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Characterization of Ni-YSZ cermet anode for SOFC prepared by glycine nitrate process (Glycine nitrate process에 의한 제조된 SOFC anode용 Ni-YSZ cermet의 물성)

  • Lee, Tae-Suk;Ko, Jung-Hoon;Lee, Kang-Sik;Kim, Bok-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.1
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    • pp.21-26
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    • 2011
  • Ni-YSZ (Yttria Stabilized Zirconia) composite powders were fabricated by glycine nitrate process. The prepared powders were sintered at $1300{\sim}1400^{\circ}C$ for 4 h in air and reduced at $1000^{\circ}C$ for 2 h in a nitrogen and hydrogen atmosphere. The microstructure, electrical conductivity, thermal expansion and mechanical properties of the Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. It was found that the open porosity, electrical conductivity, thermal expansion and bending strength of the cermets are sensitive to the volume content of Ni. The Ni-YSZ cermet containing 40 vol% Ni was ascertained to be the optimum composition. This composition offers sufficient open porosity of more than 30 %, superior electrical conductivities of 917.4 S/cm at $1000^{\circ}C$ and a moderate average thermal expansion coefficient of $12.6{\times}10^{-6}^{\circ}C^{-1}$ between room temperature and $1000^{\circ}C$.

Effect of Low Temperature-Darkness Treatment on Floral Initiation and Flowering Response of Korean Strawberry Cultivars (저온암흑처리가 국내 육성 신품종 딸기의 화아분화에 미치는 영향)

  • Jun, Ha Joon;Liu, Shi Sheng;Jeon, Eui Hwan;Bae, Geun Hye;Kang, Su In
    • Horticultural Science & Technology
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    • v.31 no.6
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    • pp.726-731
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    • 2013
  • Experiments were conducted to evaluate the effect of low temperature-darkness treatment on floral initiation in four kinds of Korean strawberry cultivars. Mother plants were planted on March 29 and daughter plants were raised for the experiment. Temperature treatment was done for 7, 14, and 21 days keeping $13^{\circ}C$ in cooling storage from August 29, September 5 and September 14 to September 21. After the treatment, flower bud initiation was examined by a microscope, and the seedlings were transplanted on hydroponic system with Yamazaki's strawberry solution of EC $0.8dS{\cdot}m^{-1}$ to check the flowering. 'Ssanta' and 'Maehyang' showed early flower bud initiation in 7 days treatment than 'Seolhyang' by microscope check. 'Ssanta', 'Daewang', and 'Maehyang' showed early flower bud initiation in 14 days treatment than 'Seolhyang'. There were no differences among the treatments in 21 days treatment. Percentage of flowering of 'Seolhyang' and 'Maehyang' by low temperature-darkness treatment didn't show any difference but 'Daewang' and 'Ssanta' showed high percentage of flowering. It suggested that low temperature-darkness treatment technique can be use for improving early flowering and yield of 'Ssanta' and 'Daewang' cultivars.

Determination of Biogenic Amines using an Amperometric Biosensor with a Carbon Nanotube Electrode and Enzyme Reactor (Carbon Nanotube 전극과 효소반응기로 구성된 Amperometric Biosensor를 이용한 Biogenic Amines 검출)

  • Kim, Jong-Won;Jeon, Yeon-Hee;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.5
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    • pp.735-742
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    • 2010
  • Biogenic amines are synthesized by microbial decarboxylation for the putrefaction or fermentation of foods containing protein. Although biogenic amines such as histamine, tyramine, and putrescine are required for many physiological functions in humans and animals, consumption of high amounts of biogenic amines can cause toxicological effects, including serious gastrointestinal, cutaneous, hemodynamic, and neurological symptoms. In this study, a novel amperometric biosensor wasdeveloped to detect biogenic amines. The biosensor consisted of a working electrode, a reference electrode, a counter electrode, an enzyme reactor with immobilized diamine oxidase, an injector, a peristaltic pump and a potentiostat. A working electrode was fabricated with a glassy carbon electrode (GCE) by coating functionalized multi-walled carbon nanotubes (MWCNT-$NH_2$) and by electrodepositing Prussian blue (PB) to enhance electrical conductivity. A sensor system with PB/MWCNT-$NH_2$/GCE showed linearity in the range of $0.5 {\mu}M{\sim}100 {\mu}M$ hydrogen peroxide with a detection limit of $0.5 {\mu}M$. The responses for tyramine, 2-phenylethylamine, and tryptamine were 95%, 75%, and 70% compared to that of histamine, respectively. These results imply that the biosensor system can be applied to the quantitative measurement of biogenic amines.

