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Enhancement of Electrochemical Performance of Cathode by Optimizing Laccase-Carbon Nanotubes Layers for Enzymatic Fuel Cells (Laccase-탄소나노튜브 적층을 통한 효소 연료전지의 cathode 성능 향상)

  • Wang, Xue;Kim, Chang-Joon
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.550-556
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    • 2022
  • The performance of enzymatic fuel cells that convert chemical energy contained in various organic molecules such as sugar, alcohol, organic acids, and amino acids into electrical energy is greatly affected by the cathode as well as the anode. This study aimed to develop a laccase-based cathode with high performance. An enzyme composite composed of an laccase, redox mediator, and carbon nanotubes was immobilized on the surface of electrode in multiple layers, and the effect of the number of layers and the presence or absence of carbon nanotubes on electrode performance was investigated. As the number of layers of the enzyme-mediator (Lac-(PVI-Os-dCl)) on the electrode surface increased, the amount of reduction current generated at the electrode increased. The enzyme-carbon nanotube-mediator composite electrode (Lac-SWCNTs-(PVI-Os-dCl)) generated a current 1.7 times greater than that of the Lac-(PVI-Os-dCl). It was found that the largest amount of current (10.1±0.1 µA) was generated in the electrode composed of two layers of Lac-(PVI-Os-dCl) and two layers of Lac-SWCNTs-(PVI-Os-dCl) in the evaluation of electrodes with different ratio of Lac-SWCNTs-(PVI-Os-dCl) and Lac-(PVI-Os-dCl). The maximum power density of the cell using the cathode composed of a single layer of Lac-(PVI-Os-dCl) and the cell using the optimized cathode were 0.46±0.05 and 1.23±0.04 µW/cm2, respectively. In this study, it was demonstrated that the performance of cathode and the enzymatic fuel cell using the same can be improved by optimizing the layers of composites composed of laccase, redox mediator, and carbon nanotubes on the electrode surface.

Morphological Development of Egg and Larvae of Hemiculter leucisculus (치리(Hemiculter leucisculus)의 난 발생 및 자치어 형태 발달)

  • Kim, Kyeong-Mu;Kim, Seung-Yong;Song, Mi-Young;Song, Ha-Yun
    • Korean Journal of Ichthyology
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    • v.32 no.4
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    • pp.222-231
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    • 2020
  • The egg development and early life history of Sharpbelly Hemiculter leucisculus were investigated. For the experiments, the mature adults were collected at the Lake Yedang in Korea. The eggs from the females were obtained by injecting 10 IU/g of human chorionic gonadotropin and inseminated by wet method in the laboratory. The fertilized eggs were 0.97±0.02 mm (0.9~1.0 mm n=30) in diameter. The embryo began to hatch about 32 hrs after fertilization under water temperature of 22±1℃. The newly-hatched larvae were 3.0±0.2 mm (2.6~3.4 mm, n=15) in total length, and they haven't Melanophore. Six days after hatching, the Preflexion larva were 5.7±0.1 mm (5.4~5.8 mm, n=15) in total length, and they began to eat a Rotifer. 17 days after hatching, the Flexion larva were 6.8±0.2 mm (6.5~7.0 mm, n=15) in total length, and a gas bladder develop above the intestine. 30 days after hatching, the Postflexion larva were 8.8±0.7 mm (7.9~10.3 mm, n=15) in total length, three dorsal fin rays began to develop in the membrane fins. 50 days after hatching, the Juvenile were 20.8±0.8 mm (18.8~24.6 mm, n=15) in total length, and all their fin-rays were formed.

