• Journal of the Korean Electrochemical Society
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• v.14 no.4
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• pp.208-213
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• 2011

Solid polymer electrolytes using $BF_3LiMA$ as monomer were synthesized by usual one step radical polymerization in THF solvent. The effect of $BF_3LiMA$ concentration on ionic conductivity and electrochemical stability was investigated by AC impedance measurement and linear sweep voltammetry. As a result, the highest ionic conductivity reached $7.71{\times}10^{-6}S\;cm^{-1}$ at $25^{\circ}C$ was obtained in 12.9 wt% of $BF_3LiMA$ content. Further increase or decrease of $BF_3LiMA$ content result to decrease the ionic conductivity due to the brittle matrix properties in former case and the insufficient number of charge carrier in the latter case. Furthermore, since the counter-anion was immobilized in the self-doped solid polymer electrolytes, high electrochemical stability up to 6.0 V was observed even in $60^{\circ}C$.

• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.121-126
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• 2000

The effect of electroless Ni and Cu plating on $LaNi_5$, $AB_5$ type hydrogen storage alloy was investigated by the various electrochemical techniques such as constant current charge-discharge test, cyclic voltammeoy, and a.c. impedance spectroscopy. Scanning electron microscopy and X-ray diffraction test were conducted for phenomenological logical analyses. Cyclic Voltammetry results show that activation characteristics, cycle life and reaction ,rate were improved through electroless Ni and Cu plating. Compared with bare $LaNi_5$ the charge transfer resistance of electrode was greatly reduced as charge-discharge cycle increases. Therefore, electroless Ni and Cu plating on $LaNi_5$ alloy tends to accelerate the early activation, increasing the cyclic lift of electrode.

• Journal of the Korean Electrochemical Society
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• v.14 no.2
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• pp.77-82
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• 2011

The surface of $Li[Ni_{0.35}Co_{0.3}Mn_{0.35}]O_2$ cathode was modified by $[Li,La]TiO_3$ coating using pH controlled coating solution. At low pH values (acidic solution), cathode powders, which is oxides, have a positive surface charge, whereas, they have a negative surface charge at high pH values. As a result, their charge could affect the formation of the coating layer on the surface of cathode powder. To determine the optimal pH value, the surface coating of the pristine powder was carried out at various pH values of the coating solution. The surface morphology of coated samples was characterization by SEM and TEM analyses. Impedance analysis and cyclic voltammogram presented that internal resistance of the cell was dependent upon the pH of coating solution.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.626-626
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• 2013

P-N 접합에 의해 절연된 게이트를 통해 전류 통로를 제어하는 접합형 전계효과 트랜지스터(Junction Field Effect Transistors; JFETs)는, 입력 임피던스가 크고, 온도에 덜 민감하며, 제조가 간편하여 집적회로(IC) 제조가 용이하고, 동작의 해석이 단순하다는 장점을 가지고 있다. 특히 JFET는 선형적인 전류의 증폭 특성을 가지고 있으며, 잡음이작기 때문에, 감도가 우수한 음향 센서의 증폭회로, 선형성이 우수한 증폭회로, 입력 계측 증폭 회로 등에 주로 사용되고 있다. 기존에 사용되는 JFET 소자는 구조와 제조 공정에 따라서, 컷 오프 전압($V_{cut-off}$)과 드레인-소스 포화 전류($I_{DSS}$)의 변화가 심하게 발생하여, 소자의 전기적 특성 제어가 어렵고, 소자의 수율이 낮다는 문제점이 있다. 본 연구에서는 TCAD 시뮬레이션을 통해 게이트 전압에 의해 채널이 형성되는 채널 층의 상하부에 각각 $Si_xGe_{1-x}$로 이루어진 상부 및 하부 확산 저지층을 삽입한 JFET 소자 형성하여, 게이트 접합부의 접합 영역 확산을 저지하고, 상기 게이트 접합부가 계면에서 날카로운 농도 구배를 갖도록 함으로써, 공정 변화에 따른 전기적 특성의 편차가 작아지는 JFET 소자 구조를 만들어 전기적 특성을 개선하였다. JFET은 채널층에 삽입된 $Si_xGe_{1-x}$ 층의 두께, Ge 함유량 및 n채널층의 두께를 변화하였을 때, off 상태의 게이트-소스 전압이 감소한 반면에 드레인-소스 포화 전류($I_{DSS}$)와 컨덕턴스(gm) 값이 증가하였다. 삽입된 $Si_xGe_{1-x}$층이 Boron이 밖으로 확산되는 현상이 감소하여 채널이 좁아지는 현상을 막아 소자의 전기적 특성을 개선함으로써 제조공정의 변화에 관계없이 컷오프 전압을 정확하고 안정되게 제어할 수 있고 이를 통해 소자의 수율을 높일 수 있을 것으로 기대된다.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.386.2-386.2
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• 2014