Resistive E-band Textile Strain Sensor Signal Processing and Analysis Using Programming Noise Filtering Methods (프로그래밍 노이즈 필터링 방법에 의한 저항 방식 E-밴드 텍스타일 스트레인 센서 신호해석)

  • Kim, Seung-Jeon;Kim, Sang-Un;Kim, Joo-yong
    • Science of Emotion and Sensibility
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    • v.25 no.1
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    • pp.67-78
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    • 2022
  • Interest in bio-signal monitoring of wearable devices is increasing significantly as the next generation needs to develop new devices to dominate the global market of the information and communication technology industry. Accordingly, this research developed a resistive textile strain sensor through a wetting process in a single-wall carbon nanotube dispersion solution using an E-Band with low hysteresis. To measure the resistance signal in the E-Band to which electrical conductivity is applied, a universal material tester, an Arduino, and LCR meters that are microcontroller units were used to measure the resistance change according to the tensile change. To effectively handle various noises generated due to the characteristics of the fabric textile strain sensor, the filter performance of the sensor was evaluated using the moving average filter, Savitsky-Golay filter, and intermediate filters of signal processing. As a result, the reliability of the filtering result of the moving average filter was at least 89.82% with a maximum of 97.87%, and moving average filtering was suitable as the noise filtering method of the textile strain sensor.

Comparision of Combined Stress Tests for Predicting Field Emergence of Lotus corniculatus and Trifolium pratense (Birdsfoot Trefoil과 Red Clover의 포장출현율 예측을 위한 몇가지 Stress 검정법 비교)

  • Kim, Seok-Hyeon;Choe, Zhin-Ryong;Chung, Min-Hong;Han, Kyeong-Ho
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.37 no.2
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    • pp.171-177
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    • 1992
  • The purpose of this study was to compare the test methods for predicting field emergence of Lotus corniculatus and Trifolium pratense. Four seed lots of two herbage legumes were controlled deteriorated, accelerated aged before germination test and conductivity of each seed lot was determined. Those germination percent and conductivity of seed lots were compared with actual field emergence rate. Field emergence rate could be estimated by the controlled deterioration test ($R^2$=0.687), by the accelerated aging test ($R^2$=0.260), and by the conductivity test ($R^2$=0.238). A multiple regression equation for predicting field emergence rate(equation omitted) was estimated as (equation omitted)=-198.16 + 2.3493X$_1$-1.5564X$_2$ + 1.9812X$_3$where X$_1$, percent germination of controlled deterioration test ; X$_2$, percent germination of accelerated aging test; and X$_3$, conductivity of solute leakage in the conductivity test. Conclusively, unless multiple tests are not available, the controlled deterioration test was comparatively high efficient for predicting field emergence rate, however, the combined measurements of those three tests can enhance the efficiency.

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Availability of Slurry Composting and Biofiltration for Cultivation of Cherry Tomato (방울 토마토 재배 시 퇴비단 여과 액비의 이용가능성)

  • Kim, Eun-Young;Park, Bong-Ju;Oh, Myung-Min
    • Journal of Bio-Environment Control
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    • v.22 no.4
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    • pp.385-391
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    • 2013
  • In this study, the availability of slurry composting and biofiltration (SCB) solution as an alternative for synthetic nutrient solution was determined by monitoring the growth, fruit yield, and fruit quality of cherry tomato (Solanum lycopersicum L. 'Unicon'). Treatments for nutrient solution were consist of SCB 1/2N, 1N, 2N, and commercial nutrient solution 1N (CNS 1N) based on nitrogen concentration (218.32 $mg{\cdot}L^{-1}$) of cherry tomato nutrient solution (control 1N). All nutrient solution including SCB solution (440~520 mL per day) was supplied to rock wool medium using a timer. After 31 days of transplanting, fresh and dry weights of shoots, leaf area, plant height, stem diameter, SPAD value and number of node were measured. After measuring growth characteristics of tomato plants, total fruit yield, ratio of marketable fruit yield, fruit weight, total soluble solids content, total acidity, total phenolic concentration, and antioxidant capacity were determined once a week for 7 weeks. As a result, among the SCB treatments, SCB 1/2N was similar to control 1N and CNS 1N in terms of fresh and dry weights of shoots, leaf area, stem diameter, number of node, and SPAD value. Increased N concentration of SCB inhibited the growth of tomato plants. Total fruit yield of SCB 1/2N was 47% of that of control 1N which showed the best result. Percentage of marketable fruit yield in SCB 1/2N was about 58%. Soluble solids contents, total acidity, total phenolic concentration and antioxidant capacity was the highest in SCB 2N and the other treatments were not shown any difference. Blossom-end rot rarely occurred in control 1N and CNS 1N while SCB treatments without Ca induced the physiological disorder of 7~19%. In conclusion, SCB 1/2N was good for the vegetative growth of cherry tomato plants but reduced yield and quality of fruit compared with control 1N and CNS 1N. Thus, it is possible to apply SCB solution to grow cherry tomato plants hydroponically but in the consideration of fruits yield and quality additional supply of several minerals would be required.