Morphological Development of Eggs, Larvae and Juveniles of Siberian Stone Loach, Barbatula nuda (Pisces: Nemacheilidae) in the Sangcheoncheon Stream, a Tributary of Bukhangang River, Korea (북한강 지류 상천천에 서식하는 대륙종개 Barbatula nuda (Pisces: Nemacheilidae)의 난발생 및 자치어 형태 발달)

  • Kwak, Yeong-Ho;Song, Mi-Young;Song, Ha-Yoon
    • Korean Journal of Ichthyology
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    • v.34 no.1
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    • pp.25-33
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    • 2022
  • We investigated to elucidate the early life history of siberian stone loach, Barbatula nuda (Pisces: Nemacheilidae). Adult fish were collected using net in the Sangcheoncheon Stream, Cheongpyeong-myeon, Gapyeong-gun, Gyeonggi-do, Korea, 26th April 2020. HCG 10 IU/g was injected to female and male fish and fertilized by dry method in the laboratory. The number of eggs of B. nuda was 1,308±293 (TL: 70.64~79.24 mm), and the egg color was yellowish grey. Fertilized eggs measured 1.13±0.01 mm (n=10) in diameter and showed adhesion. The fertilized eggs started hatching after 104 hours. At the time of egg development, the 15℃ group showed an average hatching rate of 80.1±1.2% and the 20℃ group showed 61.5±6.8%, so the 15℃ group was suitable (p<0.05). Newly hatched larva an average were 3.12±0.06 mm (n=10) in total length. At 4 days after hatching, the total length was 4.89±0.09 mm (n=10), and feeding began with the mouth and anus opened, and entered to preflexion larvae stage. At 21 days after hatching, the total length was 10.98±0.40 mm (n=10), and the distal part of the notochord was bent to 45°, and entered to postflexion larvae stage At 26 days after hatching, the total length was 13.47±0.37 mm (n=10), and entered the juvenile stage.

Revision of related Regulations and Construction Standards for the Use of Information on Underground Facilities Quality Level (지하시설물 품질등급 정보의 활용을 위한 관련 규정 및 건설기준 개정 방안)

  • Park, Joon Kyu;Kim, Tae Hoon;Kim, Won Dae
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.40 no.4
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    • pp.343-350
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    • 2022
  • The computerization project for underground facilities in Korea began in earnest after the city gas explosion in Seoul in 1994, and the Daegu subway explosion in 1995. As such a large-scale gas explosion accident caused enormous economic loss including human casualties and potential benefits, the need for computerized for efficient management of underground facilities was greatly emphasized in society. Meantime, computerization of underground facilities has been carried out according to the basic plan for building national geographic information system. In this study, problems were identified based on the current status of construction and management of underground facility information, as well as laws and regulations, and directions for establishing quality standards were presented. In addition, construction work standards such as 「Public Survey Work Regulations」, design standards, standard specifications, and technical specifications, gas technology standards, design standards, and communication works so that underground facility information can be linked and utilized in construction work by examining the linkage of the underground facilities, the targets that can be used for quality level information on underground facilities were derived, and a proposal to revise the construction standards was presented. In the future, if the quality standards are established, it is expected that the accuracy and utilization in the construction field will be increased.

Development of Data Analysis and Interpretation Methods for a Hybrid-type Unmanned Aircraft Electromagnetic System (하이브리드형 무인 항공 전자탐사시스템 자료의 분석 및 해석기술 개발)

  • Kim, Young Su;Kang, Hyeonwoo;Bang, Minkyu;Seol, Soon Jee;Kim, Bona
    • Geophysics and Geophysical Exploration
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    • v.25 no.1
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    • pp.26-37
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    • 2022
  • Recently, multiple methods using small aircraft for geophysical exploration have been suggested as a result of the development of information and communication technology. In this study, we introduce the hybrid unmanned aircraft electromagnetic system of the Korea Institute of Geosciences and Mineral resources, which is under development. Additionally, data processing and interpretation methods are suggested via the analysis of datasets obtained using the system under development to verify the system. Because the system uses a three-component receiver hanging from a drone, the effects of rotation on the obtained data are significant and were therefore corrected using a rotation matrix. During the survey, the heights of the source and the receiver and their offsets vary in real time and the measured data are contaminated with noise. The noise makes it difficult to interpret the data using the conventional method. Therefore, we developed a recurrent neural network (RNN) model to enable rapid predictions of the apparent resistivity using magnetic field data. Field data noise is included in the training datasets of the RNN model to improve its performance on noise-contaminated field data. Compared with the results of the electrical resistivity survey, the trained RNN model predicted similar apparent resistivities for the test field dataset.