본 연구에서는 바이오 센서 응용을 위해 그래핀을 전극으로 제작하여 그래핀 표면 결함준위에 따른 센서의 민감도를 전기화학 실험을 통해 관찰하였다. 그래핀은 니켈/구리촉매를 이용한 저 진공 화학 기상 증착 장비(Low-Pressure Chemical Vapor Deposition; LP-CVD)와 Photo-lithography로 제작한 것과 탄소 산화물을 환원시켜 만든 환원-그래핀, 두 가지를 사용하였다. 전기화학 실험에서 그래핀 전극 및 Silver/Silver chloride (Ag/AgCl), Fluorine doped Tin Oxide (FTO)은 작업 전극 및 기준 전극, 상대 전극으로 각각 사용하였고, 반응용액은 potassium hexacyanoferrate (III)를 농도를 다르게 하여 사용하였다. 그래핀의 표면 상태, 층수, 결함 정도 등 구조적인 특성은 원자력현미경(Atomic Force Microscopy; AFM), 주사 전자 현미경(Secondary Electron Microscopy; SEM)과 Raman spectroscopy를 각각 이용하여 확인하였고, 그래핀의 결함준위에 따른 반응면적 및 센서 감도 의존성을 전류모드-원자력현미경(Current-Atomic Force Microscopy; I-AFM)과 전기화학 임피던스 분광법(Electrochemical Impedance Spectroscopy; EIS)를 통해 그래핀 전극의 성능을 분석하고, 그래핀 결함 준위에 따른 센서 감도 의존성은 순환전위 분광법 (Cyclic Voltammetry; CV)를 이용하여 관찰하였다. 또한 농도가 다른 반응용액은 센서의 민감도를 관찰하는데 사용하였다. 결과적으로 LP-CVD로 성장한 그래핀과 환원-그래핀의 결함준위에 따른 센서의 성능을 비교 분석한 결과와 반응용액 농도에 따른 센서의 민감도 결과는 그래핀 바이오센서에 대한 응용 및 상용화를 앞당기는데 기여할 것으로 예상한다.

• Journal of the Korean Electrochemical Society
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• v.23 no.3
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• pp.73-80
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• 2020

Fenton oxidation method using hydrogen peroxide is an eco-friendly oxidation method used in water treatment and soil restoration. When removing pollutants by this method, it is quite important to properly regulate the concentration of hydrogen peroxide according to the concentration of the contaminants. In this study, electrochemical biosensors using HRP (horseradish peroxidase) enzymes were manufactured and studies were conducted on the activity of enzymes and the detection characteristics of hydrogen peroxide. HRP were electro deposited with chitosan and AuNP on the working electrode surface of the SPCE (Screen Printed Carbon Electrode). Then, the fixation of enzymes was confirmed using the cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The activity of HRP enzymes was also identified from chronoamperometry (CA) and UV spectroscopy. After immersing the biosensor in PBS solution the current generated from electrodes by titrating hydrogen peroxide was measured from CA analysis. The generated current increased linearly for the concentration of hydrogen peroxide, and a calibration curve was derived that could predict the concentration of hydrogen peroxide from the current.

• Membrane Journal
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• v.15 no.4
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• pp.349-354
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• 2005

YSZ (yttria-stabilized zirconia) determined with an electrolyte that analyzed thermal stability along sintering condition and an electric characteristic. As sintering temperature increases by SEM, grain grows and it showed that pore decreases relatively. and confirmed effect by grain size. It evaluated that particle internal resistance and electric performance by resistance in an electrolyte and electricity conductivity measurement through ac impedance measurement in temperature of $800\~1000^{\circ}C$ in 2-probe method In order to recognize an electric characteristic. In dry process and wet process, density was each 6.13, 6.25 $g/cm^3$ and the relative density was each 98, 99$\%$ when sintering condition is $1400^{\circ}C$.

• Journal of the Korean Electrochemical Society
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• v.8 no.2
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• pp.99-105
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• 2005

In this study, the $PPy/CLO_4$ and PPy/PVS composite electrodes were prepared at various polymerization potential by incorporating electrolyte anions of different anion size during constant potential polymerization. The reulting Polypyrrole surfaces were inspected by SEM, and their electrochemical Properties were investigated with CV and ac impedance method. The results of electrochemical analysis were suggested that anion for $PPy/CLO_4$ electrode and cation fir PPy/PVS electrode were transferred during redox reaction. As constant potential of polymerization was increased, the charge transfer resistance of $PPy/CLO_4$ and PPy/PVS was decreased and the electric double layer capacitances of $PPy/CLO_4$ was higher than that of PPy/PVS. The change of PPy/PVS surface was relatively smaller than that of $PPy/CLO_4$ according to electropolymerization potential.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.159-164
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• 2021

As the attachable-type wearable devices have received considerable interests, the need for the development of high-performance electrode materials of fabric or textiles type is emerging. In this study, we demonstrated the electrochemical property of CNT fibers electrode as a flexible electrode material and its non-enzymatic glucose sensing performance. Surface morphology of CNT fibers was observed by SEM. And the electrochemical characteristics were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The CNT fibers based sensor exhibited improved sensing performances such as high sensitivity, a wide linear range, and low detection limit due to improved electrochemical properties such as low capacitive current, good electrochemical activity by efficient direct electron transfer between the redox species and the electrode interface. Therefore, this study is expected to be used as a basic research for the development of high performance flexible electrode materials based on CNT fibers.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.18 no.8
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• pp.866-872
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• 2007

In this paper, we present a frequency tunable and compact antenna which consists of a first-order Peano curve, two shorting posts, and two inductors which are serially connected between the posts and the edge of the Peano curve. By properly choosing the inductance of two inductors, the operating frequency of the antenna can be controlled without sacrificing the fractional bandwidth. To give good demonstration of the operating mechanism, the equivalent circuit of this antenna is included. To validate the simulation results, we have fabricated the several antennas of being integrated with different inductors, and the measured results show a good agreement with the simulated ones. The measured results reveal that the operating frequency is shifted from 1.47 GHz to 0.586 GHz without the decrease of the input impedance bandwidth. In case of integrating two inductors of 91nH and 470nH, the electric size of the antenna is only $0.0246 {\lambda}{\times}0.0246{\lambda}{\times}0.0114{\lambda}$. The measured fractional bandwidth$(S_{11}{\leq}-10 dB)$ and the radiation efficiency of the antenna are 5.22% and 47.25%, respectively.