A Comparative Study on the Electrophysiological Properties of Medial and Lateral Spinoreticular Tract Cells in Cats (고양이의 내측 및 외측 척수망상로 세포의 전기생리학적 비교연구)

  • Lee, Suk-Ho;Jun, Jae-Yeol;Park, Choon-Ok;Goo, Yong-Sook;Kim, Jun;Sung, Ho-Kyung
    • The Korean Journal of Physiology
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    • v.24 no.1
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    • pp.181-194
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    • 1990
  • Antidromically activated spinoreticular tract (SRT) cell units in the lumbosacral enlargement of ${\alpha}-chloralose$ anesthetized cats were classified as medial and lateral SRT units according to the location of their axonal termination. Identified SRT units were tested fer antidromic conduction velocity, laterality of their axonal projection, the location in spinal gray, peripheral receptive field, the response pattern to graded mechanichal stimulation and the responsiveness to $A{\delta}$ and C volley of the peripheral nerve. 1) The 59% of 34 medial SRT units were recorded in ipsilateral side to the antidromic stimulation site, but 60% of the 47 lateral SRT units projected to contralateral side. 2) Most of the medial SRT cells and rostral ventrolateral medulla (RVLM)-projecting lateral SRT cells were recorded in lamina VII & VIII. The LRN (lateral reticular nucleus)-projecting SRT cells, however, distributed through all the laminae except superficial ones (I & II). 3) The identified SRT units were classified as low theshold (LT), deep, high threshold (HT), wide dynamic range (WDR) cells, based on the response patterns to graded mechanical stimuli. The proportion of SRT units which receive noxious input was 37.5%, 25% and 75% in the medial, LRN-projecting and RVLM SRT group, respectively. 4) There was no significant difference in the mean conduction velocities between the 3 groups. But the deep cells had significantly higher velocity than that of the HT cells. The above results show that the peripheral inputs to the SRT units are different in the 3 groups: medial, LRN & RVLM SRT group. Especially in case of the SRT cells projecting to RVLM which is a probable candidate fur the integration center of various pressor reflexes such as somatosympathetic reflex, the noxious informations occupy higher proportion of input to them than in other groups. Therefore the noxious information transmitted through the lateral SRT destined for RVLM is expected to play a role in somatosymapthetic reflex.

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Environmental Studies in the Lower Part of the Han River Vl. The Statistical Analysis of Eutrophication Factors (한강 하류의 환경학적 연구 Vl. 부영양 요인의 통계적 해석)

  • Jung, Seung-Won;Hue, Hoi-Kwon;Lee, Jin-Hwan
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.78-86
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    • 2004
  • In order to reveal the relationship between the concentration of chlorophyll- a and the environmental factors affecting eutrophication, the present study was biweekly conducted at G stations in the lower part of the Han river during the period from Feb. 24,2001 to Feb. 9,2002. Water temperature was changed from $0.5^{\circ}C$ to $26.4^{\circ}C$, pH was 5.77${\sim}$8.99, DO 3.15${\sim}$14,36 mg $L^{-1}$, BOD 0.90${\sim}$7.45 mg $L^{-1}$, and COD 1.16${\sim}$9.13 mg $L^{-1}$. TN and TP were ranged from 1.68${\sim}$20.96 mg $L^{-1}$, and 0.02 ${\sim}$ 1.17 mg $L^{-1}$, respectively. $NH_4\;^+$-N, $NO_3\;^-$-N, and $PO_4\;^{3-}$-P were ranged from 0.56${\sim}$3.60 mg $L^{-1}$, 0.03${\sim}$7.29 mg $L^{-1}$, and 0.002${\sim}$0.754 mg $L^{-1}$. Chlorophyll- a was extensively changed from 2.29 ${\mu}g\;L^{-1}$ to 136.28 ${\mu}g\;L^{-1}$ by month and stations. Results of nutrients indicated the eutrophic level in this area and water quality was the gradual worsening in the lower stations than those of upper stations during the period studied. The Pearson correlation analysis between the concentration of chlorophyll- a and the environmental factors indicated that BOD, COD, pH, $NH_4\;^+$-N, TP, TN, conductivity and $PO_4\;^{3-}$-P were positive correlation, but $NO_3\;^-$-N was negative. The environmental factors investigated using the principal component method could be triparted. The first factor group included conductivity, BOD, COD, TN, TP, $NH_4\;^+$-N, $PO_4\;^{3-}$-P and SS, the second WT and DO, and the third pH and $NO_3\;^-$-N. Using the stepwise regression analysis, chlorophyll- a was under the influence of conductivity, $PO_4\;^{3-}$-P, $>NO_3\;^-$-N and $NH_4\;^+$-N Chlorophyll-a = 0.3661 ${\times}$ (Conductivity) - 0.3592 ${\times}$ ($PO_4\;^{3-}$-P) - 0.3449 ${\times}$ ($NO_3\;^-$-N)+0.4362 ${\times}$ ($NH_4\;^+$-N.

