• Title/Summary/Keyword: 전기화학 센서

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Electrochemical Rectification at Electrode Chemically Modified with Redox Active Agents at Monolayer (산화환원 화학 종이 단 분자 층으로 화학 흡착된 전극에서의 전기화학적 정류)

  • Lee, Chi-Woo J.;Yoon, Jung-Hyun;Oh, Mi-Kyung
    • Journal of the Korean Electrochemical Society
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    • v.10 no.1
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    • pp.43-47
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    • 2007
  • Electrochemical rectification at electrode chemically modified with redox active agents isolated at monolayer level was considered. Formulation of the rising part of linear sweep voltammogram at steady and rotating disc electrode was introduced.

Surface Plasmon Resonance (바이오센서로서 표면 플라즈몬 공명)

  • 구수진
    • BT NEWS
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    • v.11 no.2
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    • pp.24-34
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    • 2004
  • 센서란 측정 대상물로부터 정보를 검지 또는 측정하여 그 측정량을 인식 가능한 유용한 신호로 변화하는 장치(device)로 정의할 수 있으며, 바이오센서(biosensor)는 생물학적 요소와분석 대상 물질과의 반응에서 나타나는 전기화학적 변화, 열에너지의 변화, 형광 또는 색의 변화 등을 인식 가능한 신호로 변환시켜 주는 장치와 결합하여 제작한 기구를 지칭한다. 바이오센서의 효시는 1962년 포도당을 측정하기 위해 Clark이 dialysis membrane을 이용하여 최초의 Glucose센서를 개발한 이래로 생물공학, 화학공학, 전자공학, 생명공학 및 컴퓨터 공학 등 여러 분야가 접목되면서 급속도로 연구 개발되어 왔다.(중략)

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Flexible Micro Sensor

  • 신규호;황은수;김용호;임창현;김용준
    • Electrical & Electronic Materials
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    • v.17 no.8
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    • pp.25-32
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    • 2004
  • 센서는 인간의 오감에 해당하는 감지기로서 온도, 소리, 빛 등의 물리, 화학적 신호를 전기적 신호로 변환시켜주는 일련의 장치를 말한다. 물론 센서에 대한 정의 및 분류 방법은 다양하게 표현될 수 있으나 본 논문에서는 MEMS(Micro Electro-Mechanical System) 기술을 적용하여 Smart화 혹은 Wireless화에 필요한 Micro 센서로 그 범위를 한정하고자 한다. 만일 센서를 아주 작게(Micro Sensor) 만들 수 있고 그것들끼리 무선으로 연결될 수(Wireless Network) 있다면 우리의 삶의 형태는 지금과는 매우 다른 모습으로 전개 될 것이다. 그림 1은 2004년에 정보통신부가 발표한 Ubiquitous Sensor Network의 개념도이다.(중략)

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Synthesis of Segmented Conjugated Polymer based Optical Sensing Material with Metal Cation Recognition Property (금속 양이온인식 특성을 갖는 세그먼트화 공액계 고분자센서소재의 합성)

  • 나종호;박원호;이택승
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.305-308
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    • 2002
  • 선택적인 이온센서의 개발은 환경적, 생리학적, 의학적 중요성에 의해 높은 관심을 받고 있다. 지금까지 전기 화학적인 검출, 형광검출, 그리고 다른 광학적인 방법들에 근거한 매우 다양한 이온센서들이 연구되어 왔다. 금속이온들의 선택적인 결합은 음이온들이나 중성물질 보다 상당히 쉽게 결합하기 때문에, 금속이온 인식을 위한 형광 화학센서들의 개발이 일찍부터 이루어졌다. (중략)

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Electrochemical Growth of Palladium Nanowire for Highly Sensitive Hydrogen Sensor (고감도 수소센서를 위한 팔라듐 나노선의 전기화학적인 성장)

  • Jo, S.Y.;Kang, B.R.;Im, Y.H.
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.21-24
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    • 2010
  • We present a novel electrochemical method to fabricate a single Pd nanowire based on direct current assisted dielectropheresis (DEP) process between two predefined metal electrodes. The electrochemical methods was investigated as functions of frequency and voltage for optimal growth conditions of Pd nanowire. The synthesized Pd nanowire have a good resistance of $1\;k{\Omega}$, diameters of several hundred nanometers on average and lengths of $8\;{\mu}m$. Finally, the single Pd nanowire was capable of detecting hydrogen in the concentration range from 100 to 2500 ppm with high sensitivity and response time, thus demonstrating its suitability for use as a hydrogen sensor.

