• Title/Summary/Keyword: 전기적 비선형성

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Electrochemical Characteristics of Li3V2(PO4)3 Negative Electrode as a Function of Crystallinity (결정화도에 따른 Li3V2(PO4)3 음극의 전기화학적 특성)

  • Ku, Jun-Whan;Park, Kyung-Jin;Ryu, Ji-Heon;Oh, Seung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.15 no.1
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    • pp.27-34
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    • 2012
  • $Li_3V_2(PO_4)_3$/carbon composite materials are synthesized from a sucrose-containing precursor. Amorphous $Li_3V_2(PO_4)_3/C$ (a-LVP/C) and crystalline $Li_3V_2(PO_4)_3/C$ (c-LVP/C) are obtained by calcining at $600^{\circ}C$ and $800^{\circ}C$, respectrively, and electrochemical performance as the negative electrode for lithium secondary batteries is compared for two samples. The a-LVP electrode shows much larger reversible capacity than c-LVP, which is ascribed to the spatial $Li^+$ channels and flexible structure of amorphous material. In addition, this electrode shows an excellent rate capability, which can be accounted for by the facilitated $Li^+$ diffusion through the defect sites. The sloping voltage profile is another advantageous feature for easy SOC (state of charge) estimation.

Determination of Biogenic Amines using an Amperometric Biosensor with a Carbon Nanotube Electrode and Enzyme Reactor (Carbon Nanotube 전극과 효소반응기로 구성된 Amperometric Biosensor를 이용한 Biogenic Amines 검출)

  • Kim, Jong-Won;Jeon, Yeon-Hee;Kim, Mee-Ra
    • Journal of the East Asian Society of Dietary Life
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    • v.20 no.5
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    • pp.735-742
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    • 2010
  • Biogenic amines are synthesized by microbial decarboxylation for the putrefaction or fermentation of foods containing protein. Although biogenic amines such as histamine, tyramine, and putrescine are required for many physiological functions in humans and animals, consumption of high amounts of biogenic amines can cause toxicological effects, including serious gastrointestinal, cutaneous, hemodynamic, and neurological symptoms. In this study, a novel amperometric biosensor wasdeveloped to detect biogenic amines. The biosensor consisted of a working electrode, a reference electrode, a counter electrode, an enzyme reactor with immobilized diamine oxidase, an injector, a peristaltic pump and a potentiostat. A working electrode was fabricated with a glassy carbon electrode (GCE) by coating functionalized multi-walled carbon nanotubes (MWCNT-$NH_2$) and by electrodepositing Prussian blue (PB) to enhance electrical conductivity. A sensor system with PB/MWCNT-$NH_2$/GCE showed linearity in the range of $0.5 {\mu}M{\sim}100 {\mu}M$ hydrogen peroxide with a detection limit of $0.5 {\mu}M$. The responses for tyramine, 2-phenylethylamine, and tryptamine were 95%, 75%, and 70% compared to that of histamine, respectively. These results imply that the biosensor system can be applied to the quantitative measurement of biogenic amines.

Electromagnetic Traveltime Tomography with Wavefield Transformation (파동장 변환을 이용한 전자탐사 주시 토모그래피)

  • Lee, Tae-Jong;Suh, Jung-Hee;Shin, Chang-Soo
    • Geophysics and Geophysical Exploration
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    • v.2 no.1
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    • pp.17-25
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    • 1999
  • A traveltime tomography has been carried out by transforming electromagnetic data in frequency domain to wave-like domain. The transform uniquely relates a field satisfying a diffusion equation to an integral of the corresponding wavefield. But direct transform of frequency domain magnetic fields to wave-field domain is ill-posed problem because the kernel of the integral transform is highly damped. In this study, instead of solving such an unstable problem, it is assumed that wave-fields in transformed domain can be approximated by sum of ray series. And for further simplicity, reflection and refraction energy compared to that of direct wave is weak enough to be neglected. Then first arrival can be approximated by calculating the traveltime of direct wave only. But these assumptions are valid when the conductivity contrast between background medium and the target anomalous body is low enough. So this approach can only be applied to the models with low conductivity contrast. To verify the algorithm, traveltime calculated by this approach was compared to that of direct transform method and exact traveltime, calculated analytically, for homogeneous whole space. The error in first arrival picked by this study was less than that of direct transformation method, especially when the number of frequency samples is less than 10, or when the data are noisy. Layered earth model with varying conductivity contrasts and inclined dyke model have been successfully imaged by applying nonlinear traveltime tomography in 30 iterations within three CPU minutes on a IBM Pentium Pro 200 MHz.

