-10% Pb excess were crystallized to perovskite phase from $500^{\circ}C$ temperature. In summary, we show that Pb composition and annealing temperature were critically influenced on crystallinity to perovskite phase. When PFN film with 17% Pb excess was annealed at $600^{\circ}C$ at the $N_2$ atmosphere for 300kV/cm and 88. Its remnant polarization coercive field $2.0 MC/cm^2$ and 144kV/cm, respectively.

• Polymer(Korea)
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• v.25 no.4
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• pp.575-586
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• 2001

Stabilized polyacrylonitrile (PAN) fibers can be transformed into quasi-carbon fibers with different properties depending on heat-treatment processing parameters at lower temperatures than temperature for the fabrication of carbon fibers. It has been investigated from the preliminary work that appropriate quasi-carbonization processes at about 1100$^{\circ}C$ strongly influence various properties of quasi-carbon fiber/polymer composite as well as quasi-carbon fiber itself. The objective of the present work is to prepare quasi-carbon fibers from stabilized PAN fibers using various quasi-carbonization cycles and to examine their properties. Two temperature regions, up to 800$^{\circ}C$ and above 1000$^{\circ}C$, were used for quasi-carbonization processes. The chemical composition, physical properties, thermal stability, microstructure, mechanical properties and electrical resistivity of the quasi-carbon fibers prepared with different final heat-treatment temperatures, heating rates, holding times, heating steps, and purging gas purity were extensively examined. The results were also compared with those from stabilized PAN fiber and commercial PAN-based carbon fiber. The present study showed that a variety of properties of quasi-carbon fibers significantly depended on several quasi-carbonization process parameters.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.2
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• pp.45-50
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• 2022

Ga₂O₃ thin films were grown on n-type Si substrates at various growth temperatures of 500, 550, 600, 650 and 700℃. The Ga₂O₃ thin films grown at 500℃ and 550℃ were characterized as featureless flat surface. Grown at higher temperatures (600, 650, and 700℃) showed very rough surface morphology. To figure out the annealing effect on the thin films grown at relatively low temperatures (500, 550, 600, 650 and 700℃), the Ga₂O₃ films were thermally treated at 900℃ for 10 minutes. Crystal structure of the Ga₂O₃ films grown at 500 and 550℃ were changed from amorphous to polycrystalline structure with flat surface. Ga₂O₃ film grown at 550℃ was chosen for the fabrication of a Schottky barrier diode (SBD). Electrical properties of the SBDs depend on the thermal treatment were evaluated. A MSM type photodetector was made on the low temperature grown Ga₂O₃ thin film. The photocurrent for the illumination of 266 nm wavelength showed 5.32 times higher than dark current at the operating voltage of 10 V.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2205-2213
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• 2000

To investigate removal efficiency of dissolved matter by NF and RO, a pilot plant was operated for six months using groundwater treated by UF membrane. After the pilot plant operation, we performed autopsy test to identify characteristics of foulant attached on the membrane surface applying the used NF and RO in the pilot plant test. In autopsy test, we measured permeate flux and recovery rate of flux by chemical cleaning in each membrane. We also analyzed chemical cleaning disposal to examine component of foulant. Permeate flux of NF and RO1 showed rapid decline after 100 days of operation. Especially, reduction of specific flux in RO1 was more serious than in NF. Specific flux of RO2 with a low recovery rate resulted in gradual flux decline. Removal efficiencies of dissolved inorganic matters as a conductivity were 76.3%, 88.2% and 95.3% respectively for NF, RO1 and RO2, and RO2 presented the highest removal efficiency. And those of dissolved organic matters as TOC were about 80% for both NF and RO. The specific flux of membranes declined gradually from the feed water inlet to outlet of the membrane module and it showed that membrane fouling increased along the feed flow direction. Namely, concentration of pollutants became higher and volume of feed water was less as the feed flow approached to the outlet. It seemed that major foul ants were Ca consolidated into inorganic material and Si consolidated into organic material on the membrane surface. Fe was a great contribution to irreversible fouling. The SEM results indicated that the organic matter was attached to the first layer, closer to the membrane, and then inorganic matter with tetragonal shape layered over them. We could not observe biofouling because microorganism, which was cause of biofouling, was almost pretreated in UF membrane.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.495-501
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• 2016

Mineral oil has been widely used as an insulating oil for electrical transformers for a long time, but the necessity of employing new insulation oil such as vegetable oil has been increased due to urgent needs for the biodegradability when it leaks and also for the thermal stability at a higher operation temperature. Although specific periods are required between the production and consumption, there are still short of the data to prove the insulation oils' storage stability depending upon various circumstances and their resources. Thus, this paper demonstrates the insulation oils' oxidation characteristics of both mineral and vegetable oils when each was exposed to different environments for 12 weeks. From this test, some properties including total acid number, water content and dielectric breakdown were changed under specific conditions and resources. Vegetable oils showed higher hydrophilicity and water saturation than those of mineral oils due to their molecular compositions. Under sunlight exposure condition, all insulation oils oxidized and changed their properties when exposing to the direct light, regardless of the resource used.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.40 no.7
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• pp.486-493
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• 2003

Schottky type A $l_{0.33}$G $a_{0.67}$N ultraviolet photodetectors were fabricated on the MOCVD grown AlGaN/ $n^{＋}$-GaN and AlGaN/AlGaN interlayer/ $n^{＋}$-GaN structures. The grown layers have the carrier concentrations of -$10^{18}$, and the mobilities were 236 and 269 $\textrm{cm}^2$/V.s, respectively. After mesa etching by ICP etching system, the Si3N4 layer was deposited for passivation between the contacts and Ti/AL/Ni/Au and Pt were deposited for ohmic and Schottky contact, respectively. The fabricated Pt/A $l_{0.33}$G $a_{0.67}$N Schottky diode revealed a leakage current of 1 nA for samples with interlayer and 0.1$\mu\textrm{A}$ for samples without interlayer at a reverse bias of -5 V. In optical measurement, the Pt/A $l_{0.33}$G $a_{0.67}$N diode with interlayer showed a cut-off wavelength of 300 nm, a prominent responsivity of 0.15 A/W at 280 nm and a UV-visible extinction ratio of 1.5x$10^4./TEX>.