Thrombin Detection with Tetrabromophenolphthalein Ethyl Ester Adsorbed on Aptamer-attached Conductive Polymer (전기전도성 고분자 위에 고정된 압타머에 흡착된 테트라브롬페놀프탈레인 에틸 에스테르를 이용한 트롬빈 검출)

  • Chung, Saeromi;Noh, Hui-Bog;Shim, Yoon-Bo
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.134-140
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    • 2016
  • An aptamer-based biosensor using a new redox indicator has been examined for the electrochemical detection of thrombin. The aptamer modified primary aliphatic amine was covalently immobilized onto poly-(5,2':5',2"-terthiophene-3'-carboxylic acid) (polyTTCA) layer. Tetrabromophenolphthalein ethyl ester (KTBPE) was interacted to aptamer and used as an electrochemical indicator. Prior to the detection, the oxidation reaction of KTBPE onto aptamer modified layer was also investigated using differential pulse voltammetry. The characterization of the final sensor (KTBPE/aptamer -polyTTCA) was performed by voltammetry, QCM, and ESCA. After binding of thrombin onto KTBPE/aptamer based sensor, the peak signal of KTBPE was gradually decreased. The sensor exhibited a dynamic range between 10.0 and 100.0 nM with the detection limit of $1.0{\pm}0.2nM$.

Evaluation of Pretreatment Effect and Non-enzymatic Glucose Sensing Performance of Carbon Fibers Tow Electrode (탄소섬유 토우의 전처리 효과와 비효소적 포도당 센싱 성능 평가)

  • Min-Jung Song
    • Korean Chemical Engineering Research
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    • v.62 no.1
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    • pp.13-18
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    • 2024
  • To develop flexible electrode materials for wearable devices, we investigated the electrochemical characteristics of carbon fibers tow according to pretreatment. And an electrochemical non-enzymatic sensor was fabricated using glucose as a target. The carbon fibers tow was pretreated through desizing and activation processes, and activation was performed in two ways: chemical oxidation and electrochemical oxidation. Surface morphology of carbon fibers tow samples was observed by SEM and their electrochemical characteristics and sensing performance were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. Carbon fibers tow samples showed improved electrochemical properties such as reduced Ret, ΔEp, and increased Ip through pretreatment. And similar electrochemical properties were obtained with both activation methods. We selected electrochemically activated carbon fibers tow as the final electrode material for application of electrochemical sensor. The non-enzymatic glucose sensor based on this electrode has an enhanced sensitivity of 0.744 A/mM (in a linear range of 0.09899~3.75423 mM) and 0.330 mA/mM (3.75423~50 mM), respectively. Through this study, the possibility of using carbon fibers tow was confirmed as an electrode material. It is expected to be used as basic research for development of high-performance flexible electrode materials.

Improvement in Sensitivity of Electrochemical Glucose Biosensor Based on CuO/Au@MWCNTs Nanocomposites (CuO/Au@MWCNTs 나노복합재 기반 전기화학적 포도당 바이오센서의 민감도 개선)

  • Park, Mi-Seon;Bae, Tae-Sung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.145-152
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    • 2016
  • In this study, CuO was introduced on MWCNTs dispersed with Au nanoparticles to improve the glucose sensing capability of electrochemical biosensors. Nano-cluster shaped CuO was synthesized due to the presence of Au nanoparticle, which affects glucose sensing performance. The biosensor featuring CuO/Au@MWCNTs nanocomposite as an electrode material when 0.1 mole of CuO was synthesized showed the highest sensitivity of $504.1{\mu}A\;mM^{-1}cm^{-2}$, which is 4 times better than that of MWCNTs based biosensors. In addition, it shows a wider linear range from 0 to 10 mM and lower limit of detection (LOD) of 0.008 mM. These results demonstrate that CuO/Au@MWCNTs nanocomposite sensors are superior to other CuO based biosensors which are attributed that the nano-cluster shaped CuO is favorable for the electrochemical reaction with glucose molecules.