ECG Compression and Transmission based on Template Matching (템플릿 매칭 기반의 심전도 압축 전송)

  • Lee, Sang-jin;Kim, Sang-kon;Kim, Tae-kon
    • Journal of Internet Computing and Services
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    • v.23 no.1
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    • pp.31-38
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    • 2022
  • An electrocardiogram(ECG) is a recoding of electrical signals of the heart's cyclic activity and an important body information for diagnosing myocardial rhythm. Large amount of information are generated continuously and a significant period of cumulative signal is required for the purpose of diagnosing a specific disease. Therefore, research on compression including clinically acceptable lossy technique has been developed to reduce the amount of information significantly. Recently, wearable smart heart monitoring devices that can transmit electrocardiogram(ECG) are being developed. The use of electrocardiogram, an important personal information for healthcare service, is rapidly increasing. However, devices generally have limited capability and power consumption for user convenience, and it is often difficult to apply the existing compression method directly. It is essential to develop techniques that can process and transmit a large volume of signals in limited resources. A method for compressing and transmitting the ECG signals efficiently by using the cumulative average (template) of the unit waveform is proposed in the paper. The ECG is coded lovelessly using template matching. It is analyzed that the proposed method is superior to the existing compression methods at high compression ratio, and its complexity is not relatively high. And it is also possible to apply compression methods to template matching values.

Compressional and Shear Wave Properties of Cement Grout Including Carbon Fiber (탄소섬유를 포함한 시멘트 그라우트의 압축파 및 전단파 특성)

  • Choi, Hyojun;Cho, Wanjei;Yune, Chanyoung
    • Journal of the Korean GEO-environmental Society
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    • v.22 no.12
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    • pp.15-24
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    • 2021
  • In Korea, which is mostly mountainous, the proportion of tunnel and underground space development are increasing. Although the ground is reinforced by applying the ground improvement method during underground space development, accidents still occur frequently in Korea. In the grouting method, a representative ground reinforcement method, the effect was judged by comparing the total amount of injection material with the amount of injection material used during the actual grouting construction. However, it is difficult to determine whether the ground reinforcement is properly performed during construction or within the target ground. In order to solve this problem, it is necessary to study a new method for quality control during or after construction by measuring electrical resistivity after performing grouting by mixing carbon fiber, which is a conductive material, and microcement, which is a grout material. In this study, as a basic study, a cement specimen mix ed with 0%, 3%, 5%, 7% of carbon fiber was prepared to evaluate the performance of the grout material mixed with carbon fiber, which is a conductive material. The prepared specimens were wet curing for 3 days, 7 days, and 28 days under 99% humidity, and then compression wave velocity and shear wave velocity were measured. As a result of the compression wave velocity and shear wave velocity measurement, it showed a tendency to increase with the increase in the compounding ratio of carbon fibers and the number of days of age, and it was confirmed that the elastic modulus and shear modulus, which are the stiffness of the material, also increased.

Effect of Body Weight in Growing Period on Laying Performance of Korean Native Chicken Breeders (토종 종계 육성기 체중이 산란 능력에 미치는 영향)