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Quantitative evaluation of collapse hazard levels of tunnel faces by interlinked consideration of face mapping, design and construction data: focused on adaptive weights (막장관찰 및 설계/시공자료가 연계 고려된 터널막장 붕괴 위험도의 정량적 산정: 가변형 가중치 중심으로)

  • Shin, Hyu-Soung;Lee, Seung-Soo;Kim, Kwang-Yeom;Bae, Gyu-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.15 no.5
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    • pp.505-522
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    • 2013
  • Previously, a new concept of indexing methodology has been proposed for quantitative assessment of tunnel collapse hazard level at each tunnel face with respect to the given geological data, design condition and the corresponding construction activity (Shin et al, 2009a). In this paper, 'linear' model, in which weights of influence factors are invariable, and 'non-linear' model, in which weights of influence factors are variable, are taken into account with some examples. Then, the 'non-linear' model is validated by using 100 tunnel collapse cases. It appears that 'non-linear' model allows us to have adapted weight values of influence factors to characteristics of given tunnel site. In order to make a better understanding and help for an effective use of the system, a series of operating processes of the system are built up. Then, by following the processes, the system is applied to a real-life tunnel project in very weak and varying ground conditions. Through this approach, it would be quite apparent that the tunnel collapse hazard indices are determined by well interlinked consideration of face mapping data as well as design/construction data. The calculated indices seem to be in good agreement with available electric resistivity distribution and design/construction status. In addition, This approach could enhance effective usage of face mapping data and lead timely and well corresponding field reactions to situation of weak tunnel faces.

A Study on Distance Relay of Transmission UPFC Using Artificial Neural Network (신경회로망을 이용한 UPFC가 연계된 송전선로의 거리계전기에 관한 연구)

  • Lee, Jun-Kyong;Park, Jeong-Ho;Lee, Seung-Hyuk;Kim, Jin-O
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.6
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    • pp.37-44
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    • 2004
  • This paper represents a new approach for the protective relay of power transmission lines using a Artificial Neural Network(ANN). A different fault m transmission lines need to be detected classified and located accurately and cleared as fast as possible. However, The protection range of the distance relay is always designed on the basis of fixed settings, and unfortunately these approach do not have the ability to adapt dynamically to the system operating condition. ANN is suitable for the adaptive relaying and the detection of complex faults. The backpropagation algerian based multi-layer protection is utilized for the teaming process. It allows to make control to various protection functions. As expected, the simulation result demonstrate that this approach is useful and satisfactory.

Numerical Analysis and Experimental Investigation of Duct Flows of an MHD Propulsion System (사각형의 MHD 추진 덕트 내부유동에 관한 수치해석 및 실험적 연구)

  • J.W. Lee;S.J. Lee;C.M. Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.32 no.1
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    • pp.83-93
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    • 1995
  • A numerical and experimental investigation on the flow characteristics in the rectangular duct of an MHD propulsion system has been carried out. In numerical analysis, three-dimensional, steady-state, viscous, incompressible electrically conducting fluid flow under the influence of uniformly applied magnetic and electric fields was treated using a finite-difference technique. It was found from the numerical study that when the Lorentz force is weak, the typical parabolic velocity profile under a laminar flow condition changes to an M shaped profile near the electrode region and that the pressure increases linearly from the inlet toward the outlet of the MHD duct under constant electro-magnetic field. In experiment, thrust of the MHD propulsion system can be controlled easily by varying electrode current. The measured pressure gradient along the MHD duct is proportional to the Lorentz force, which is in agreement with the numerical results.