• Korean Journal of Ecology and Environment
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• v.56 no.3
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• pp.229-241
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• 2023

Microphysogobio rapidus is designated as endangered species class I by Ministry of Environment, and its distribution and population have been gradually declining, and it is now limited to the Nam River and some tributary streams of the Nakdong River Watershed. For the restoration of this highly endangered species, it is important to identify the causes of the decline and establish appropriate restoration plans. However, due to lack of basic data and ecological research, most steps are stagnant. Therefore, in this study, we identified the differences in the physical, biological, and sociological habitats between current and past distributed sites through field surveys and literature reviews. As a result of the field survey, there were differences in conductivity between the current and past distributed sites, and fish communities were also showed differences. The literature data also showed that the physico-chemical values of the past distributed sites were generally unfavorable, which generated negative consequences on biological factors. In particular, the effects of urbanization were found to be a major factor affecting the habitat of M. rapidus. Habitat stabilization is crucial for the recovery of this endangered species. However, in the past distributed sites, disturbances such as stream development and weir construction have altered streams physico-chemically and result in changes of M. rapidus. Therefore, a comprehensive plan that considers both stream connectivity and water quality is needed to manage and restore the habitat of M. rapidus.

• The Journal of Engineering Geology
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• v.14 no.1
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• pp.1-20
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• 2004

This study focuses on the hydrochemical characteristics in goundwater affected by reclamation at 2000 Sydney Olympic Games site, Sydney, Australia. The Olympic Games site can be divided into three areas, i.e. reclaimed areas; landfill areas and non-infilled areas. In the current work, 'reclaimed areas' were previously estuarine, and were filled with waste materials and are now above present high tide level, whereas 'landfill areas' are areas where deposition of waste materials occurred above sea level. No deposition of waste took place in 'non-infilled areas'. This study was also evaluated by three different types such as deep boreholes, shallow boreholes and standpipes. The hydrochemishy of groundwaters in reclaimed and non-in-filled areas is characterized by Mg- and Ca-enrichment, whereas groundwaters in landfill areas are elevated in K and NO₃. Na, K and Mg are the dominant cations in groundwater from reclaimed areas and Na and K are the dominant cations in groundwater in landfill areas. Na and Mg are the dominant cations in groundwater in deep boreholes, whereas Na and K are the dominant cations in groundwater in shallow boreholes and standpipes. There is no distinct trend in heavy metals with electrical conductivity in the groundwater between the re-claimed, landfill and non-infilled areas. Fe and Mn in landfill areas with respect to reclaimed areas and non-infilled areas show a distinct increase in concentration with declining pH. Mean electrical conductivity values in the deep and shallow boreholes are higher than that of standpipes, but the minimum and maximum value of electrical conductivity in groundwater in standpipes shows remarkably different value, probably due to perched pond. There is no correlation between Cu, Pb, Zn, Cr concentrations in groundwater with pH, from deep boreholes, shallow boreholes and standpipes, except for Fe and Mn, which demonstrate increasing concentrations with declining pH. The results revealed a close association between elevated concentrations in groundwater and the presence of fill materials at the site. Trace metals teachability from re-claimed soils adjacent to estuary plays a significant role in determining their potential environmental risk to surrounding environment.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.116-120
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• 2010

$CO_2$ is regarded as one of the greenhouse gases(GHG), which is the main reason of climate change. In order to achieve lower $CO_2$ emissions, several efforts have been conducted worldwide. $CO_2$ capture & storage(CCS) technology development is needed for a coal-fired combustion power plant because of huge $CO_2$emission. Oxy fuel combustion, one of the CCS technologies has been considered as a primary concern, nowadays. Oxy-fuel combustion needs flue gas recirculation(FGR) for stable operation and enrichment of $CO_2$ concentration in the flue gas. FGR adoption for oxy-fuel combustion requires development of effective desulfurization and dust removal technology. In this study, desulfurization characteristics of lime and dust removal technology have been researched in the laboratory scale coal combustor.

• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.47-53
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• 2009

In this study, highly ordered AAO (Anodic Aluminum Oxide) with nanopores was prepared by commercial grade Al substrate containing 3.5 wt.% impurities through two step anodizing method. Nanopores of prepared AAO arrays were used as templates for preparing nanofiber. $TiO_2$ was deposited by using DP (deposition-precipitation) method into AAO pores to grow nanofiber. Au particles were loaded on this $TiO_2$ nanofiber which was grown vertically. Prepared 2 wt.% $Au/TiO_2$ nanofiber was characterized by XRD, SEM and Raman. The crystal structure was analyzed by the XRD. SEM was used to observe pore size and pore wall thickness. Photocatalytic activity of co-oxidation was compared with $TiO_2$ and $Au/TiO_2$ nanofiber on AAO arrays.