  • See Hwan Sohn;Kigon Kim;Eun Sik Choi;Sang-Hyon Oh
    • Korean Journal of Poultry Science
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    • v.50 no.1
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    • pp.15-22
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    • 2023
  • This study was to investigate the relationship between chick weight in the growing period and the laying performance of Korean native chicken (KNC) breeders. We measured the body weights of 1,384 KNC breeders at 1-140 days of age at two-week intervals. The age at first egg laying, hen-day and hen-housed egg production, and the egg weights were investigated. Correlation coefficients between the body weight and egg production traits were analyzed. The results showed that the correlation coefficients between body weight and age at first egg laying were significantly positive before 4 weeks, but negative after 8 weeks of age. The correlation coefficients between body weight and egg production rate were estimated to be negative before 8 weeks and positive after 12 weeks of age. Coefficients of hen-day and hen-housed egg production were similar. There was little correlation between body weight and egg weight at 32 weeks of age, whereas a low positive correlation was with egg weight at 50 weeks. In conclusion, there was little correlation between body weight and laying performance before 8 weeks of age, whereas a significant positive correlation was with body weight after 12 weeks. The results suggest that as the chick's weight increases in the late growing stage, sexual maturity is faster, the egg production rate is higher, and the egg weight increases. Therefore, the weight management of KNC female breeders is very important in the late growing stage, and the body weight of chicks must be maintained above the standard weight.

Analysis of Crushing/Classification Process for Recovery of Black Mass from Li-ion Battery and Mathematical Modeling of Mixed Materials (폐배터리 블랙 매스(black mass) 회수를 위한 파쇄/분급 공정 분석 및 2종 혼합물의 수학적 분쇄 모델링)

  • Kwanho Kim;Hoon Lee
    • Resources Recycling
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    • v.31 no.6
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    • pp.81-91
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    • 2022
  • The use of lithium-ion batteries increases significantly with the rapid spread of electronic devices and electric vehicle and thereby an increase in the amount of waste batteries is expected in the near future. Therefore, studies are continuously being conducted to recover various resources of cathode active material (Ni, Co, Mn, Li) from waste battery. In order to recover the cathode active material, black mass is generally recovered from waste battery. The general process of recovering black mass is a waste battery collection - discharge - dismantling - crushing - classification process. This study focus on the crushing/classification process among the processes. Specifically, the particle size distribution of various samples at each crushing/classification step were evaluated, and the particle shape of each particle fraction was analyzed with a microscope and SEM (Scanning Electron Microscopy)-EDS(Energy Dispersive Spectrometer). As a result, among the black mass particle, fine particle less than 74 ㎛ was the mixture of cathode and anode active material which are properly liberated from the current metals. However, coarse particle larger than 100 ㎛ was present in a form in which the current metal and active material were combined. In addition, this study developed a PBM(Population Balance Model) system that can simulate two-species mixture sample with two different crushing properties. Using developed model, the breakage parameters of two species was derived and predictive performance of breakage distribution was verified.

XQuery Query Rewriting for Query Optimization in Distributed Environments (분산 환경에 질의 최적화를 위한 XQuery 질의 재작성)

  • Park, Jong-Hyun;Kang, Ji-Hoon
    • Journal of the Korea Society of Computer and Information
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    • v.14 no.3
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    • pp.1-11
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    • 2009
  • XQuery query proposed by W3C is one of the standard query languages for XML data and is widely accepted by many applications. Therefore the studies for efficient Processing of XQuery query have become a topic of critical importance recently and the optimization of XQuery query is one of new issues in these studies. However, previous researches just focus on the optimization techniques for a specific XML data management system and these optimization techniques can not be used under the any XML data management systems. Also, some previous researches use predefined XML data structure information such as XML schema or DTD for the optimization. In the real situation, however applications do not all refer to the structure information for XML data. Therefore, this paper analyzes only a XQuery query and optimize by using itself of the XQuery query. In this paper, we propose 3 kinds of optimization method that considers the characteristic of XQuery query. First method removes the redundant expressions described in XQuery query second method replaces the processing order of operation and clause in XQuery query and third method rewrites the XQuery query based on FOR clause. In case of third method, we consider FOR clause because generally FOR clause generates a loop in XQuery query and the loop often rises to execution frequency of redundant operation. Through a performance evaluation, we show that the processing time for rewritten queries is less than for original queries. also each method in our XQuery query optimizer can be used separately because the each method is independent.