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Improvement of Color Reproduction Using Gamma and CCT Correction on Small LCD Display for Mobile Phone (휴대폰용 소형 LCD 디스플레이에서 감마 및 상관 색온도 보정을 이용한 색재현 성능 향상)

  • Han Chan-Ho;Sohng Kyu-Ik;Kwon Seong-Geun
    • Journal of Korea Multimedia Society
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    • v.9 no.4
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    • pp.451-459
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    • 2006
  • Color reproduction of small LCD display is quite different from that of standard CRT due to the difference of physical, electrical, and optical characteristics. In this paper, we propose a simple and practical method using gamma and CCT correction for improvement of color reproduction on a small LCD display. First, we investigate characteristics of a small LCD display such as brightness, uniformity, color temperature, white and black balance, and nonlinear gamma. And, we also analyze color reproduction region and CCT trajectory according to LCD's input levels. Finally, the optimum gamma and CCT compensation method using LUT is proposed, and our proposed method was realized at mobile phone without hardware modification. In the experimental results, the result image of proposed algorithm is more close to standard color.

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A Study on the Audio Compensation System (음향 보상 시스템에 관한 연구)

  • Jeoung, Byung-Chul;Won, Chung-Sang
    • The Journal of the Acoustical Society of Korea
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    • v.32 no.6
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    • pp.509-517
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    • 2013
  • In this paper, we researched a method that makes a good acoustic-speech system using a digital signal processing technique with dynamic microphone as a transducer. Good acoustic-speech system should deliver the original sound input to electric signal without distortion. By measuring the frequency response of the microphone, adjustment factors are obtained by comparing measured data and standard frequency response of microphone for each frequency band. The final sound levels are obtained using the developed adjustment factors of frequency responses from the microphone and speaker to match the original sound levels using the digital signal processing technique. Then, we minimize the changes in the frequency response and level due to the variation of the distance from source to microphone, where the frequency responses were measured according to the distance changes.

Extraction of Cole-Cole Parameters from Time-domain Induced Polarization Data (시간영역 유도분극 자료로부터 Cole-Cole 변수 산출)

  • Kim, Yeon-Jung;Cho, In-Ky
    • Geophysics and Geophysical Exploration
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    • v.24 no.4
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    • pp.164-170
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    • 2021
  • Frequency-domain and time-domain induced polarization methods can provide spectral information about subsurface media. Analysis of spectral characteristics has been studied mainly in the frequency-domain, however, time-domain induced polarization research has recently become popular. In this study, assuming a homogeneous half-space model, an inversion method was developed to extract Cole-Cole parameters from the measured secondary potential or electrical resistivity. Since the Cole-Cole parameters of chargeability, time constant, and frequency index are not independent of each other, various problems, such as slow convergence rate, initial model problem, local minimum problem, and divergence, frequently occur when conventional nonlinear inversion is applied. In this study, we developed an effective inversion method using the initial model close to the true model by introducing a grid search method. Finally, the validity of the developed inversion method was verified using inversion experiments.

Corrosion Resistance of Blended Concrete and Its Application to Crack Healing (혼합 콘크리트의 부식 저항성과 균열 치유 적용)

  • Lee, Chang-Hong;Kim, Tae-Sang;Song, Ha-Won
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.689-696
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    • 2009
  • In this study, electro-deposition method was applied to heal cracks in various blended concrete. The performance of the method was indirectly monitored by measuring impressed voltage, electrolyte, galvanic current monitoring, linear polarization resistance, and directly by image analysis of the cracks. The indirect and direct monitoring values are compared to develop guidelines for relating the indirect measures to actual crack healing. As a result, It was found that impressed voltage was convergence to 2.9V after 20000 minutes. From the galvanic current test results of artificial crack healing, the corrosion resistance showed that the order of 0.4 $>$ 0.6 $>$ 0.5 water to cement ratio. Furthermore, in view of binder, the corrosion resistance order was calculated OPC $>$ 60%GGBS $>$ 10%SF $>$ 30%PFA. Finally, It was found that 76.47% of healed crack surface calculated from the artificial crack healing technique using electrochemical deposition method.