Chungkook-jang Koji Fermentation with Rice Straw (볏짚을 이용(利用)한 청국장 제조(製造)에 관(關)한 연구(硏究))

  • Kim, Kyung-Ja;Ryu, Myung-Ki;Kim, Sang-Soon
    • Korean Journal of Food Science and Technology
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    • v.14 no.4
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    • pp.301-308
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    • 1982
  • Chungkook-jang Koji was fermented with rice straw at $40^{\circ}C\;and\;50^{\circ}C$ for 72 hours. The changes of proximate composition, pH, titrable acidity, nitrogen compounds, protease activity and free-amino acids during the fermentation were investigated. Moisture, lipid and protein contents remained essentially unchanged during the fermentation. The pH was gradually increased from 6.4 to 7.46 and 7.82 at $40^{\circ}C\;and\;50^{\circ}C$, respectively, after 72 hour fermentation. Amino type and water soluble nitrogen increased as fermentation progressed. however, the former slightly decreased after 60 hour fermentation. Chungkook-jang fermented at $40^{\circ}C$ showed somewhat higher protease activity than $50^{\circ}C$. However, protease activity at both fermentation temperatures showed the same trend; that is, it increased until 48 hour fermentation and thereafter decrease. Free amino acid content of Chung-kook-jang after 72 hour fermentation at $40^{\circ}C$ was 6 times greater than that of the steamed soybean, while it was 2.5 times greater at $50^{\circ}C$. Based on these results. it seems that the optimum fermentation conditions for Chungkook-jang were $40^{\circ}C$ and 72 hours.

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Available Phosphours Phosphorus and Electrical Conductivity of the Saturated Extracts of Soils from the Plastic Film Houses (포화침출액법에 의한 시설하우스 토양의 유효인산과 전기전도도)

  • Jung, Yeong-Sang;Cho, Su-Hyun;Yang, Jae E.;Kim, Jeong-Je;Um, Hyung-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.1
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    • pp.1-7
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    • 2000
  • Management of phosphorus availability in the plastic film house soils in Korea merits attention because salts have been accumulated for last decades due to the heavy application of fertilizers and intensive cropping practices. In an attempt to characterize the P availability, available phosphorus contents and electrical conductivity of the saturated extracts ($EC_e$) were measured for soils collected from the 169 plastic film houses in Kangwon-do. Soil phosphorus contents were analyzed by methods of Lancaster, Bray No. 1, Olsen, Truog, water extractable and saturation extracts. Phosphorus concentrations in the saturated extracts of the plastic film house soils ranged from 0.02 to $34mg\;L^{-1}$, with the average of $8mg\;L^{-1}$. The available $P_2O_5$ of the soils ranged from 136 to $3,689mg\;Kg^{-1}$, with the average of $1,261mg\;Kg^{-1}$. The water soluble $P_2O_5$ ranged from 2 to $118mg\;L^{-1}$, with the average of $39mg\;L^{-1}$. A significant correlation existed between saturation extract P (Y) and available $P_2O_5$ (X) [Y = -5.075 + 0.018X, $r=0.662^{***}$] indicating $1.0mg\;P\;L^{-1}$ of in the saturated extract was equivalent to $337mg\;Kg^{-1}$ of the available $P_2O_5$ by Lancaster method. Electrical conductivity of the saturated pastes ($EC_e$) was highly significantly correlated with EC (1:5), yielding the slope of 12.2 for the coarse textured plastic film house soils. Results of higher concentrations of available P in soil solution and dilution factor of 12.2 for $EC_e$ demonstrate that a special care must be taken in terms of fertilizer management and data interpretation for soils under this specific condition.

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